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31. 发明申请

US20050166707A1 Method of recovering platinum group element and apparatus therefor 有权
标题翻译：铂族元素回收方法及其设备
公开(公告)号：US20050166707A1
公开(公告)日：2005-08-04
申请号：US10521818
申请日：2003-08-04
申请人： Koji Yamada , Masahiko Ogino , Nobuyasu Ezawa , Hiroshi Inoue
发明人： Koji Yamada , Masahiko Ogino , Nobuyasu Ezawa , Hiroshi Inoue
IPC分类号： B09B3/00 , B01J23/96 , B01J38/00 , C22B7/00 , C22B9/16 , C22B11/02 , C22B15/00 , C22B11/00
CPC分类号： C22B9/16 , C22B11/02 , C22B11/021 , C22B11/026 , C22B15/0054 , Y02P10/214
摘要： A method for recovering platinum group elements comprises charging into a closed electric furnace and melting, together with flux components and a reducing agent, a platinum group element-containing substance to be processed and a copper source material containing copper oxide, sinking molten metal of primarily metallic copper below a molten slag layer of primarily oxides, and enriching the platinum group elements in the molten metal sunk below, and is characterized in that molten slag whose copper content has decreased to 3.0 wt % or less is discharged from the electric furnace and that the copper source material charged into the electric furnace is a granular copper source material of a grain diameter of not less than 0.1 mm and not greater than 10 mm.
摘要翻译：回收铂族元素的方法包括：向封闭的电炉中加入熔融物，与助熔剂成分和还原剂一起熔化待加工的含铂族元素的物质和含有氧化铜的铜源材料，主要沉入熔融金属金属铜在主要氧化物的熔融渣层以下，并且将熔融金属中的铂族元素富集在下面，并且其特征在于，铜含量已降至3.0重量％以下的熔渣从电炉中排出，装入电炉的铜源材料是粒径不小于0.1mm且不大于10mm的粒状铜源材料。

32. 发明授权

US06921731B2 Process for regenerating Pd catalysts 失效
标题翻译： Pd催化剂再生方法
公开(公告)号：US06921731B2
公开(公告)日：2005-07-26
申请号：US10297237
申请日：2001-06-19
申请人： Floris Jacobus Parlevliet , Johannes Gerardus Vries De , Andreas Hendrikus Maria Vries De
发明人： Floris Jacobus Parlevliet , Johannes Gerardus Vries De , Andreas Hendrikus Maria Vries De
IPC分类号： B01J38/42 , B01J23/96 , B01J31/40 , B01J38/54 , C07B37/04 , C07B61/00 , B01J20/34 , B01J23/44
CPC分类号： B01J31/1616 , B01J21/04 , B01J21/08 , B01J21/18 , B01J23/44 , B01J23/96 , B01J27/13 , B01J31/1805 , B01J31/2239 , B01J31/4038 , B01J38/54 , B01J2231/4205 , B01J2231/4211 , B01J2231/4261 , B01J2531/0222 , B01J2531/824 , C07B37/04 , Y02P20/584
摘要： Process for regenerating a Pd catalyst after a homogeneously catalyzed C—C coupling reaction in which the Pd catalyst precipitates, is separated from the reaction mixture and subsequently treated with I2 or Br2. The Pd catalyst can then be used in a subsequent reaction run.Preferably between 1 and 3 mole equivalents of I2 or Br2, relative to the quantity of Pd catalyst is usedThe C—C coupling reaction is preferably carried out in the presence of a support material.The C—C coupling reaction may be for example a Heck reaction, a Suzuki reaction or a cross-coupling reaction.
摘要翻译：在其中Pd催化剂沉淀的均匀催化的C-C偶联反应后，从反应混合物中分离出Pd催化剂再生方法，随后用I 2或Br 2 N处理。然后可以在随后的反应运行中使用Pd催化剂。相对于Pd催化剂的量，优选1〜3摩尔当量的I 2或Br 2 N。CC偶联反应优选在支撑材料 C-C偶联反应可以是例如Heck反应，Suzuki反应或交叉偶联反应。

