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31. 发明授权

US4786623A Catalytic (CO)dimerization of alkyl acrylates 失效
标题翻译：烷基丙烯酸酯的催化（CO）二聚
公开(公告)号：US4786623A
公开(公告)日：1988-11-22
申请号：US28569
申请日：1987-03-20
申请人： Pierre Grenouillet , Denis Neibecker , Igor Tkatchenko
发明人： Pierre Grenouillet , Denis Neibecker , Igor Tkatchenko
IPC分类号： C07F15/00 , B01J31/00 , B01J31/22 , B01J31/24 , B01J31/28 , C07B61/00 , C07C67/333 , C07C67/465 , C07C69/593 , C07C69/73 , B01J31/04 , B01J31/02 , B01J31/12
CPC分类号： B01J31/0268 , B01J31/0225 , B01J31/04 , B01J31/24 , B01J31/2404 , B01J31/2409 , B01J31/26 , C07C67/465 , C07C69/593 , B01J2231/12 , B01J2531/824
摘要： The alkyl acrylates, e.g., methyl or ethyl acrylate, are improvedly dimerized, or codimerized with a conjugated diene, by contacting same with a catalytically effective amount of (a) at least one palladium source, (b) at least one organophosphorus(III) compound, and (c) at least one hydracid HY, the anion Y.sup.- of which does not coordinate with palladium ions.
摘要翻译：丙烯酸烷基酯，例如丙烯酸甲酯或乙酯，通过使其与催化有效量的（a）至少一种钯源，（b）至少一种有机磷（III））接触而改进二聚或共轭二烯化，化合物，和（c）至少一种氢化物HY，阴离子Y-不与钯离子配位。

32. 发明授权

US4594447A Process for catalytic dimerization of acrylic acid derivatives 失效
标题翻译：丙烯酸衍生物的催化二聚方法
公开(公告)号：US4594447A
公开(公告)日：1986-06-10
申请号：US657292
申请日：1984-10-03
申请人： Gunther Wilke , Karin Sperling , Ludwig Stehling
发明人： Gunther Wilke , Karin Sperling , Ludwig Stehling
IPC分类号： B01J31/00 , B01J31/24 , C07B61/00 , C07C67/347 , C07C67/465 , C07C69/593 , C07C67/343
CPC分类号： C07C67/347
摘要： The invention relates to a process for the dimerization of derivatives of acrylic acid in the homogeneous phase which process is characterized in that a compound having the general formula H.sub.2 C.dbd.CR.sup.1 -COOR.sup.2, wherein R.sup.1 represents H or a linear alkyl group having from 1 to 3 carbon atoms and R.sup.2 represents a linear alkyl group having from 1 to 3 carbon atoms, is reacted in a solvent at a temperature of from -50.degree. C. to +50.degree. C. in the presence of nickel compounds as catalysts which contain complex anions X in a molar ratio Ni:X=1:1 and organic or hydride ligands and are modifed with phosphanes having the general formula PR.sub.2 R', wherein R and R' may be same or different and represent alkyl residues having from 1 to 8 carbon atoms or phenyl residues, as well as the use of the dimers formed in the dimerization.
摘要翻译：本发明涉及在均相中使丙烯酸衍生物二聚的方法，该方法的特征在于具有通式H 2 C = CR 1 -COOR 2的化合物，其中R 1表示H或具有1至3个直链烷基碳原子和R 2表示具有1至3个碳原子的直链烷基，在溶剂中在-50℃至+ 50℃的温度下在镍化合物作为催化剂存在下反应，所述催化剂含有复合阴离子 X与Ni：X = 1：1的摩尔比和有机或氢化物配体，并用具有通式PR2R'的磷烷改性，其中R和R'可以相同或不同，代表具有1至8个碳原子的烷基或苯基残基，以及二聚体中形成的二聚体的用途。

