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41. 发明申请

US20080171204A1 Fabrication of light emitting film coated fullerenes and their application for in-vivo light emission 失效
标题翻译：发光薄膜包覆的富勒烯的制备及其在体内发光的应用
公开(公告)号：US20080171204A1
公开(公告)日：2008-07-17
申请号：US11834471
申请日：2007-08-06
申请人： Andrew R. Barron , Dennis J. Flood , John R. Loscutova
发明人： Andrew R. Barron , Dennis J. Flood , John R. Loscutova
IPC分类号： B32B9/00 , H01L21/36
CPC分类号： G02B6/32 , B82Y15/00 , B82Y20/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C30B7/14 , C30B19/12 , C30B29/48 , C30B29/605 , H01L21/02376 , H01L21/02521 , H01L21/02601 , H01L21/02628 , Y10S977/70 , Y10S977/734 , Y10S977/737 , Y10S977/742 , Y10T428/2991 , Y10T428/30
摘要： A nanoparticle coated with a semiconducting material and a method for making the same. In one embodiment, the method comprises making a semiconductor coated nanoparticle comprising a layer of at least one semiconducting material covering at least a portion of at least one surface of a nanoparticle, comprising: (A) dispersing the nanoparticle under suitable conditions to provide a dispersed nanoparticle; and (B) depositing at least one semiconducting material under suitable conditions onto at least one surface of the dispersed nanoparticle to produce the semiconductor coated nanoparticle. In other embodiments, the nanoparticle comprises a fullerene. Further embodiments include the semiconducting material comprising CdS or CdSe.
摘要翻译：涂覆有半导体材料的纳米颗粒及其制备方法。在一个实施方案中，该方法包括制备半导体涂覆的纳米颗粒，其包含覆盖纳米颗粒的至少一个表面的至少一部分的至少一种半导体材料的层，包括：（A）在合适的条件下分散纳米颗粒以提供分散的纳米颗粒和（B）在合适的条件下将至少一种半导体材料沉积在分散的纳米颗粒的至少一个表面上以产生半导体涂覆的纳米颗粒。在其它实施方案中，纳米颗粒包含富勒烯。其它实施方案包括包含CdS或CdSe的半导体材料。

