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41. 发明申请

US20090030162A1 Polyether-Functional Siloxanes, Polyether Siloxane-Containing Compositions, Methods For The Production Thereof And Use Thereof 有权
标题翻译：聚醚官能硅氧烷，含聚醚硅氧烷的组合物，其生产方法及其用途
公开(公告)号：US20090030162A1
公开(公告)日：2009-01-29
申请号：US11576504
申请日：2004-11-05
申请人： Ekkehard Mueh , Peter Jenkner , Max Preisenberger , Burkhard Standke
发明人： Ekkehard Mueh , Peter Jenkner , Max Preisenberger , Burkhard Standke
IPC分类号： C08G77/46 , C08L83/12
CPC分类号： C08G77/46 , A61K8/893 , C08L83/12
摘要： The present invention provides a linear, cyclic or branched polyether-functional siloxane or a mixture of polyether-functional siloxanes of the general formula (I) R[—O(3-h)/2Si(R1)(OR)h]x[—O(3-i-j)/2Si(R2)(R3)i(OR)j]y, (II) in which groups R are identical or different and R is essentially H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, 2-methoxyethyl or 2-hydroxyethyl or, in the case of cyclic siloxanes, may be a silyl radical of the silyl units of the formula (I), groups R1 are identical or different and R1 is a terminally blocked polyether group of the formula (II), R4—O[—R5—O]n[(—R6)m]— (II) and groups R2 are identical or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having 1 to 18 carbon atoms or a mercaptoalkyl group or an alkenyl group having 2 to 8 carbon atoms or an alkenyl group having 2 to 8 carbon atoms or an aryl group having 6 to 12 carbon atoms or an aminoalkyl group or the general formula (III) H2N(CH2)d[(NH)e(CH2)f]g—(CH2)3— (III) The present invention further provides aqueous and/or alcoholic compositions which comprise a polyether siloxane according to formula (I), to methods for the production of said systems, and to the use thereof.
摘要翻译：本发明提供通式（I）R [-O（3-h）/ 2Si（R 1）（OR）h] x]的直链，环状或支链聚醚官能的硅氧烷或聚醚官能的硅氧烷的混合物， -O（3-ij）/ 2Si（R2）（R3）i（OR）j] y，（Ⅱ）其中基团R相同或不同，R基本上为H，甲基，乙基，正丙基，异丙基，正丁基，异丁基，叔丁基，2-甲氧基乙基或2-羟乙基，或在环状硅氧烷的情况下，可以是式（I）的甲硅烷基单元的甲硅烷基，基团R1相同或不同，R1 是式（II）的末端封闭的聚醚基团，R4-O [-R5-O] n [（ - R6）m] - （Ⅱ）和基团R2相同或不同，R2是直链，支链或环状，可以具有取代基的碳原子数1〜18的烷基或巯基烷基或碳原子数2〜8的烯基或碳原子数2〜8的烯基或碳原子数6〜12的芳基或氨基烷基，通式（III）H 2 N（CH 2）d [（NH）e（CH 3） 2）f] g-（CH 2）3 - （III）本发明进一步提供包含式（I）的聚醚硅氧烷，用于生产所述体系的方法和用途的水性和/或醇组合物其中。

