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    • 42. 发明授权
    • Reactive systems and a process for the preparation of polyurethane
plastics
    • 反应体系和制备聚氨酯塑料的方法
    • US5173559A
    • 1992-12-22
    • US429264
    • 1989-10-20
    • Hanns-Peter MullerOtto GansterBruno Luckas
    • Hanns-Peter MullerOtto GansterBruno Luckas
    • C08G18/30C08G18/00C08G18/08C08G18/09C08G18/58C08G18/70C08G101/00
    • C08G18/003C08G18/089C08G18/092C08G18/58C08G18/70C08G2101/00
    • The present invention relates to reactive systems comprising(a) a storable mixture of (i) a polyisocyanate component comprising at least one organic polyisocyanate, and (ii) an epoxide component stabilized by heating in the presence of an alkylating agent, wherein said heating is optionally carried out in the further presence of part of the polyisocyanate component (i),(b) an isocyanate-reactive component containing at least two isocyanate-reactive groups in a quantity such that 0.1 to 0.9 isocyanate-reactive groups are present for every isocyanate group in component (a), wherein at least 10% by weight of component (b) comprises compounds having a molecular weight greater than about 2000,(c) optionally, tertiary amines in a quantity such that the total storable mixture contains at least 0.005 mole of tertiary amine nitrogen atoms for each 100 g of the total amount of the storable mixture, and, optionally,(d) other auxiliaries and additives.The present invention also relates to a process for the preparation of optionally foamed polyurethane plastics containing isocyanurate groups comprising (1) mixing the components of such reactive systems at a temperature less than 60.degree. C. and (2) heating said reactive system to a temperature of at least 60.degree. C.
    • 本发明涉及反应体系,其包括(a)(i)包含至少一种有机多异氰酸酯的多异氰酸酯组分和(ii)在烷基化剂存在下通过加热稳定的环氧化物组分的可储存混合物,其中所述加热为 任选地在部分多异氰酸酯组分(i)的另外存在下进行,(b)含有至少两个异氰酸酯反应性基团的异氰酸酯反应性组分,其量使得每个异氰酸酯存在0.1至0.9个异氰酸酯反应性基团 组分(a)中的组,其中至少10重量%的组分(b)包含分子量大于约2000的化合物,(c)任选的叔胺,其量使得总可储存混合物含有至少0.005 每100g存储混合物的总量的叔胺氮原子摩尔数,和任选的(d)其它助剂和添加剂。 本发明还涉及一种制备含有异氰脲酸酯基团的任选发泡聚氨酯塑料的方法,包括(1)在低于60℃的温度下混合这些反应体系的组分,和(2)将所述反应体系加热至 至少60℃