42. 发明授权

US06207130B1 Metal-exchanged carboxylato-alumoxanes and process of making metal-doped alumina 失效
标题翻译：金属交换的羧基铝氧烷和制备金属掺杂氧化铝的方法
公开(公告)号：US06207130B1
公开(公告)日：2001-03-27
申请号：US09058587
申请日：1998-04-10
申请人： Aivaras Kareiva , Chuansheng Bai , Charles Jeffrey Harlan , D. Brent MacQueen , Andrew R. Barron , Ronald L. Cook
发明人： Aivaras Kareiva , Chuansheng Bai , Charles Jeffrey Harlan , D. Brent MacQueen , Andrew R. Barron , Ronald L. Cook
IPC分类号： C01F702
CPC分类号： C01F7/002 , B82Y30/00 , C01F7/04 , C01F7/16 , C01F7/30 , C01F17/0025 , C01G1/00 , C01G45/006 , C01G51/006 , C01P2002/32 , C01P2002/34 , C01P2002/52 , C01P2002/54 , C01P2004/64 , C07F5/069 , C07F15/025 , C07F15/045 , C07F15/065
摘要： A method has been developed for the solution-based metal exchange of carboxylato-alumoxanes [Al(O)x(OH)y(O2CR)z]n with a wide range of metal cations. Metal-exchanged carboxylato-alumoxanes are new, particularly those in which about 10% to about 50% or more of the Al ions are exchanged for other metal ions. Additionally, the carboxylic acid ligands can be stripped from the boehmite core of metal-exchanged carboxylato-alumoxanes at low temperature leading to the formation of metal-exchanged boebmite particles. These new material phases can be used as intermediates for preparation of mixed metal aluminum oxide materials. Thermolysis of the metal-exchanged carboxylato-alumoxanes or metal-exchanged boehmite particles results in doped aluminas (M/Al2O3), binary (MAlOx), ternary (MM′AlOx) and even more complex metal aluminum oxide compounds, where M and M′ are metal ions other than those of aluminum and are preferably those of Lanthanide metals or transition metals. The method allows preparation of pure phase materials as well as the preparation of metastable metal aluminum oxide phases. The carboxylato-alumoxanes are prepared by the reaction of boehmite (or pseudoboehmite) with carboxylic acids in a suitable solvent. Up to at least half of the aluminum cations in the boehmite lattice of the carboxylato-alumoxanes can be replaced by the reaction of metal acetylacetonates with the carboxylato-alumoxane in a suitable solvent. The metal exchange reaction can also be carried out by reaction with soluble metal salts. Reactions of boehmite with the metal acetylacetonates (or soluble metal salts) do not lead to the metal exchange reaction observed for the carboxylato-alumoxanes.
摘要翻译：已经开发了用于宽范围的金属阳离子的羧基 - 铝氧烷[Al（O）x（OH）y（O 2 CR）z] n的基于溶液的金属交换的方法。金属交换的羧基铝氧烷是新的，特别是其中约10％至约50％或更多的Al离子被交换为其它金属离子的那些。此外，羧酸配体可以在低温下从金属交换的羧酸 - 铝氧烷的勃姆石芯中汽提，导致形成金属交换的勃姆沸石颗粒。这些新材料相可以用作制备混合金属氧化铝材料的中间体。金属交换的羧酸 - 铝氧烷或金属交换的勃姆石颗粒的热解导致掺杂的氧化铝（M / Al 2 O 3），二元（MA 1 O x），三元（MM'AlO x）和甚至更复杂的金属氧化铝化合物，其中M和M' 是除铝以外的金属离子，优选为镧系金属或过渡金属的金属离子。该方法允许制备纯相材料以及制备亚稳态金属氧化铝相。羧基铝氧烷通过勃姆石（或假勃姆石）与羧酸在合适溶剂中的反应来制备。羧酸 - 铝氧烷的勃姆石晶格中的至少一半的铝阳离子可以通过金属乙酰丙酮化物与羧基 - 铝氧烷在合适的溶剂中的反应来代替。金属交换反应也可以通过与可溶性金属盐反应来进行。勃姆石与金属乙酰丙酮化物（或可溶性金属盐）的反应不会导致对羧基铝氧烷观察到的金属交换反应。

43. 发明申请

US20160163652A1 COATED FULLERENES, COMPOSITES AND DIELECTRICS MADE THEREFROM 审中-公开
标题翻译：包覆的富勒烯，复合材料和电介质
公开(公告)号：US20160163652A1
公开(公告)日：2016-06-09
申请号：US15042445
申请日：2016-02-12
申请人： Andrew R. Barron , Dennis J. Flood , Elizabeth Whitsitt
发明人： Andrew R. Barron , Dennis J. Flood , Elizabeth Whitsitt
IPC分类号： H01L23/532 , H01L21/768 , C01B31/02
CPC分类号： H01L23/53276 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/168 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01B2202/28 , C01P2002/54 , C01P2004/03 , C01P2004/04 , C01P2004/12 , C01P2004/13 , C01P2004/32 , C01P2004/84 , C01P2006/40 , C04B35/62807 , C04B2235/5288 , C08K9/02 , C09C1/3045 , C09C1/44 , H01L21/76838 , H01L51/0046 , H01L51/0048 , H01L51/0052 , H01L2924/0002 , Y10T428/30 , H01L2924/00
摘要： The present invention relates to coated fullerenes comprising a layer of at least one inorganic material covering at least a portion of at least one surface of a fullerene and methods for making. The present invention further relates to composites comprising the coated fullerenes of the present invention and further comprising polymers, ceramics, and/or inorganic oxides. A coated fullerene interconnect device where at least two fullerenes are contacting each other to form a spontaneous interconnect is also disclosed as well as methods of making. In addition, dielectric films comprising the coated fullerenes of the present invention and methods of making are further disclosed.
摘要翻译：本发明涉及包含覆盖富勒烯的至少一个表面的至少一部分的至少一种无机材料的层的涂层富勒烯的制备方法。本发明还涉及包含本发明的涂覆的富勒烯并且还包含聚合物，陶瓷和/或无机氧化物的复合材料。还公开了其中至少两个富勒烯彼此接触以形成自发互连的涂覆的富勒烯互连装置以及制备方法。此外，还公开了包含本发明的被覆富勒烯和制造方法的介电膜。

