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41. 发明授权

US07851547B2 Curable composition and coated article 有权
标题翻译：可固化组合物和涂层制品
公开(公告)号：US07851547B2
公开(公告)日：2010-12-14
申请号：US11710993
申请日：2007-02-27
申请人： Koichi Higuchi , Masaaki Yamaya , Hisashi Muramatsu , Koichi Chigita , Toshio Watanabe , Takayuki Nagai , Toshiro Kondo
发明人： Koichi Higuchi , Masaaki Yamaya , Hisashi Muramatsu , Koichi Chigita , Toshio Watanabe , Takayuki Nagai , Toshiro Kondo
IPC分类号： C08L83/00 , C08L33/06 , C08K5/34 , C08F220/12 , B32B9/04
CPC分类号： C08J7/047 , C08J2369/00 , C08J2483/00 , C08L83/06 , C08L101/00 , C09D143/04 , C09D183/10 , Y10T428/31663 , C08L2666/02
摘要： A curable composition comprises (A) an organic/inorganic composite in which a hydrolyzable silyl group and/or SiOH group-containing polysiloxane is bonded to a vinyl polymer through a Si—C bond, and (B) an organic UV absorber having a molecular weight of at least 500 and a weight retentivity of at least 95% when held at 150° C. for 24 hours in an open state. The curable composition is coated and cured to an article, whereby the article is endowed with satisfactory weathering resistance while minimizing coloration or degradation.
摘要翻译：可固化组合物包含（A）通过Si-C键将可水解甲硅烷基和/或含SiOH基的聚硅氧烷键合到乙烯基聚合物上的有机/无机复合物，（B）具有分子重量至少为500，当在150℃下保持24小时时的重量保持率为95％以上。将可固化组合物涂覆并固化成制品，由此使制品具有令人满意的耐候性，同时最小化着色或降解。

42. 发明授权

US07838616B2 Perfluoropolyether rubber composition and ion-conducting polymer electrolyte membrane 有权
标题翻译：全氟聚醚橡胶组合物和离子导电高分子电解质膜
公开(公告)号：US07838616B2
公开(公告)日：2010-11-23
申请号：US11924181
申请日：2007-10-25
申请人： Motoo Fukushima , Masaaki Yamaya , Akira Yamamoto , Shinichi Sato , Hirofumi Kishita
发明人： Motoo Fukushima , Masaaki Yamaya , Akira Yamamoto , Shinichi Sato , Hirofumi Kishita
IPC分类号： C08G77/12
CPC分类号： C08L71/02 , C08G65/007 , C08G2650/48 , C08J5/2275 , C08J5/2281 , C08J2371/02 , C08J2383/08 , H01M8/1027 , H01M8/103 , H01M8/1037 , H01M8/1039 , H01M8/1072 , Y02P70/56 , C08L83/00
摘要： A perfluoropolyether rubber composition is useful for forming a polymer electrolyte membrane, comprising (A) an alkenyl-containing perfluoropolyether, (B) a silicon-oxygen crosslinked structure having ionic conduction, and (C) a peroxide crosslinker. The silicon-oxygen crosslinked structure is obtained by simultaneously effecting oxidation and hydrolysis on an organoxysilane having an epoxy group and an organoxysilane having a mercapto group for thereby converting the mercapto group into a sulfonic group, and neutralizing the resulting sulfonic group-containing siloxane with a nitrogen-containing compound.
摘要翻译：全氟聚醚橡胶组合物可用于形成聚合物电解质膜，其包含（A）含烯基的全氟聚醚，（B）具有离子导电性的硅 - 氧交联结构和（C）过氧化物交联剂。通过在具有环氧基的有机氧基硅烷和具有巯基的有机氧基硅烷上同时进行氧化和水解，从而将巯基转化为磺酸基，并将所得的含磺酸基的硅氧烷中和，得到硅 - 氧交联结构含氮化合物。

43. 发明授权

US07642299B2 Multi-functional (meth) acrylate compound, photocurable resin composition and article 失效
标题翻译：多官能（甲基）丙烯酸酯化合物，光固化树脂组合物和制品
公开(公告)号：US07642299B2
公开(公告)日：2010-01-05
申请号：US11602991
申请日：2006-11-22
申请人： Yuji Yoshikawa , Koichi Higuchi , Masaaki Yamaya
发明人： Yuji Yoshikawa , Koichi Higuchi , Masaaki Yamaya
IPC分类号： C08G77/20 , C08G77/04 , C08G77/14 , C08L83/07 , C08L83/06 , B32B9/04 , B32B27/30 , C08F283/12
CPC分类号： C09D4/00 , C07F7/0838 , C07F7/21 , C08F283/12 , C08F290/06 , C08F290/068 , Y10T428/3154 , Y10T428/31663
摘要： A multi-functional (meth)acrylate compound containing at least three F atoms and at least three Si atoms per molecule is provided. A photocurable resin composition comprising the compound can endow support substrates with antifouling properties with respect to organic stains such as oil mist and fingerprints, without detracting from surface mar resistance.
摘要翻译：提供每分子含有至少三个F原子和至少三个Si原子的多官能（甲基）丙烯酸酯化合物。包含该化合物的光固化性树脂组合物可以赋予支撑基材相对于有机污渍如油雾和指纹的防污性能，而不会降低表面耐磨性。