42. 发明申请

US20080003448A1 Stable Solutions of N-Substituted Aminopolysiloxanes, Their Preparation and Use 有权
标题翻译： N-取代氨基聚硅氧烷的稳定溶液及其制备与应用
公开(公告)号：US20080003448A1
公开(公告)日：2008-01-03
申请号：US11569363
申请日：2005-05-12
申请人： Burkhard Standke , Peter Jenkner
发明人： Burkhard Standke , Peter Jenkner
IPC分类号： C07F7/21 , C08G77/26 , C09D183/00 , C09D4/00
CPC分类号： C08J3/095 , C07F7/21 , C08J2383/08 , Y10T428/12569 , Y10T428/31612 , Y10T428/31663
摘要： Stable, low-chloride solutions of hydrosalts of organic acids with cationic N substituted aminopolysiloxanes of the formula (I) in which groups R independently of each other are each benzyl or vinylbenzyl, groups Y are identical or different and Y is an alkoxy or hydroxyl group or 01/2, A is an organic carboxylic acid and 0≦a
摘要翻译：其中基团R各自独立地为苄基或乙烯基苄基的式（I）的阳离子N取代的氨基聚硅氧烷的有机酸稳定的低氯化物溶液是相同或不同的，Y是烷氧基或羟基或0 <1/2，A是有机羧酸，0 <= a <2,0 <= b <= c1 = 0.125,0.125 <=（a + b）≤3 和x> = 2，其基本上以低级醇中的T结构单元的形式存在。通过与NaOH或醇钠或与有机羧酸A的钠盐反应，从阳离子N-取代的氨基聚硅氧烷的相应的盐酸盐进行制备，析出和除去NaCl。这些溶液用作有机和无机表面之间的粘合促进剂，与有机聚合物与无机填料，玻璃纤维或金属颗粒的增强有关，或与无机表面与有机聚合物的涂层有关，其中氨基聚硅氧烷涂层厚度为达到800nm。

43. 发明授权

US08147918B2 Water-dilutable sol-gel composition 有权
标题翻译：水可稀释溶胶 - 凝胶组合物
公开(公告)号：US08147918B2
公开(公告)日：2012-04-03
申请号：US12159785
申请日：2006-12-06
申请人： Burkhard Standke , Christian Wassmer , Peter Jenkner
发明人： Burkhard Standke , Christian Wassmer , Peter Jenkner
IPC分类号： B05D1/00 , B05D3/00
CPC分类号： C09D4/00 , C09D5/08 , C09D183/14 , C23C2222/20 , Y10T428/31663 , C08G77/04
摘要： The present invention provides a sol-gel composition which is dilutable with water in any proportion and is based on the reaction of at least the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having a solids content of >1% by weight, (iii) an organic acid as hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, starting from a mass ratio of the solids mass of component (ii) to component (i) 0.75, a process for preparing it and its use, in particular as a sol-gel composition for corrosion control coatings, a corresponding corrosion control coat or primer coat, and articles equipped with such a coating.
摘要翻译：本发明提供一种溶胶 - 凝胶组合物，其可以以任何比例用水稀释，并且基于至少以下组分的反应：（i）缩水甘油氧基丙基烷氧基硅烷，（ii）固体含量> 1的水性硅溶胶（iii）作为水解催化剂的有机酸，和（iv）锆酸正丙酯，钛酸丁酯或乙酰丙酮钛作为交联剂，从组分（ii）与组分（i）的固体质量的质量比开始， 0.75，其制备方法及其用途，特别是作为腐蚀控制涂料的溶胶 - 凝胶组合物，相应的腐蚀控制涂层或底漆涂层以及配备有这种涂层的制品。

44. 发明申请

US20090022898A1 WATER-DILUTABLE SOL-GEL COMPOSITION 有权
标题翻译：水可溶性凝胶组合物
公开(公告)号：US20090022898A1
公开(公告)日：2009-01-22
申请号：US12159785
申请日：2006-12-06
申请人： Burkhard Standke , Christian Wassmer , Peter Jenkner
发明人： Burkhard Standke , Christian Wassmer , Peter Jenkner
IPC分类号： C09D5/00 , C09D4/00
CPC分类号： C09D4/00 , C09D5/08 , C09D183/14 , C23C2222/20 , Y10T428/31663 , C08G77/04
摘要： The present invention provides a sol-gel composition which is dilutable with water in any proportion and is based on the reaction of at least the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having a solids content of >1% by weight, (iii) an organic acid as hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, starting from a mass ratio of the solids mass of component (ii) to component (i) 0.75, a process for preparing it and its use, in particular as a sol-gel composition for corrosion control coatings, a corresponding corrosion control coat or primer coat, and articles equipped with such a coating.
摘要翻译：本发明提供一种溶胶 - 凝胶组合物，其可以以任何比例用水稀释，并且基于至少以下组分的反应：（i）缩水甘油氧基丙基烷氧基硅烷，（ii）固体含量> 1的水性硅溶胶（iii）作为水解催化剂的有机酸，和（iv）锆酸正丙酯，钛酸丁酯或乙酰丙酮钛作为交联剂，从组分（ii）与组分（i）的固体质量的质量比开始， 0.75，其制备方法及其用途，特别是作为腐蚀控制涂料的溶胶 - 凝胶组合物，相应的腐蚀控制涂层或底漆涂层以及配备有这种涂层的制品。

