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41. 发明授权

US08852788B2 Porous membrane for a secondary battery and a secondary battery 有权
标题翻译：用于二次电池和二次电池的多孔膜
公开(公告)号：US08852788B2
公开(公告)日：2014-10-07
申请号：US13499123
申请日：2010-09-29
申请人： Yasuhiro Wakizaka , Nobukazu Kaihatsu
发明人： Yasuhiro Wakizaka , Nobukazu Kaihatsu
IPC分类号： H01M2/16 , H01M2/18 , H01M4/13 , H01M2/14 , H01M10/0525
CPC分类号： H01M2/1686 , H01M2/145 , H01M2/1646 , H01M2/1653 , H01M4/13 , H01M10/0525 , Y02E60/122
摘要： Disclosed is a porous membrane used for a secondary battery, such as lithium-ion secondary battery, wherein strength is improved and break is difficult to occur while maintaining lithium-ion conductivity. The porous membrane for a secondary battery comprising a binder for the porous membrane and a nonconductive particle, wherein the binder for the porous membrane is a polymer particle having a hetero phase structure, in which internal layer is a polymer wherein vinyl monomer components are polymerized and outer layer is a polymer wherein monomer components containing a hydrophilic functional group are polymerized. The hydrophilic functional group is at least one selected from the group consisting sulfonic acid group, carboxyl group, hydroxyl group and epoxy group.
摘要翻译：公开了用于二次电池的多孔膜，例如锂离子二次电池，其中强度得到改善，并且在保持锂离子传导性的同时难以发生断裂。一种二次电池用多孔膜，其包含多孔膜用粘合剂和非导电性粒子，其中，所述多孔膜用粘合剂为具有异相结构的聚合物粒子，其中，内层为乙烯基单体成分聚合的聚合物，外层是含有亲水性官能团的单体成分聚合的聚合物。亲水性官能团是选自磺酸基，羧基，羟基和环氧基中的至少一种。

42. 发明授权

US08822074B2 Electrode for lithium-ion secondary battery 有权
标题翻译：锂离子二次电池用电极
公开(公告)号：US08822074B2
公开(公告)日：2014-09-02
申请号：US13138495
申请日：2010-02-26
申请人： Yasuhiro Wakizaka , Takumi Sugimoto
发明人： Yasuhiro Wakizaka , Takumi Sugimoto
IPC分类号： H01M4/62 , H01M4/13 , H01M4/64 , H01M10/052
CPC分类号： H01M4/13 , H01M2/166 , H01M4/62 , H01M4/621 , H01M4/622 , H01M4/64 , H01M10/052 , Y02E60/122
摘要： Disclosed is an electrode for a lithium-ion secondary battery which includes a porous membrane layer that is inhibited from decreasing in flexibility. The electrode for lithium-ion secondary battery comprises a current collector and, formed thereon in the following order, an electrode active-material layer comprising an electrode active material, a thickener, and a binder and a porous membrane layer containing an inorganic filler, wherein the binder is one which, when used to form a composite film comprising the binder and the thickener, forms a spherical island phase in a cross section of the composite film, the island phase having an average diameter of 0.5 μm or larger. The binder preferably is an unsaturated carboxylic acid ester polymer having a content of alkyl acrylate monomer units of 85 mass % or higher.
摘要翻译：公开了一种用于锂离子二次电池的电极，其包括被抑制柔性降低的多孔膜层。锂离子二次电池用电极包括集电体，并且依次形成包含电极活性物质，增稠剂和粘合剂的电极活性物质层和含有无机填料的多孔膜层，其中，粘合剂是当用于形成包含粘合剂和增稠剂的复合膜时，在复合膜的横截面中形成球形岛相，其中岛相的平均直径为0.5μm以上。粘合剂优选为具有85质量％以上丙烯酸烷基酯单体单元含量的不饱和羧酸酯聚合物。

