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41. 发明授权

US06248415B1 Aqueous polyurethane dispersions having improved water and solvent resistance 失效
标题翻译：具有改善的耐水和耐溶剂性的水性聚氨酯分散体
公开(公告)号：US06248415B1
公开(公告)日：2001-06-19
申请号：US09118657
申请日：1998-07-17
申请人： Josef Pedain , Eberhard Arning , Dieter Mager , Lutz Schmalstieg , Ronald-Karl Jerg
发明人： Josef Pedain , Eberhard Arning , Dieter Mager , Lutz Schmalstieg , Ronald-Karl Jerg
IPC分类号： C08J300
CPC分类号： C08G18/6659 , C08G18/0823 , C08G18/7837 , Y10T428/16 , Y10T428/167 , Y10T428/31551 , Y10T428/31591 , Y10T428/31989
摘要： The present invention relates to aqueous polyurethane dispersions prepared from a polyisocyanate component and one or more isocyanate-reactive compounds wherein at least 5% by weight of polyisocyanate component is a diisocyanate corresponding to formula (I) wherein R is a difunctional, C4 to C18, aliphatic, cycloaliphatic or aromatic hydrocarbon residue obtained by removing the NCO groups from an organic diisocyanate and R′ is a monofunctional, C1 to C18 hydrocarbon radical, which may contain ether oxygen atoms. The present invention also relates to the use of these PUR dispersions for coating any substrates, preferably wood substrates, such as parquet flooring.
摘要翻译：本发明涉及由多异氰酸酯组分和一种或多种异氰酸酯反应性化合物制备的水性聚氨酯分散体，其中至少5重量％的多异氰酸酯组分是对应于式（I）的二异氰酸酯，其中R是双官能的，C 4至C 18的脂族，通过从有机二异氰酸酯除去NCO基团而获得的脂环族或芳族烃残基，R'是可以含有醚氧原子的单官能的C1-C18烃基。本发明还涉及这些PUR分散体用于涂覆任何基材，优选木质基材，例如镶木地板。

42. 发明授权

US5925711A Polyamines and their use in aqueous coating compositions 失效
标题翻译：多胺及其在水性涂料组合物中的用途
公开(公告)号：US5925711A
公开(公告)日：1999-07-20
申请号：US882852
申请日：1997-06-26
申请人： Christian Wamprecht , Hans-Josef Laas , Jurgen Meixner , Josef Pedain
发明人： Christian Wamprecht , Hans-Josef Laas , Jurgen Meixner , Josef Pedain
IPC分类号： C08G18/32 , C08G18/46 , C08G18/64 , C08G18/70 , C08G73/00 , C08G73/02 , C08L79/08 , C09D5/00 , C09D175/04 , C09D179/08 , C09J179/02 , C07C209/16
CPC分类号： C08G18/6415 , C08G18/4669 , C08G18/706 , C08G73/02 , C08G73/028 , C08L79/08 , C09D179/08 , C09J179/02 , C08G2261/135 , C08G2261/334 , C08G2261/76
摘要： The present invention relates to polyamines which are the reaction products ofa) unsaturated oligoesters containing an average of 2 to 4 double bonds per molecule andb) optionally other unsaturated compounds which are suitable as Michael addition acceptors and which contain an average of 1 to 4 double bonds per molecule, withc) (cyclo)aliphatic diamines which contain two primary amino groups, andd) optionally other amino-functional compounds which are suitable as Michael addition donors.The present invention also relates to aqueous, two-component coating compositions containing as binderA) the polyamines according to the invention andB) water dispersible polyisocyanates, andto coatings obtained from these coating compositions.
摘要翻译：本发明涉及多胺，其为a）每分子平均含有2〜4个双键的不饱和低聚酯的反应产物，以及b）任选的其它适合作为迈克尔加成受体的不饱和化合物，其平均含有1至4个每个分子具有双键，c）（环）脂族二胺，其含有两个伯氨基，以及d）任选的其它适合作为迈克尔加成供体的氨基官能化合物。本发明还涉及包含作为粘合剂A）本发明的多胺和B）水分散性多异氰酸酯的水性双组分涂料组合物以及由这些涂料组合物获得的涂料。

