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41. 发明授权

US4528338A Polymerization process using chromium catalyst on mixed metal phosphate with organoboron cocatalysts 失效
标题翻译：使用铬催化剂的混合金属磷酸盐与有机硼助催化剂的聚合方法
公开(公告)号：US4528338A
公开(公告)日：1985-07-09
申请号：US635081
申请日：1984-07-27
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F4/06 , C08F10/00 , C08F4/72
CPC分类号： C08F10/00
摘要： A catalyst system suitable for olefin polymerization comprising a mixed phosphate base made up of 75-99 mole percent aluminum phosphate and 1 to 25 mole percent of a phosphate of at least one other metal selected from gallium, yttrium, zirconium, lanthanum, neodymium and thorium in conjunction with an organoboron cocatalyst. The resulting catalyst system is capable of giving ethylene polymer having relatively low melt index and at the same time exhibits great sensitivity to molecular weight control agents so as to enable the production of a broad spectrum of polymers so far as melt index is concerned from a single catalyst system.
摘要翻译：一种适用于烯烃聚合的催化剂体系，包括由75-99摩尔％的磷酸铝和1至25摩尔％的选自镓，钇，锆，镧，钕和钍的至少一种其它金属的磷酸盐组成的混合磷酸盐基与有机硼助催化剂结合使用。所得到的催化剂体系能够提供具有相对较低熔体指数的乙烯聚合物，并且同时对分子量控制剂显示出很高的灵敏度，以便能够生产广谱聚合物，只要熔体指数从单一催化剂体系。

42. 发明授权

US4460756A Olefin polymerization method 失效
标题翻译：烯烃聚合法
公开(公告)号：US4460756A
公开(公告)日：1984-07-17
申请号：US479238
申请日：1983-03-28
申请人： Max P. McDaniel , John A. Sanbrano , Marvin M. Johnson
发明人： Max P. McDaniel , John A. Sanbrano , Marvin M. Johnson
IPC分类号： B01J23/26 , C08F10/00
CPC分类号： B01J23/26 , C08F10/00
摘要： A supported chromium oxide polymerization catalyst is prepared by a process which includes the steps of heating silica-supported chromium oxide or a substance oxidizable to chromium oxide in a nonoxidizing atmosphere in the presence of formaldehyde or a compound thermally decomposable to formaldehyde, and then heating the thus-treated catalyst in an oxygen-containing atmosphere. The temperatures of the respective heating steps can vary depending upon the properties desired in the polymer to be produced with the invention catalyst; however, the invention catalyst preparation method enables the production of a catalyst having a high melt index potential at relatively low treatment temperatures, e.g. no higher than about 600.degree. C.
摘要翻译：一种负载型氧化铬聚合催化剂的制备方法包括以下步骤：在甲醛或可热分解成甲醛的化合物的存在下，在非氧化性气氛中加热二氧化硅负载的氧化铬或氧化铬的物质，然后加热在含氧气氛中处理的催化剂。各加热步骤的温度可以根据本发明催化剂生产的聚合物中所需的性能而变化; 然而，本发明的催化剂制备方法使得能够在相对低的处理温度下制备具有高熔体指数电位的催化剂，例如，不高于约600℃

43. 发明授权

US4444968A Olefin polymerization with phosphate supported zerovalent chromium 失效
标题翻译：烯烃聚合与磷酸盐支持零价铬
公开(公告)号：US4444968A
公开(公告)日：1984-04-24
申请号：US424803
申请日：1982-09-27
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F10/00 , C08F4/02 , C08F4/62
CPC分类号： C08F10/00
摘要： In accordance with one embodiment of this invention, a zerovalent chromium compound is introduced onto an activated phosphate-containing support and utilized in conjunction with an organometal cocatalyst, such as a trialkylborane. In accordance with another embodiment of this invention, a phosphate-containing xerogel is formed by removing water from an aluminum phosphate-containing hydrogen by means of azeotropic distillation or washing with a volatile, water miscible organic compound, activated and thereafter zerovalent chromium is incorporated therewith. In other embodiments of this invention, a phosphate-containing support is formed by forming aluminum phosphate from an aluminum alkoxide or from a melt, or by phosphating silica or alumina, or by forming an aluminum phosphate/silica combination. A support thus formed is activated and a zerovalent chromium compound added. The resulting catalysts are capable of giving high melt index, broad molecular weight distribution polymer, which polymer also exhibits other deviations from typical olefin polymers including lower flexural modulus. The catalyst is ideally suited for forming olefin polymers such as ethylene and ethylene copolymers in a slurry system.
摘要翻译：根据本发明的一个实施方案，将零价铬化合物引入到活化的含磷酸盐载体上并与有机金属助催化剂如三烷基硼烷结合使用。根据本发明的另一个实施方案，通过共沸蒸馏或用挥发性水混溶性有机化合物洗涤来从含磷酸氢盐的氢中除去水而形成含磷酸的干凝胶，然后活化其中的零价铬。在本发明的其他实施方案中，通过由烷氧基铝或熔体形成磷酸铝，或通过磷酸二氧化硅或氧化铝，或通过形成磷酸铝/二氧化硅组合形成含磷酸盐的载体。如此形成的载体被活化并加入零价铬化合物。所得到的催化剂能够提供高熔体指数，宽分子量分布的聚合物，该聚合物还表现出与典型烯烃聚合物的其它偏差，包括较低的弯曲模量。该催化剂理想地适用于在淤浆体系中形成烯烃聚合物如乙烯和乙烯共聚物。