43. 发明申请

US20130273421A1 SLURRY FOR SECONDARY BATTERY POROUS MEMBRANE, A SECONDARY BATTERY POROUS MEMBRANE, AN ELECTRODE FOR SECONDARY BATTERY, A SEPARATOR FOR SECONDARY BATTERY AND A SECONDARY BATTERY 有权
标题翻译：用于二次电池多孔膜，二次电池多孔膜，二次电池用电极，二次电池用分离器和二次电池
公开(公告)号：US20130273421A1
公开(公告)日：2013-10-17
申请号：US13878095
申请日：2011-10-07
申请人： Taku Matsumura , Takuya Kaneda , Yasuhiro Wakizaka
发明人： Taku Matsumura , Takuya Kaneda , Yasuhiro Wakizaka
IPC分类号： H01M2/16
CPC分类号： H01M2/1653 , C08L33/20 , H01M2/168 , H01M4/13 , H01M4/622 , H01M10/052 , H01M10/4235
摘要： A secondary battery porous membrane, manufactured by a slurry for secondary battery porous membrane, which is superior in coating priority and dispersibility of non-conductive organic particles, which improves cycle characteristic of the obtained secondary battery, which has high flexibility and can prevent powder falls, and which has less content of moisture amount; and non-conductive organic particles, which can be suitably used as a secondary battery porous membrane and has less content of metallic foreign particles. The slurry for secondary battery porous membrane comprises; a binder including a polymerized unit of vinyl monomer having a hydrophilic acid group, a non-conductive organic particle having a functional group, cross-linkable with the hydrophilic acid group and a solvent.
摘要翻译：通过二次电池用多孔膜的浆料制造的二次电池用多孔膜，其具有优异的非导电性有机粒子的涂布优先性和分散性，能够提高所获得的二次电池的循环特性，该二次电池具有高柔性并能够防止粉末落下，水分含量较少; 和非导电性有机颗粒，其可以适合用作二次电池多孔膜并且具有较少的金属外来颗粒含量。用于二次电池多孔膜的浆料包括：包含具有亲水性酸基的乙烯基单体的聚合单元，具有与亲水性酸基交联的官能团的非导电性有机粒子和溶剂的粘合剂。

44. 发明申请

US20120189897A1 POROUS MEMBRANE FOR SECONDARY BATTERY AND SECONDARY BATTERY 审中-公开
标题翻译：用于二次电池和二次电池的多孔膜
公开(公告)号：US20120189897A1
公开(公告)日：2012-07-26
申请号：US13498993
申请日：2010-09-30
申请人： Yasuhiro Wakizaka , Naoki Yoshida
发明人： Yasuhiro Wakizaka , Naoki Yoshida
IPC分类号： H01M2/16 , H01M4/64 , B05D3/00 , H01M4/02 , C09D133/08 , B05D5/00
CPC分类号： H01M2/1653 , H01M2/145 , H01M10/052
摘要： Disclosed is a porous membrane for a secondary battery, which has further improved output characteristics and long-term cycle characteristics when compared with conventional porous membranes. The porous membrane for a secondary battery is used for a lithium ion secondary battery or the like. Specifically disclosed is a porous membrane for a secondary battery, which contains polymer particles A that have a number average particle diameter of 0.4 μm or more but less than 10 μm and a glass transition temperature of 65° C. or more and polymer particles B that have a number average particle diameter of 0.04 μm or more but less than 0.3 μm and a glass transition temperature of 15° C. or less. It is preferable that the polymer particles B have a crystallization degree of 40% or less and a main chain structure that is composed of a saturated structure.
摘要翻译：公开了一种用于二次电池的多孔膜，与常规多孔膜相比，其具有进一步改善的输出特性和长期循环特性。用于二次电池的多孔膜用于锂离子二次电池等。具体公开了一种二次电池用多孔膜，其含有数均粒径为0.4μm以上且小于10μm的聚合物粒子A，玻璃化转变温度为65℃以上，聚合物粒子B为数均粒径为0.04μm以上且小于0.3μm，玻璃化转变温度为15℃以下。优选聚合物粒子B的结晶度为40％以下，主链结构由饱和结构构成。

45. 发明申请

US20110171526A1 BINDER COMPOSITION FOR SECONDARY BATTERY ELECTRODE AND METHOD FOR PRODUCING SAME 审中-公开
标题翻译：用于二次电池电极的焊接组合物及其制造方法
公开(公告)号：US20110171526A1
公开(公告)日：2011-07-14
申请号：US13119681
申请日：2009-09-17
申请人： Yasuhiro Wakizaka , Yosuke Yabuuchi
发明人： Yasuhiro Wakizaka , Yosuke Yabuuchi
IPC分类号： H01M4/64 , H01M4/62 , C08L55/02
CPC分类号： H01M4/621 , H01M4/04 , H01M4/139 , H01M10/052
摘要： A binder composition for secondary batteries having excellent stability over time is produced. A method for producing a binder composition for secondary batteries containing at least a polymer and a dispersion medium, which comprises a metal particulate removal step wherein metal particulates contained in a polymer dispersion containing a polymer and a dispersion medium are removed. A binder composition for secondary batteries, which is obtained by the above-mentioned production method and has a metal particulate content of not more than 10 ppm, said metal particulate content is composed of particles formed from a transition metal component and having a particle diameter of not less than 20 μm. A slurry for secondary battery electrodes, which contains the binder composition for secondary batteries and an electrode active material. A secondary battery electrode wherein an electrode active material layer containing the binder composition for secondary batteries and a positive electrode active material or a negative electrode active material is adhered to a collector. A secondary battery comprising the secondary battery electrode.
摘要翻译：生产具有优异的时间稳定性的二次电池用粘合剂组合物。一种包含至少含有聚合物和分散介质的二次电池用粘合剂组合物的方法，其包括金属颗粒除去步骤，其中除去含有聚合物和分散介质的聚合物分散体中所含的金属微粒。一种用于二次电池的粘合剂组合物，其通过上述制备方法获得并且具有不大于10ppm的金属颗粒含量，所述金属颗粒含量由过渡金属组分形成的颗粒由粒径为不小于20μm。二次电池电极用浆料，其含有二次电池用粘合剂组合物和电极活性物质。二次电池电极，其中含有二次电池用粘合剂组合物的电极活性物质层和正极活性物质或负极活性物质附着在集电体上。一种二次电池，包括二次电池电极。