43. 发明授权

US5882544A Polycyclic iminooxadiazinediones from (cyclo)aliphatic 1,4-diisocyanates 失效
标题翻译：（环）脂族1,4-二异氰酸酯的多环亚氨基恶二嗪二酸酯
公开(公告)号：US5882544A
公开(公告)日：1999-03-16
申请号：US989066
申请日：1997-12-11
申请人： Frank Richter , Dieter Mager , Josef Pedain
发明人： Frank Richter , Dieter Mager , Josef Pedain
IPC分类号： C07D498/04 , C08G18/00 , C08G18/79 , C08G101/00 , C09D175/04 , C09K3/12 , A61K31/535 , C07D267/14 , C07D273/04
CPC分类号： C07D498/04 , C08G18/79 , C08G2101/00 , C08G2150/20
摘要： The present invention relates to polycyclic iminooxadiazinediones A corresponding to formula I ##STR1## The present invention also relates to mixtures of these polycyclic iminooxadiazinediones with other isocyanate derivatives and to their use for the production of optionally foamed polyurethane plastics, for the production of paints and coatings and for the production or formulation of active ingredients, pharmaceutical products, etc.
摘要翻译：本发明涉及对应于式I的多环亚氨基恶二嗪二酮A（I）本发明还涉及这些多环亚氨基恶二嗪二酸与其它异氰酸酯衍生物的混合物及其用于生产任选发泡聚氨酯塑料的用途，用于生产油漆和涂料以及生产或配制活性成分，药品等。

44. 发明授权

US5747582A Aqueous coating compositions and their use for the preparation of coatings that are permeable to water vapor 失效
标题翻译：水性涂料组合物及其用于制备可渗透水蒸气的涂料的用途
公开(公告)号：US5747582A
公开(公告)日：1998-05-05
申请号：US460178
申请日：1995-06-02
申请人： Detlef-Ingo Schutze , Wilhelm Thoma , Klaus Nachtkamp , Josef Pedain , Reinold Schmitz
发明人： Detlef-Ingo Schutze , Wilhelm Thoma , Klaus Nachtkamp , Josef Pedain , Reinold Schmitz
IPC分类号： C08G18/08 , C08G18/28 , C08G18/44 , C08G18/50 , C14C11/00 , D06N3/14 , D21H19/62 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/0823 , C08G18/0804 , C08G18/0828 , C08G18/283 , C08G18/3228 , C08G18/3231 , C08G18/3855 , C08G18/44 , C08G18/5072 , C08G18/73 , C14C11/006 , D06N3/14 , D21H19/62 , Y10T428/31551 , Y10T428/31558 , Y10T428/31591
摘要： The invention relates to coating compositions used to prepare coatings having water vapor permeabilities of at least 2500 g/m.sup.2 per day (DS 2109 TM1 method) containing (A) a polyurethane containing (1) 0.1 to 75 meq/100 g of ionic groups and (2) 11 to 50% by weight of --(CH.sub.2 CH.sub.2 O).sub.n -- units (wherein n is 2 to 25) incorporated into the main chain prepared from reactive components comprising (I) one or more polyisocyanates, (II) one or more polyols having a number average molecular weight of 350 to 5000, with the proviso that if any such polyol is a sulfonated polyether diol having the formula ##STR1## in which R is hydrogen or an organic group having 1 to 8 carbon atoms, m and n are 1 to 10, p is 0, 1, or 2, and M is ammonium or alkali metal cation, then an additional ethoxy-containing polyether polyol must also be present, and (III) one or more chain lengthening agents having a molecular weight of 32 to 349; and (B) 30 to 80% by weight, based on the sum of components (A) and (B), of an aqueous phase.
摘要翻译：本发明涉及用于制备具有每天至少2500g / m 2的水蒸汽渗透性（DS 2109 TM1方法）的涂层的涂料组合物，其包含（A）含有（1）0.1至75meq / 100g离子基团的聚氨酯和（2）由反应性组分制备的包含（I）一种或多种多异氰酸酯的主链中的 - （CH 2 CH 2 O）n-单元（其中n为2至25）的11至50重量％，（II）一种或多种多元醇数均分子量为350至5000，条件是如果任何这样的多元醇是具有式“IMAGE”的磺化聚醚二醇，其中R是氢或具有1至8个碳原子的有机基团，m和n分别为 1至10，p为0,1或2，M为铵或碱金属阳离子，则还必须含有另外的含乙氧基的聚醚多元醇，和（III）一种或多种链增长剂，其分子量为 32至349; 和（B）基于水相的组分（A）和（B）的总和为30至80重量％。