33. 发明申请

US20050148456A1 Off-site regeneration of reforming catalysts 审中-公开
标题翻译：重整催化剂的异位再生
公开(公告)号：US20050148456A1
公开(公告)日：2005-07-07
申请号：US10993149
申请日：2004-11-22
申请人： Pierre Dufresne , Pauline Galliou , Jean Bergougnou , Gerard Lenain
发明人： Pierre Dufresne , Pauline Galliou , Jean Bergougnou , Gerard Lenain
IPC分类号： B01J23/96 , B01J38/30 , B01J38/44 , C10G35/06
CPC分类号： B01J38/30 , B01J23/96 , B01J38/44 , C10G35/06
摘要： The invention relates to a process for regenerating catalysts for conversion of hydrocarbons, the catalyst generally comprising at least one precious metal, preferably a group VIII metal from the periodic table of the elements, optionally at least one additional metal, at least one halogen and at least one porous substrate, the process according to the invention having at least one combustion step for the spent catalyst and at least one oxyhalogenation step, these steps being performed in a same, single regeneration zone in which the catalyst to be regenerated is located in the form of a fluidized bed.
摘要翻译：本发明涉及用于再生用于烃转化的催化剂的方法，催化剂通常包含至少一种贵金属，优选VIII族金属，优选元素周期表，任选至少一种另外的金属，至少一个卤素和至少一个多孔基材，根据本发明的方法具有用于废催化剂的至少一个燃烧步骤和至少一个卤代卤化步骤，这些步骤在相同的单个再生区域中进行，其中待再生催化剂位于形式的流化床。

34. 发明授权

US6100208A Outdoor fabric 失效
标题翻译：户外布料
公开(公告)号：US6100208A
公开(公告)日：2000-08-08
申请号：US999911
申请日：1997-10-14
申请人： Trina Buce Brown , Robert Leslie Hudson , Mary Lucille DeLucia
发明人： Trina Buce Brown , Robert Leslie Hudson , Mary Lucille DeLucia
IPC分类号： B01J23/96 , B01J38/44 , B32B5/26 , B32B27/12 , D04H13/00 , D04H1/06
CPC分类号： B01J23/96 , B01J38/44 , B32B27/12 , B32B5/26 , D04H1/541 , D04H1/559 , D04H3/147 , D04H3/16 , Y10T428/2929 , Y10T442/2139 , Y10T442/62 , Y10T442/637 , Y10T442/638 , Y10T442/64 , Y10T442/641 , Y10T442/668 , Y10T442/674 , Y10T442/675 , Y10T442/676 , Y10T442/678 , Y10T442/679
摘要： An outdoor protective fabric is disclosed having (i) a UV stable outer nonwoven web of multicomponent sheath/core fibers having a polyethylene polymer sheath component and a polypropylene polymer core component; (ii) a breathable barrier layer such as a meltblown web or microporous film; and (iii) an interior nonwoven web of multicomponent fibers comprising a polyethyfene polymer component and a nylon component.
摘要翻译：公开了一种室外防护织物，其具有（i）具有聚乙烯聚合物护套组分和聚丙烯聚合物芯组分的多组分鞘/芯纤维的UV稳定的外非织造纤维网; （ii）透气阻隔层，例如熔喷网或微孔膜; 和（iii）包含聚乙烯聚合物组分和尼龙组分的多组分纤维的内部非织造纤维网。