45. 发明授权

US08394972B2 Process for controlled hydrolysis and condensation of epoxy-functional organosilanes and the cocondensation thereof with further organofunctional alkoxysilanes 有权
标题翻译：控制水解和缩合环氧官能有机硅烷的方法及其与另外的有机官能烷氧基硅烷的共缩聚
公开(公告)号：US08394972B2
公开(公告)日：2013-03-12
申请号：US12673390
申请日：2008-06-17
申请人： Christian Wassmer , Burkhard Standke , Irene Lippert , Peter Jenkner
发明人： Christian Wassmer , Burkhard Standke , Irene Lippert , Peter Jenkner
IPC分类号： C07F7/02
CPC分类号： C08G77/08 , C08G77/14
摘要： The present invention relates to a process for performing a controlled hydrolysis and condensation of an epoxy-functional silane of the general formula I R1-SiR′m(OR)3-m (I) in which R1 is a (III) or (IV) group and R, R′ and R″ groups are the same or different and are each hydrogen (H) or a linear, branched or cyclic, optionally substituted alkyl group having from 1 to 6 carbon atoms, A and A′ groups are the same or different and are each a bivalent alkyl group having from 1 to 10 carbon atoms, R2 groups are the same or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having from 1 to 20 carbon atoms, and m is 0 or 1, and optionally of at least one further organofunctional silane of the general formula II R2-SiR′n(OR)3-n (II) in which R2 is an organofunctional group as already defined above, R′ is methyl, R groups are each independently hydrogen or a linear, branched or cyclic alkyl group having from 1 to 6 carbon atoms and n is 0 or 1, where from 0.001 to ≦5 mol of water is used per mole of alkoxy function of the silanes used, no further hydrolysis or condensation catalyst is used apart from boric acid as the hydrolysis catalyst and condensation component, and the condensates formed in the reaction are based on Si—O—B— and/or Si—O—Si bonds.
摘要翻译：本发明涉及一种通式I R 1 -Si R'm（OR）3-m（I）的环氧官能硅烷进行受控水解和缩合的方法，其中R 1是（III）或（IV ）基团，R，R'和R“基团相同或不同，各自为氢（H）或具有1至6个碳原子的直链，支链或环状，任选取代的烷基，A和A'基团为相同或不同，各自为具有1至10个碳原子的二价烷基，R 2基团相同或不同，并且R 2为具有1至20个碳原子的直链，支链或环状的任选取代的烷基，m为 0或1，以及任选地至少一种另外的通式为R 2 -SiR'n（OR）3-n（II）的有机官能硅烷，其中R 2是如上定义的有机官能团，R'是甲基，R 基团各自独立地为氢或具有1至6个碳原子且n为0或1，w的直链，支链或环状烷基这里为0.001至＆lt; nlE;每摩尔使用的硅烷的烷氧基官能度使用5摩尔的水，除了作为水解催化剂和缩合组分的硼酸之外不再使用进一步的水解或缩合催化剂，反应中形成的缩合物基于Si-O-B和/或Si-O-Si键。

