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41. 发明授权

US08120245B2 Interdigitated electrode dual electroemissive/electrochromic devices 有权
标题翻译：交叉电极双电子发射/电致变色器件
公开(公告)号：US08120245B2
公开(公告)日：2012-02-21
申请号：US12936854
申请日：2009-04-15
申请人： John R. Reynolds , Aubrey Lynn Dyer
发明人： John R. Reynolds , Aubrey Lynn Dyer
IPC分类号： H01J1/62 , G02F1/153 , H01L29/04
CPC分类号： H01L51/5203 , G02F1/155
摘要： A dual electrochromic/electroluminescent (EC/EL) device of at least one pixel includes an interdigitated electrode where an electroactive layer is dispersed on and between the digits of the two electrodes of the interdigitated electrode. The electroactive layer is in contact with an electrolyte layer that also contacts a third electrode. The device acts as an electroluminescence device when an electrical bias between the two electrodes of the interdigitated electrode is established. The device acts as an electrochromic device when the electrical bias is established between the combined electrodes of the interdigitated electrode and the third electrode.
摘要翻译：至少一个像素的双电致变色/电致发光（EC / EL）器件包括交叉电极，其中电活性层分散在交叉电极的两个电极的数位之间和之间。电活性层与也与第三电极接触的电解质层接触。当建立交叉电极的两个电极之间的电偏压时，该器件用作电致发光器件。当在交叉电极和第三电极的组合电极之间建立电偏压时，器件用作电致变色器件。

42. 发明申请

US20110251370A1 BLACK SOLUBLE CONJUGATED POLYMERS WITH HIGH CHARGE CARRIER MOBILITIES 有权
标题翻译：具有高充电承载力的黑色可溶性聚合物
公开(公告)号：US20110251370A1
公开(公告)日：2011-10-13
申请号：US13130697
申请日：2009-11-25
申请人： Pierre Marc Beaujuge , John R. Reynolds , Stefan Martin Ellinger , Chad Martin Amb
发明人： Pierre Marc Beaujuge , John R. Reynolds , Stefan Martin Ellinger , Chad Martin Amb
IPC分类号： C08G77/60 , C08G75/32
CPC分类号： C08G61/126 , C08G77/52 , C08G79/14 , C08G2261/3142 , C08G2261/3223 , C08G2261/3243 , C08G2261/3247 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0094 , H01L51/0558 , H01L51/42
摘要： A soluble fused donor-acceptor conjugated polymer (fDA-CP) is prepared that absorbs light throughout nearly all the visible spectrum and is essentially black to the human eye when in the neutral state. The conjugated polymer has acceptor units that are isolated by a plurality of fused donor units. The fDA-CP assumes a conformation that results in a close π-stacking between adjacent lamella with a separation of less than 4.5 Å in the solid state and extended conjugation to promote high charge carrier mobilities. The fDA-CP is prepared by the polycondensation of a plurality of at least one fused donor-acceptor oligomer (fDA-oligomer) that has a flat internal acceptor unit and at least one fused donor unit incorporated in the oligomers, and optionally, an additional conjugated aromatic monomer or oligomer copolymerized with the fDA-oligomers.
摘要翻译：制备可溶性融合供体 - 受体共轭聚合物（fDA-CP），其在几乎所有可见光谱下吸收光，当处于中性状态时，其基本上为黑色。共轭聚合物具有由多个融合供体单元分离的受体单元。 fDA-CP假设一个构象，导致相邻薄片之间的密集和堆叠，在固态下分离小于4.5，扩展共轭以促进高电荷载流子迁移率。 fDA-CP通过多个至少一个具有平坦的内部受体单元的融合供体 - 受体寡聚物（fDA-低聚物）的缩聚和至少一个结合到低聚物中的融合供体单元，以及任选的另外共轭芳族单体或低聚物与fDA-低聚物共聚。

43. 发明申请

US20100265562A1 DUAL ACTIVE FILM ELECTROCHROMIC DISPLAY DEVICE 有权
标题翻译：双活性薄膜电致发光显示装置
公开(公告)号：US20100265562A1
公开(公告)日：2010-10-21
申请号：US12746541
申请日：2009-03-24
申请人： John R. Reynolds , Aubrey Lynn Dyer , Ece Unur
发明人： John R. Reynolds , Aubrey Lynn Dyer , Ece Unur
IPC分类号： G02F1/15
CPC分类号： G02F1/155 , G02F1/15 , G02F1/1521 , G02F2001/1515 , G02F2001/1552 , G02F2001/1555
摘要： A dual active electrochromic device is a combination of at least two working electrodes that contain electrochromic materials and at least one counter electrode where the potentials between each working electrode and a counter electrode are independently supplied. No more than one electrode is reflective. The color of the device results from the additive color of the electrochromic materials and varies according to the potentials applied independently. The electrochromic materials can be electrochromic polymers that are deposited as film on substrates to form the working electrodes. The electrochromic device can be used for display or window applications.
摘要翻译：双活性电致变色装置是包含电致变色材料的至少两个工作电极和至少一个相对电极的组合，其中每个工作电极和对电极之间的电位被独立地供给。不超过一个电极是反射的。设备的颜色来自电致变色材料的添加颜色，并根据独立应用的电位而变化。电致变色材料可以是在基底上作为膜沉积以形成工作电极的电致变色聚合物。电致变色装置可用于显示或窗口应用。

