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41. 发明授权

US4880859A Light-stabilized star polymer microparticles 失效
标题翻译：光稳定的星形聚合物微粒
公开(公告)号：US4880859A
公开(公告)日：1989-11-14
申请号：US202741
申请日：1988-06-03
申请人： Mario Slongo , Jean Rody , Franciszek Sitek , Andreas Valet
发明人： Mario Slongo , Jean Rody , Franciszek Sitek , Andreas Valet
IPC分类号： C08J3/12 , C08F20/10 , C08F20/52 , C08F220/00 , C08F220/10 , C08F220/12 , C08F220/20 , C08F220/54 , C08F220/56 , C08F291/00 , C08F293/00 , C08F297/00 , C08F297/02 , C08K5/3435 , C08K5/3495 , C08L53/00 , C09D133/02 , C09D133/04 , C09D133/24 , C09D153/00
CPC分类号： C08K5/3435 , C08F293/005 , C09D153/00
摘要： Light-stabilized star polymer microparticles are described which are prepared with particular advantage by group transfer polymerization. The light stabilization is effected by carrying out at least a part step of the polymerization in the presence of a light stabilizer, for example a hindered amine or/and a UV absorber. With particular advantage, those light stabilizers are used which contain reactive groups in the molecule and, in this way, can be chemically incorporated into the polymer. The polymer microparticles show excellent light stability and are outstandingly suitable as constituents in coating compositions which can be processed, for example, to give coating films of high light stability.
摘要翻译：描述了通过组转移聚合特别有利地制备的光稳定的星形聚合物微粒。光稳定化通过在光稳定剂例如受阻胺或/和UV吸收剂的存在下进行聚合的至少一部分步骤来实现。特别有利的是，使用在分子中含有反应性基团的这些光稳定剂，并且以这种方式可以化学地掺入到聚合物中。聚合物微粒显示出优异的光稳定性，并且作为可以加工的涂料组合物中的成分非常适合，例如得到高光稳定性的涂膜。

42. 发明授权

US4629682A Recording material for color photography 失效
标题翻译：录制材料进行彩色摄影
公开(公告)号：US4629682A
公开(公告)日：1986-12-16
申请号：US717096
申请日：1985-03-28
申请人： David G. Leppard , Jean Rody
发明人： David G. Leppard , Jean Rody
IPC分类号： G03C7/26 , C07D211/14 , C07D211/46 , C07D211/58 , C07D409/12 , C07D409/14 , C07D413/04 , G03C7/392 , G03C1/40 , G03C1/84
CPC分类号： C07D409/12 , C07D211/14 , C07D211/46 , C07D211/58 , C07D409/14 , C07D413/04 , G03C7/39248
摘要： Recording material for color photography which contains in at least one photosensitive silver halide emulsion layer, one intermediate layer and/or one protective layer, at least one polyalkylpiperidine compound of the formula I ##STR1## in which n is the number 0 or 1 and X is a group of the formula ##STR2## or of the formula ##STR3## Color-forming agents which are obtained by imagewise exposure and development of this recording material for color photography are particularly stable towards the effect of visible and ultraviolet light.Reference is made to the description in respect of the meanings of the substituents and symbols in the formulae.
摘要翻译：用于彩色摄影的记录材料，其包含至少一个光敏卤化银乳剂层，一个中间层和/或一个保护层，至少一种式I的聚烷基哌啶化合物（I），其中n是数字0或 1和X是通过图像曝光和显影这种用于彩色摄影的记录材料获得的成色剂“IMAGE”或式“IMAGE”的成色剂对于可见光和紫外光的作用特别稳定。参考关于式中取代基和符号的含义的描述。

43. 发明授权

US4518679A Color-photographic recording material 失效
标题翻译：彩色摄影材料
公开(公告)号：US4518679A
公开(公告)日：1985-05-21
申请号：US557366
申请日：1983-12-02
申请人： David G. Leppard , Jean Rody
发明人： David G. Leppard , Jean Rody
IPC分类号： G03C7/26 , C07D471/10 , C07D491/10 , G03C7/392 , G03C7/40
CPC分类号： C07D471/10 , C07D491/10 , G03C7/39248
摘要： A color-photographic recording material which, in at least one light-sensitive silver halide emulsion layer, one intermediate layer and/or one protective layer, contains, as a stabilizer, at least one polyalkylpiperidine compound of the formula I or II ##STR1## in which m is the numbers 1 or 2 and, if m=1, A is a group of the formula ##STR2## and, if m=2, A is a group of the formula ##STR3## Color images which are obtained by image-wise exposure and development of this color-photographic recording material, display good stability towards the action of visible and ultraviolet light.Reference is made to the description in respect of the meanings of the substituents and symbols in the formulae I and II.
摘要翻译：一种彩色照相记录材料，其在至少一个感光卤化银乳剂层中，一个中间层和/或一个保护层中含有至少一种式I或II的多烷基哌啶化合物作为稳定剂，（I）（II）其中m是数字1或2，并且如果m = 1，则A是公式“IMAGE”的组，并且如果m = 2，则A是式图像>通过图像曝光和显影这种彩色照相记录材料获得的彩色图像，对可见光和紫外光的作用显示良好的稳定性。参考式I和II中取代基和符号的含义的描述。