46. 发明授权

US08236918B2 Polyether-functional siloxanes, polyether siloxane-containing compositions, methods for the production thereof and use thereof 有权
标题翻译：聚醚官能硅氧烷，含聚醚硅氧烷的组合物，其制备方法和用途
公开(公告)号：US08236918B2
公开(公告)日：2012-08-07
申请号：US11576504
申请日：2004-11-05
申请人： Ekkehard Mueh , Peter Jenkner , Max Preisenberger , Burkhard Standke
发明人： Ekkehard Mueh , Peter Jenkner , Max Preisenberger , Burkhard Standke
IPC分类号： C08G77/26 , C08G77/00 , C08G77/04 , C08G77/14 , C08G77/22
CPC分类号： C08G77/46 , A61K8/893 , C08L83/12
摘要： The present invention provides a linear, cyclic or branched polyether-functional siloxane or a mixture of polyether-functional siloxanes of the general formula (I) R[—O(3-h)/2Si(R1)(OR)h]x[—O(3-i-j)/2Si(R2)(R3)i(OR)j]y, (II) in which groups R are identical or different and R is essentially H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, 2-methoxyethyl or 2-hydroxyethyl or, in the case of cyclic siloxanes, may be a silyl radical of the silyl units of the formula (I), groups R1 are identical or different and R1 is a terminally blocked polyether group of the formula (II), R4—O[—R5—O]n[(—R6)m]— (II) and groups R2 are identical or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having 1 to 18 carbon atoms or a mercaptoalkyl group or an alkenyl group having 2 to 8 carbon atoms or an alkenyl group having 2 to 8 carbon atoms or an aryl group having 6 to 12 carbon atoms or an aminoalkyl group or the general formula (III) H2N(CH2)d[(NH)e(CH2)f]g—(CH2)3— (III) The present invention further provides aqueous and/or alcoholic compositions which comprise a polyether siloxane according to formula (I), to methods for the production of said systems, and to the use thereof.
摘要翻译：本发明提供通式（I）R [-O（3-h）/ 2Si（R 1）（OR）h] x]的直链，环状或支链聚醚官能的硅氧烷或聚醚官能的硅氧烷的混合物， -O（3-ij）/ 2Si（R2）（R3）i（OR）j] y，（Ⅱ）其中基团R相同或不同，R基本上为H，甲基，乙基，正丙基，异丙基，正丁基，异丁基，叔丁基，2-甲氧基乙基或2-羟乙基，或在环状硅氧烷的情况下，可以是式（I）的甲硅烷基单元的甲硅烷基，基团R1相同或不同，R1 是式（II）的末端封闭的聚醚基团，R 4 -O [-R 5 -O] n [（ - R 6）m] - （II）和基团R 2相同或不同，并且R 2是直链，支链或环状，可以具有取代基的碳原子数1〜18的烷基或巯基烷基或碳原子数2〜8的烯基或碳原子数2〜8的烯基或碳原子数6〜12的芳基或氨基烷基，通式（III）H2N（ CH 2）d [（NH）e（CH 2）f] g - （CH 2）3 - （III）本发明进一步提供包含根据式（I）的聚醚硅氧烷的水性和/或醇组合物，所述系统的生产及其使用。

47. 发明授权

US07834073B2 Stable solutions of N-substituted aminopolysiloxanes, their preparation and use 有权
标题翻译： N-取代氨基多硅氧烷的稳定溶液，其制备和用途
公开(公告)号：US07834073B2
公开(公告)日：2010-11-16
申请号：US11569363
申请日：2005-05-12
申请人： Burkhard Standke , Peter Jenkner
发明人： Burkhard Standke , Peter Jenkner
IPC分类号： C08K5/54
CPC分类号： C08J3/095 , C07F7/21 , C08J2383/08 , Y10T428/12569 , Y10T428/31612 , Y10T428/31663
摘要： Stable low chloride solutions of hydrosalts of an organic acid with a N-substituted aminopolysiloxane in the form of a T structural unit contain at least one lower alcohol, and at least one stabilizer. Methods to prepare the stable low-chloride solutions are also provided.
摘要翻译：有机酸的氢化钠与T结构单元形式的N-取代的氨基聚硅氧烷的稳定的低氯化物溶液含有至少一种低级醇和至少一种稳定剂。还提供了制备稳定的低氯化物溶液的方法。