46. 发明申请

US20110091774A1 POROUS FILM AND SECONDARY BATTERY ELECTRODE 有权
标题翻译：多孔电池和二次电池电极
公开(公告)号：US20110091774A1
公开(公告)日：2011-04-21
申请号：US12935437
申请日：2009-03-31
申请人： Yasuhiro Wakizaka , Mayumi Fukumi
发明人： Yasuhiro Wakizaka , Mayumi Fukumi
IPC分类号： H01M2/16 , H01M4/04 , H01M4/02 , C09D105/00 , C09D101/08
CPC分类号： H01G9/02 , C08J5/18 , C08J2301/02 , H01G11/38 , H01M2/1646 , H01M2/166 , H01M2/168 , H01M10/0525 , Y02E60/122 , Y02E60/13 , Y02P70/54
摘要： Provided is a porous film that can contribute to improving the cycle characteristics of an electric cell by improving binding characteristics, for a porous film provided on a surface of an electrode used in a secondary cell and the like. The porous film comprises a water-soluble polymer, an inorganic filler, and a water-insoluble particulate polymer including 0.5-40 mass % of a monomer unit having a hydrophilic group selected from the group consisting of carboxylic acid groups, hydroxyl groups, and sulfonate groups.
摘要翻译：提供了一种多孔膜，其可以通过提高结合特性，对于在二次电池中使用的电极的表面上提供的多孔膜等来改善电池的循环特性。多孔膜包括水溶性聚合物，无机填料和包含0.5-40质量％具有选自羧酸基，羟基和磺酸酯的亲水基团的单体单元的水不溶性颗粒聚合物团体

47. 发明申请

US20110020709A1 POROUS FILM AND SECONDARY BATTERY ELECTRODE 有权
标题翻译：多孔电池和二次电池电极
公开(公告)号：US20110020709A1
公开(公告)日：2011-01-27
申请号：US12865299
申请日：2009-01-30
申请人： Mayumi Fukumine , Yasuhiro Wakizaka
发明人： Mayumi Fukumine , Yasuhiro Wakizaka
IPC分类号： H01M2/16 , H01M4/04 , H01M4/13 , H01M10/052 , C08J9/00
CPC分类号： H01M2/1653 , C08J5/18 , C08J2301/02 , H01M2/162 , H01M2/1646 , H01M4/13 , Y02E60/122 , Y02P70/54 , Y10T428/24554
摘要： The present invention is intended for providing a porous film having excellent film uniformity, and is capable to contribute for improving cyclic and rate properties, which is provided on a surface of electrode used for a secondary battery and the like.The porous film of the present invention is characterized by including water soluble polymer having an average polymerization degree of 500 to 2500, an inorganic filler and water soluble particulate polymer. In the present invention particularly, it is preferable that said water soluble polymer is thickening polysaccharides, further said water-insoluble polymer is preferably selected from the group consisting of semisynthetic cellulose polymer, sodium salt and ammonium salt thereof.
摘要翻译：本发明旨在提供具有优异的膜均匀性的多孔膜，并且能够有助于提高在用于二次电池等的电极的表面上的循环和速率特性。本发明的多孔膜的特征在于包含平均聚合度为500〜2500的水溶性聚合物，无机填料和水溶性粒状聚合物。在本发明中，特别优选所述水溶性聚合物为增稠多糖，所述水不溶性聚合物优选选自半合成纤维素聚合物，钠盐及其铵盐。

