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    • 41. 发明授权
    • Shoot and run printing materials
    • 拍摄和运行印刷材料
    • US5395734A
    • 1995-03-07
    • US983124
    • 1992-11-30
    • Dennis E. VogelLeonard J. Stulc
    • Dennis E. VogelLeonard J. Stulc
    • B41N1/08B41N1/14B41N3/08G03F7/00G03F7/004G03F7/029G03F7/033G03F7/039G03F7/075G03F7/26G03F7/021G03C1/77
    • G03F7/0758G03F7/039Y10S430/111Y10S430/12Y10S430/122Y10S430/126
    • Acid-sensitive polymers and imageable articles employing them are disclosed. In particular, photosensitive compositions are disclosed comprising: (a) a photoinitiator which generates an acid upon exposure to radiation; and (b) a polymer having acid labile groups pendant from the polymer backbone, said acid labile pendant groups comprising at least one each of A and B wherein A has the formula --T--(C.dbd.O)OCR.sup.1 R.sup.2 OR.sup.3, and B has the formula --T--(C.dbd.O)OR.sup.4 Si(R.sup.5).sub.3, wherein R.sup.1 and R.sup.2 each represent H or an alkyl group with the proviso that at least one of R.sup.1 and R.sup.2 must be hydrogen; R.sup.3 represents an alkyl group; or any two of R.sup.1, R.sup.2, and R.sup.3 may together form a ring group having from 3 to 36 carbon atoms; R.sup.5 represents an alkyl group, aryl group, an alkoxy group, an aryloxy group, an acyloxy group, or a trialkylsiloxy group; and R.sup.4 and T represents a divalent linking group wherein T is bonded to the polymer backbone and R.sup.4 is not bonded to the polymer backbone, the divalent linking group containing a total of from 0 (a covalent bond) or 1 to 18 carbon atoms where up to one of each three carbon atoms may be replaced by oxygen, nitrogen, or sulfur atoms or combinations thereof in the polymer backbone.
    • 公开了使用它们的酸敏感聚合物和可成像制品。 特别地,公开了光敏组合物,其包含:(a)在暴露于辐射时产生酸的光引发剂; 和(b)具有从聚合物主链悬挂的酸不稳定基团的聚合物,所述酸不稳定侧基包含A和B中的至少一个,其中A具有式-T-(C = O)OCR 1 R 2 R 3,B具有式 -T-(C = O)OR 4 Si(R 5)3,其中R 1和R 2各自表示H或烷基,条件是R 1和R 2中的至少一个必须是氢; R3表示烷基; 或者R 1,R 2和R 3中的任何两个可以一起形成具有3至36个碳原子的环基; R5表示烷基,芳基,烷氧基,芳氧基,酰氧基或三烷基甲硅烷氧基; 并且R 4和T表示二价连接基团,其中T与聚合物主链键合,并且R 4不与聚合物主链结合,二价连接基团含有总共0(共价键)或1至18个碳原子 可以在聚合物主链中被氧,氮或硫原子或其组合替代为每三个碳原子中的一个。