44. 发明申请

US20100207074A1 HIGHLY ACCESSIBLE, NANOTUBE ELECTRODES FOR LARGE SURFACE AREA CONTACT APPLICATIONS 审中-公开
标题翻译：高可接触性，用于大面积面积的纳米电极接触应用
公开(公告)号：US20100207074A1
公开(公告)日：2010-08-19
申请号：US12732438
申请日：2010-03-26
申请人： Andrew Gabriel Rinzler , John R. Reynolds , Rajib Kumar Das
发明人： Andrew Gabriel Rinzler , John R. Reynolds , Rajib Kumar Das
IPC分类号： H01B1/04 , D01F9/12
CPC分类号： H01G11/36 , B82Y10/00 , H01L51/444 , Y02E60/13 , Y10S977/75 , Y10T428/24603
摘要： An highly porous electrically conducting film that includes a plurality of carbon nanotubes, nanowires or a combination of both. The highly porous electrically conducting film exhibits an electrical resistivity of less than 0.1 Ω·cm at 25 C and a density of between 0.05 and 0.70 g/cm3. The film can exhibit a density between 0.50 and 0.85 g/cm3 and an electrical resistivity of less than 6×10−3 Ω·cm at 25 C. Also included is a method of forming these highly porous electrically conducting films by forming a composite film using carbon nanotubes or nanowires and sacrificial nanoparticles or microparticles. At least a portion of the nanoparticles or microparticles are then removed from the composite film to form the highly porous electrically conducting film.
摘要翻译：包括多个碳纳米管，纳米线或两者的组合的高度多孔的导电膜。高度多孔的导电膜在25℃下的电阻率小于0.1Ω·cm·cm，密度为0.05-0.70g / cm3。该膜可以在25℃下显示出0.50至0.85g / cm 3的密度和小于6×10-3＆OHgr·cm的电阻率。还包括通过形成复合材料形成这些高度多孔的导电膜的方法使用碳纳米管或纳米线和牺牲纳米颗粒或微粒的膜。然后从复合膜中除去至少一部分纳米颗粒或微粒，以形成高度多孔的导电膜。

45. 发明申请

US20100038597A1 ELECTROACTIVE POLYMERS CONTAINING PENDANT PI-INTERACTING/BINDING SUBSTITUENTS, THEIR CARBON NANOTUBE COMPOSITES, AND PROCESSES TO FORM THE SAME 有权
标题翻译：含有PI相互作用/结合取代基的电动聚合物，其碳纳米管复合材料及其形成方法
公开(公告)号：US20100038597A1
公开(公告)日：2010-02-18
申请号：US12445429
申请日：2007-10-11
申请人： John R. Reynolds , Ryan M. Walczak , Andrew G. Rinzler
发明人： John R. Reynolds , Ryan M. Walczak , Andrew G. Rinzler
IPC分类号： H01B1/12
CPC分类号： C09D5/24 , G02F2001/1515 , H01B1/24 , H01L51/0039 , H01L51/0043 , H01L51/0054
摘要： A composition of matter comprises a polymer with a fully conjugated backbone or a conjugated block with a plurality of binding groups connected to the backbone by a linking moiety. The binding groups permit a non-covalent binding to a graphitic surface such as a carbon nanotube. A composition of matter where an electroactive polymer with binding groups connected to a conjugated backbone through a linking moiety is bound to carbon nanotubes. Such compositions can be used for a variety of applications using electroactive materials.
摘要翻译：物质组合物包含具有完全共轭骨架的聚合物或具有多个通过连接部分连接至主链的结合基团的共轭嵌段。结合基团允许与石墨表面如碳纳米管非共价结合。其中具有通过连接部分与共轭骨架连接的结合基团的电活性聚合物与碳纳米管结合的物质组合物。这种组合物可用于使用电活性材料的各种应用。