44. 发明申请

US20120261343A1 Methods, Systems and Membranes for Separation of Organic Compounds from Liquid Samples 有权
标题翻译：用于从液体样品中分离有机化合物的方法，系统和膜
公开(公告)号：US20120261343A1
公开(公告)日：2012-10-18
申请号：US13087706
申请日：2011-04-15
申请人： Andrew R. Barron , Samuel J. Maguire-Boyle
发明人： Andrew R. Barron , Samuel J. Maguire-Boyle
IPC分类号： C02F1/44 , B01D71/02 , B01D71/06 , B05D5/00 , B01D71/00 , B01D71/04 , C02F101/32
CPC分类号： C02F1/444 , B01D63/066 , B01D67/0088 , B01D69/02 , B01D2323/02 , B01D2325/36 , C02F2101/32 , C02F2103/08
摘要： Various aspects of the present invention pertain to porous membranes that comprise: (1) a plurality of pores with pore sizes of more than about 0.1 μm in diameter; and (2) a plurality of hydrophilic molecules. Additional aspects of the present invention pertain to methods of separating organic compounds from a liquid sample by: (1) providing the porous membrane; and (2) flowing the liquid sample through the porous membrane in order to retain organic compounds on the porous membrane. Further aspects of the present invention pertain to systems for separating organic compounds from a liquid sample. Such systems comprises: (1) the porous membrane; and (2) a flowing unit that enables the liquid sample to flow through the porous membrane. Additional aspects of the present invention pertain to methods of making the above-described porous membranes by: (1) coating a surface of a porous membrane containing 0.1 μm pores with a ceramic material; and (2) associating the coated surface of the porous membrane with hydrophilic molecules.
摘要翻译：本发明的各个方面涉及多孔膜，其包括：（1）孔径大于约0.1μm的多个孔; 和（2）多个亲水性分子。本发明的另外的方面涉及通过以下步骤从液体样品中分离有机化合物的方法：（1）提供多孔膜; 和（2）使液体样品流过多孔膜以便将有机化合物保留在多孔膜上。本发明的其它方面涉及从液体样品中分离有机化合物的系统。这种系统包括：（1）多孔膜; 和（2）使液体样品能够流过多孔膜的流动单元。本发明的另外的方面涉及通过以下步骤制造上述多孔膜的方法：（1）用陶瓷材料涂覆含有0.1μm孔的多孔膜的表面; 和（2）将多孔膜的涂覆表面与亲水分子缔合。

45. 发明申请

US20100186665A1 Method for low temperature growth of inorganic materials from solution using catalyzed growth and re-growth 有权
公开(公告)号：US20100186665A1
公开(公告)日：2010-07-29
申请号：US12751434
申请日：2010-03-31
申请人： Andrew R. Barron , Elizabeth Anne Whitsitt
发明人： Andrew R. Barron , Elizabeth Anne Whitsitt
IPC分类号： B05C17/01
CPC分类号： H01L21/316 , C23C8/02 , C23C8/40 , C23C18/00
摘要： The present invention involves a method and apparatus for depositing a silicon oxide onto a substrate from solution at low temperatures in a manner that produces homogeneous growth of the silicon oxide. The method generally comprises the following steps: (a) Chemically treating a substrate to activate it for growth of the silicon oxide. (b) Immersing the treated substrate into a bath with a reactive solution. (c) Regenerating the reactive solution to allow for continued growth of the silicon oxide. In another embodiment of the present invention, the apparatus includes a first container holding a reactive solution, a substrate on which the silicon oxide is deposited, a second container holding silica, and a means for adding silica to the reactive solution.