44. 发明授权

US4404124A Selective hydrogenation catalyst 失效
标题翻译：选择性氢化催化剂
公开(公告)号：US4404124A
公开(公告)日：1983-09-13
申请号：US260946
申请日：1981-05-06
申请人： Marvin M. Johnson , Darrell W. Walker , Gerhard P. Nowack
发明人： Marvin M. Johnson , Darrell W. Walker , Gerhard P. Nowack
IPC分类号： B01J23/44 , B01J23/50 , C07C5/08 , C07C7/167 , B01J23/48 , B01J23/82
CPC分类号： C07C5/08 , B01J23/50 , C07C7/167 , B01J23/44 , B01J35/008 , C07C2523/44 , C07C2523/50 , Y02P20/52
摘要： A catalyst and process for the selective hydrogenation of acetylene, said catalyst comprising palladium and silver with the palladium concentrated as a skin and the silver distributed throughout.
摘要翻译：用于乙炔选择性氢化的催化剂和方法，所述催化剂包含钯和银，其中钯作为皮肤浓缩，银分布在整个过程中。

45. 发明授权

US4398004A Olefin polymerization with phosphated silica-chromium catalyst with boron-containing cocatalyst 失效
标题翻译：烯烃聚合与磷化二氧化硅 - 铬催化剂与含硼助催化剂
公开(公告)号：US4398004A
公开(公告)日：1983-08-09
申请号：US424793
申请日：1982-09-27
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F10/00 , C08F4/02 , C08F4/62
CPC分类号： C08F10/00
摘要： A catalyst system suitable for olefin polymerization comprising a catalyst component made up of chromium on a phosphated silica-containing base and a boron-containing cocatalyst. The resulting catalyst is particularly sensitive to the effects of hydrogen as a molecular weight control agent, thus allowing the production of polymers of having a melt flow varying over a wide spectrum utilizing the same catalyst.
摘要翻译：一种适用于烯烃聚合的催化剂体系，包括由磷化二氧化硅基底上的铬构成的催化剂组分和含硼助催化剂。所得到的催化剂对氢作为分子量控制剂的作用特别敏感，从而允许使用相同的催化剂制备在宽谱上具有变化的熔体流动的聚合物。

46. 发明授权

US4394255A Isomerization process 失效
标题翻译：异构化过程
公开(公告)号：US4394255A
公开(公告)日：1983-07-19
申请号：US395940
申请日：1982-07-07
申请人： Semyon Kukes , Gerhard P. Nowack , Marvin M. Johnson
发明人： Semyon Kukes , Gerhard P. Nowack , Marvin M. Johnson
IPC分类号： B01J27/16 , C07C5/25
CPC分类号： C07C5/2537 , B01J27/16 , C07C5/2562
摘要： An aliphatic mono-olefin e.g. butene-2 is isomerized in the presence of a catalyst comprising zirconium phosphate and zirconium phosphate prepared from an aryl phosphonic acid to produce a corresponding terminal olefin selectively.
摘要翻译：脂族单烯烃丁烯-2在由芳基膦酸制备的包含磷酸锆和磷酸锆的催化剂存在下异构化，以选择性地生成相应的末端烯烃。