46. 发明授权

US06261040B1 Self-tapping fastener 有权
标题翻译：自攻紧固件
公开(公告)号：US06261040B1
公开(公告)日：2001-07-17
申请号：US09560773
申请日：2000-04-28
申请人： John R. Reynolds , Alan Pritchard
发明人： John R. Reynolds , Alan Pritchard
IPC分类号： F16B2500
CPC分类号： B21K1/56 , B21K1/46 , F16B25/0021 , F16B25/0078
摘要： A self-tapping fastener is provided. The fastener is formed from a blank having an odd number of lobes along a cross section taken perpendicular to its axis of rotation. The lobes define a relatively high out-of-round cross section along a tapered thread-forming zone, and a relatively low out-of-round cross section along the main body taken in a direction toward the drive head. Between the main body and tapered thread-forming zone is located an additional thread forming zone having an axial length of approximately one thread pitch and a cross section that conforms to the high out-of-round of the tapered zone. The maximum diameter (at the lobes) of the additional thread-forming section approximately matches that of the full-diameter main body section. A lower-diameter stabilizing section can be provided ahead of the tapered zone, adjacent the tip of the fastener.
摘要翻译：提供自攻式紧固件。紧固件由沿着垂直于其旋转轴线截取的横截面具有奇数数量的凸角的坯件形成。叶片沿着锥形螺纹形成区域限定相对较高的非圆形横截面，沿着主体沿朝向驱动头的方向截取的相对较小的非圆形横截面。在主体和锥形螺纹形成区之间设有一个额外的螺纹形成区，其具有大约一个螺距的轴向长度和符合锥形区的高度不圆形的横截面。附加线形成部分的最大直径（在叶片处）与全直径主体部分的最大直径大致匹配。可以在紧邻紧固件的尖端的锥形区域的前方设置下直径稳定部。

47. 发明授权

US10115972B2 Single wall carbon nanotube based air cathodes 有权
公开(公告)号：US10115972B2
公开(公告)日：2018-10-30
申请号：US13265976
申请日：2010-04-22
申请人： Andrew Gabriel Rinzler , Rajib Kumar Das , John R. Reynolds , Ryan M. Walczak
发明人： Andrew Gabriel Rinzler , Rajib Kumar Das , John R. Reynolds , Ryan M. Walczak
IPC分类号： H01M4/86 , H01M8/1007 , H01M8/1011 , H01M12/06 , H01M8/1018
摘要： An embodiment of the invention is an air cathode having a porous membrane with at least one hydrophobic surface that contacts a conductive catalytic film that comprises single walled carbon nanotubes (SWNTs) where the nanotubes are in intimate electrical contact. The conductive film can include fullerenes, metals, metal alloys, metal oxides, or electroactive polymers in addition to the SWNTs. In other embodiments of the invention the air cathode is a component of a metal-air battery or a fuel cell.

48. 发明授权

US08648247B2 SolarTurf: solar energy harvesting artificial turf 有权
标题翻译： SolarTurf：太阳能收割人造草坪
公开(公告)号：US08648247B2
公开(公告)日：2014-02-11
申请号：US12745285
申请日：2008-11-26
申请人： Jiangeng Xue , Franky So , Kirk S. Schanze , John R. Reynolds
发明人： Jiangeng Xue , Franky So , Kirk S. Schanze , John R. Reynolds
IPC分类号： H01L31/045
CPC分类号： H01L27/301 , H01L27/304
摘要： A SolarTurf unit has a plurality of solar blades, each blade comprising a donor-acceptor conjugated polymer (DA-CP) disposed between and electrically contacting a working electrode and a counter electrode where at least one of electrodes is transparent and where the plurality of solar blades have like or different DA-CPs having like color or different colors, for example, green. The SolarTurf unit includes an interconnect strip having a first electrically conductive surface and a second electrically conductive surface separated by an insulator. The working electrodes are electrically connected to the first electrically conductive surface and the counter electrodes are electrically connected to the second electrically conductive surface. The SolarTurf units can be combined into a device for harvesting light energy to provide an electric output. The SolarTurf device can have the appearance of a lawn or other plant, fungi, rock, sand or animal.
摘要翻译： SolarTurf单元具有多个太阳能叶片，每个叶片包括设置在工作电极和对电极之间的电接触共轭聚合物（DA-CP），其中至少一个电极是透明的，并且多个太阳能叶片具有类似或不同的具有相似颜色或不同颜色的DA-CP，例如绿色。 SolarTurf单元包括具有第一导电表面和由绝缘体隔开的第二导电表面的互连条。工作电极电连接到第一导电表面，并且相对电极电连接到第二导电表面。 SolarTurf单元可以组合成用于收集光能的设备以提供电力输出。 SolarTurf设备可以具有草坪或其他植物，真菌，岩石，沙子或动物的外观。