33. 发明授权

US4299976A Preparation of unsaturated diester precursor for sebacic acid 失效
标题翻译：制备癸二酸的不饱和二酯前体
公开(公告)号：US4299976A
公开(公告)日：1981-11-10
申请号：US80354
申请日：1979-09-28
申请人： Chao-Yang Hsu , Haven S. Kesling, Jr.
发明人： Chao-Yang Hsu , Haven S. Kesling, Jr.
IPC分类号： C07C67/465 , B01J31/00 , C07B61/00 , C07C69/50 , C07C69/602
CPC分类号： C07C69/50 , C07C69/602
摘要： A process for producing an unsaturated diester useful as a precursor for sebacic acid which comprises contacting, in a reaction inert medium, methyl penta-2,4-dienoate at a temperature of 30 to 150.degree. C. under an inert atmosphere with a catalytic amount of a homogeneous palladium (II) complex of the formula ##STR1## wherein Q is phosphorous or arsenic; R is alkyl, trichloroalkyl, tribromoalkyl or trifluoroalkyl having from 1 to 6 carbon atoms or aryl having 6 to 12 carbon atoms and R' is alkyl, aminoalkyl or alkoxy having 1 to 6 carbon atoms or aryl or aryloxy having 6 to 12 carbon atoms.The foregoing precursor may subsequently be hydrogenated to dimethyl sebacate and sebacic acid may then be obtained by acid-catalyzed hydrolysis of dimethyl sebacate.
摘要翻译：一种制备用作癸二酸前体的不饱和二酯的方法，该方法包括在惰性介质中，在惰性气氛下，在惰性气氛下，在催化剂量的温度下，在30-150℃的温度下，使反应惰性介质中的甲基-2,4-二烯酸甲酯的具有下式的均匀的钯（II）络合物：其中Q是磷或砷; R是具有1至6个碳原子的烷基，三氯烷基，三溴烷基或三氟烷基或具有6至12个碳原子的芳基，R'是具有1至6个碳原子的烷基，氨基烷基或烷氧基或具有6至12个碳原子的芳基或芳氧基。随后将上述前体氢化成癸二酸二甲酯，然后可以通过酸式催化水解癸二酸二甲酯来获得癸二酸。

34. 发明授权

US10800735B2 Intermediate compound for manufacturing bixin ethyl ester and method of manufacturing the same 有权
公开(公告)号：US10800735B2
公开(公告)日：2020-10-13
申请号：US16510243
申请日：2019-07-12
申请人： MYONGJI UNIVERSITY INDUSTRY AND ACADEMIA COOPERATION FOUNDATION
发明人： Sangho Koo , Dahye Kim , Mohammad Shariful Alam
IPC分类号： C07C317/24 , C07C67/30 , C07C69/34 , C07C315/02 , C07C317/44 , C07C67/465 , C07C67/313 , C07D277/76
摘要： The present invention relates to a method of manufacturing norbixin or bixin ethyl ester, which is a carotenoid-based compound, from a novel intermediate compound. When the novel intermediate compound is used, it is possible to manufacture norbixin or bixin ethyl ester in high yield through a simple process.

35. 发明申请

US20180273464A1 SYNTHESIS AND IN VITRO ACTIVITY OF D-LACTIC ACID OLIGOMERS 审中-公开
公开(公告)号：US20180273464A1
公开(公告)日：2018-09-27
申请号：US15990011
申请日：2018-05-25
申请人： Joel Steven Goldberg , David Martin Gooden
发明人： Joel Steven Goldberg , David Martin Gooden
IPC分类号： C07C67/465 , C07C69/68
CPC分类号： C07C67/465 , A61K31/702 , C07B2200/07 , C07C67/28 , C07C67/317 , C07C69/68 , C07F7/1804 , A61K2300/00
摘要： This invention describes the synthesis and pharmacologic activity of n=2, n=3, n=4, n=5, and n=6 D-lactic acid oligomers. D-lactic acid dimer has pharmacologic activity and sequesters L-lactate, and the other D-lactic acid oligomers have no activity in vitro, but may have pharmacologic activity in vivo as prodrugs of D-lactic acid dimer.