44. 发明授权

US07511089B2 Polyphenylene ether oligomer sulfonic acid salt, making method, flame retardant resin composition, and molded article 失效
标题翻译：聚苯醚低聚物磺酸盐，制备方法，阻燃树脂组合物和模塑制品
公开(公告)号：US07511089B2
公开(公告)日：2009-03-31
申请号：US11220702
申请日：2005-09-08
申请人： Akinari Itagaki , Masaki Tanaka , Masaaki Yamaya , Takahiro Adachi , Yasumasa Norisue , Satoshi Kanayama
发明人： Akinari Itagaki , Masaki Tanaka , Masaaki Yamaya , Takahiro Adachi , Yasumasa Norisue , Satoshi Kanayama
IPC分类号： C08K5/42
CPC分类号： C08L71/126 , C08G59/00 , C08G65/485 , C08L55/02 , C08L63/00 , C08L69/00 , C08L71/12 , C08L83/04 , C08L2666/02 , C08L2666/14 , C08L2666/22 , C08L71/00
摘要： An alkali metal or alkaline earth metal salt of sulfonic acid of polyphenylene ether oligomer is useful as a modifier for thermoplastic resins, typically as a flame retardant, compatibilizing agent or antistatic agent.
摘要翻译：聚苯醚低聚物的磺酸的碱金属或碱土金属盐可用作热塑性树脂的改性剂，通常作为阻燃剂，相容剂或抗静电剂。

45. 发明申请

US20080097066A1 Photocurable and thermosetting coating composition and article having cured coating of such coating composition 有权
标题翻译：光固化和热固性涂料组合物和具有这种涂料组合物固化涂层的制品
公开(公告)号：US20080097066A1
公开(公告)日：2008-04-24
申请号：US11976317
申请日：2007-10-23
申请人： Kazuhiro Tsuchida , Masaaki Yamaya
发明人： Kazuhiro Tsuchida , Masaaki Yamaya
IPC分类号： C08G77/04
CPC分类号： C09D183/04
摘要： A photocurable and thermosetting coating composition which is solventless and liquid at room temperature is provided. This coating composition provides scratch resistance, crack resistance, smudge resistance, and removability of oil-base felted markers by wiping with the underlying substrate, and this coating composition contains a silicone resin represented by: (R1R2R3SiO1/2)a(R4R5SiO2/2)b(R6SiO3/2)c(SiO4/2)d(O1/2X)e (1) wherein X is hydrogen atom or an alkyl group; R1 to R6 are respectively at least one monovalent organic group which is a monovalent aliphatic hydrocarbon group or a monovalent aromatic hydrocarbon group optionally substituted with a substituent such as a poly(hexafluoropropylene oxide) structure-containing group; a, b, d, and e are 0 or a positive number; c is a positive number; and a+b+c+d is 1. The silicone resin contains at least one group represented by: CH2═C(R7)COOCH2— (2) wherein R7 is hydrogen atom or methyl group.
摘要翻译：提供在室温下为无溶剂且液体的光固化性和热固性涂料组合物。该涂料组合物通过用下面的基材擦拭来提供油基毡标记物的耐刮擦性，抗裂纹性，耐污染性和可除去性，并且该涂料组合物含有由以下公式表示的硅酮树脂：<？in-line-formula description =“In “公式”end =“lead”？>（R 1）1 2 （R 4）4（R 5）2 SiO 2/2）（R （SiO 2/2/2）d（SiO 2/2/2）n（SiO 2/2/2）（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X是氢原子或烷基; R 1至R 6分别为至少一个一价有机基团，其为单价脂族烃基或任选被取代基取代的单价芳族烃基，例如聚（六氟环氧丙烷）结构基团; a，b，d和e为0或正数; c是正数; 并且a + b + c + d为1.硅树脂含有至少一个由下式表示的基团：<？in-line-formula description =“In-line Formulas”end =“lead”？> CH 2 （2）<？in-line-formula description =“In-line Formulas”end =“tail”？其中R 7为氢原子或甲基。

