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31. 发明授权

US09187834B2 Electrochemical hydroxide systems and methods using metal oxidation 有权
标题翻译：电化学氢氧化物系统和使用金属氧化的方法
公开(公告)号：US09187834B2
公开(公告)日：2015-11-17
申请号：US13474598
申请日：2012-05-17
申请人： Thomas A. Albrecht , Ryan J. Gilliam , Bryan Boggs , Kyle Self , Dennis W. Solas , Michael Kostowskyj , Margarete K. Leclerc , Alexander Gorer , Michael Joseph Weiss
发明人： Thomas A. Albrecht , Ryan J. Gilliam , Bryan Boggs , Kyle Self , Dennis W. Solas , Michael Kostowskyj , Margarete K. Leclerc , Alexander Gorer , Michael Joseph Weiss
IPC分类号： C07C17/00 , C07C315/00 , C08F14/06 , C25B1/20 , C25B1/00 , C25B1/02
CPC分类号： C25B3/06 , B01J27/122 , B01J27/132 , C07C17/02 , C07D301/03 , C25B1/00 , C25B1/02 , C25B1/16 , C25B1/18 , C25B1/20 , C25B1/26 , C25B1/46 , C25B3/02 , C25B9/06 , C25B9/08 , C25B11/0489 , Y02E60/366
摘要： There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with hydrogen gas, an unsaturated hydrocarbon, and/or a saturated hydrocarbon to form products.
摘要翻译：提供了包括阳极和阴极的电化学电池的方法和系统，其中阳极与将金属离子从较低氧化态转化为较高氧化态的金属离子接触。较高氧化态的金属离子与氢气，不饱和烃和/或饱和烃反应形成产物。

32. 发明申请

US20130161200A1 MAGNESIUM RECOVERY METHOD AND MAGNESIUM RECOVERY APPARATUS 审中-公开
标题翻译： MAGNESIUM恢复方法和镁恢复装置
公开(公告)号：US20130161200A1
公开(公告)日：2013-06-27
申请号：US13820630
申请日：2011-09-06
申请人： Tatsushi Iwamoto , Kenichi Akamine , Junichi Okuyama
发明人： Tatsushi Iwamoto , Kenichi Akamine , Junichi Okuyama
IPC分类号： C25B1/20
CPC分类号： C02F1/46104 , C01F5/14 , C02F1/461 , C02F1/5236 , C02F9/00 , C02F2201/46115 , C02F2201/4618 , C02F2209/06 , C25B1/04 , C25B1/20 , C25B15/08 , Y02E60/366 , Y02P20/133 , Y02P20/134 , Y02W10/37
摘要： In the magnesium recovery method and magnesium recovery apparatus, anode electrolyzed water (7a) and cathode electrolyzed water (7b) produced by electrolysis of seawater are separated, alkaline material is inputted into the anode electrolyzed water to adjust pH, magnesium is precipitated as magnesium hydroxide in the cathode electrolyzed water, and recovered, and the anode electrolyzed water after pH adjustment and cathode electrolyzed water after carbonate fixation are intermixed, and discharged in a state where a pH of the intermixed water is identical to a pH of the seawater. As a result, magnesium can be recovered from seawater while minimizing impact on the environment.
摘要翻译：在镁回收方法和镁回收装置中，阳极电解水（7a）和由电解海水产生的阴极电解水（7b）分离，将碱性物质输入阳极电解水中以调节pH，镁以氢氧化镁在阴极电解水中回收，pH调节后的阳极电解水和碳酸盐固定后的阴极电解水混合后，在混合水的pH与海水的pH相同的状态下排出。因此，镁可以从海水中回收，同时减少对环境的影响。

