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    • 31. 发明授权
    • Method for processing gaseous effluent streams recovered from the vapor
phase oxidation of metal halides
    • 从金属卤化物的气相氧化中回收的气态流出物流的处理方法
    • US4578090A
    • 1986-03-25
    • US660875
    • 1984-10-15
    • Theodore A. Rado
    • Theodore A. Rado
    • B01D47/05C01B33/18C01G23/07C01G49/02
    • C01G49/02B01D47/05C01B33/183C01G23/075
    • In the manufacture of particulated metal oxides by the vapor phase oxidation of volatile metal halides, hot gaseous effluent streams are produced which, after separation of the desired particulated metal oxide therefrom, contain residual amounts of the particulated metal oxide as well as unreacted, volatile metal halide and halogen gas. The method of this invention provides for the recovery of these materials, individually, through a succession of contacting and separating steps utilizing a recycle stream of previously recovered, unreacted, liquid metal halide. Utilization of the recycle stream of metal halide provides for both evaporative cooling of the hot gaseous effluent stream to permit recovery of the residual particulated metal oxide therein and scrubbing of the resulting off-gas to recover the unreacted volatile metal halide therein as a liquid and provide a gas phase containing the by-product halogen gas. The recovered unreacted volatile metal halide liquid constitutes the recycle stream of liquid metal halide used in the process. The gas phase is subjected to a further scrubbing to separate and recover therefrom any remaining unreacted, volatile metal halide.
    • 在通过挥发性金属卤化物的气相氧化制造颗粒状金属氧化物时,产生热的气态流出物流,其中所需的颗粒状金属氧化物从其中分离后,含有残留量的微粒金属氧化物以及未反应的挥发性金属 卤化物和卤素气体。 本发明的方法通过使用先前回收的未反应的液态金属卤化物的再循环流通过一系列接触和分离步骤分别回收这些材料。 使用金属卤化物的再循环流提供热气态流出物流的蒸发冷却,以允许其中残留的微粒金属氧化物回收并洗涤所得到的废气以回收其中的未反应的挥发性金属卤化物作为液体,并提供 含有副产物卤素气体的气相。 回收的未反应的挥发性金属卤化物液体构成在该方法中使用的液态金属卤化物的再循环流。 对气相进行进一步的洗涤以分离并从其中回收剩余的未反应的挥发性金属卤化物。
    • 32. 发明授权
    • Process and system for elimination of paint solvent vapors
    • 消除油漆溶剂蒸气的工艺和系统
    • US4261707A
    • 1981-04-14
    • US74647
    • 1979-09-12
    • Norman F. BradshawIvan Bloomer
    • Norman F. BradshawIvan Bloomer
    • B01D53/44B01D47/05B01D53/77B05B15/12B01D19/00B01D47/00
    • B01D47/05B05B15/1233Y02P70/34Y02P70/36Y10S118/07Y10S55/46
    • A system and process is disclosed for eliminating paint solvents released during paint spraying operations into the circulated air including a liquid spray solvent stripper over which the exhaust air is passed, and a heating and cooling arrangement for regenerating the solvent absorber liquid. A heat exchanger recovering heat from an incinerator vaporizes the solvent and the absorber is recovered by being passed over cooling coils in a condensing chamber. The exhaust air is treated with a water circulation system to remove paint solids, a proportion of the solvent vapors passing into solution with the treatment water. A solvent stripper is provided consisting of an arrangement for applying a vacuum to the water circulated from a paint solid removal unit, causing the solvent to be vaporized out of solution, with the vapors condensed by being passed over cooling coils in a condensing chamber. The air and water stripper condensing chambers are purged by a vacuum pump directing the uncondensed solvent vapors into the incinerator.
    • 公开了一种系统和方法,用于消除在喷涂操作期间释放的涂料溶剂到循环空气中,所述循环空气包括通过排气的液体喷雾溶剂汽提器,以及用于再生溶剂吸收剂液体的加热和冷却装置。 从焚烧炉回收热量的热交换器蒸发溶剂,并且通过冷凝室中的冷却盘管通过吸收器来回收吸收剂。 排气用水循环系统处理以除去油漆固体,一部分溶剂蒸气与处理水一起进入溶液。 提供了一种溶剂汽提器,其由用于对从涂料固体去除单元循环的水进行真空的装置构成,使溶剂从溶液中蒸发出来,蒸气通过冷凝盘中的冷却盘管冷凝。 空气和水汽提器冷凝室由真空泵吹扫,将未冷凝的溶剂蒸气引导到焚烧炉中。