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    • 41. 发明授权
    • Electrochemical cell systems comprising fuel consuming agents
    • 包含燃料消耗剂的电化学电池系统
    • US07544435B2
    • 2009-06-09
    • US10438004
    • 2003-05-15
    • Stuart M. Davis
    • Stuart M. Davis
    • H01M2/00
    • C01B5/00F17C11/005H01M8/04089H01M8/22H01M8/247
    • Electrochemical cell systems are provided. In some implementations, the electrochemical cell system includes a fuel cell and a fuel cartridge connected to the fuel cell. The fuel cell includes (i) a fuel cell housing having a first external surface and a first internal surface defining a first internal volume of the fuel cell housing, and (ii) a cathode, an anode. and an electrolyte disposed within the first internal volume. The fuel cartridge includes (F) a cartridge housing having a second external surface and a second internal surface defining a second internal volume of the cartridge housing, wherein the second internal volume includes a fuel; and (ii) a fuel consuming agent disposed on at least one of the first external surface and the second external surface.
    • 提供电化学电池系统。 在一些实施方案中,电化学电池系统包括燃料电池和连接到燃料电池的燃料盒。 燃料电池包括(i)具有第一外表面和限定燃料电池壳体的第一内部体积的第一内表面的燃料电池壳体,以及(ii)阴极,阳极。 以及设置在所述第一内部容积内的电解质。 燃料盒包括(F)具有第二外表面的盒壳体和限定盒壳体的第二内部容积的第二内表面,其中第二内部容积包括燃料; 和(ii)设置在第一外表面和第二外表面中的至少一个上的燃料消耗剂。
    • 45. 发明授权
    • Process for manufacture and improved manganese dioxide for electrochemical cells
    • 电化学电池的制造和改善二氧化锰的方法
    • US06585881B2
    • 2003-07-01
    • US09788754
    • 2001-02-20
    • Stuart M. DavisPeter R. MosesGary Miller
    • Stuart M. DavisPeter R. MosesGary Miller
    • C25B100
    • C01G45/02C01P2006/10C01P2006/12C01P2006/40C01P2006/80C25B1/21H01M4/50
    • A process for manufacture of manganese dioxide comprising subjecting an aqueous bath comprising manganese sulfate (MnSO4) and sulfuric acid (H2SO4) to electrolysis in a closed cell wherein the electrolysis bath is maintained at an elevated temperature above 110° C., preferably above 115° C. and at superatmospheric pressure. Desirably the bath can be maintained at an elevated temperature between about 115° C. and 155° C. The electrolysis is carried out preferably at elevated current density of between about 12.5 and 37 Amp/sq. ft (135 and 400 Amp/sq. meter) which allows for smaller or fewer electrolysis units. An MnO2 product having a specific surface area (SSA) within desired range of between 18-45 m2/g can be obtained. A doping agent, preferably a soluble titanium dopant is employed to help obtain the desired specific surface area (SSA) of the MnO2 product. The manganese dioxide product in zinc/MnO2 alkaline cells gives excellent service life, particularly in high power application.
    • 一种制造二氧化锰的方法,包括使包含硫酸锰(MnSO 4)和硫酸(H 2 SO 4)的水浴在闭孔中电解,其中电解浴保持在110℃以上,优选高于115℃的高温 C.和超大气压。 理想地,浴可以保持在约115℃和155℃之间的升高的温度。电解优选在升高的电流密度为约12.5A和37安培/平方米之间进行。 ft(135和400安培/平方米),允许更小或更少的电解单元。 可以获得具有在18-45m 2 / g之间的期望范围内的比表面积(SSA)的MnO 2产物。 使用掺杂剂,优选可溶性钛掺杂剂来帮助获得MnO 2产物的所需比表面积(SSA)。 锌/锰氧化物碱性电池中的二氧化锰产品具有优异的使用寿命,特别是在高功率应用中。