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41. 发明授权

US07247287B2 Synthesis of aluminophosphates and silicoaluminophosphates 有权
标题翻译：铝磷酸盐和硅铝磷酸盐的合成
公开(公告)号：US07247287B2
公开(公告)日：2007-07-24
申请号：US10459204
申请日：2003-06-11
申请人： Guang Cao , Matu J. Shah
发明人： Guang Cao , Matu J. Shah
IPC分类号： C01B37/08
CPC分类号： C01B37/04 , B01J29/85 , B01J2229/42 , C01B37/08 , C01B39/54 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2400/20 , Y10S423/30 , C07C11/02
摘要： The invention is directed to a method of synthesising silicoaluminophosphate and aluminophosphate molecular sieves using synthesis templates that contain at least one template of general formula R1R2N—R3, wherein R1 and R2 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R3 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms, and 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S. In particular, the present invention relates to the synthesis of silicoaluminophosphate molecular sieves of the CHA framework type having a low silicon to aluminium atomic ratio.
摘要翻译：本发明涉及一种使用含有至少一个通式为R 1，R 2，R 2，R 3，R 3，R 3，R 3，R 3，其中R 1和R 2独立地选自具有1至3个碳原子的烷基和具有1至3个碳原子的羟基烷基原子 R 3选自4-8元环烷基，任选被1至3个具有1至3个碳原子的烷基取代，以及4至8元杂环基具有1至3个杂原子，所述杂环基团任选被1至3个具有1至3个碳原子的烷基取代，并且所述杂环基中的杂原子选自O，N和S.特别地，本发明涉及具有低硅铝原子比的CHA骨架类型的硅铝磷酸盐分子筛的合成。

42. 发明申请

US20070100185A1 Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
标题翻译：含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途
公开(公告)号：US20070100185A1
公开(公告)日：2007-05-03
申请号：US11521155
申请日：2006-09-14
申请人： Guang Cao , Machteld Mertens , Matu Shah , Marc Anthonis , Hailian Li , Anil Guram , Robert Saxton , Mark Muraoka , Jeffrey Yoder , Anthony Volpe
发明人： Guang Cao , Machteld Mertens , Matu Shah , Marc Anthonis , Hailian Li , Anil Guram , Robert Saxton , Mark Muraoka , Jeffrey Yoder , Anthony Volpe
IPC分类号： C07C1/00 , C01B39/00 , C01B39/48
CPC分类号： C01B39/48 , B01J29/70 , B01J29/7015 , B01J29/80 , C01B37/02 , C01B39/023 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/1011 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R1R2R3N—R4]+Q− wherein R1 and R2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R1 and R2 may be joined to form a nitrogen-containing heterocyclic structure, R3 is an alkyl group having 2 to 4 carbon atoms and R4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R3 and R4 are hydrocarbyl groups having from 1 to 3 carbon atoms joined to form a nitrogen-containing heterocyclic structure; and Q− is a anion.
摘要翻译：包含菱沸石型框架分子筛的结晶材料，特别是高二氧化硅沸石的合成在有机导向剂的存在下进行，所述有机导向剂具有以下结构式：<？in-line-formula description =“In-line 公式“end =”lead“？> [R 1] 2 3 <？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1和R 2 > 2个独立地选自烃基和具有1至3个碳原子的羟基取代的烃基，条件是R 1和R 2可以连接形成含氮杂环结构，R 3是具有2至4个碳原子的烷基，R 4选自4-至8-元环烷基任选被1至3个具有1至3个碳原子的烷基取代; 和具有1至3个杂原子的4至8元杂环基，所述杂环基任选被1至3个具有1至3个碳原子的烷基取代，并且所述杂环基中的每个杂原子被选定由O，N和S组成的组，或R 3和R 4是具有1至3个碳原子的烃基，连接形成含氮杂环结构体; 而Q ^{是阴离子。}