48. 发明申请

US20100191001A1 PROCESS FOR CONTROLLED HYDROLYSIS AND CONDENSATION OF EPOXY-FUNCTIONAL ORGANOSILANES AND THE COCONDENSATION THEREOF WITH FURTHER ORGANOFUNCTIONAL ALKOXYSILANES 有权
标题翻译：环氧官能有机物的控制水解和缩合方法及其与有机官能烷氧基化合物的共聚
公开(公告)号：US20100191001A1
公开(公告)日：2010-07-29
申请号：US12673390
申请日：2008-06-17
申请人： Christian Wassmer , Burkhard Standke , Irene Lippert , Peter Jenkner
发明人： Christian Wassmer , Burkhard Standke , Irene Lippert , Peter Jenkner
IPC分类号： C07D303/02 , C07F7/02
CPC分类号： C08G77/08 , C08G77/14
摘要： The present invention relates to a process for performing a controlled hydrolysis and condensation of an epoxy-functional silane of the general formula I R1-SiR′m(OR)3-m (I) in which R1 is a (III) or (IV) group and R, R′ and R″ groups are the same or different and are each hydrogen (H) or a linear, branched or cyclic, optionally substituted alkyl group having from 1 to 6 carbon atoms, A and A′ groups are the same or different and are each a bivalent alkyl group having from 1 to 10 carbon atoms, R2 groups are the same or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having from 1 to 20 carbon atoms, and m is 0 or 1, and optionally of at least one further organofunctional silane of the general formula II R2-SiR′n(OR)3-n (II) in which R2 is an organofunctional group as already defined above, R′ is methyl, R groups are each independently hydrogen or a linear, branched or cyclic alkyl group having from 1 to 6 carbon atoms and n is 0 or 1, where from 0.001 to ≦5 mol of water is used per mole of alkoxy function of the silanes used, no further hydrolysis or condensation catalyst is used apart from boric acid as the hydrolysis catalyst and condensation component, and the condensates formed in the reaction are based on Si—O—B— and/or Si—O—Si bonds.
摘要翻译：本发明涉及一种通式I R 1 -Si R'm（OR）3-m（I）的环氧官能硅烷进行受控水解和缩合的方法，其中R 1是（III）或（IV ）基团，R，R'和R“基团相同或不同，各自为氢（H）或具有1至6个碳原子的直链，支链或环状，任选取代的烷基，A和A'基团为相同或不同，各自为具有1至10个碳原子的二价烷基，R 2基团相同或不同，并且R 2为具有1至20个碳原子的直链，支链或环状的任选取代的烷基，m为 0或1，以及任选地至少一种另外的通式II的有机官能硅烷R2-SiR'n（OR）3-n（II），其中R2是如上定义的有机官能团，R'是甲基，R 基团各自独立地为氢或具有1至6个碳原子且n为0或1，w的直链，支链或环状烷基这里为0.001至＆lt; nlE;每摩尔使用的硅烷的烷氧基官能度使用5摩尔的水，除了作为水解催化剂和缩合组分的硼酸之外不再使用进一步的水解或缩合催化剂，反应中形成的缩合物基于Si-O-B和/或Si-O-Si键。