49. 发明授权

US08450449B2 Multi-colored conjugated polymers with highly transmissive oxidized state 有权
标题翻译：具有高透射氧化态的多色共轭聚合物
公开(公告)号：US08450449B2
公开(公告)日：2013-05-28
申请号：US13111350
申请日：2011-05-19
申请人： John R. Reynolds , Pengjie Shi , Jianguo Mei , Chad Martin Amb
发明人： John R. Reynolds , Pengjie Shi , Jianguo Mei , Chad Martin Amb
IPC分类号： C08G75/00
CPC分类号： C08G61/126 , C08G61/122 , C08G2261/122 , C08G2261/1424 , C08G2261/3223 , C08G2261/3246 , C08G2261/414 , C08G2261/54 , C09K9/02 , C09K2211/1458 , C09K2211/1491 , G02F2001/1515
摘要： Embodiments of the invention are directed to random conjugated copolymers comprising a plurality of one or more different donor (D) repeating units and a plurality of at least one acceptor (A) repeating unit. At least one of the D units has a solubilizing substituent, statistically a portion of the A repeating units are separated from each other by only one D units and a plurality of the A unit are adjacent to one the D units having the solubilizing substituents. The random conjugated copolymers are black or colored in the neutral state and highly transmissive in the oxidized state. The random conjugated copolymers have the structure -[(D)xA]n-, where x>1 and n(x+1)≧10 or the structure -[(DA))x-(D′A)y]n-, where D represents one substituted D unit and D′ represents another D units and where x≧1, y≧1 and 2n(x+y)≧10. Other embodiments of the invention are directed to forming the -[(D)xA]n- or -[(DA)x-(D′A)y]n- random conjugated copolymers by condensation polymerizations between monomers containing complementary reactive groups.
摘要翻译：本发明的实施方案涉及包含多个一个或多个不同施主（D）重复单元和多个至少一个受体（A）重复单元的无规共轭共聚物。 D单元中的至少一个具有增溶取代基，统计上，A重复单元的一部分通过仅一个D单元彼此分离，并且多个A单元与具有增溶取代基的D单元中的一个相邻。无规共轭共聚物在中性状态下为黑色或着色，在氧化态下具有高透射性。无规共轭共聚物具有结构 - [（D）xA] n-，其中x> 1和n（x + 1）> = 10或结构 - [（DA）x-（D'A）y] n- 其中D表示一个取代的D单元，D'表示另一D单元，其中x> = 1，y> = 1和2n（x + y）> = 10。本发明的其它实施方案涉及通过在含有互补反应性基团的单体之间进行缩聚而形成 - [（D）xA] n或 - [（DA）x-（D'A）y] n-无规共轭共聚物。

50. 发明授权

US08399603B2 Cathodically coloring yellow soluble electrochromic and light emitting polymers 有权
标题翻译：阴极染色黄色可溶性电致变色和发光聚合物
公开(公告)号：US08399603B2
公开(公告)日：2013-03-19
申请号：US13282999
申请日：2011-10-27
申请人： Chad Martin Amb , Justin Adam Kerszulis , John R. Reynolds , Aubrey Lynn Dyer , Emily Thompson
发明人： Chad Martin Amb , Justin Adam Kerszulis , John R. Reynolds , Aubrey Lynn Dyer , Emily Thompson
IPC分类号： C08G75/00
CPC分类号： C09K9/02 , C07D495/04 , C09K2211/1458 , C09K2211/1466
摘要： Embodiments of the invention are directed to yellow-to-transmissive conjugated polymers, a method to prepare the yellow conjugated polymers, the use of the yellow conjugated polymers in an electrochromic and/or electroluminescent device comprising neutral state primary subtractive colored conjugated polymers, and a method to prepare the device comprising the yellow conjugated polymer. The yellow conjugated polymers comprise a sequence of dioxythiophene units alternating with aromatic units, thiophene units, furan units, and/or pyrrole units. The yellow conjugated polymers are prepared by cross-condensation reactions. The yellow conjugated polymers can be soluble and preparation of the device involves deposition of the yellow conjugated polymer from solution onto a surface.
摘要翻译：本发明的实施方案涉及黄色至透射的共轭聚合物，制备黄色共轭聚合物的方法，在含有中性状态的主要减色共轭聚合物的电致变色和/或电致发光装置中使用黄色共轭聚合物，以及制备包含黄色共轭聚合物的装置的方法。黄色共轭聚合物包含与芳族单元，噻吩单元，呋喃单元和/或吡咯单元交替的二氧噻吩单元的序列。通过交联缩合反应制备黄色共轭聚合物。黄色共轭聚合物可以是可溶的，并且该装置的制备涉及将黄色共轭聚合物从溶液沉积到表面上。

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