45. 发明授权

US5710209A Aqueous binders for coating compositions based on polyester polyurethanes 失效
标题翻译：用于基于聚酯聚氨酯的涂料组合物的水性粘合剂
公开(公告)号：US5710209A
公开(公告)日：1998-01-20
申请号：US602539
申请日：1996-02-20
申请人： Harald Blum , Josef Pedain
发明人： Harald Blum , Josef Pedain
IPC分类号： C08G18/00 , C08G18/08 , C08G18/42 , C08G18/66 , C08G18/73 , C08G18/75 , C09D5/00 , C09D175/06 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C09D175/06 , C08G18/0819 , C08G18/4288 , C08G18/6659 , C08G18/751
摘要： An aqueous dispersion of a polyester polyurethane which contains as essential building component 1-methyl-2,4- and/or -2,6-diisocyanatocyclohexane and its use as the binder for one- or two-component coating compositions, optionally in combination with cross-linking agent resins selected from optionally blocked polyisocyanates and/or aminoplast resins.
摘要翻译：聚酯聚氨酯的水性分散体，其含有作为必要的构建成分1-甲基-2,4-和/或-2,6-二异氰酸基环己烷及其作为单组分或双组分涂料组合物的粘合剂的用途，任选地与选自任选封闭的聚异氰酸酯和/或氨基塑料树脂的交联剂树脂。

46. 发明授权

US5623045A Process for the preparation of coatings 失效
标题翻译：涂料制备工艺
公开(公告)号：US5623045A
公开(公告)日：1997-04-22
申请号：US430045
申请日：1995-04-27
申请人： Christian Zwiener , Reinhard Halpaap , Josef Pedain , Wolfgang Kiel
发明人： Christian Zwiener , Reinhard Halpaap , Josef Pedain , Wolfgang Kiel
IPC分类号： B05D7/24 , B05D7/14 , C08G18/30 , C08G18/32 , C08G18/38 , C09D175/00
CPC分类号： C08G18/3821 , C08G18/3256 , C08G18/3262
摘要： A process for the preparation of coatings using a coating composition having a binder containing a two-component system of a) a polyisocyanate component and b) an isocyanate-reactive component b) which is essentially free from hydroxyl groups and contains b1) 5 to 95 parts by weight of a polyamine containing ester groups and secondary amino groups and b2) 5 to 95 parts by weight of polyketimines.
摘要翻译：一种使用具有包含a）多异氰酸酯组分和b）基本上不含羟基的异氰酸酯反应性组分b）的含有双组分体系的粘合剂的涂料组合物制备涂料的方法，并且含有b1）5至95 重量份的含多胺的酯基和仲氨基，和b2）5至95重量份的聚酮亚胺。

