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41. 发明授权

US06306673B1 Thermoelectric conversion module and method of manufacturing the same 失效
标题翻译：热电转换模块及其制造方法
公开(公告)号：US06306673B1
公开(公告)日：2001-10-23
申请号：US09320461
申请日：1999-05-27
申请人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
发明人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
IPC分类号： H01L2100
CPC分类号： H01L35/325 , H01L35/34
摘要： A thermoelectric conversion module having a large capacity and a curved surface which can be secured to a corresponding curved surface of a base member is manufactured by inserting N type and P type semiconductor strips into through holes formed in a honeycomb structural body, filling spaces between walls defining the through holes and the semiconductor strips with an electrically insulating filler members made of an easily deformable material such as polyimide resin and silicone resin, cutting the honeycomb structural body into a plurality of thermoelectric conversion module main bodies each having a desired surface configuration, and providing metal electrodes on both surfaces of a thermoelectric conversion module main body such that alternate N type and P type semiconductor elements are connected in cascade.
摘要翻译：通过将N型和P型半导体条插入到形成在蜂窝结构体中的通孔中，在壁之间填充空间来制造具有大容量的热电转换模块和可固定到基体的相应弯曲表面的曲面用诸如聚酰亚胺树脂和有机硅树脂的容易变形的材料制成的电绝缘填料构件来限定通孔和半导体条，将蜂窝结构体切割成具有所需表面形状的多个热电转换模块主体，以及在热电转换模块主体的两个表面上提供金属电极，使得交替的N型和P型半导体元件级联连接。

42. 发明授权

US5705434A Method of manufacturing thermoelectric conversion module 失效
标题翻译：制造热电转换模块的方法
公开(公告)号：US5705434A
公开(公告)日：1998-01-06
申请号：US744599
申请日：1996-11-07
申请人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
发明人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
IPC分类号： H01L35/14 , H01L35/32 , H01L35/34 , H01L21/324 , H01L21/477 , H01L35/28
CPC分类号： H01L35/34 , H01L35/325
摘要： A thermoelectric conversion module having a large capacity and a curved surface which can be secured to a corresponding curved surface of a base member is manufactured by inserting N type and P type semiconductor strips into through holes formed in a honeycomb structural body, filling spaces between walls defining the through holes and the semiconductor strips with filler members, cutting the honeycomb structural body into a plurality of thermoelectric conversion module main bodies each having a desired surface configuration, providing metal electrodes on both surfaces of a thermoelectric conversion module main body such that alternate N type and P type semiconductor elements are connected in cascade, and removing the filler members or the honeycomb structural body and filler members.
摘要翻译：通过将N型和P型半导体条插入到形成在蜂窝结构体中的通孔中，在壁之间填充空间来制造具有大容量的热电转换模块和可固定到基体的相应弯曲表面的曲面通过填充部件限定通孔和半导体条，将蜂窝结构体切割成具有所需表面构造的多个热电转换模块主体，在热电转换模块主体的两个表面上设置金属电极，使得N 类型和P型半导体元件级联连接，并且去除填充部件或蜂窝结构体和填充部件。