35. 发明授权

US6021638A Engine management strategy to improve the ability of a catalyst to withstand severe operating enviroments 失效
标题翻译：发动机管理策略提高催化剂承受严重运行环境的能力
公开(公告)号：US6021638A
公开(公告)日：2000-02-08
申请号：US976712
申请日：1997-11-24
申请人： John Karl Hochmuth
发明人： John Karl Hochmuth
IPC分类号： F01N3/10 , B01J23/96 , B01J38/04 , F01N3/08 , F01N3/20 , F01N3/24 , F02D41/02 , F02D41/04 , F02D41/12 , F01N3/00
CPC分类号： F01N3/0871 , F01N3/0842 , F01N3/0885 , F01N3/20 , F02D41/0275 , F02D41/126 , F01N2250/12 , F01N2610/03
摘要： A method and engine control strategy is described that enables improved catalyst performance after having been exposed to severe operating environments. More specifically, rhodium-containing catalysts are reactivated by being subjected to fuel-rich spikes after being exposed to high temperature, excess oxygen conditions which typically arise during programmed fuel-cut engine control strategies. Thus the present invention represents a departure from current control strategies by providing fuel-rich spikes during engine control modes when conventional practice is not to provide rich-fuel spikes.
摘要翻译：描述了一种方法和发动机控制策略，其在暴露于恶劣的操作环境之后能够改善催化剂性能。更具体地说，含铑催化剂在暴露于通常在编程的燃料切割发动机控制策略中通常出现的高温，过量氧气条件下经历富燃料尖峰而被再活化。因此，当传统做法不提供富燃料尖峰时，本发明通过在发动机控制模式期间提供富燃料尖峰来表现出偏离当前控制策略。

36. 发明授权

US5908803A Process for isolation of a catalyst containing palladium 失效
标题翻译：用于分离含钯催化剂的方法
公开(公告)号：US5908803A
公开(公告)日：1999-06-01
申请号：US831580
申请日：1997-04-09
申请人： Philippe Leconte , Carl Patois
发明人： Philippe Leconte , Carl Patois
IPC分类号： B01J23/44 , B01J23/96 , B01J27/32 , B01J31/40 , B01J38/00 , B01J38/60 , C07B61/00 , C07C51/14 , C07C51/42 , C07C57/02 , C07C57/03 , C07C67/38 , B01J20/34
CPC分类号： B01J31/2291 , B01J31/4038 , B01J38/60 , C07C51/42 , C07C67/38 , C22B11/048 , B01J2231/321 , B01J2531/824 , B01J27/10 , Y02P10/214 , Y02P20/584
摘要： The present invention relates to the isolation of a palladium-based catalyst from a mixture in which it is dissolved. More specifically, the invention relates to the isolation of a palladium-based catalyst from a mixture originating from the reaction of hydroxycarbonylation of butadiene to pentenoic acids. It therefore consists of a process for the isolation of at least a portion of the palladium dissolved in a solution also containing at least 3-pentenoic acid, characterized in that the said solution is acidified and stirred with an aqueous solution of hydrochloric acid, so as to obtain two liquid phases including an aqueous phase containing at least a portion of the palladium.
摘要翻译：本发明涉及从其中溶解的混合物中分离钯基催化剂。更具体地，本发明涉及从源自丁二烯羟基羰基化反应与戊烯酸的混合物中分离钯基催化剂。因此，它包括分离溶解在还含有至少3-戊烯酸的溶液中的至少一部分钯的方法，其特征在于所述溶液用盐酸水溶液酸化并搅拌，因此以获得包含含有至少一部分钯的水相的两个液相。