46. 发明申请

US20100151248A1 Fabrication of light emitting film coated fullerenes and their application for in-vivo emission 有权
标题翻译：发光膜包覆的富勒烯的制备及其在体内发射中的应用
公开(公告)号：US20100151248A1
公开(公告)日：2010-06-17
申请号：US12708225
申请日：2010-02-18
申请人： Andrew R. Barron , Dennis J. Flood , John R. Loscutova
发明人： Andrew R. Barron , Dennis J. Flood , John R. Loscutova
IPC分类号： B05D5/12 , C09K11/65
CPC分类号： G02B6/32 , B82Y15/00 , B82Y20/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C30B7/14 , C30B19/12 , C30B29/48 , C30B29/605 , H01L21/02376 , H01L21/02521 , H01L21/02601 , H01L21/02628 , Y10S977/70 , Y10S977/734 , Y10S977/737 , Y10S977/742 , Y10T428/2991 , Y10T428/30
摘要： A nanoparticle coated with a semiconducting material and a method for making the same. In one embodiment, the method comprises making a semiconductor coated nanoparticle comprising a layer of at least one semiconducting material covering at least a portion of at least one surface of a nanoparticle, comprising: (A) dispersing the nanoparticle under suitable conditions to provide a dispersed nanoparticle; and (B) depositing at least one semiconducting material under suitable conditions onto at least one surface of the dispersed nanoparticle to produce the semiconductor coated nanoparticle. In other embodiments, the nanoparticle comprises a fullerene. Further embodiments include the semiconducting material comprising CdS or CdSe.
摘要翻译：涂覆有半导体材料的纳米颗粒及其制备方法。在一个实施方案中，该方法包括制备半导体涂覆的纳米颗粒，其包含覆盖纳米颗粒的至少一个表面的至少一部分的至少一种半导体材料的层，包括：（A）在合适的条件下分散纳米颗粒以提供分散的纳米颗粒和（B）在合适的条件下将至少一种半导体材料沉积在分散的纳米颗粒的至少一个表面上以产生半导体涂覆的纳米颗粒。在其它实施方案中，纳米颗粒包含富勒烯。其它实施方案包括包含CdS或CdSe的半导体材料。

47. 发明授权

US07718550B2 Method for low temperature growth of inorganic materials from solution using catalyzed growth and re-growth 有权
标题翻译：使用催化生长和再生长从溶液中低温生长无机材料的方法
公开(公告)号：US07718550B2
公开(公告)日：2010-05-18
申请号：US10535358
申请日：2003-11-18
申请人： Andrew R. Barron , Elizabeth Anne Whitsitt
发明人： Andrew R. Barron , Elizabeth Anne Whitsitt
IPC分类号： H01L21/31
CPC分类号： H01L21/316 , C23C8/02 , C23C8/40 , C23C18/00
摘要： The present invention involves a method and apparatus for depositing a silicon oxide onto a substrate from solution at low temperatures in a manner that produces homogeneous growth of the silicon oxide. The method generally comprises the following steps: (a) Chemically treating a substrate to activate it for growth of the silicon oxide. (b) Immersing the treated substrate into a bath with a reactive solution. (c) Regenerating the reactive solution to allow for continued growth of the silicon oxide. In another embodiment of the present invention, the apparatus includes a first container holding a reactive solution, a substrate on which the silicon oxide is deposited, a second container holding silica, and a means for adding silica to the reactive solution.
摘要翻译：本发明涉及一种用于在氧化硅均匀生长的方式在低温下从溶液中沉积氧化硅到衬底上的方法和装置。该方法通常包括以下步骤：（a）化学处理底物以使其活化以生长氧化硅。（b）将经处理的基材浸入具有反应性溶液的浴中。（c）再生反应溶液以允许氧化硅的持续生长。在本发明的另一个实施方案中，该装置包括容纳反应性溶液的第一容器，沉积氧化硅的基底，保持二氧化硅的第二容器和用于向反应溶液中加入二氧化硅的装置。