36. 发明申请

US20180155747A1 Lactate Production Process 审中-公开
公开(公告)号：US20180155747A1
公开(公告)日：2018-06-07
申请号：US15886632
申请日：2018-02-01
申请人： NatureWorks LLC
发明人： Edward Leslie Marshall , Alan Keasey , David Mark Sutton
IPC分类号： C12P7/62 , C07C67/29 , C12P41/00 , C12P7/56 , C07C51/09 , C07C67/465 , C07D319/12
CPC分类号： C12P7/62 , C07C51/09 , C07C67/29 , C07C67/465 , C07D319/12 , C12P7/56 , C12P7/625 , C12P41/005
摘要： A process for producing alkyl R-lactate from an initial compound comprising substructure (I) is provided. The process involves producing an intermediate comprising R,R- and S,S-lactide from the initial compound, wherein the initial compound is subjected to stereoisomerisation conditions; and reacting at least a portion of the intermediate with an alkyl alcohol to produce a product comprising alkyl R-lactate, wherein alkyl R-lactate is produced in the presence of an enzyme. Also provided are processes for the production of R-lactic acid, oligomeric R-lactic acid, R,R-lactide, poly-R-lactic acid and stereocomplex lactic acid.

37. 发明授权

US09982087B2 Method for producing compound 有权
公开(公告)号：US09982087B2
公开(公告)日：2018-05-29
申请号：US14912946
申请日：2014-07-31
申请人： Sumitomo Chemical Company, Limited
发明人： Ken Kashima , Noriyuki Hida
IPC分类号： C07C69/76 , C08G61/12 , C07C67/465 , C07C209/60 , C07C1/32
CPC分类号： C08G61/121 , C07C1/321 , C07C67/465 , C07C209/60 , C07C2531/22 , C07C2531/24 , C07C2603/18 , C08G61/12 , C08G61/122 , C08G2261/1424 , C08G2261/1426 , C08G2261/3142 , C08G2261/3162 , C08G2261/3245 , C08G2261/411 , C07C13/567
摘要： A method is provided for producing a compound, including a step of mixing a compound (1) having one or two leaving groups, a compound (2) having one or two boron atom-containing leaving groups, an organic base (P), and at least one selected from a phase transfer catalyst and an organic base (Q) larger in the number of carbon atoms than the above-mentioned organic base in the presence of a transition metal catalyst. The method thereby performs a coupling reaction between the above-mentioned compound (1) and the above-mentioned compound (2).

38. 发明授权

US09878973B2 Catalytic processes for preparing estolide base oils 有权
公开(公告)号：US09878973B2
公开(公告)日：2018-01-30
申请号：US15143884
申请日：2016-05-02
申请人： BIOSYNTHETIC TECHNOLOGIES, LLC
发明人： Jakob Bredsguard , Jeremy Forest , Travis Thompson
IPC分类号： C07C67/465 , C07C69/675 , C10M107/32 , C07C69/34 , C07C57/02 , C10M105/36 , C07C67/48 , C07C67/54 , C07C69/604 , C10M105/34 , C11C3/00 , C11C3/08
CPC分类号： B05B1/326 , B05B1/1636 , B05B1/3026 , C07C57/02 , C07C67/465 , C07C67/48 , C07C67/54 , C07C69/34 , C07C69/604 , C07C69/675 , C10M105/34 , C10M105/36 , C10M107/32 , C10M2207/2825 , C10M2207/286 , C10M2209/1023 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2220/027 , C10N2220/028 , C10N2220/10 , C10N2230/02 , C10N2230/64 , C10N2240/04 , C11C3/00 , C11C3/003 , C11C3/08 , Y10T137/86549 , Y10T137/86863
摘要： Provided herein are processes for preparing estolides and estolide base oils from fatty acid reactants utilizing catalysts. Further provided herein are processes for preparing carboxylic esters from at least one carboxylic acid reactant and at least one olefin.

