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    • 46. 发明授权
    • Immobilized Lewis Acid catalysts
    • 固定化路易斯酸催化剂
    • US5600055A
    • 1997-02-04
    • US436508
    • 1995-05-08
    • Tze-Chiang ChungFrank J.-Y. ChenJon E. StanatAlok Kumar
    • Tze-Chiang ChungFrank J.-Y. ChenJon E. StanatAlok Kumar
    • C08F4/02C08F4/00C08F4/06C08F4/14C08F8/00C08F10/00C07C2/62
    • C08F10/00
    • Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula: ##STR1## wherein a represents about 1 to about 99 mole %b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR2## C is selected from the group consisting of: ##STR3## (III) combinations thereof. D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM";E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkyl group, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
    • 固定化路易斯酸催化剂,其包含具有固定在其结构内的至少一种路易斯酸的聚合物,所述聚合物具有由结构式表示的单体单元:其中a表示约1至约99摩尔%b表示约0至约50摩尔 %c表示约1至约99摩尔%a + b + c优选为约100%; C选自:(I)(II)(III)组合。 D是OH,卤化物,OR4,NH2,NHR3,OM'或OM“; E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R1表示质子,C1-C24烷基或C3-C24环烷基; R2表示C1-C24烷基,C3-C24环烷基,C6-C18芳基或C7-C30烷基芳基; R3表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; R4表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了利用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
    • 47. 发明授权
    • Immobilized lewis acid catalysts
    • 固定的路易斯酸催化剂
    • US5571885A
    • 1996-11-05
    • US398635
    • 1995-03-03
    • Tze-Chiang ChungFrank J.-Y. ChenJon E. StanatAlok Kumar
    • Tze-Chiang ChungFrank J.-Y. ChenJon E. StanatAlok Kumar
    • C08F4/02C08F4/00C08F4/06C08F4/14C08F8/00C08F10/00C08F10/08C08F36/02C08F36/06
    • C08F10/00
    • Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula:--[A].sub.a --[B].sub.b --[C].sub.c --whereina represents about 1 to about 99 mole %b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR1## C is selected from the group consisting of: ##STR2## (III) combinations thereof, wherein D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM";E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkylene group, C.sub.3 -C.sub.24 cycloalkylene, C.sub.6 -C.sub.18 arylene, or C.sub.7 -C.sub.30 alkylarylene;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
    • 固定化路易斯酸催化剂,其包含具有固定在其结构内的至少一种路易斯酸的聚合物,所述聚合物具有由以下结构式表示的单体单元: - [A] a- [B] b- [C] c - 其中a表示约1 至约99摩尔%b表示约0至约50摩尔%c表示约1至约99摩尔%a + b + c优选约100%; 其中D为OH,卤化物,OR4,NH2,NHR3,OM'或OM“;其中D为OH,卤素,OR4,NH2,NHR3,OM'或OM”。 E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R1表示质子,C1-C24烷基或C3-C24环烷基; R2表示C1-C24亚烷基,C3-C24亚环烷基,C6-C18亚芳基或C7-C30烷基亚芳基; R3表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; R4表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了利用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
    • 49. 发明授权
    • Bandwidth allocation of bursty signals
    • 突发信号的带宽分配
    • US08547840B1
    • 2013-10-01
    • US13018905
    • 2011-02-01
    • Alok KumarAnand RaghuramanUday NaikAspi SiganporiaSushant Jain
    • Alok KumarAnand RaghuramanUday NaikAspi SiganporiaSushant Jain
    • H04L12/26
    • H04L43/0894H04L47/821H04L67/322
    • Bandwidth is allocated by leveraging a bursty characteristic of data transmission signals to efficiently utilize network resources. Network performance is observed over a time period to identify patterns of data transmission rates as different signals are processed. To compensate for the fact that different jobs/tasks peak at different times, the total bandwidth limit may be increased by a scaling factor. The scaling factor is calculated using information obtained by observing network performance during the time period. The scaling factor is used to increase the total bandwidth available for all jobs/tasks executing during the time period without exceeding any bandwidth limits. The data transmission rate of each job/task may then be adjusted to utilize the newly available bandwidth.
    • 通过利用数据传输信号的突发特性来分配带宽以有效地利用网络资源。 在一段时间内观察网络性能,以识别处理不同信号的数据传输速率的模式。 为了补偿不同作业/任务在不同时间达到峰值的事实,可以通过缩放因子来增加总带宽限制。 使用通过在该时间段期间观察网络性能获得的信息来计算缩放因子。 缩放因子用于增加在该时间段内执行的所有作业/任务可用的总带宽,而不超过任何带宽限制。 然后可以调整每个作业/任务的数据传输速率以利用新可用的带宽。