37. 发明授权

US5817592A Process for the preparation of a hydrogenation catalyst 失效
标题翻译：制备氢化催化剂的方法
公开(公告)号：US5817592A
公开(公告)日：1998-10-06
申请号：US590455
申请日：1996-01-23
申请人： Daniel Heineke , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Heinz-Walter Schneider , Alfred Thome
IPC分类号： B01J23/42 , B01J23/96 , B01J37/16 , B01J38/64 , C01B21/14 , B01J21/18 , B01J23/16 , B01J27/185
CPC分类号： B01J23/42 , B01J37/16 , C01B21/1418
摘要： A process for the preparation of a hydrogenation catalyst by reduction of platinum in an oxidation stage of not less than 2 in an aqueous medium in the presence of a carboniferous support, optionally following partial poisoning with a sulfur, arsenic, tellurium, or antimony-containing compound, using a reducing agent, in which the reducing agent used is an ammonium or phosphonium salt of the general formula I �XR.sup.4 !.sub.n Y I in which X stands for N or P, R stands for hydrogen, C.sub.1 --C.sub.18 alkyl, C.sub.5 --C.sub.10 cycloalkyl, phenyl radical, and also a C.sub.1 --C.sub.4 alkyl radical substituted by phenyl, the phenyl radicals being mono-to tri-substituted by C.sub.1 --C.sub.6 alkyl, halogen, nitro or amino, if desired, provided that the radicals R may be the same or different but cannot simultaneously denote hydrogen, if X is P, n is an integer of 1 to 3, and Y is an organic anion which can reduce platinum in an oxidation stage other than zero to platinum in the oxidation stage of zero.
摘要翻译：一种通过在含水载体的存在下在水性介质中在不少于2的氧化阶段还原铂的氢化催化剂的方法，任选地在用硫，砷，碲或含锑的部分中毒后化合物，使用还原剂，其中所用的还原剂是通式I [XR4] nYinin的铵盐或鏻盐，其中X代表N或P，R代表氢，C1-C18烷基，C5-C10环烷基苯基，以及被苯基取代的C1-C4烷基，如果需要，苯基由C1-C6烷基，卤素，硝基或氨基单取代至三取代，条件是基团R可以相同或不同，但不能同时表示氢，如果X为P，n为1至3的整数，Y为有机阴离子，在氧化阶段为零的情况下，铂可以在除氧以外的氧化阶段中还原为铂。

38. 发明授权

US5811628A Method for the complete hydrodechlorination of chlorinated hydrocarbons 失效
标题翻译：氯代烃完全加氢脱氯的方法
公开(公告)号：US5811628A
公开(公告)日：1998-09-22
申请号：US504628
申请日：1995-07-20
申请人： Klaus Weber , Rainer Schoedel , Peter Birke , Reinhard Geyer , Ulrich Neumann , Werner Haertwig , Gerhard Vogel , Willi Sattelmayer , Rudolf Schumann , Anette Hoppe
发明人： Klaus Weber , Rainer Schoedel , Peter Birke , Reinhard Geyer , Ulrich Neumann , Werner Haertwig , Gerhard Vogel , Willi Sattelmayer , Rudolf Schumann , Anette Hoppe
IPC分类号： A62D3/00 , B01D53/86 , B01J23/96 , B01J38/10 , B01J38/12 , C07C1/26 , B01J20/34
CPC分类号： B01J38/12 , B01D53/8662 , B01J23/96 , B01J38/10
摘要： A method for the hydrodechlorination of a reaction gas primarily composed of chlorinated hydrocarbons is carried out sequentially. A first step is advantageously carried out in a tubular reactor filled with catalyst and cooled externally, to maintain a temperature within a preferred range of 80.degree. to 230.degree. C. and a radial temperature difference of not more than 40.degree. C. Hydrogen is added to the tubular reactor with a hydrogen excess in a preferred range of 1.1 to 1.5 relative to the reaction gas, based on the stoichiometric consumption. The catalyst is present in a catalyst loading in a preferred range of 0.1 to 1.5 v/vh based on the volume of reaction gas. A fixed bed reactor is advantageously used for a second step, optimally connected in straight transit with the output of the reactor of the first step. The full-space reactor is maintained at a temperature within a preferred range of 200.degree. to 300.degree. C. and a hydrogen excess relative to the stoichiometric consumption is in a preferred range of 2 to 100. Catalyst is present in a preferred amount related to a volume of catalyst in step one according to a ratio in a range of 2:1 to 10:1. The dechlorination is preferably carried out at pressures between 1 and 50 bar. A method is further provided for regenerating deactivated catalysts without accumulation of dioxin in the waste gas, achieved by a reducing treatment, followed by an oxidizing treatment at a temperature at or above the last operating temperature of the catalyst.
摘要翻译：依次进行主要由氯代烃组成的反应气体的加氢脱氯的方法。第一步有利地在填充有催化剂的管式反应器中进行并在外部冷却，以将温度保持在80℃至230℃的优选范围和不超过40℃的径向温度差。加入氢气基于化学计量消耗，相对于反应气体，相对于反应气体，优选范围为1.1〜1.5的氢过渡到管式反应器。基于反应气体的体积，催化剂以0.1至1.5v / vh的优选范围存在于催化剂负载中。固定床反应器有利地用于第二步骤，最佳地连续地与第一步骤的反应器的输出相连。全空间反应器保持在200℃至300℃的优选范围内的温度，相对于化学计量消耗的氢过量在优选的范围为2至100.催化剂以优选的量存在根据比例在2:1至10:1的范围内的步骤1中的催化剂体积。脱氯优选在1至50巴之间的压力下进行。还提供一种方法，用于再生失活的催化剂，而不会在废气中积聚二恶英，通过还原处理实现，然后在等于或高于催化剂的最后操作温度的温度下进行氧化处理。

