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    • 31. 发明授权
    • Method for making cereal products naturally sweetened with fructose
    • 制作谷物制品的方法是用果糖自然增甜
    • US4857339A
    • 1989-08-15
    • US101561
    • 1987-09-28
    • John A. MaselliSaul L. NeidlemanRichard L. AntrimRichard A. Johnson
    • John A. MaselliSaul L. NeidlemanRichard L. AntrimRichard A. Johnson
    • A23B5/03A23L7/104C12P19/24C13K1/06C13K11/00
    • C12Y302/01001A23L7/107C12P19/24C12Y302/01003C12Y302/01004C12Y503/01005C13K1/06C13K11/00
    • Breakfast cereals are sweetened by treating cereal grains or at least one cereal grain fraction such as bran, with enzymes comprising glucoamylase and glucose isomerase to produce fructose while retaining cereal particle discreteness or integrity. Enzymatic treatment with alpha-amylase may be initiated prior to, during, or after cooking. The enzymatically treated, cooked cereal grains are formed into breakfast cereal shapes and the enzymes are inactivated to provide a shelf-stable cereal product. The cereal products exhibit a sweet, pleasing complex-honey-like taste and aroma. Producing fructose provides a greater level of sweetness for a given amount of starch conversion into low molecular weight reducing sugars such as mono- and di-saccharides. In achieving a given level of sweetness, more starch or high molecular weight dextrins may be retained for their matrix forming ability or for improved machineability of the enzymatically treated cereal grains into breakfast cereal shapes. The naturally sweetened cereal products of the present invention may be in shredded, flaked, ground, or extruded form.
    • 早餐谷物通过处理谷物或至少一种谷物谷物部分如麸皮,通过酶包含葡糖淀粉酶和葡萄糖异构酶来甜化以产生果糖,同时保持谷物颗粒离散性或完整性。 用α-淀粉酶进行酶法处理可以在烹饪之前,期间或之后开始。 酶处理的熟熟谷物形成早餐谷物形状,酶被灭活以提供货架稳定的谷物产品。 谷物产品呈现甜美,复杂的蜂蜜样味道和香气。 生产果糖为给定量的淀粉转化成低分子量还原糖如单糖和二糖提供了更高水平的甜度。 为了达到一定水平的甜度,可以保留更多的淀粉或高分子量糊精用于其基质形成能力,或者将酶处理过的谷物的可加工性提高为早餐谷物形状。 本发明的天然甜味谷物产品可以是切碎的,片状的,研磨的或挤出的形式。
    • 36. 发明授权
    • Alkylidenation of fructose with perfluorinated acid catalysts
    • 用全氟酸催化剂对果糖进行烷基化
    • US4464204A
    • 1984-08-07
    • US445114
    • 1982-11-29
    • Carl W. NiekampMartin Seidman
    • Carl W. NiekampMartin Seidman
    • C07H3/02C07H9/04C07H1/06C13D3/14C13K11/00
    • C07H9/04C07H3/02
    • Aqueous fructose and aldehydes, ketones and/or acetals may be effectively catalyzed into alkylidene fructose derivatives with immobilized acid catalysts. The reaction provides a means for enriching the fructose content of conventional high fructose corn syrups. Perfluorinated acid resins are especially effective catalysts for converting aqueous fructose and acetone solutions into diacetone fructose. Catalysis with the perfluorinated acid resins may be conducted at significantly lower conversion temperatures with superior reactant and reaction product exchange rates. Enrichment of high fructose corn syrups may be generally accomplished by catalyzing the fructose and acetone into a diacetone fructose solution with the perfluorinated acid resin, allowing the dextrose to precipitate from the diacetone solution, hydrolyzing the diacetone fructose to fructose and recovery of the enriched fructose product therefrom. The water-insoluble catalysts afford a reusable catalyst system which can be easily separated from the processed products. The perfluorinated acid resins produce a high quality, food-grade syrup products essentially free of ash, organoleptic bodies (e.g. flavoring, coloring, etc.) and other objectionable by-product contaminants.
    • 含水果糖和醛,酮和/或缩醛可以用固定化的酸催化剂有效地催化成亚烷基果糖衍生物。 该反应提供了富集常规高果糖玉米糖浆的果糖含量的方法。 全氟酸树脂是将水果果糖和丙酮溶液转化为双丙酮果糖的特别有效的催化剂。 使用全氟酸树脂的催化可以在显着较低的转化温度下进行,具有优异的反应物和反应产物的交换速率。 高果糖玉米糖浆的富集通常可以通过用全氟酸树脂将果糖和丙酮催化成双丙酮果糖溶液,使右旋糖从双丙酮溶液中沉淀出来,将双丙酮果糖水解成果糖并回收富含果糖的产物 由此。 水不溶性催化剂提供可重复使用的催化剂体系,其可以容易地与加工产物分离。 全氟酸树脂产生基本上不含灰分,感官体(如调味剂,着色剂等)和其它令人反感的副产物污染物的高质量食品级糖浆产品。
    • 38. 发明授权
    • Process for preparation of fructose-containing solid sugar
    • 制备含果糖固体糖的方法
    • US4371402A
    • 1983-02-01
    • US290198
    • 1981-08-05
    • Hiroshi Kubota
    • Hiroshi Kubota
    • C13K11/00C13F1/02C13F1/04
    • C13K11/00
    • This invention is directed to a process for obtaining fructose-containing solid sugar from fructose-containing liquid sugar by the steps of dehydration, aging and solidification. In the step of dehydration, fructose-containing liquid sugar is brought in the presence of an organic solvent exhibiting azeotropic behavior with respect to water, in contact with a stream of gas causing no denaturation of fructose-containing sugar to remove moisture contained therein. The fructose-containing liquid sugar obtained from said step of dehydration is subject to seed crystal addition treatment in the following step of aging. Lastly, the aged fructose-containing sugar obtained from said step of aging is introduced into anhydrous alcohol for solidification.
    • 本发明涉及通过脱水,老化和凝固的步骤从含果糖液体糖中获得含果糖固体糖的方法。 在脱水步骤中,含有果糖的液体糖在有机溶剂的存在下进行,该有机溶剂相对于水具有共沸作用,与气流接触,导致不含果糖糖变性以除去其中含有的水分。 从所述脱水步骤获得的含果糖的液体糖在下面的老化步骤中进行晶种加成处理。 最后,将从所述老化步骤获得的含有老化果糖的糖引入无水乙醇中固化。