43. 发明授权

US6080303A Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus 失效
标题翻译：沸石催化剂活性提高磷酸铝和磷
公开(公告)号：US6080303A
公开(公告)日：2000-06-27
申请号：US38649
申请日：1998-03-11
申请人： Guang Cao , Luc R. M. Martens , Jeffrey L. White , Tan-Jen Chen , Matu J. Shah
发明人： Guang Cao , Luc R. M. Martens , Jeffrey L. White , Tan-Jen Chen , Matu J. Shah
IPC分类号： B01J29/84 , B01J27/16 , B01J29/06 , C10G11/05 , C10G11/18
CPC分类号： C10G11/05 , B01J27/16 , B01J29/06
摘要： The present invention provides a process for improving the catalytic activity of small and medium pore acidic zeolite catalyst which comprises the steps of treating a zeolite with a phosphorus compound to form a phosphorus treated zeolite and combining the phosphorus treated zeolite with AlPO.sub.4. Optionally the phosphorus treated zeolite is calcined. The step of combining the zeolite with AlPO.sub.4 may optionally be followed by steaming the combined catalyst. Examples of useful phosphorus containing compounds useful in treating the zeolite include phosphoric acid, ammonium mono or dihydrogen phosphate, organic phosphites, and organophosphines. Preferably the phosphorus containing compound is an ammonium acid phosphate. An additional alternate embodiment provides a process for increasing the hydrothermal stability of a zeolite catalyst which comprises first treating a zeolite with a phosphorus containing compound then blending with AlPO.sub.4. The catalyst of the invention may be combined with other catalysts or used alone. The invention may be used in a process for cracking hydrocarbons which comprises contacting a hydrocarbon feedstock with a catalyst prepared as described above.
摘要翻译：本发明提供了改善中孔酸性沸石催化剂的催化活性的方法，其包括用磷化合物处理沸石以形成磷处理的沸石并将磷处理的沸石与AlPO 4组合的步骤。任选地，将经磷处理的沸石煅烧。将沸石与AlPO 4组合的步骤可以任选地随后蒸合组合的催化剂。可用于处理沸石的含磷化合物的实例包括磷酸，磷酸一铵或二磷酸酯，有机亚磷酸酯和有机膦。含磷化合物优选为磷酸铵。另外的替代实施方案提供了一种提高沸石催化剂的水热稳定性的方法，其包括首先用含磷化合物处理沸石，然后与AlPO 4共混。本发明的催化剂可与其它催化剂组合使用或单独使用。本发明可用于裂解烃的方法，其包括使烃原料与如上所述制备的催化剂接触。

44. 发明授权

US08674313B2 X-ray image detection device 有权
标题翻译： X射线图像检测装置
公开(公告)号：US08674313B2
公开(公告)日：2014-03-18
申请号：US13498904
申请日：2009-12-16
申请人： Hong-guang Cao , Zhi-li Cui
发明人： Hong-guang Cao , Zhi-li Cui
IPC分类号： G01T1/20 , H01L27/146
CPC分类号： G01T1/2018 , H01L27/14603 , H01L27/14632 , H01L27/14663 , H04N5/32 , H04N5/335
摘要： An X-ray image detection device includes a scintillator, a data integration processing unit and a plurality of X-ray image sensors. The X-ray image sensors are arranged in a matrix form and located on the back of the scintillator and connected to the data integration processing unit. Each X-ray image sensor includes a plurality of pixels, and each pixel has a dual driving pixel structure and includes two thin film transistors and two thin film photodiodes. The source electrodes of the thin film transistors are connected to the cathodes of the thin film photodiodes respectively, and the gate electrodes are connected to an odd row driving line and an even row driving line respectively, and the drain electrodes are connected to a common signal output line. Both anodes of the two thin film photodiodes are connected to a common ground wire of the pixels.
摘要翻译： X射线图像检测装置包括闪烁体，数据积分处理单元和多个X射线图像传感器。 X射线图像传感器以矩阵形式布置，并且位于闪烁体的背面并连接到数据集成处理单元。每个X射线图像传感器包括多个像素，并且每个像素具有双驱动像素结构，并且包括两个薄膜晶体管和两个薄膜光电二极管。薄膜晶体管的源电极分别连接到薄膜光电二极管的阴极，并且栅极电极分别连接到奇数行驱动线和偶数行驱动线，并且漏电极连接到公共信号输出线。两个薄膜光电二极管的两个阳极连接到像素的公共接地线。

45. 发明授权

US08415518B2 Production of light olefins 有权
标题翻译：轻质烯烃的生产
公开(公告)号：US08415518B2
公开(公告)日：2013-04-09
申请号：US11818333
申请日：2007-06-14
申请人： Richard B. Hall , Guang Cao , Christopher David William Jenkins , James R. Lattner , Michael J. Veraa , Thomas H. Colle
发明人： Richard B. Hall , Guang Cao , Christopher David William Jenkins , James R. Lattner , Michael J. Veraa , Thomas H. Colle
IPC分类号： C07C1/20
CPC分类号： B01J29/7015 , B01J29/70 , B01J29/80 , C07C1/20 , C07C2529/80 , Y02P30/42 , C07C11/02
摘要： This invention is directed to a process for producing olefin product from an oxygenate feed that includes dimethyl ether (DME). The process uses an olefin forming catalyst that contains a porous crystalline material, preferably a porous crystalline aluminosilicate molecular sieve material. The process produces high quantities of light olefin (i.e., ethylene, propylene, and mixtures thereof).
摘要翻译：本发明涉及由包含二甲醚（DME）的含氧化合物进料生产烯烃产物的方法。该方法使用含有多孔结晶材料的烯烃形成催化剂，优选多孔结晶硅铝酸盐分子筛材料。该方法产生大量轻质烯烃（即乙烯，丙烯及其混合物）。

