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    • 48. 发明申请
    • MOLDING MATERIALS COMPRISING HIGHLY CROSSLINKED ORGANIC NANOPARTICLES
    • 包含高交联有机纳米颗粒的成型材料
    • US20100036041A1
    • 2010-02-11
    • US12445138
    • 2007-10-02
    • Marc SchröderAndreas EipperMatthias ScheibitzHiroki FukuharaJens Assmann
    • Marc SchröderAndreas EipperMatthias ScheibitzHiroki FukuharaJens Assmann
    • C08L67/00
    • C08L67/00C08L25/04C08L67/02C08L77/00C08L2666/04C08L2666/06
    • Thermoplastic molding compositions, comprisingE) from 10 to 99.9% by weight of a thermoplastic polymer,F) from 0.01 to 10% by weight of a copolymer obtainable via free-radical-initiated aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of at least one dispersing agent and of at least one free-radical initiator by the feed process, where the emulsion polymerization uses from 70 to 99.5% by weight of α,β-monoethylenically unsaturated compounds [monomers A], and from 0.5 to 30% by weight of compounds having at least two ethylenically unsaturated groups capable of free-radical copolymerization [monomers B], and also, if appropriate, up to 5% by weight of α,β-monoethylenically unsaturated mono- or dicarboxylic acids having from 3 to 6 carbon atoms and/or their amides [monomers C], where the monomers A to C give a total of 100% by weight (entire amount of monomers) and the monomer feeds take place in such a way that ≧60% by weight of the entire amount of monomers B are fed to the polymerization mixture under polymerization conditions at a juncture after ≧60% by weight of the entire amount of monomer have been fed to the polymerization mixture under polymerization conditions, from 0 to 70% by weight of further additives,where the total of the percentages by weight of components A) to C) gives 100%.
    • 热塑性模塑组合物,其包含E)10至99.9重量%的热塑性聚合物,F)0.01至10重量%的共聚物,其通过烯键式不饱和单体的自由基引发的水乳液聚合在有 至少一种分散剂和至少一种自由基引发剂,其中乳液聚合使用70-99.5重量%的α,β-单烯属不饱和化合物[单体A]和0.5-30重量% 具有至少两个能够自由基共聚的烯属不饱和基团(单体B)的化合物的重量,以及如果合适的话,至多5重量%的具有3至6个碳原子的α,β-单烯属不饱和单或二羧酸 碳原子和/或它们的酰胺[单体C],其中单体A至C的总量为100重量%(单体的总量),并且单体进料的发生方式使得≥60重量% e 在聚合条件下,在聚合条件下,在聚合条件下,聚合条件下,在聚合条件下,在聚合条件下,将0〜70重量%的全部量的单体进料量= 60重量% 添加剂,其中组分A)至C)的重量百分比的总和给出100%。