39. 发明授权

US5750458A Combustion catalysts containing binary oxides and processes using the same 失效
公开(公告)号：US5750458A
公开(公告)日：1998-05-12
申请号：US271687
申请日：1994-07-07
申请人： Teresa Kennelly , John K. Hochmuth , Ting C. Chou , Robert J. Farrauto
发明人： Teresa Kennelly , John K. Hochmuth , Ting C. Chou , Robert J. Farrauto
IPC分类号： B01J23/63 , B01J23/96 , B01J38/12 , C01G55/00 , F23C13/00 , B01J23/10 , C01F17/00
CPC分类号： B01J38/12 , B01J23/63 , B01J23/96
摘要： A catalyst composition containing one or more binary oxides of palladium and rare earth metal such as Ce, La, Nd, Pr and/or Sm. The catalyst composition is used for the catalytic combustion of gaseous combustion mixtures of oxygen and carbonaceous fuels such as methane, e.g., a natural gas/air combustion mixture. Specific preferred binary oxides may be, for example, M.sub.2 O.sub.3.PdO (e.g., La.sub.2 O.sub.3.PdO) or 2M.sub.2 O.sub.3.PdO, wherein in each case M is La, Nd or Sm. A process of combusting gaseous carbonaceous fuels includes contacting a catalyst as described above under combustion conditions, e.g., 925.degree. C. to 1650.degree. C. and 1 to 20 atmospheres pressure, to carry out sustained combustion of the combustion mixture, including catalytically supported thermal combustion. Regeneration of over-temperatured M.sub.2 O.sub.3.PdO catalyst is also provided for.

40. 发明授权

US5695634A Process for catalytic treatment of waste water as well as a process for regenerating a catalyst 失效
标题翻译：用于催化废水处理的方法以及再生催化剂的方法
公开(公告)号：US5695634A
公开(公告)日：1997-12-09
申请号：US397685
申请日：1995-03-01
申请人： Gerhard Neuenfeldt , Alfred Ottmann , Hubert Schindler
发明人： Gerhard Neuenfeldt , Alfred Ottmann , Hubert Schindler
IPC分类号： C02F1/70 , B01J23/44 , B01J23/96 , B01J38/02 , B01J38/52 , B01J38/60
CPC分类号： B01J23/96 , Y10S210/908 , Y10S210/909
摘要： A process for regenerating a supported noble metal catalyst and also a process for catalytic treatment of wastewater containing, in particular, organohalogen contaminants, in which the process for regenerating the catalyst is a part of the overall wastewater treatment process.
摘要翻译：用于再生负载的贵金属催化剂的方法以及用于催化处理含有特别是有机卤素污染物的废水的方法，其中用于再生催化剂的方法是整个废水处理过程的一部分。

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