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41. 发明申请

US20110230692A1 Process for producing high quality gasoline blending components in two modes 有权
标题翻译：以两种模式生产高品质汽油调和组分的方法
公开(公告)号：US20110230692A1
公开(公告)日：2011-09-22
申请号：US12725987
申请日：2010-03-17
申请人： Hye-Kyung Timken , Shawn Winter , Howard S. Lacheen , Sven Ivar Hommeltoft
发明人： Hye-Kyung Timken , Shawn Winter , Howard S. Lacheen , Sven Ivar Hommeltoft
IPC分类号： C07C2/54 , B01J8/00
CPC分类号： C10G29/205 , C07C2/58 , C07C2527/125 , C07C2531/02 , C10G2300/20 , C10G2300/202 , C10G2300/305 , C10G2400/02 , C07C9/16
摘要： We provide a process for producing high quality gasoline blending components, comprising: a) operating an alkylation reactor in an alkylate mode wherein a gasoline blending component is made having a RON of 90 or higher; and b) operating the alkylation reactor in a distillate mode wherein a second gasoline blending component and a distillate product is made, and wherein the second gasoline blending component has a RON of 85 or higher. Also, we provide an alkylation process unit, comprising: a control system connected to an alkylation reactor, that enables the alkylation reactor to operate in both an alkylate mode that produces a gasoline blending component having a RON of 90 or higher and in a distillate mode that produces a second gasoline blending component having a RON of 85 or higher.
摘要翻译：我们提供一种生产高质量汽油调和组分的方法，包括：a）以烷基化方式操作烷基化反应器，其中制得的RON为90或更高的汽油共混组分; 和b）以蒸馏模式操作所述烷基化反应器，其中制备第二汽油调和组分和馏出物产物，并且其中所述第二汽油调和组分具有85或更高的RON。另外，我们提供烷基化处理单元，其包括：连接到烷基化反应器的控制系统，其使得烷基化反应器能够以产生RON为90或更高的汽油调和组分的烷基化模式和馏出模式其产生RON为85以上的第二汽油调和组分。

42. 发明申请

US20110184219A1 ALKYLATION PROCESS COMPRISING MONITORING IONIC LIQUID CATALYST ACIDITY 审中-公开
标题翻译：包含监测离子液体催化剂酸度的烷基化方法
公开(公告)号：US20110184219A1
公开(公告)日：2011-07-28
申请号：US13008633
申请日：2011-01-18
申请人： Hye Kyung Timken , Annie T. Pathiparampil
发明人： Hye Kyung Timken , Annie T. Pathiparampil
IPC分类号： C07C2/58
CPC分类号： G01N31/10 , B01J27/06 , B01J27/125 , B01J31/00 , B01J31/0284 , B01J31/40 , C07C2/58 , C10G11/02 , C10G29/06 , C10G29/205 , C10G50/00 , G01N31/16 , Y02P20/584 , Y10T436/145555 , C07C9/16
摘要： A process for determining ionic liquid catalyst deactivation including (a) collecting at least one sample of an ionic liquid catalyst; (b) hydrolyzing the at least one sample to provide at least one hydrolyzed sample; (c) titrating the at least one hydrolyzed sample with a basic reagent to determine a volume of the basic reagent necessary to neutralize a Lewis acid species of the ionic liquid catalyst; and (d) calculating the acid content of the at least one sample from the volume of basic reagent determined in step (c) is described. Processes incorporating such a process for determining ionic liquid catalyst deactivation are also described. These processes are an alkylation process, a process for controlling ionic liquid catalyst activity in a reaction producing by-product conjunct polymers, and a continuous process for maintaining the acid content of an ionic liquid catalyst at a target acid content in a reaction producing by-product conjunct polymers.
摘要翻译：一种用于测定离子液体催化剂失活的方法，包括（a）收集至少一种离子液体催化剂样品; （b）水解所述至少一种样品以提供至少一种水解样品; （c）用碱性试剂滴定至少一种水解样品以确定中和离子液体催化剂的路易斯酸物质所需的碱性试剂的体积; 并且（d）描述从步骤（c）中确定的碱性试剂的体积计算至少一种样品的酸含量。还描述了结合这种用于确定离子液体催化剂失活的方法的方法。这些方法是烷基化方法，用于控制产生副产物结合聚合物的反应中的离子液体催化剂活性的方法，以及在反应生成副产物的反应中将离子液体催化剂的酸含量保持在目标酸含量的连续方法，产品结合聚合物。