46. 发明申请

US20070116971A1 Multi-functional (meth) acrylate compound, photocurable resin composition and article 失效
标题翻译：多官能（甲基）丙烯酸酯化合物，光固化树脂组合物和制品
公开(公告)号：US20070116971A1
公开(公告)日：2007-05-24
申请号：US11602991
申请日：2006-11-22
申请人： Yuji Yoshikawa , Koichi Higuchi , Masaaki Yamaya
发明人： Yuji Yoshikawa , Koichi Higuchi , Masaaki Yamaya
IPC分类号： B32B27/30 , C08L83/00 , B32B9/04
CPC分类号： C09D4/00 , C07F7/0838 , C07F7/21 , C08F283/12 , C08F290/06 , C08F290/068 , Y10T428/3154 , Y10T428/31663
摘要： A multi-functional (meth)acrylate compound containing at least three F atoms and at least three Si atoms per molecule is provided. A photocurable resin composition comprising the compound can endow support substrates with antifouling properties with respect to organic stains such as oil mist and fingerprints, without detracting from surface mar resistance.
摘要翻译：提供每分子含有至少三个F原子和至少三个Si原子的多官能（甲基）丙烯酸酯化合物。包含该化合物的光固化性树脂组合物可以赋予支撑基材相对于有机污渍如油雾和指纹的防污性能，而不会降低表面耐磨性。

47. 发明申请

US20060172136A1 Coated member 审中-公开
标题翻译：涂层会员
公开(公告)号：US20060172136A1
公开(公告)日：2006-08-03
申请号：US11345101
申请日：2006-01-31
申请人： Takashi Komori , Hisashi Muramatsu , Osamu Hidaka , Kenichi Yasunaga , Takayuki Nagai , Masaaki Yamaya , Koichi Higuchi
发明人： Takashi Komori , Hisashi Muramatsu , Osamu Hidaka , Kenichi Yasunaga , Takayuki Nagai , Masaaki Yamaya , Koichi Higuchi
IPC分类号： B32B27/36
CPC分类号： B05D7/53 , B05D2201/00 , Y10T428/31507
摘要： A coated member includes a resinous substrate, a primer layer, and a hard coat layer. The primer layer is formed on a surface of the resinous substrate, and is composed of a resinous primer. The hard coat layer is formed on the primer layer, and contains a flexibility-imparting agent. At least one of the primer layer and the hard coat layer further contains an ultraviolet ray-absorbing agent. The coated member exhibits good weatherability, adhesiveness and crack resistance.
摘要翻译：涂布部件包括树脂基材，底漆层和硬涂层。底漆层形成在树脂基材的表面上，由树脂底漆构成。硬涂层形成在底漆层上，并含有柔性赋予剂。底涂层和硬涂层中的至少一层还含有紫外线吸收剂。涂覆部件具有良好的耐候性，粘合性和抗裂纹性。

48. 发明申请

US20050158566A1 Silicone resin compositions and coated articles 有权
标题翻译：硅树脂组合物和涂层制品
公开(公告)号：US20050158566A1
公开(公告)日：2005-07-21
申请号：US11033840
申请日：2005-01-13
申请人： Koichi Higuchi , Masaaki Yamaya
发明人： Koichi Higuchi , Masaaki Yamaya
IPC分类号： C08G77/14 , C08G77/06 , C08G77/16 , C08G77/18 , C08J7/04 , C09D183/04 , B32B9/04 , C08L83/04
CPC分类号： C08J7/047 , C08G77/06 , C08G77/16 , C08G77/18 , C08J2483/00 , C09D183/04 , Y10T428/31663
摘要： To a silicone resin obtained through cohydrolytic condensation of 100 pbw of a mixture of 1-50 Si mol % of tetraalkoxysilane, 50-99 Si mol % of trialkoxysilane and 0-10 Si mol % of dialkoxysilane with less than 100 pbw of water, having a Mn of at least 1,500 and containing 30-80 mol % of R1SiO3/2 units and 20-70 mol % of R1SiO2/2(OX) and R1SiO1/2(OX)2 units combined, a curing catalyst and a solvent are added to formulate a silicone resin composition. It is applied and heat cured to a plastic substrate to form a protective coat having a high hardness and improved properties such as mar resistance, crack resistance, adhesion, water resistance, heat resistance and weathering resistance.
摘要翻译：对于通过100pbw的1-50Si摩尔％的四烷氧基硅烷，50-99Si摩尔％的三烷氧基硅烷和0-10Si摩尔％的二烷氧基硅烷与少于100pbw的水的共水解缩合而获得的硅树脂，其具有至少1500的Mn和含有30-80摩尔％的R 1 SiO 3/2/2单元和20-70摩尔％的R 1 SUP / > SiO 2/2（OX）和R 1 SiO 2 1/2（OX）2单元组合，加入固化催化剂和溶剂以配制有机硅树脂组合物。将其施加并热固化到塑料基材上以形成具有高硬度和改进性能如耐损伤性，抗裂性，粘合性，耐水性，耐热性和耐候性的保护涂层。