48. 发明申请

US20110020703A1 CATHODE PLATE FOR SECONDARY BATTERY, MANUFACTURING METHOD THEREOF AND SECONDARY BATTERY PROVIDED WITH THE CATHODE PLATE 审中-公开
标题翻译：用于二次电池的阴极板，其制造方法和带阴极板的二次电池
公开(公告)号：US20110020703A1
公开(公告)日：2011-01-27
申请号：US12893688
申请日：2010-09-29
申请人： Tomonori SUZUKI , Hidetoshi Abe , Yasuhiro Wakizaka
发明人： Tomonori SUZUKI , Hidetoshi Abe , Yasuhiro Wakizaka
IPC分类号： H01M4/58 , B05D5/12
CPC分类号： H01M4/136 , H01M4/0404 , H01M4/1397 , H01M4/366 , H01M4/5825 , H01M10/052
摘要： Disclosed is a cathode plate for a secondary battery, which includes a collector, and a cathode active material layer, wherein the cathode active material layer is formed of multiple layers of coating films formed on a surface of the collector and obtained by application and drying of an aqueous paste, which is obtained by kneading and dispersing an iron lithium phosphate material having an olivine structure as the cathode active material, an electroconductive material, a water-soluble thickner, a binder, and water as a dispersion medium.
摘要翻译：公开了一种二次电池用阴极板，其包括集电体和正极活性物质层，其中，所述阴极活性物质层由形成在所述集电体的表面上的多层涂膜形成，并通过涂布和干燥通过将具有橄榄石结构的磷酸铁锂材料作为正极活性物质，导电材料，水溶性增稠剂，粘合剂和水作为分散介质进行捏和分散而获得的水性糊料。

49. 发明授权

US07396588B2 Curable composition, varnish and laminate 有权
标题翻译：可固化组合物，清漆和层压板
公开(公告)号：US07396588B2
公开(公告)日：2008-07-08
申请号：US11598766
申请日：2006-11-14
申请人： Yasuhiro Wakizaka , Toshiyasu Matsui , Daisuke Uchida , Koichi Ikeda
发明人： Yasuhiro Wakizaka , Toshiyasu Matsui , Daisuke Uchida , Koichi Ikeda
IPC分类号： B32B27/20 , B32B27/38 , B32B15/08 , B32B15/092 , C08K5/49 , C08L63/00 , C09K21/00 , C09K21/12
CPC分类号： H05K3/285 , C09D5/18 , H05K3/4676 , H05K2201/012 , Y10S428/901 , Y10T428/26 , Y10T428/31511 , Y10T428/31529
摘要： A curable composition comprises an insulating resin and a halogen-free flame retardant. The halogen-free flame retardant has a particulate form, and whose primary particles have an average major axis from 0.01 to 5 μm, an aspect ratio of 5 or less, and the proportion of a major axis of more than 10 μm being at most 10% by number. A varnish comprises an insulating resin, a curing agent, a flame retardant and an organic solvent. The flame retardant is a flame retardant in particulate form surface-treated with a coupling agent, and the flame retardant particles present in the varnish have a secondary particle diameter of 30 μm or less.
摘要翻译：可固化组合物包含绝缘树脂和无卤阻燃剂。无卤阻燃剂具有颗粒形式，其一次颗粒的平均长轴为0.01至5μm，纵横比为5或更小，长径大于10μm的长度比例至多为10 ％的数量。清漆包括绝缘树脂，固化剂，阻燃剂和有机溶剂。阻燃剂是用偶联剂表面处理的颗粒形式的阻燃剂，并且存在于清漆中的阻燃颗粒的二次粒径为30μm以下。

50. 发明申请

US20070060674A1 Curable composition, varnish and laminate 有权
标题翻译：可固化组合物，清漆和层压板
公开(公告)号：US20070060674A1
公开(公告)日：2007-03-15
申请号：US11598766
申请日：2006-11-14
申请人： Yasuhiro Wakizaka , Toshiyasu Matsui , Daisuke Uchida , Koichi Ikeda
发明人： Yasuhiro Wakizaka , Toshiyasu Matsui , Daisuke Uchida , Koichi Ikeda
IPC分类号： C08K5/52
CPC分类号： H05K3/285 , C09D5/18 , H05K3/4676 , H05K2201/012 , Y10S428/901 , Y10T428/26 , Y10T428/31511 , Y10T428/31529
摘要： A curable composition comprises an insulating resin and a halogen-free flame retardant. The halogen-free flame retardant has a particulate form, and whose primary particles have an average major axis from 0.01 to 5 μm, an aspect ratio of 5 or less, and the proportion of a major axis of more than 10 μm being at most 10% by number. A varnish comprises an insulating resin, a curing agent, a flame retardant and an organic solvent. The flame retardant is a flame retardant in particulate form surface-treated with a coupling agent, and the flame retardant particles present in the varnish have a secondary particle diameter of 30 μm or less.
摘要翻译：可固化组合物包含绝缘树脂和无卤阻燃剂。无卤阻燃剂具有颗粒形式，其一次颗粒的平均长轴为0.01至5μm，纵横比为5或更小，长径大于10μm的长度比例至多为10 ％的数量。清漆包括绝缘树脂，固化剂，阻燃剂和有机溶剂。阻燃剂是用偶联剂表面处理的颗粒形式的阻燃剂，并且存在于清漆中的阻燃颗粒的二次粒径为30μm以下。

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