43. 发明授权

US07326484B2 Solid oxide fuel cell 失效
标题翻译：固体氧化物燃料电池
公开(公告)号：US07326484B2
公开(公告)日：2008-02-05
申请号：US11088892
申请日：2005-03-25
申请人： Itaru Shibata , Tatsuo Sugiyama , Masaharu Hatano , Mitsugu Yamanaka , Makoto Uchiyama , Tatsuhiro Fukuzawa , Naoki Hara , Keiko Kushibiki , Fuminori Satou
发明人： Itaru Shibata , Tatsuo Sugiyama , Masaharu Hatano , Mitsugu Yamanaka , Makoto Uchiyama , Tatsuhiro Fukuzawa , Naoki Hara , Keiko Kushibiki , Fuminori Satou
IPC分类号： H01M8/10 , H01M8/24 , H01M4/86
CPC分类号： H01M4/8657 , H01M4/8642 , H01M8/1213 , H01M8/2425 , H01M8/2432 , H01M8/249 , H01M2008/1293 , Y02P70/56
摘要： A single cell for a fuel cell in which an air electrode or a fuel electrode includes at least two layers. The air electrode includes an adhering cathode layer formed on one surface of the solid electrolyte layer and configured to show a function to allow the air electrode and the solid electrolyte layer to adhere electrically and mechanically to each other, and an electricity collecting cathode layer formed on the adhering cathode layer and configured to show an electricity collecting function of the air electrode. Alternatively, the fuel electrode includes an adhering anode layer formed on the other surface of the solid electrolyte layer and configured to show a function to allow the fuel electrode and the solid electrolyte layer to adhere electrically and mechanically to each other, and an electricity collecting anode layer formed on the adhering anode layer and configured to show an electricity collecting function.
摘要翻译：用于燃料电池的单电池，其中空气电极或燃料电极包括至少两层。空气电极包括形成在固体电解质层的一个表面上的粘附阴极层，并且被配置为显示使空气电极和固体电解质层彼此电和机械地粘附的功能，以及形成在粘附阴极层并且被配置为显示空气电极的集电功能。或者，燃料电极包括形成在固体电解质层的另一个表面上的粘附阳极层，并且被配置为具有允许燃料电极和固体电解质层彼此电和机械粘合的功能，并且集电阳极层，其形成在粘附阳极层上并且被配置为显示集电功能。

44. 发明授权

US06926852B2 Cell plate structure for solid electrolyte fuel cell, solid electrolyte fuel cell and related manufacturing method 有权
标题翻译：固体电解质燃料电池，固体电解质燃料电池的细胞板结构及相关制造方法
公开(公告)号：US06926852B2
公开(公告)日：2005-08-09
申请号：US10216237
申请日：2002-08-12
申请人： Fuminori Satou , Mitsugu Yamanaka , Makoto Uchiyama , Masaharu Hatano , Keiko Kushibiki , Naoki Hara , Tatsuhiro Fukuzawa , Itaru Shibata
发明人： Fuminori Satou , Mitsugu Yamanaka , Makoto Uchiyama , Masaharu Hatano , Keiko Kushibiki , Naoki Hara , Tatsuhiro Fukuzawa , Itaru Shibata
IPC分类号： H01M4/88 , H01M4/86 , H01M8/02 , H01M8/12
CPC分类号： H01M8/1226 , H01M4/881 , H01M4/8878 , H01M4/8889 , H01M8/1213 , H01M8/122 , H01M8/124 , H01M8/1286 , Y02P70/56
摘要： A cell plate structure for a solid oxide electrolyte type fuel cell is provided with a lower electrode layer, an upper electrode layer provided in opposition to the lower electrode layer, a solid electrolyte layer provided between the lower electrode layer and the upper electrode layer, and an area provided in at least one of the lower electrode layer and the upper electrode layer. The area has a portion which is formed by removing a substance, contained in the at least one of the lower electrode layer and the upper electrode layer during formation thereof, after the at least one of the lower electrode layer and the upper electrode layer has been formed. Such a fuel cell plate structure can be applied to a solid electrolyte fuel cell representatively by being disposed between a pair of separators that have gas flow passages supplying the lower electrode layer and the upper electrode layer with gasses, respectively.
摘要翻译：用于固体氧化物电解质型燃料电池的电池板结构设置有下电极层，与下电极层相对设置的上电极层，设置在下电极层和上电极层之间的固体电解质层，以及设置在下电极层和上电极层中的至少一个中的区域。该区域具有通过在其形成之后在下电极层和上电极层中的至少一个之后除去包含在下电极层和上电极层中的至少一个的物质而形成的部分，在下电极层和上电极层中的至少一个已经被形成。这种燃料电池板结构可以通过设置在一对分离器之间来代替地施加到固体电解质燃料电池，所述隔板具有分别供给下电极层和上电极层的气体流通气体。