49. 发明授权

US06727303B2 Flame retardant aromatic polycarbonate resin composition and molded articles thereof 有权
标题翻译：阻燃性芳香族聚碳酸酯树脂组合物及其成型体
公开(公告)号：US06727303B2
公开(公告)日：2004-04-27
申请号：US10229221
申请日：2002-08-28
申请人： Tetsushi Ono , Akinari Itagaki , Masaaki Yamaya , Yoshiteru Kobayashi
发明人： Tetsushi Ono , Akinari Itagaki , Masaaki Yamaya , Yoshiteru Kobayashi
IPC分类号： C08K524
CPC分类号： C08L67/02 , C08L25/00 , C08L83/00
摘要： A flame retardant aromatic polycarbonate resin composition comprising: (1) 100 parts by weight of resin components comprising 50 to 100 wt % of an aromatic polycarbonate resin (component A-1), 0 to 50 wt % of a styrene-based resin (component A-2) and 0 to 50 wt % of an aromatic polyester resin (component A-3); and (2) 0.1 to 10 parts by weight of a silicone compound (component B) which contains an Si—H group and an aromatic group in the molecule based on 100 parts by weight of the total of the resin components, wherein the silicone compound is at least one selected from silicone compounds which have (1) an Si—H group content (Si—H content) of 0.1 to 1.2 mols/100 g and (2) a content of an aromatic group represented by the following general formula (1) (aromatic group content) of 10 to 70 wt %: wherein X's are each independently an OH group or the residual monovalent organic group having 1 to 20 carbon atoms, and n is 0 or an integer of 1 to 5, with the proviso that when n is 2 or more, X's can differ from one another, and molded articles thereof. A halogen-free polycarbonate resin composition having excellent transparency and dripping preventing properties and molded articles thereof are provided according to the present invention.
摘要翻译：一种阻燃芳族聚碳酸酯树脂组合物，其包含：（1）100重量份的包含50至100重量％的芳族聚碳酸酯树脂（组分A-1），0至50重量％的苯乙烯基树脂（组分 A-2）和0〜50重量％的芳香族聚酯树脂（A-3成分）。和（2）分子中含有Si-H基和芳香族基团的硅氧烷化合物（B成分）为0.1〜10重量份，相对于树脂成分的总量为100重量份，硅化合物为选自（1）Si-H基含量（Si-H含量）为0.1〜1.2摩尔/ 100g的硅酮化合物中的至少一种，（2）由以下通式（1）表示的芳香族基团的含量）（芳族基团含量）为10〜70重量％：其中X分别独立地为OH基或碳原子数1〜20的残存的一价有机基，n为0或1〜5的整数，条件是当n为2以上时，X可以彼此不同，以及其成型体。根据本发明提供了具有优异的透明性和防滴落性的无卤聚碳酸酯树脂组合物及其成型体。

50. 发明授权

US06656598B2 Aqueous coating composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US06656598B2
公开(公告)日：2003-12-02
申请号：US09973768
申请日：2001-10-11
申请人： Muneo Kudo , Masaaki Yamaya
发明人： Muneo Kudo , Masaaki Yamaya
IPC分类号： B32B904
CPC分类号： C09D183/08 , C08K5/06 , Y10T428/31663 , C08L83/08 , C08L2666/34 , C08L2666/14
摘要： An aqueous coating composition including (A) an amino group-containing organopolysiloxane, (B) water and (C) at least one of a surface-active agent represented by the general formula (I): wherein R1 to R4are a C1-C8 alkyl group, R5 and R6 are a C1-C6 alkylene group, R7 and R8 are selected from a hydrogen atom, a C1-C6 alkyl group and a C2-C6 acyl group, and m and n are an integer of 0 to 40, provided that m and n are not 0 at the same time and that of m+n ranges from 1 to 40 on the average; and a nonionic surface-active agent containing a perfluoroalkyl group and an alkylene oxide group. In the composition, (C) is present in a content of 0.01% to 5% by weight based on the total of (A), (B) and (C), and an alcohol is present in an amount not more than 10% by weight of the composition. The aqueous coating composition has superior uniform-coating properties and storage stability.
摘要翻译：一种水性涂料组合物，其包含（A）含氨基的有机聚硅氧烷，（B）水和（C）由通式（I）表示的表面活性剂中的至少一种：其中R 1至R 4 >是C 1 -C 8烷基，R 5和R 6是C 1 -C 6亚烷基，R 7和R 8选自氢原子，C 1 -C 6烷基和 C2-C6酰基，m和n为0〜40的整数，条件是m和n不同时为0，m + n的平均值为1〜40; 和含有全氟烷基和环氧烷基的非离子表面活性剂。在组合物中，（C）的含量相对于（A），（B）和（C）的总量为0.01〜5重量％，醇的含量不超过10重量％的组合物。水性涂料组合物具有优异的均匀涂布性能和储存稳定性。

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