44. 发明授权

US4465765A Colorphotographic recording material 失效
标题翻译：彩色照相记录材料
公开(公告)号：US4465765A
公开(公告)日：1984-08-14
申请号：US523411
申请日：1983-08-16
申请人： David G. Leppard , Jean Rody
发明人： David G. Leppard , Jean Rody
IPC分类号： G03C7/26 , C07D211/46 , C07D211/58 , G03C7/392 , G03C1/84
CPC分类号： G03C7/39248 , C07D211/46 , C07D211/58
摘要： Compounds of the formula I ##STR1## in which A is a direct bond or a substituted or unsubstituted alkylene radical, X is --O-- or --N(R.sup.16)--, R.sup.2 is a monovalent radical, R.sup.5 or R.sup.3 is hydroxyl, and R.sup.1, R.sup.4, R.sup.6, R.sup.7 and R.sup.8 are hydrogen or monovalent radicals, are effective stabilizers for photographic dyes and precursors thereof. In particular, they increase the light fastness of the developed color images.
摘要翻译：其中A是直接键或取代或未取代的亚烷基的式I（I）化合物，X是-O-或-N（R 16） - ，R 2是单价基团，R 5或R 3是羟基 R 1，R 4，R 6，R 7和R 8为氢或一价基团，是照相染料及其前体的有效稳定剂。特别地，它们增加了显影的彩色图像的耐光性。

45. 发明授权

US4369275A Malonate derivatives as stabilizers for organic materials 失效
标题翻译：丙二酸酯衍生物作为有机材料的稳定剂
公开(公告)号：US4369275A
公开(公告)日：1983-01-18
申请号：US271263
申请日：1981-06-08
申请人： Jean Rody
发明人： Jean Rody
IPC分类号： C08K5/00 , C07D211/46 , C07D211/94 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/02 , C08L25/04 , C08L51/00 , C08L51/02 , C08L75/06 , C08L101/00 , C09K15/30 , C07D401/12
CPC分类号： C09K15/30 , C07D211/46 , C08K5/3435
摘要： Malonates of the formula I ##STR1## in which R.sub.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sub.2 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.4 -alkenyl, benzyl or phenyl which is optionally substituted by C.sub.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.8 -alkoxy, or is cyano, R.sub.3 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.4 -alkenyl or benzyl and X denotes hydrogen, oxyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.2 -C.sub.21 -alkoxyalkyl, C.sub.7 -C.sub.8 -aralkyl, 2,3-epoxypropyl, an aliphatic acyl group with 1-4 C atoms or one of the groups --CH.sub.2 COOR.sub.4, --CH.sub.2 -CH(R.sub.5)--OR.sub.6, --COOR.sub.7 or --CONHR.sub.7, in which R.sub.4 is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.6 -alkenyl, phenyl, C.sub.7 -C.sub.8 -aralkyl or cyclohexyl and R.sub.5 is hydrogen, methyl or phenyl and R.sub.6 denotes hydrogen or an aliphatic or aromatic, araliphatic or alicyclic acyl group with 1-18 C atoms, in which the aromatic part can optionally be substituted by chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.8 -alkoxy and/or by hydroxyl, and R.sub.7 is C.sub.1 -C.sub.12 -alkyl, cyclohexyl, phenyl or benzyl as stabilizer for organic polymers.
摘要翻译：其中R 1是氢或C 1 -C 4 - 烷基，R 2是C 1 -C 12 - 烷基，C 3 -C 4 - 链烯基，苄基或被C 1 -C 8 - 烷基任意取代的苯基的式I化合物或C 1 -C 8 - 烷氧基，或者是氰基，R 3是C 1 -C 12 - 烷基，C 3 -C 4 - 烯基或苄基，X表示氢，氧基，C 1 -C 12烷基，C 3 -C 6 - 烯基，C 3 -C 4 - ，C 2 -C 21 - 烷氧基烷基，C 7 -C 8 - 芳烷基，2,3-环氧丙基，具有1-4个C原子的脂族酰基或基团-CH 2 COOR 4，-CH 2 -CH（R 5）-OR 6，-COOR 7或 -CONHR 7，其中R 4是C 1 -C 8 - 烷基，C 3 -C 6 - 烯基，苯基，C 7 -C 8 - 芳烷基或环己基，R 5是氢，甲基或苯基，R 6表示氢或脂族或芳族，芳脂族或脂环族酰基其中芳族部分可以任选被氯，C 1 -C 4 - 烷基或C 1 -C 8 - 烷氧基和/或被羟基取代，并且R 7是C 1 -C 12 - 烷基，环己基，苯基或苄基作为有机聚合物的稳定剂。