45. 发明授权

US06235981B1 P-type thermoelectric converting substance and method of manufacturing the same 失效
标题翻译： P型热电转换物质及其制造方法
公开(公告)号：US06235981B1
公开(公告)日：2001-05-22
申请号：US09270102
申请日：1999-03-16
申请人： Makoto Miyoshi , Yuichiro Imanishi , Keiko Kushibiki , Masakazu Kobayashi , Kenji Furuya , Kazuhiko Shinohara
发明人： Makoto Miyoshi , Yuichiro Imanishi , Keiko Kushibiki , Masakazu Kobayashi , Kenji Furuya , Kazuhiko Shinohara
IPC分类号： H01L3534
CPC分类号： H01L35/18 , H01L35/22
摘要： A p-type thermoelectric converting substance used as a p-type semiconductor in a thermoelectric converting module consisting essentially of a substance expressed by a chemical formula CoSbxSny or CoSbxGey (2.7 3), and containing a small amount of oxygen z defined by 2(x+y−3)≧z. The amount of oxygen z is preferably limited such that it is not higher than 0.1 molecules per 1 molecule of Co. An alloy ingot consisting essentially of CoSbxSny or CoSbxGey (2.7 3) is ground to obtain a raw material powder. Then, the powder is cast into a mold, and the mold is sintered under a non-oxidizing or reducing atmosphere. The thus obtained substance reveals p-conductivity in a stable manner over a wide temperature range, and has excellent thermoelectric converting properties.
摘要翻译：在热电转换模块中用作p型半导体的p型热电转换物质，其主要由化学式CoSbxSny或CoSbxGey（2.7 3）表示的物质组成），并且含有由2（x + y-3）> = z定义的少量氧z。优选限定氧气的量，使得每1分子公司不超过0.1分子。基本上由CoSbxSny或CoSbxGey（2.7 3）组成的合金锭）粉碎，得到原料粉末。然后将粉末浇注到模具中，并将模具在非氧化或还原气氛下烧结。由此获得的物质在宽的温度范围内以稳定的方式显示出p导电性，并且具有优异的热电转换性能。

46. 发明授权

US5994637A Thermoelectric conversion module and method of manufacturing the same 失效
标题翻译：热电转换模块及其制造方法
公开(公告)号：US5994637A
公开(公告)日：1999-11-30
申请号：US201000
申请日：1998-11-30
申请人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
发明人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
IPC分类号： H01L35/16 , H01L35/32 , H01L35/34
CPC分类号： H01L35/32 , H01L35/34
摘要： A thermoelectric conversion module having a large capacity and a curved surface is manufactured by immersing a honeycomb structural body having a number of through holes, openings of every other through holes being closed by clogging members, into a semiconductor material melt of one conductivity type to suck the semiconductor material melt into through holes whose openings are not closed, cooling the thus sucked semiconductor material melt to form semiconductor elements of one conductivity type, immersing again the honeycomb structural body after removing said clogging members into a semiconductor material melt of the other conductivity type to suck the semiconductor material melt into the through holes, cooling the thus sucked semiconductor material melt to form semiconductor elements of the other conductivity type, cutting the honeycomb structural body into a plurality of thermoelectric conversion module main bodies, and providing metal electrodes of both surfaces of a thermoelectric conversion module main body such that alternate semiconductor elements of one and the other conductivity types are connected in series.
摘要翻译：通过将具有多个通孔的蜂窝结构体浸渍到一个导电类型的半导体材料熔体中，将具有多个通孔的每隔一个通孔的开口浸入到具有一个导电类型的半导体材料熔体中来制造具有大容量和弯曲表面的热电转换模块半导体材料熔化成开口未闭合的通孔，冷却由此被吸引的半导体材料熔融物形成一种导电类型的半导体元件，在将所述堵塞构件移除到另一种导电类型的半导体材料熔体中之后，再次将蜂窝结构体再次浸没将半导体材料熔体吸入通孔中，冷却由此吸收的半导体材料熔体形成另一种导电类型的半导体元件，将蜂窝结构体切割成多个热电转换模块主体，并且提供两个表面的金属电极的热电 c转换模块主体，使得一种和另一种导电类型的交替半导体元件串联连接。