43. 发明申请

US20110155632A1 PROCESS FOR MAKING PRODUCTS WITH LOW HYDROGEN HALIDE. 有权
标题翻译：用低氢卤化物制造产品的方法。
公开(公告)号：US20110155632A1
公开(公告)日：2011-06-30
申请号：US12650816
申请日：2009-12-31
申请人： Hye-Kyung Timken , Christine Phillips , Robert F. Cleverdon
发明人： Hye-Kyung Timken , Christine Phillips , Robert F. Cleverdon
IPC分类号： C10L1/04 , C10G7/00
CPC分类号： C10G7/00 , C10G7/08 , C10G29/205 , C10G45/60 , C10G50/00 , C10G57/00 , C10G57/005 , C10G57/02 , C10G2300/305 , C10G2300/4081 , C10G2400/02
摘要： A process for making products with low hydrogen halide, comprising: a) stripping or distilling an effluent from a reactor into a first fraction having an amount of hydrogen halide, and a second fraction having a reduced amount of hydrogen halide; wherein the reactor comprises: an ionic liquid catalyst having a metal halide, and a hydrogen halide or an organic halide; and b) recovering one or more product streams, from the second fraction, having less than 25 wppm hydrogen halide. In one embodiment the ionic liquid catalyst has metal halide; and the recovering recovers propane, n-butane, and alkylate gasoline having less than 25 wppm hydrogen halide. In another embodiment the recovering uses a distillation column having poor corrosion resistance to hydrogen halide; and the distillation column does not exhibit corrosion. There is also provided an alkylate gasoline having less than 5 wppm hydrogen halide, a high RON, and low RVP.
摘要翻译：一种制备具有低卤化氢的产物的方法，包括：a）将反应器的流出物汽提或蒸馏成具有一定量卤化氢的第一级分，和具有减少量的卤化氢的第二级分; 其中所述反应器包括：具有金属卤化物的离子液体催化剂和卤化氢或有机卤化物; 和b）从具有小于25wppm卤化氢的第二级分回收一种或多种产物流。在一个实施方案中，离子液体催化剂具有金属卤化物; 并且回收回收具有小于25wppm卤化氢的丙烷，正丁烷和烷基化汽油。在另一个实施方案中，回收使用对卤化氢具有差的耐腐蚀性的蒸馏塔; 并且蒸馏塔不显示腐蚀。还提供了具有小于5wppm卤化氢，高RON和低RVP的烷基化汽油。

44. 发明申请

US20110105811A1 PRODUCTION OF DISTILLATE BLENDING COMPONENTS 审中-公开
标题翻译：蒸馏混合组分的生产
公开(公告)号：US20110105811A1
公开(公告)日：2011-05-05
申请号：US12610010
申请日：2009-10-30
申请人： Dennis J. O'Rear , Sven Ivar Hommeltoft , Steve S. Mathur , Jerome F. Mayor , Hye-Kyung Timken
发明人： Dennis J. O'Rear , Sven Ivar Hommeltoft , Steve S. Mathur , Jerome F. Mayor , Hye-Kyung Timken
IPC分类号： C07C7/20 , C07C2/62 , C07C2/60
CPC分类号： C10G2/32 , B01J27/125 , B01J31/0277
摘要： A process to produce an alkylate distillate blending component in one embodiment comprising: providing at least one olefinic C5+ product which was produced by conversion of synthesis gas in a Fischer Tropsch process; and alkylating the olefinic C5+ product in the presence of an acidic ionic liquid alkylation catalyst with hydrocarbons selected from the group consisting of isoparaffins, cycloparaffins, and their mixtures to form an alkylate distillate blending component is described.
摘要翻译：一种在一个实施方案中生产烷基化馏分共混组分的方法，包括：提供至少一种烯烃C5 +产物，其通过在费托方法中转化合成气产生; 并在酸性离子液体烷基化催化剂存在下烷烃化烯烃C5 +产物，其中烃选自异链烷烃，环烷烃及其混合物，形成烷基化物馏分共混组分。

45. 发明申请

US20060135839A1 Alkylation process using chloroaluminate ionic liquid catalysts 有权
标题翻译：使用氯铝酸盐离子液体催化剂的烷基化方法
公开(公告)号：US20060135839A1
公开(公告)日：2006-06-22
申请号：US11021165
申请日：2004-12-21
申请人： Saleh Elomari , Steve Trumbull , Hye Kyung Timken , Robert Cleverdon
发明人： Saleh Elomari , Steve Trumbull , Hye Kyung Timken , Robert Cleverdon
IPC分类号： C07C2/58
CPC分类号： C10G29/205 , C07C2/58 , C10G50/00 , C07C9/16
摘要： A process for the production of a high quality gasoline blending components from refinery process streams by the alkylation of light isoparaffins with olefins using an ionic liquid catalyst is disclosed. The process includes reacting a refinery stream containing isopentane and/or isobutane with a refinery stream containing ethylene and/or propylene and butylenes under alkylation conditions in the presence of a chloroaluminate ionic liquid catalyst comprising a hydrocarbyl substituted pyridinium halide or a hydrocarbyl substituted imidazolium halide of the general formulas A and B, respectively. Where R=H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a halide and preferably a chloride, and R1 and R2=H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and where R1 and R2 may or may not be the same.
摘要翻译：公开了一种通过使用离子液体催化剂通过烯烃使轻质异链烷烃烷基化从炼厂工艺流中生产高品质汽油调和组分的方法。该方法包括在烷基化条件下，在氯铝酸盐离子液体催化剂存在下使包含异戊烷和/或异丁烷的炼油厂物流与含有乙烯和/或丙烯和丁烯的炼油厂物流反应，所述氯铝酸盐离子液体催化剂包含烃基取代的吡啶鎓卤化物或烃基取代的咪唑鎓卤化物分别是通式A和B。其中R = H，甲基，乙基，丙基，丁基，戊基或己基，X是卤化物，优选氯化物，R1和R2 = H，甲基，乙基，丙基，丁基，戊基或己基，其中R1和 R2可能或可能不一样。

46. 发明申请

US20050189260A1 Gasoline sulfur reduction in fluid catalytic cracking 有权
公开(公告)号：US20050189260A1
公开(公告)日：2005-09-01
申请号：US11118541
申请日：2005-04-29
申请人： Arthur Chester , Terry Roberie , Hye Kyung Timken , Michael Ziebarth
发明人： Arthur Chester , Terry Roberie , Hye Kyung Timken , Michael Ziebarth
IPC分类号： B01J29/072 , B01J29/076 , B01J29/16 , C10G11/05
CPC分类号： B01J29/076 , B01J29/072 , B01J29/166 , B01J2229/42 , C10G11/05
摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.

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