49. 发明申请

US20110118496A1 PROCESS FOR PREPARING ALKYLAMINOALKYLALKOXYSILANES 有权
标题翻译：制备烷基氨基烷基氧化硅的方法
公开(公告)号：US20110118496A1
公开(公告)日：2011-05-19
申请号：US12995852
申请日：2009-04-17
申请人： Eckhard Just , Philipp Albert , Peter Jenkner
发明人： Eckhard Just , Philipp Albert , Peter Jenkner
IPC分类号： C07F7/20
CPC分类号： C07F7/1892 , Y02P20/582
摘要： A process for preparing an alkylaminoalkylalkoxysilane of formula (I) R—(NR′)—Y—Si(R1)n(OR2)3-n (I) in which R is a linear, branched or cyclic alkyl group having 1 to 12 carbon atoms, R′ is a hydrogen (H) or is a linear, branched or cyclic alkyl group having 1 to 12 carbon atoms, Y is a bivalent alkyl group from the group of —CH2—, —(CH2)2—, —(CH2)3—, —(CH2)(CH(CH3))(CH2)— and —(CH2)4—, R1 and R2 groups are the same or different and are each a linear or branched alkyl group having 1 to 4 carbon atoms, and n is 0 or 1 or 2, by reacting an alkylamine, used in excess, with a haloalkylalkoxysilane, distilling off excess free alkylamine, treating the remaining product mixture with the alkylaminoalkylalkoxysilane and working up.
摘要翻译：制备式（I）所示的烷基氨基烷基烷氧基烷氧基硅烷的方法R-（NR'）-Y-Si（R 1）n（OR 2）3-n（I）其中R是具有1至12个直链，支链或环状的烷基碳原子，R'是氢（H）或是具有1至12个碳原子的直链，支链或环状烷基，Y是来自-CH 2 - ， - （CH 2）2 - ， - （CH 2）3 - ， - （CH 2）（CH（CH 3））（CH 2） - 和 - （CH 2）4 - ，R 1和R 2相同或不同，各自为具有1-4个碳原子，n为0或1或2，通过使过量使用的烷基胺与卤代烷基烷氧基硅烷反应，蒸馏掉过量的游离烷基胺，用烷基氨基烷基烷氧基硅烷处理剩余的产物混合物并加工。

50. 发明申请

US20100160649A1 SYSTEM AND PROCESS FOR CONTINUOUS INDUSTRIAL PREPARATION OF 3-GLYCIDYLOXYPROPYLALKOXYSILANES 审中-公开
标题翻译： 3-GLYCIDYLOXYPROPYLALKOXYSILESES连续工业制备的系统与工艺
公开(公告)号：US20100160649A1
公开(公告)日：2010-06-24
申请号：US12376786
申请日：2007-07-09
申请人： Juergen Erwin Lang , Georg Markowz , Dietmar Wewers , Harald Metz , Norbert Schladerbeck , Peter Jenkner
发明人： Juergen Erwin Lang , Georg Markowz , Dietmar Wewers , Harald Metz , Norbert Schladerbeck , Peter Jenkner
IPC分类号： C07F7/08 , B01J19/00 , B01J8/00
CPC分类号： B01J19/0093 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00831 , B01J2219/00835 , B01J2219/00837 , B01J2219/0086 , B01J2219/00867 , B01J2219/00869 , B01J2219/00873 , B01J2219/00889 , C07F7/1876
摘要： The present invention relates to a system, to a reactor and to a process for continuous industrial performance of a reaction wherein allyl glycidyl ether A is reacted with an HSi compound B in the presence of a catalyst C and optionally of further assistants, and the system is based at least on the combination of reactants (3) for components A (1) and B (2), at least one multielement reactor (5) which in turn comprises at least two reactor units in the form of exchangeable pre-reactors (5.1) and at least one further reactor unit (5.3) connected downstream of the prereactors, and on a product workup (8).
摘要翻译：本发明涉及反应器的系统，以及连续工业化反应的方法，其中烯丙基缩水甘油醚A与催化剂C和任选的其它助剂的存在下与HSi化合物B反应，并且系统至少基于组分A（1）和B（2）的反应物（3）的组合，至少一个多元素反应器（5），其又包含至少两个可交换的预反应器形式的反应器单元（ 5.1）和连接在预反应器下游的至少一个另外的反应器单元（5.3）和产品后处理（8）。

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