47. 发明授权

US5952728A Thermoelectric conversion module having channels filled with semiconducting material and insulating fillers 失效
标题翻译：具有填充有半导体材料和绝缘填料的通道的热电转换模块
公开(公告)号：US5952728A
公开(公告)日：1999-09-14
申请号：US744600
申请日：1996-11-07
申请人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
发明人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
IPC分类号： F25B21/02 , H01L35/14 , H01L35/32 , H01L35/34 , H01L23/56
CPC分类号： H01L35/325 , H01L35/34
摘要： A thermoelectric conversion module having a large capacity and a curved surface which can be secured to a corresponding curved surface of a base member is manufactured by inserting N type and P type semiconductor strips into through holes formed in a honeycomb structural body, filling spaces between walls defining the through holes and the semiconductor strips with an electrically insulating filler members made of an easily deformable material such as polyimide resin and silicone resin, cutting the honeycomb structural body into a plurality of thermoelectric conversion module main bodies each having a desired surface configuration, and providing metal electrodes on both surfaces of a thermoelectric conversion module main body such that alternate N type and P type semiconductor elements are connected in cascade.
摘要翻译：通过将N型和P型半导体条插入到形成在蜂窝结构体中的通孔中，在壁之间填充空间来制造具有大容量的热电转换模块和可固定到基体的相应弯曲表面的曲面用诸如聚酰亚胺树脂和有机硅树脂的容易变形的材料制成的电绝缘填料构件来限定通孔和半导体条，将蜂窝结构体切割成具有所需表面形状的多个热电转换模块主体，以及在热电转换模块主体的两个表面上提供金属电极，使得交替的N型和P型半导体元件级联连接。

48. 发明授权

US5886291A Thermoelectric conversion module and method of manufacturing the same 失效
标题翻译：热电转换模块及其制造方法
公开(公告)号：US5886291A
公开(公告)日：1999-03-23
申请号：US744990
申请日：1996-11-07
申请人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
发明人： Yuichiro Imanishi , Makoto Miyoshi , Tetsuo Watanabe , Keiko Kushibiki , Kazuhiko Shinohara , Masakazu Kobayashi , Kenji Furuya
IPC分类号： H01L35/16 , H01L35/32 , H01L35/34 , H01L35/28
CPC分类号： H01L35/32 , H01L35/34
摘要： A thermoelectric conversion module having a large capacity and a curved surface is manufactured by immersing a honeycomb structural body having a number of through holes, openings of every other through holes being closed by clogging members, into a semiconductor material melt of one conductivity type to suck the semiconductor material melt into through holes whose openings are not closed, cooling the thus sucked semiconductor material melt to form semiconductor elements of one conductivity type, immersing again the honeycomb structural body after removing the clogging members into a semiconductor material melt of the other conductivity type to suck the semiconductor material melt into the through holes, cooling the thus sucked semiconductor material melt to form semiconductor elements of the other conductivity type, cutting the honeycomb structural body into a plurality of thermoelectric conversion module main bodies, and providing metal electrodes of both surfaces of a thermoelectric conversion module main body such that alternate semiconductor elements of one and the other conductivity types are connected in series.
摘要翻译：通过将具有多个通孔的蜂窝结构体浸渍到一个导电类型的半导体材料熔体中，将具有多个通孔的每隔一个通孔的开口浸入到具有一个导电类型的半导体材料熔体中来制造具有大容量和弯曲表面的热电转换模块半导体材料熔化成开口不闭合的通孔，冷却由此被吸引的半导体材料熔融物形成一种导电类型的半导体元件，在将堵塞件移除到另一种导电类型的半导体材料熔体中之后再次将蜂窝结构体再次浸没将半导体材料熔体吸入通孔中，冷却由此吸收的半导体材料熔体形成另一种导电类型的半导体元件，将蜂窝结构体切割成多个热电转换模块主体，并且提供两个表面的金属电极的热电转换模块主体，使得一种和另一种导电类型的交替半导体元件串联连接。