46. 发明授权

US08048402B2 Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins 有权
标题翻译：具有菱沸石骨架类型的分子筛的合成及其在将含氧化合物转化为烯烃的用途
公开(公告)号：US08048402B2
公开(公告)日：2011-11-01
申请号：US11206444
申请日：2005-08-18
申请人： Guang Cao , Matu J. Shah
发明人： Guang Cao , Matu J. Shah
IPC分类号： C01B33/36 , C01B39/02 , C01B39/04 , C01B39/00 , C01F7/00
CPC分类号： C01B39/54 , B01J29/83 , B01J29/85 , C01B37/04 , C01B37/08 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2400/20 , Y02P30/42
摘要： The synthesis of a crystalline aluminophosphate or silicoaluminophosphate molecular sieve having a chabazite-type framework type is conducted in the presence of an organic directing agent having the formula (I) [R1R2R3N—R4]+X− (I) wherein R1, R2 and R3 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R4 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms; 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S; and aromatic groups optionally substituted by 1 to 3 alkyl groups, said alkyl groups having from 1 to 3 carbon atoms; and X− is an anion.
摘要翻译：在具有式（I）的有机导向剂[R1R2R3N-R4] + X-（I）的存在下进行具有菱沸石型骨架型的结晶铝磷酸盐或硅铝磷酸盐分子筛的合成，其中R1，R2和R3 独立地选自具有1至3个碳原子的烷基和具有1至3个碳原子的羟烷基; R4选自4-8元环烷基，任选被1至3个具有1至3个碳原子的烷基取代; 具有1至3个杂原子的4-至8-元杂环基，所述杂环基团任选被1至3个具有1至3个碳原子的烷基取代，所述杂环基中的杂原子选自O， N和S; 和任选被1至3个烷基取代的芳族基团，所述烷基具有1至3个碳原子; 而X-是阴离子。

47. 发明授权

US07939043B2 Synthesis of chabazite structure-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
标题翻译：含有菱沸石结构的分子筛的合成及其在含氧化合物转化为烯烃的用途
公开(公告)号：US07939043B2
公开(公告)日：2011-05-10
申请号：US12137208
申请日：2008-06-11
申请人： Guang Cao , Matu J. Shah
发明人： Guang Cao , Matu J. Shah
IPC分类号： C01B37/04 , C01B37/08
CPC分类号： C01B37/08 , B01J29/83 , B01J29/85 , C01B39/54 , C10G2400/20 , Y02P30/20 , Y02P30/42
摘要： In a method of synthesizing a silicoaluminophosphate or aluminophosphate molecular sieve comprising a CHA framework-type material, a synthesis mixture is provided comprising a source of aluminum, a source of phosphorus, optionally a source of silicon and at least one organic template of formula (I): [R1R2R3R4N]+ X− (I) wherein each of R1, R2, R3, and R4 is independently an acyclic alkyl group having at least one carbon atom, the total number of carbon atoms in said alkyl groups R1, R2, R3, and R4 is greater than 8 but less than 16, and X− is an anion. The synthesis mixture can then be crystallized to produce the desired molecular sieve.
摘要翻译：在合成包含CHA骨架型材料的硅铝磷酸盐或磷酸铝分子筛的方法中，提供了合成混合物，其包含铝源，磷源，任选的硅源和至少一种式（I ）：[R1R2R3R4N] + X-（I）其中R1，R2，R3和R4各自独立地为具有至少一个碳原子的无环烷基，所述烷基中的总碳原子数为R1，R2，R3 并且R4大于8但小于16，X-是阴离子。然后可以将合成混合物结晶以产生所需的分子筛。