46. 发明授权

US4299926A Polymeric light stabilizers for plastics 失效
标题翻译：用于塑料的聚合物光稳定剂
公开(公告)号：US4299926A
公开(公告)日：1981-11-10
申请号：US175689
申请日：1980-08-05
申请人： Jean Rody , Michael Rasberger
发明人： Jean Rody , Michael Rasberger
IPC分类号： C08G69/00 , C08F26/00 , C08G18/00 , C08G18/28 , C08G18/32 , C08G63/00 , C08G63/68 , C08G63/685 , C08G64/00 , C08G65/00 , C08G69/26 , C08G71/00 , C08G71/02 , C08G73/00 , C08G73/02 , C08G73/06 , C08G77/54 , C08G85/00 , C08K5/00 , C08K5/34 , C08K5/3412 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/02 , C08L23/04 , C08L23/10 , C08L25/04 , C08L27/00 , C08L27/04 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L59/00 , C08L67/00 , C08L75/00 , C08L75/06 , C08L77/00 , C08L77/02 , C08L101/00
CPC分类号： C08G85/00 , C08G18/32 , C08G18/3246 , C08G63/685 , C08G69/26 , C08G71/02 , C08G73/0627 , C08G77/54 , C08L101/00
摘要： Condensation polymers or addition polymers which contain sterically hindered polyalkylpiperidine groups are proposed as light stabilizers for plastics. The polymers concerned are relatively low-molecular polymers and a difunctional derivatives of a polyalkylpiperidine is additionally used for the manufacture of these. The piperidine radical can be present in the main chain or as a side group of the polymeric stabilizer. Polymeric stabilizers of this type do not tend to migrate out of the plastic or to be removed by extraction; they are therefore very permanent in use.
摘要翻译：提出含有空间位阻聚烷基哌啶基团的缩合聚合物或加成聚合物作为塑料的光稳定剂。所涉及的聚合物是相对低分子量的聚合物，并且另外使用聚烷基哌啶的双官能衍生物来制造这些聚合物。哌啶基可以存在于主链或作为聚合物稳定剂的侧基。这种类型的聚合物稳定剂不会倾向于从塑料中迁移或通过萃取而被除去; 因此它们在使用中是非常永久的。

47. 发明授权

US4250268A Polysilylesters having a polyalkylpiperidine as part of the polymer useful as light stabilizers for plastics 失效
标题翻译：具有聚烷基哌啶作为聚合物的一部分的聚甲硅烷酯可用作塑料的光稳定剂
公开(公告)号：US4250268A
公开(公告)日：1981-02-10
申请号：US964443
申请日：1978-11-28
申请人： Jean Rody , Michael Rasberger
发明人： Jean Rody , Michael Rasberger
IPC分类号： C07D211/14 , C07D211/22 , C07D211/34 , C07D211/44 , C07D211/58 , C07D211/66 , C07D211/94 , C07D471/10 , C07D491/22 , C07D498/10 , C08G77/62 , C08K5/544 , C08L101/00 , C08G77/26
CPC分类号： C07D471/10 , C07D211/14 , C07D211/22 , C07D211/34 , C07D211/44 , C07D211/58 , C07D211/66 , C07D211/94 , C08G77/62 , C08K5/5442 , C08L101/00
摘要： Condensation polymers or addition polymers which contain sterically hindered polyalkylpiperidine groups are proposed as light stabilizers for plastics. The polymers concerned are relatively low-molecular polymers and a difunctional derivative of a polyalkylpiperidine is additionally used for the manufacture of these. The piperidine radical can be present in the main chain or as a side group of the polymeric stabilizer. Polymeric stabilizers of this type do not tend to migrate out of the plastic or to be removed by extraction; they are therefore very permanent in use.
摘要翻译：提出含有空间位阻聚烷基哌啶基团的缩合聚合物或加成聚合物作为塑料的光稳定剂。所涉及的聚合物是相对低分子量的聚合物，并且另外使用多烷基哌啶的双官能衍生物来制造这些聚合物。哌啶基可以存在于主链或作为聚合物稳定剂的侧基。这种类型的聚合物稳定剂不会倾向于从塑料中迁移或通过萃取而被除去; 因此它们在使用中是非常永久的。