49. 发明授权

US08530103B2 Fuel cell system and control method thereof 有权
标题翻译：燃料电池系统及其控制方法
公开(公告)号：US08530103B2
公开(公告)日：2013-09-10
申请号：US12595175
申请日：2008-05-26
申请人： Dong Song , Masaharu Hatano , Keiko Kushibiki , Kazufumi Takeuchi
发明人： Dong Song , Masaharu Hatano , Keiko Kushibiki , Kazufumi Takeuchi
IPC分类号： H01M8/06
CPC分类号： H01M8/04447 , H01M4/9016 , H01M4/9041 , H01M4/9066 , H01M4/92 , H01M8/04089 , H01M8/04917 , H01M8/0618 , H01M8/0637 , H01M8/0656 , H01M8/0681 , H01M8/2404 , H01M8/2425 , H01M16/00 , H01M2008/1293 , H01M2250/20 , H01M2250/40 , Y02E60/525 , Y02E60/56 , Y02E60/566 , Y02T90/32
摘要： A fuel cell system includes: a power generation stack (1) composed by stacking a plurality of fuel cells (10); and a hydrocarbon-oxidizing device (2) disposed on an upstream side of the power generation stack (1) in a fuel supply passage (8). The hydrocarbon-oxidizing device (2) directly and electrochemically oxidizes hydrocarbons with a carbon number of 2 or more, which are contained in fuel gas, or decomposes the hydrocarbons and electrochemically oxidizes carbon obtained by decomposing the hydrocarbons.
摘要翻译：燃料电池系统包括：通过堆叠多个燃料电池（10）构成的发电堆（1）; 以及在燃料供给通路（8）中配置在发电堆（1）的上游侧的烃类氧化装置（2）。烃氧化装置（2）直接并电化学地氧化燃料气体中所含的碳数为2以上的碳氢化合物，或者分解烃，并对通过分解烃获得的碳进行电化学氧化。

50. 发明授权

US07186475B2 Unit cell for solid oxide electrolyte type fuel cell and related manufacturing method 有权
标题翻译：固体氧化物电解质型燃料电池单元及相关制造方法
公开(公告)号：US07186475B2
公开(公告)日：2007-03-06
申请号：US10128307
申请日：2002-04-24
申请人： Itaru Shibata , Keiko Kushibiki , Fuminori Satou , Mitsugu Yamanaka , Makoto Uchiyama , Masaharu Hatano
发明人： Itaru Shibata , Keiko Kushibiki , Fuminori Satou , Mitsugu Yamanaka , Makoto Uchiyama , Masaharu Hatano
IPC分类号： H01M8/10
CPC分类号： H01M8/1213 , H01M4/9033 , H01M4/9066 , H01M8/0202 , H01M8/1226 , H01M2300/0074 , Y02P70/56
摘要： A unit cell for a solid electrolyte fuel cell is provided with an air electrode, a fuel electrode, a solid electrolyte sandwiched between the air electrode and the fuel electrode, and a porous metallic base body joined to at lease one of the air electrode and the fuel electrode. The porous metallic base body includes a plurality of porous base body layers stacked to form a laminated structure in which one layer joined to at least one of the air electrode and the fuel electrode has porosity lower than that of the other layer not joined to at least one of the air electrode and the fuel electrode.
摘要翻译：用于固体电解质燃料电池的单元电池设置有空气电极，燃料电极，夹在空气电极和燃料电极之间的固体电解质，以及多孔金属基体，其与至少一个空气电极和燃料电极。多孔金属基体包括堆叠形成层叠结构的多个多孔基体层，其中与空气电极和燃料电极中的至少一个接合的一个层的孔隙率低于至少没有连接的另一层的孔隙率一个空气电极和燃料电极。

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