47. 发明授权

US5334637A Isocyanatocarboxylic acids, a process for their preparation and their use in coating compositions as cross-linking agents 失效
标题翻译：异氰酸酯羧酸，其制备方法及其在涂料组合物中作为交联剂的用途
公开(公告)号：US5334637A
公开(公告)日：1994-08-02
申请号：US988663
申请日：1992-12-10
申请人： Christian Zwiener , Rainer Rettig , Klaus Nachtkamp , Josef Pedain , Dieter Arlt
发明人： Christian Zwiener , Rainer Rettig , Klaus Nachtkamp , Josef Pedain , Dieter Arlt
IPC分类号： C08G18/77 , C07C263/16 , C07C265/04 , C07C265/10 , C07C265/14 , C07C271/20 , C07C271/24 , C08G18/70 , C08G18/75 , C08G18/80 , C09D175/00 , C09D175/04 , C08J3/00 , C08K3/20 , C08L51/00 , C08L75/00
CPC分类号： C07C271/24 , C07C271/20 , C08G18/706 , C08G18/756 , C08G18/8048 , C07C2101/14
摘要： The present invention relates to isocyanatocarboxylic acids containinga) 1 to 30% by weight of isocyanate groups attached to (cyclo)aliphatic tertiary carbon atoms andb) 0.5 to 500 milliequivalents, per 100 g of isocyanatocarboxylic acids, of carboxyl groups which may be at least partially present in carboxylate salt form.The present invention also relates to a process for the preparation of these isocyanatocarboxylic acids and to their use as cross-linking agents for aqueous coating compositions.
摘要翻译：本发明涉及异氰酸酯基羧酸，其含有a）1〜30重量％的连接于（环）脂肪族叔碳原子的异氰酸酯基团，b）每100克异氰酸酯羧酸0.5〜500毫当量，羧基可以在最少部分以羧酸盐形式存在。本发明还涉及制备这些异氰酸酯基羧酸的方法及其作为水性涂料组合物的交联剂的用途。

48. 发明授权

US5276125A Heat-curable coating compositions 失效
标题翻译：热固化涂料组合物
公开(公告)号：US5276125A
公开(公告)日：1994-01-04
申请号：US616546
申请日：1990-11-21
申请人： Josef Pedain , Wilhelm Thoma , Walter Schroer , Waldemar Kling , Manfred Dietrich
发明人： Josef Pedain , Wilhelm Thoma , Walter Schroer , Waldemar Kling , Manfred Dietrich
IPC分类号： C08G18/65 , C08G18/08 , C08G18/10 , C08G18/40 , C09D175/00 , C09D175/04 , C08G18/81
CPC分类号： C08G18/10 , C08G18/0819 , C08G18/40 , C08G18/409 , C09D175/04
摘要： The present invention relates to heat-curable coating compositions containingA) a prepolymer having an average of 2-4 ketoxime-blocked NCO groups, having an average moleculer weight of 500-15,000 and prepared from aliphatic, cycloaliphatic and aromatic polyisocyanates and one or more polyhydroxy components which contain 0 to 30% by weight of ethylene oxide units andB) a crosslinking agent of the formula ##STR1## wherein R and R.sup.1 represent H or C.sub.1 -C.sub.4 -alkyl, the ratio of equivalents of blocked NCO groups in A) to NH.sub.2 groups in B) being 1.35:1 to 0.95:1, characterized in that at least one of the polyhydroxy compounds used for the preparation of the prepolymer contains, in stable dispersion, a polyurethane, a polyurethane-urea and/or a polyurea, which is substantially free from NCO groups, hydroxyl groups and amino groups and which are synthesized from aromatic, aliphatic and/or cycloaliphatic diisocyanates and from diamines, hydrazine and/or diols, provided that at least one of these components carries a radical having hydrophilic characteristics.The present invention also relates to the use of these coating compositions in a process for the coating, particularly water vapor-permeable coating, of substrates, preferably textile sheet-like structures and leather.
摘要翻译：本发明涉及可热固化的涂料组合物，其包含A）具有平均2-4个酮肟封闭的NCO基团的预聚物，其平均分子量为500-15,000，并由脂族，脂环族和芳族多异氰酸酯和一种或多种含有0至30重量％环氧乙烷单元的多羟基组分和B）式（*化学结构*）的交联剂，其中R和R 1表示H或C 1 -C 4烷基，封闭的NCO基团的当量比在A）中的B）中的NH 2基团为1.35:1至0.95:1，其特征在于用于制备预聚物的至少一种多羟基化合物以稳定的分散体含有聚氨酯，聚氨酯 - 脲和/ 或基本上不含NCO基团，羟基和氨基并且由芳族，脂族和/或脂环族二异氰酸酯和二胺，肼和/或二醇合成的聚脲，条件是至少这些组分之一携带具有亲水特性的基团。本发明还涉及这些涂料组合物在基材，优选纺织片状结构和皮革的涂覆，特别是水蒸气可渗透涂层的方法中的用途。