33. 发明申请

US20060185985A1 Removing carbon dioxide from waste streams through co-generation of carbonate and/or bicarbonate minerals 有权
标题翻译：通过共同生成碳酸盐和/或碳酸氢盐矿物从废物流中去除二氧化碳
公开(公告)号：US20060185985A1
公开(公告)日：2006-08-24
申请号：US11233509
申请日：2005-09-22
申请人： Joe Jones
发明人： Joe Jones
IPC分类号： B01D53/14 , C01B17/16 , C25B1/16 , C25B1/20
CPC分类号： B01D53/62 , B01D53/1418 , B01D53/1475 , B01D53/73 , B01D53/965 , B01D2251/304 , B01D2251/604 , B01D2258/0283 , C01B32/60 , C01D7/07 , C01D7/14 , C01F1/00 , Y02C10/04 , Y02C10/06 , Y02P20/129 , Y02P20/133 , Y02P20/134 , Y02P20/152
摘要： Apparatuses and methods for removing carbon dioxide and other pollutants from a gas stream are provided. The methods include obtaining hydroxide in an aqueous mixture, and mixing the hydroxide with the gas stream to produce carbonate and/or bicarbonate. Some of the apparatuses of the present invention comprise an electrolysis chamber for providing hydroxide and mixing equipment for mixing the hydroxide with a gas stream including carbon dioxide to form an admixture including carbonate and/or bicarbonate.
摘要翻译：提供了从气流中除去二氧化碳和其他污染物质的装置和方法。所述方法包括在含水混合物中获得氢氧化物，并将氢氧化物与气流混合以产生碳酸盐和/或碳酸氢盐。本发明的一些装置包括用于提供用于将氢氧化物与包含二氧化碳的气流混合以形成包含碳酸盐和/或碳酸氢盐的混合物的氢氧化物和混合设备的电解室。

34. 发明授权

US6132590A Electrolytic process for treating aqueous waste streams 失效
标题翻译：用于处理含水废水流的电解过程
公开(公告)号：US6132590A
公开(公告)日：2000-10-17
申请号：US88195
申请日：1998-06-01
申请人： Stephen W. Moran , John R. Jackson
发明人： Stephen W. Moran , John R. Jackson
IPC分类号： B01D53/14 , C10G19/08 , C25B1/16 , C25B1/20 , C25B1/00
CPC分类号： C25B1/16 , B01D53/1418 , B01D53/1425 , C10G19/08 , C25B1/20
摘要： An electrochemical process for the production of a hydroxide solution and a sulfate by the electrolysis of a waste aqueous mixture of oxidizable sulfur impurities in the anode compartment of at least one electrolytic cell while producing a hydroxide solution in the cathode compartment of the cell. The process is particularly applicable to the treatment of spent caustic solutions obtained by scrubbing a hydrocarbon process stream contaminated with oxidizable sulfur impurities. The electrolytic cell used in the electrolysis process of the invention can use either a porous membrane or a cationic permselective membrane to separate the anode and cathode compartments of the electrolysis cell. The electrolysis cell can be monopolar or bipolar and when bipolar, the bipolar electrodes if dissimilar, or the respective anode and cathode current collectors if dissimilar, which are attached thereto, are electrically connected by bonding with a conductive polymer or are joined by welding with or without an intermediate metal layer therebetween. Control of pH in the anolyte compartment of the electrolytic cell can be achieved by passing a selected amount of catholyte to the anolyte compartment. Pre-treatment with oxygen produced in the anolyte compartment of the cell avoids release of gaseous products from the anolyte compartment and increases process efficiency. Where the process is conducted in multiple electrolytic cells, such cells are hydraulically connected in a cascading series.
摘要翻译：一种用于通过在至少一个电解池的阳极室中电解可氧化硫杂质的废水性混合物，同时在电池的阴极室中产生氢氧化物溶液来生产氢氧化物溶液和硫酸盐的电化学方法。该方法特别适用于通过洗涤被可氧化的硫杂质污染的烃工艺流而获得的废碱溶液的处理。在本发明的电解方法中使用的电解槽可以使用多孔膜或阳离子选择性选择膜来分离电解槽的阳极室和阴极室。电解电池可以是单极的或双极的，并且当双极性时，双极电极如果不相似，或者相关的阳极和阴极集电器（如果不相似）通过与导电聚合物的结合而电连接，或者通过焊接或/ 其间没有中间金属层。可以通过将选定量的阴极电解液通入阳极电解液室来实现对电解池的阳极电解液室中的pH的控制。在细胞的阳极电解液室中产生的氧的预处理避免了气体产物从阳极电解液室释放并提高了工艺效率。当该工艺在多个电解槽中进行时，这种电池在级联系列中液压连接。