47. 发明授权

US4364855A Production of aluminum phosphate from concentrated mass 失效
标题翻译：浓缩磷酸铝生产
公开(公告)号：US4364855A
公开(公告)日：1982-12-21
申请号：US221753
申请日：1980-12-31
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： B01J27/16 , C08F10/00 , B01J27/18 , C01B15/16 , C01B25/16
CPC分类号： C08F10/00 , B01J27/16
摘要： Aluminum orthophosphate is prepared by combining a source of orthophosphate ions with an aluminum salt to form a concentrated mass, gelling, and thereafter converting the resulting hydrogel to a xerogel by removing water. The resulting aluminum phosphate is particularly suited for use as a base for a chromium olefin polymerization catalyst.
摘要翻译：通过将正磷酸盐源与铝盐组合以形成浓缩物质，凝胶化，然后通过除去水将所得水凝胶转化成干凝胶来制备正磷酸铝。所得到的磷酸铝特别适合用作铬烯烃聚合催化剂的基质。

48. 发明授权

US4364842A Phosphate supported chromium catalyst 失效
标题翻译：磷酸盐负载铬催化剂
公开(公告)号：US4364842A
公开(公告)日：1982-12-21
申请号：US221877
申请日：1980-12-31
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F4/00 , C08F4/24 , C08F4/60 , C08F4/69 , C08F10/00 , B01J31/02
CPC分类号： C08F10/00
摘要： In accordance with one embodiment of this invention, a chromium catalyst supported on an aluminum phosphate-containing base is used in conjunction with a boron component either as a part of the base or as a cocatalyst. The resulting catalyst is unique both in its favorable sensitivity to molecular weight control agents such as hydrogen and in its ability to produce a fundamentally different olefin polymer. In accordance with another embodiment of this invention, the chromium is supported on a phosphate base produced using a melt of the aluminum salt.
摘要翻译：根据本发明的一个实施方案，负载在含磷酸铝的碱上的铬催化剂与作为碱的一部分的硼组分或作为助催化剂一起使用。所得催化剂在其对分子量控制剂如氢气的良好的敏感性以及其产生基本上不同的烯烃聚合物的能力方面是独特的。根据本发明的另一个实施方案，将铬负载在使用铝盐熔体制备的磷酸盐基底上。

49. 发明授权

US4309311A Ammonia synthesis with catalyst derived by heating on a support a salt selected from alkali metal, alkaline earth metal, iron and cobalt hexacyanocobaltates and hexacyanoruthenates 失效
公开(公告)号：US4309311A
公开(公告)日：1982-01-05
申请号：US110303
申请日：1980-01-08
申请人： Marvin M. Johnson , Donald C. Tabler , Gerhard P. Nowack
发明人： Marvin M. Johnson , Donald C. Tabler , Gerhard P. Nowack
IPC分类号： B01J27/26 , C01C1/04 , B01J27/24 , C01C3/11 , C01C3/12
CPC分类号： B01J27/26 , C01C1/0411 , Y02P20/52
摘要： Synthesis of ammonia employing at least one salt selected from alkali metal-, an alkaline earth metal-, iron- and cobalt hexacyanocobaltate and hexacyanoruthenate on a suitable support and then heating the composition to provide it with suitable activity.

50. 发明授权

US4276200A Catalyst and process for producing hydroperoxides 失效
标题翻译：催化剂和生产氢过氧化物的方法
公开(公告)号：US4276200A
公开(公告)日：1981-06-30
申请号：US94253
申请日：1979-11-14
申请人： Yulin Wu , Marvin M. Johnson , Gerhard P. Nowack
发明人： Yulin Wu , Marvin M. Johnson , Gerhard P. Nowack
IPC分类号： B01J23/50 , C07C409/04 , C07C409/08 , C07C409/10 , C07C409/14 , C07C409/40 , B01J27/20 , B01J21/10 , B01J23/06
CPC分类号： B01J23/50 , C07C409/08 , C07C409/14 , C07C2101/14
摘要： Organic hydroperoxides are prepared by reacting an organic compound with oxygen in the presence of a novel catalyst comprising metallic silver supported upon an inorganic support selected from the oxides and carbonates of metals of Groups IIa, IIb, IIIb, and IVb.
摘要翻译：有机氢过氧化物是通过有机化合物与氧反应制备的，该催化剂包含负载在选自IIa，Ⅱb，Ⅲb和Ⅳb族金属的氧化物和碳酸酯的无机载体上的金属银的新型催化剂。

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