49. 发明授权

US5219975A Process for the preparation of amines, the amines thus obtained and the use thereof as hardeners for epoxide resins 失效
标题翻译：制备氨基酸的方法，获得的氨基酸及其作为环氧化物树脂硬化剂的用途
公开(公告)号：US5219975A
公开(公告)日：1993-06-15
申请号：US696901
申请日：1991-05-07
申请人： Lutz Schmalstieg , Karl-Heinz Hentschel , Josef Pedain , Klaus Nachtkamp
发明人： Lutz Schmalstieg , Karl-Heinz Hentschel , Josef Pedain , Klaus Nachtkamp
IPC分类号： C08G18/10 , C08G18/32 , C08G18/80 , C08G59/00 , C08G59/50 , C08L63/00
CPC分类号： C08G18/10 , C08L63/00
摘要： The present invention is directed to a process for the preparation of amines containing urethane and urea groups. The amines are produced by reacting A) isocyanate prepolymers containing urethane groups and in which the isocyanate groups are reversibly blocked with secondary monoamines with B) amines having molecular weights of from 60 to 500, which are at least difunctional and which have a total of at least two primary or secondary amino groups, with splitting off of the secondary monoamine. The invention is also directed to the amines so produced and to the use as a hardener for an epoxide resin.
摘要翻译：本发明涉及一种制备含氨基甲酸酯和脲基的胺的方法。胺是通过使A）含有氨基甲酸酯基团的异氰酸酯预聚物与其中异氰酸酯基团与二级单胺可逆地封端的B）制备的，B）分子量为60至500的胺，其至少是双官能的，并且总共在至少两个伯或仲氨基，分离出次级单胺。本发明还涉及如此制备的胺和用作环氧树脂的硬化剂的用途。

50. 发明授权

US5081203A Moisture-hardening coating composition and method for its production 失效
标题翻译：水分硬化涂料组合物及其生产方法
公开(公告)号：US5081203A
公开(公告)日：1992-01-14
申请号：US543641
申请日：1990-06-26
申请人： Josef Pedain , Jurgen Schwindt , Theodor Engbert , Manfred Schonborn
发明人： Josef Pedain , Jurgen Schwindt , Theodor Engbert , Manfred Schonborn
IPC分类号： C08G18/10 , C08G18/30 , C08G18/76 , C08G18/80 , C09D175/00 , C09D175/04
CPC分类号： C08G18/8064 , C08G18/10 , C08G18/302 , C08G18/7664
摘要： The present invention relates to of a coating composition containing a moisture-hardening binder based on organic polyisocyanates which is prepared by forming a mixture containing at least those auxiliaries and additives which are not completely dry and an isocyanate component a) which has an average NCO functionality of 1.05 to 1.8 and is based on the reaction product ofa1) a polyisocyanate mixture of the diphenylmethane series witha2) a monohydric C.sub.1-26 alkanol which may contain ether bridges,and after the isocyanate/water reaction is substantially complete, further mixing the mixture with an isocyanate component b) which has an isocyanate content of 2.5 to 25% by weight and any remaining auxiliaries and additives, the quantities of components a) and b) corresponding to a weight ratio of a) to b) of 1:1 to 1:30.The present invention also relates to a process for the preparation of these coating compositions.
摘要翻译：本发明涉及包含基于有机多异氰酸酯的湿固化粘合剂的涂料组合物，其通过形成至少含有那些不完全干燥的那些助剂和添加剂的混合物和具有平均NCO官能度的异氰酸酯组分a）为1.05〜1.8，并且基于a1）二苯基甲烷系列的多异氰酸酯混合物与a2）可能含有醚桥的一元C1-26链烷醇的反应产物，并且在异氰酸酯/水反应基本上完成后，进一步混合与异氰酸酯含量为2.5至25重量％的异氰酸酯组分b）和任何其余助剂和添加剂的混合物，a）和b）的组分的量对应于a）至b）的重量比为1:1 至1:30。本发明还涉及制备这些涂料组合物的方法。

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