48. 发明申请

US20090288820A1 Method Of Manufacture And The Use Of A Functional Proppant For Determination Of Subterranean Fracture Geometries 有权
标题翻译：用于确定地下断裂几何的功能性支撑剂的制造方法和使用
公开(公告)号：US20090288820A1
公开(公告)日：2009-11-26
申请号：US12468088
申请日：2009-05-19
申请人： Andrew R. Barron , Robert D. Skala , Christopher E. Coker , Dilip K. Chatterjee , Yuming Xie
发明人： Andrew R. Barron , Robert D. Skala , Christopher E. Coker , Dilip K. Chatterjee , Yuming Xie
IPC分类号： E21B47/00 , E21B43/267 , E21B43/00 , E21B49/00 , C09K8/80
CPC分类号： C09K8/80 , B01J13/02 , B82Y30/00 , C04B35/62807 , C04B35/62823 , C04B35/62839 , C04B35/62842 , C04B35/62894 , C04B2235/3418 , C04B2235/422 , C04B2235/5288 , C09K8/805 , E21B43/00 , E21B43/267 , E21B47/00 , E21B47/12 , E21B49/00 , G01V3/24 , Y10S507/907 , Y10S507/924 , Y10T428/29 , Y10T428/2991 , Y10T428/2993
摘要： Proppants having added functional properties are provided, as are methods that use the proppants to track and trace the characteristics of a fracture in a geologic formation. Information obtained by the methods can be used to design a fracturing job, to increase conductivity in the fracture, and to enhance oil and gas recovery from the geologic formation. The functionalized proppants can be detected by a variety of methods utilizing, for example, an airborne magnetometer survey, ground penetrating radar, a high resolution accelerometer, a geophone, nuclear magnetic resonance, ultra-sound, impedance measurements, piezoelectric activity, radioactivity, and the like. Methods of mapping a subterranean formation are also provided and use the functionalized proppants to detect characteristics of the formation.
摘要翻译：提供了具有添加功能特性的支撑剂，以及使用支撑剂来跟踪和追踪地质构造中的断裂特征的方法。通过该方法获得的信息可用于设计压裂作业，以增加裂缝中的导电性，并提高地质构造中的油气回收率。功能化支撑剂可以通过各种方法利用例如空气磁力计测量，地面穿透雷达，高分辨率加速度计，地震检波器，核磁共振，超声，阻抗测量，压电活动，放射性和类似。还提供了映射地下地层的方法，并使用官能化的支撑剂来检测地层的特征。

49. 发明申请

US20090137433A1 Composition And Method For Making A Proppant 有权
标题翻译：制作支架的组成和方法
公开(公告)号：US20090137433A1
公开(公告)日：2009-05-28
申请号：US12360218
申请日：2009-01-27
申请人： Russell J. Smith , John R. Loscutova , Elizabeth A. Whitsitt , Christopher E. Coker , Andrew R. Barron , Mark Wiesner , Stephen A. Costantino , Rajendra Bordia
发明人： Russell J. Smith , John R. Loscutova , Elizabeth A. Whitsitt , Christopher E. Coker , Andrew R. Barron , Mark Wiesner , Stephen A. Costantino , Rajendra Bordia
IPC分类号： C09K8/60
CPC分类号： C04B18/082 , C04B35/04 , C04B35/10 , C04B35/14 , C04B35/18 , C04B35/44 , C04B35/48 , C04B35/50 , C04B35/505 , C04B38/009 , C09K8/64 , C09K8/66 , C09K8/80 , C09K8/805 , Y02W30/92 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2996 , Y10T428/2998 , C04B38/0045 , C04B38/0655 , C04B20/1066 , C04B38/08
摘要： The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.
摘要翻译：本发明涉及可用于支撑开放的地层成分的支撑剂。进一步公开了使用本发明的一种或多种支撑剂的支持剂制剂。进一步公开了开放的地下成分馏分的方法。此外，还公开了本发明的支撑剂的其它用途，以及制备支撑剂的方法。

50. 发明授权

US07459209B2 Composition and method for making a proppant 有权
标题翻译：制备支撑剂的组成和方法
公开(公告)号：US07459209B2
公开(公告)日：2008-12-02
申请号：US11347664
申请日：2006-02-03
申请人： Russell J. Smith , John R. Loscutova , Elizabeth A. Whitsitt , Christopher E. Coker , Andrew R. Barron , Mark Wiesner , Stephen A. Costantino , Rajendra Kumar Bordia
发明人： Russell J. Smith , John R. Loscutova , Elizabeth A. Whitsitt , Christopher E. Coker , Andrew R. Barron , Mark Wiesner , Stephen A. Costantino , Rajendra Kumar Bordia
IPC分类号： B32B5/16
CPC分类号： C09K8/805 , C04B18/082 , C04B35/04 , C04B35/10 , C04B35/14 , C04B35/18 , C04B35/44 , C04B35/48 , C04B35/50 , C04B35/505 , C04B38/009 , C09K8/64 , C09K8/66 , C09K8/80 , Y02W30/92 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2996 , C04B38/0045 , C04B38/0655 , C04B20/1066 , C04B38/08
摘要： The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.
摘要翻译：本发明涉及可用于支撑开放的地层成分的支撑剂。进一步公开了使用本发明的一种或多种支撑剂的支持剂制剂。进一步公开了开放的地下成分馏分的方法。此外，还公开了本发明的支撑剂的其它用途，以及制备支撑剂的方法。

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