48. 发明授权

US4237297A Piperidine containing malonic acid derivatives 失效
标题翻译：哌啶含有丙二酸衍生物
公开(公告)号：US4237297A
公开(公告)日：1980-12-02
申请号：US91630
申请日：1979-11-05
申请人： Jean Rody , Friedrich Karrer
发明人： Jean Rody , Friedrich Karrer
IPC分类号： C08K5/00 , C07D211/14 , C07D211/46 , C07D211/58 , C07D295/088 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L101/00 , C09D7/12 , C07D401/12
CPC分类号： C07D295/088 , C07D211/46 , C07D211/58 , C08K5/3435 , C09D7/1241
摘要： Malonic acid derivatives of the formula ##STR1## wherein Z contain sterically hindered piperidines as stabilizers against light-induced degradation for organic material.
摘要翻译：其中Z含有空间位阻哌啶作为稳定剂用于有机材料的光诱导降解的式“IMAGE”的丙二酸衍生物。

49. 发明授权

US4127586A Light protection agents 失效
标题翻译：防光剂
公开(公告)号：US4127586A
公开(公告)日：1978-11-28
申请号：US621453
申请日：1975-10-10
申请人： Jean Rody , Hansjorg Heller
发明人： Jean Rody , Hansjorg Heller
IPC分类号： C07D249/20 , C08K5/3475 , C09K15/30 , D06M13/35
CPC分类号： D06M13/35 , C07D249/20 , C08K5/3475 , C09K15/30
摘要： New 2-(2'-hydroxyphenyl)-benzotriazoles are used for protecting light-sensitive organic materials. They are prepared by diazotization of a 2-nitroaniline, coupling of the resulting diazo compound with a phenol and reduction of the resulting 2-nitroazo compound.
摘要翻译：新的2-（2'-羟基苯基） - 苯并三唑用于保护光敏有机材料。它们通过2-硝基苯胺的重氮化，所得重氮化合物与苯酚的偶合和所得2-硝基偶氮化合物的还原制备。

50. 发明授权

US4123418A Stabilizer system for stabilizing styrene polymers 失效
标题翻译：用于稳定苯乙烯聚合物的稳定剂体系
公开(公告)号：US4123418A
公开(公告)日：1978-10-31
申请号：US638125
申请日：1975-12-05
申请人： Bernard Gilg , Helmut Muller , Jean Rody
发明人： Bernard Gilg , Helmut Muller , Jean Rody
IPC分类号： C08K5/00 , C07D211/46 , C08K5/13 , C08K5/132 , C08K5/17 , C08K5/20 , C08K5/34 , C08K5/3412 , C08K5/3417 , C08K5/3435 , C08K5/3442 , C08K5/3475 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L101/00 , C09K15/08
CPC分类号： C08K5/3475 , C08K5/132 , C08K5/20 , C08K5/3435
摘要： Stabilizer system consisting of(a) at least one sterically hindered cyclic amine of the formula I ##STR1## in which q is 1 or 2, X represents an organic grouping which complements the nitrogen-containing ring to give a 5-membered, 6-membered or 7-membered ring, R.sub.1 and R.sub.2 represent methyl or together represent --(CH.sub.2).sub.5 --, R.sub.3 represents methyl, R.sub.4 represents alkyl with 1-5 carbon atoms or together with R.sub.3 represents the radicals --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.5 -- ##STR2## and, if q is 1, Y denotes hydrogen, --0.sup.., hydroxyl, alkyl, substituted akyl, alkenyl, alkinyl, aralkyl, substituted aralkyl or acyl or, if q is 2, Y denotes alkylene, alkenylene, alkinylene, cycloalkylene or aralkylene, and(b) at least one co-stabilizer for stabilizing plastics.
摘要翻译：稳定剂体系包括（A）式（I）的至少一种定性循环胺，其中q为1或2，X表示与含氮环互补的有机基团，得到5元，6元或7元环，R 1和R 2表示甲基或一起表示 - （CH 2）5 - ，R 3表示甲基，R 4表示具有1-5个碳原子的烷基或与R 3一起代表基团 - （CH 2）4 - ， - （CH 2）5 - ，并且如果q是1，Y表示氢，-O，羟基，烷基，取代的烷基，烯基，炔基，芳烷基，取代的芳烷基或酰基，或者如果q是2， Y表示亚烷基，亚烯基，亚炔基，亚环烷基或亚芳烷基，和（B）用于稳定塑料的至少一种稳定剂。

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