48. 发明授权

US07935330B2 Method of making porous crystalline materials 有权
标题翻译：制造多孔结晶材料的方法
公开(公告)号：US07935330B2
公开(公告)日：2011-05-03
申请号：US11899776
申请日：2007-09-07
申请人： Guang Cao
发明人： Guang Cao
IPC分类号： C01B39/04 , C01B37/00
CPC分类号： C01B37/005 , B01J29/047 , B01J29/06 , B01J29/70 , B01J29/85 , C01B37/02 , C01B39/06 , C01B39/065 , C01B39/08 , C01B39/54 , Y02P30/20 , Y02P30/42
摘要： The present invention relates to new methods of making crystalline materials, as well as to new crystalline materials obtainable by such methods, and their use in hydrocarbon conversion processes. In one of its aspects, the invention relates to a method for preparing a crystalline molecular sieve comprising oxides of one or more tetravalent element(s), optionally one or more trivalent element(s), and optionally one or more pentavalent element(s), said method comprising submitting to crystallization conditions one or more sources of said oxides in the presence of at least one organic templating agent R of formula C1C2R1R2N+ A− (I), in which C1 and C2 each independently represent a substituted or unsubstituted cyclohexyl or cyclopentyl group, R1 and R2 each independently represent a methyl group, an ethyl group or a propyl group, or R1 and R2 together with the nitrogen atom they are connected to form a ring containing 5 or 6 atoms, and A represents hydroxyl, fluorine, chlorine, bromine or iodine.
摘要翻译：本发明涉及制备结晶材料的新方法以及可通过这些方法获得的新结晶材料及其在烃转化方法中的用途。在其一个方面，本发明涉及一种制备结晶分子筛的方法，所述结晶分子筛包含一种或多种四价元素的氧化物，任选的一种或多种三价元素，以及任选的一种或多种五价元素，所述方法包括在至少一种式C 1 C 2 R 1 R 2 N + A（I）的有机模板剂R的存在下将所述氧化物的一种或多种来源结晶，其中C 1和C 2各自独立地表示取代或未取代的环己基或环戊基基团，R 1和R 2各自独立地表示甲基，乙基或丙基，或者R 1和R 2与它们连接的氮原子一起形成含有5或6个原子的环，A表示羟基，氟，氯，溴或碘。

49. 发明授权

US07906099B2 Intergrown molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins 有权
标题翻译：共生分子筛，其合成及其在含氧化合物转化为烯烃中的应用
公开(公告)号：US07906099B2
公开(公告)日：2011-03-15
申请号：US11788327
申请日：2007-04-19
申请人： Guang Cao , Matu J. Shah
发明人： Guang Cao , Matu J. Shah
IPC分类号： C01B39/02 , C01B39/04 , C01B39/46 , C01B39/48 , C01B39/54
CPC分类号： C01B39/023 , B01J29/005 , B01J29/70 , B01J29/85 , B01J29/90 , B01J2229/34 , C01B39/54 , C07C1/20 , C07C2529/83 , C07C2529/85 , C10G3/49 , C10G2400/20 , Y02P20/584 , Y02P30/42 , Y10S423/30 , C07C11/02
摘要： A molecular sieve comprises at least one intergrown phase of an AFX framework-type molecular sieve and a CHA framework-type molecular sieve and is conveniently synthesized using a combination of N,N,N′N′-tetramethylhexane-1,6-diamine and N,N-dimethylcyclohexylamine as organic directing agents.
摘要翻译：分子筛包括AFX骨架型分子筛和CHA骨架型分子筛的至少一个共生相，并且使用N，N，N'-二甲基己烷-1,6-二胺和 N，N-二甲基环己胺作为有机导向剂。

50. 发明授权

US07901664B2 Synthesis of aluminophosphate and metalloaluminophosphate molecular sieves 有权
标题翻译：铝磷酸盐和金属铝磷酸盐分子筛的合成
公开(公告)号：US07901664B2
公开(公告)日：2011-03-08
申请号：US12059178
申请日：2008-03-31
申请人： Guang Cao , Mobae Afeworki , Matu J. Shah , Machteld Maria Mertens
发明人： Guang Cao , Mobae Afeworki , Matu J. Shah , Machteld Maria Mertens
IPC分类号： C01B39/04 , C01B39/54 , C07C1/20
CPC分类号： C01B37/08 , B01J29/83 , B01J29/85 , C01B37/04 , C01B39/54 , C07C1/20 , Y02P30/20 , Y02P30/42 , Y10S423/30 , C07C11/02
摘要： In a method of synthesizing an aluminophosphate or metalloaluminophosphate molecular sieve, a synthesis mixture is provided comprising water, a source of aluminum, a source of phosphorus, optionally a source of a metal other than aluminum, a tertiary amine, and an alkylating agent capable of reacting with said tertiary amine to form a quaternary ammonium compound capable of directing the synthesis of said molecular sieve. The synthesis mixture is maintained under conditions sufficient to cause the alkylating agent to react with the tertiary amine to produce the quaternary ammonium compound and to induce crystallization of the molecular sieve.
摘要翻译：在合成磷酸铝或金属铝磷酸盐分子筛的方法中，提供了合成混合物，其包含水，铝源，磷源，任选的除铝之外的金属源，叔胺和烷基化剂，其能够与所述叔胺反应形成能够引导所述分子筛合成的季铵化合物。将合成混合物保持在足以使烷基化剂与叔胺反应以产生季铵化合物并诱导分子筛结晶的条件下。

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