39. 发明申请

US20160244397A1 PROCESSES FOR PREPARING ESTOLIDE BASE OILS AND BIOBASED COMPOUNDS THAT INCLUDE ETHYLENEOLYSIS 审中-公开
标题翻译：制备含有乙烯基化合物的酯基油和生物化合物的方法
公开(公告)号：US20160244397A1
公开(公告)日：2016-08-25
申请号：US15047112
申请日：2016-02-18
申请人： BIOSYNTHETIC TECHNOLOGIES, LLC.
发明人： Jeremy FOREST
IPC分类号： C07C67/465 , C07C67/303 , B01J31/22 , C07C67/08
CPC分类号： B01J31/2265 , B01J31/2278 , B01J2231/49 , B01J2231/543 , B01J2531/821 , C07C51/09 , C07C67/04 , C07C67/08 , C07C67/303 , C07C69/533 , C07C57/03
摘要： Provided herein are compounds prepared from processes that include ethyleneolysis. Exemplary processes include the preparation of terminally-unsaturated fatty acid reactant by ethyleneolysis catalyzed by a cyclic alkyl amino carbene ruthenium complex. The subsequent oligomerization of terminally-unsaturated fatty acid reatants provides estolide compounds, as exemplified by the process set forth below:
摘要翻译：本文提供由包括乙烯溶解的方法制备的化合物。示例性的方法包括通过环烷基氨基卡宾钌络合物催化的乙烯溶解来制备末端不饱和脂肪酸反应物。末端不饱和脂肪酸复合物的随后低聚提供了可以如下所述的方法所例示的炔雌醇化合物：

40. 发明申请

US20160031790A1 METHOD OF MANUFACTURE OF OCTANEDIOIC ACID, PRECURSORS, AND DERIVATIVES 审中-公开
标题翻译：十八烷酸，前驱体和衍生物的制备方法
公开(公告)号：US20160031790A1
公开(公告)日：2016-02-04
申请号：US14777069
申请日：2014-03-11
申请人： SEGETIS, INC.
发明人： ERICH J. MOLITOR , BRIAN D. MULLEN
IPC分类号： C07C51/353 , C07C67/03 , C07D307/33 , C07C51/09 , C07C51/36 , C07C29/149 , C07C253/06 , C07C209/48 , C07C209/16 , C07C263/10 , C07C227/08 , C07C67/313 , C07D211/02 , C07D223/10 , C07C67/465
CPC分类号： C07C51/353 , C07C29/149 , C07C51/09 , C07C51/36 , C07C67/03 , C07C67/313 , C07C67/465 , C07C209/16 , C07C209/48 , C07C227/08 , C07C253/06 , C07C263/10 , C07D211/02 , C07D211/40 , C07D223/10 , C07D301/12 , C07D305/08 , C07D307/32 , C07D307/33 , C07D307/58 , C07D317/30 , C07D493/04 , C07C57/03 , C07C57/13
摘要： A method for the manufacture of 1,8-octanedioic acid comprises: reacting gamma-valerolactone with an alcohol in the presence of an acid or a base catalyst to provide an alkyl pentenoate, converting the alkyl pentenoate in the presence of a metathesis initiator to provide the dialkyl octenedioate, reacting the dialkyl octenedioate with hydrogen in the presence of a hydrogenation catalyst to provide a dialkyl 1,8-octanedioate and hydrolyzing the dialkyl 1,8-octanedioate to provide the 1,8-octanedioic acid.
摘要翻译：制备1,8-辛二酸的方法包括：在酸或碱催化剂存在下使γ-戊内酯与醇反应，得到戊烯酸烷基酯，在复分解引发剂存在下转化戊烯酸烷基酯以提供八氢萘二酸二烷基酯，在氢化催化剂存在下使辛烯二酸二烷基酯与氢气反应，得到1,8-辛二酸二烷基酯，并水解1,8-辛二酸二烷基酯，得到1,8-辛二酸。

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