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    • 33. 发明申请
    • Stabilizing compositions
    • 稳定组合物
    • US20050252628A1
    • 2005-11-17
    • US10842476
    • 2004-05-11
    • James DayDrew Young
    • James DayDrew Young
    • D21H17/03D21H17/06D21H21/16
    • D21H21/16D21H17/06
    • A water soluble dispersant extender enhances the effectiveness and stability of hydrophobic compounds applied from aqueous solution. The invention is well suited for fluorochemical compounds applied to a substrate to impart grease and oil resistance. Exemplary substrates include paper, textiles, nonwoven, carpet and the like. The invention is also useful in firefighting foams that employ hydrophobic fluorochemical fire suppressing compounds. The present stabilizer is believed to form an inclusion complex with the hydrophobic compound whereby enhanced dispersion and solubility over the surface of the substrate allows more efficient use of the hydrophobic compound so that either less compound can be used with the same efficacy or greater efficacy is seen with the same level of active ingredient.
    • 水溶性分散剂增量剂提高了从水溶液中施加的疏水化合物的有效性和稳定性。 本发明非常适用于施加到基材上的含氟化合物以赋予油脂和油抵抗力。 示例性基材包括纸,纺织品,无纺布,地毯等。 本发明也可用于消除采用疏水性含氟化合物灭火化合物的泡沫体。 本发明的稳定剂被认为与疏水性化合物形成包合络合物,从而增加了在底物表面上的分散和溶解度,可以更有效地使用疏水性化合物,使得可以使用具有相同功效或更高功效的更少化合物 具有相同水平的活性成分。
    • 38. 发明授权
    • Method and products for sizing paper and similar materials
    • 纸张和类似材料尺寸的方法和产品
    • US4857149A
    • 1989-08-15
    • US125787
    • 1987-11-20
    • George T. TiedemanJerome M. Gess
    • George T. TiedemanJerome M. Gess
    • D21H17/03D21H17/55D21H23/76
    • D21H23/765D21H17/03D21H17/55
    • The invention is a method of sizing paper and, in particular, paper made under neutral to alkaline conditions at least as high as 10.5. The papermaking stock is first treated with a polycationic material to provide sizing receptive sites uniformly distributed over the fiber surface. The presence of the anchoring points is critical to the later redistribution of the sizing material in the dryer section of the paper machine. The sizing material is then added to the slurry. This is then brought down onto the fibers by addition of a small amount of a size precipitant such as alum. The sizing molecule should have a hydrophilic portion with two hetero atoms forming a bidentate analog structure. This must have a pK in water of 6.0 or higher and a vapor pressure preferably at least 0.0006 mm Hg at 60.degree. C. The polycationic material provides anchoring/orienting sites on the fiber to which the small globules of sizing attach when the emulsion is broken by the precipitant. Sizing will develop in the dryer section of the paper machine, presumably by vapor phase redistribtution of sizing from the attached globules to unfilled sites where an anchoring point is present. Alkyl and alkenyl substituted catechols, beta-diones, hydroxamic acids and imides are among the new classes of sizing materials disclosed.
    • 本发明是一种使纸张尺寸调整的方法,特别是在中性至碱性条件下至少高达10.5的纸张的方法。 首先用聚阳离子材料处理造纸原料,以提供均匀分布在纤维表面上的施胶接收位点。 锚定点的存在对于造纸机的干燥器部分中的上浆材料的后续再分配至关重要。 然后将上浆材料加入浆料中。 然后通过加入少量的大小沉淀剂(例如明矾)将其还原到纤维上。 上浆分子应具有亲水部分,其中两个杂原子形成双齿模拟结构。 在60℃或以上的水中必须具有pK,在60℃下蒸气压优选至少为0.0006mmHg。聚阳离子材料在乳液破碎时附着的小尺寸颗粒附着的纤维上提供锚定/取向位点 由沉淀物。 在造纸机的干燥部中会发生尺寸变化,这可能是通过气相重新分配从连接的小球到施加固定点的未填充部位。 烷基和烯基取代的邻苯二酚,β-二酮,异羟肟酸和酰亚胺是公开的新型施胶材料之一。