35. 发明授权

US4938851A Method for preparing an electrode and use thereof in electrochemical processes 失效
标题翻译：制备电极的方法及其在电化学过程中的应用
公开(公告)号：US4938851A
公开(公告)日：1990-07-03
申请号：US153283
申请日：1988-02-05
申请人： Antonio Nidola
发明人： Antonio Nidola
IPC分类号： C25B11/06 , C25B11/00 , C25B11/04 , C25B11/08 , C25D3/50 , C25B1/20 , C25B1/26
CPC分类号： C25B11/0478
摘要： The present invention concerns a method for preparing electrodes for use in electrochemical processes, said electrodes being constituted by a conductive support whereto an electrocatalytic coating is applied by galvanic deposition from a galvanic plating bath which additionally contains the groups IB, IIB, IIIA, IVA, VA, VB, VIB, VIII Of the periodic table.The electrodes of the invention, obtainable according to the method of the invention, when used as cathodes in membrane or diaphragm chlor-alkali cells, exhibit low hydrogen overvoltages, constant with time, and are substantially immune to poisoning by iron, mercury or other metal impurities present in the alkaline solutions.

36. 发明授权

US4482436A Use of H.sub.2 SO.sub.4 H.sub.3 PO.sub.4 to remove electrolytic deposits from silver cathode surfaces 失效
标题翻译：使用H 2 SO 4 H 3 PO 4从银阴极表面除去电解沉积物
公开(公告)号：US4482436A
公开(公告)日：1984-11-13
申请号：US521859
申请日：1983-08-10
申请人： Charles K. Bon
发明人： Charles K. Bon
IPC分类号： C23F1/44 , C25B3/04 , C25B11/00 , C25B15/00 , C25B1/20
CPC分类号： C25B3/04 , C23F1/44 , C25B11/00 , C25B15/00
摘要： Less co-dissolution of silver results when base metal-containing deposits on the surfaces of silver objects are dissolved off with sulphuric or phosphoric acid, rather than hydrochloric acid.
摘要翻译：当银物体表面的含贱金属的沉积物用硫酸或磷酸而不是盐酸溶解时，银的较少的共溶解。

37. 发明授权

US4155819A Removal of heavy metals from brine 失效
标题翻译：从盐水中去除重金属
公开(公告)号：US4155819A
公开(公告)日：1979-05-22
申请号：US905821
申请日：1978-05-15
申请人： William W. Carlin
发明人： William W. Carlin
IPC分类号： C01D3/16 , C25B1/34 , C25B15/08 , C25B1/20 , C25B1/26
CPC分类号： C25B1/34 , C01D3/16 , C25B15/08
摘要： Disclosed is a method of electrolyzing alkali metal chloride brine. The method comprises feeding fortified brine to an electrolytic cell, passing an electrical current through the cell, and withdrawing depleted brine from the cell. Hydrochloric acid is added to the depleted brine to dechlorinate it; and the depleted, dechlorinated brine is then contacted with solid salt to refortify the brine. The solid brine is a source of heavy metal impurities. Sodium carbonate and barium carbonate are added to the refortified brine in order to precipitate calcium and sulfate ions therefrom. The precipitate is then separated from the refortified brine in order to obtain a refortified, purified brine. According to the disclosed method, ferrous ion and sufficient hydroxyl ion are added to the dechlorinated, depleted brine prior to its refortification in order to maintain the pH thereof above about 7 during fortification. After refortification, the pH is adjusted to pH 7 by the addition of hydrochloric acid and heavy metal impurities, such as vanadium, are flocculated therefrom. According to an alternate method, the pH can be adjusted to pH 2 by the addition of HCl and then to pH 7 by the addition of NaOH.
摘要翻译：公开了一种电解碱金属氯化物盐水的方法。该方法包括将强化的盐水加入到电解池中，使电流通过电池，并从电池中取出耗尽的盐水。将盐酸加入到耗尽的盐水中以使其脱氯; 然后将贫化的脱氯盐水与固体盐接触以使盐水回收。固体盐水是重金属杂质的来源。将碳酸钠和碳酸钡加入到经过净化的盐水中以从其中沉淀出钙和硫酸根离子。然后将沉淀物与再循环的盐水分离，以获得经过再纯化的纯化盐水。根据所公开的方法，将亚铁离子和足够的羟基离子在其重新净化之前加入到脱氯的贫化盐水中，以便在强化期间将其pH保持在约7以上。经过重新组装后，通过加入盐酸将pH值调节至pH7，并从其中絮凝重金属杂质（如钒）。根据另一种方法，可以通过加入HCl将pH调节至pH 2，然后通过加入NaOH将pH调节至pH7。

38. 发明授权

US3785943A Electrolysis of magnesium chloride 失效
标题翻译：氯化镁电解
公开(公告)号：US3785943A
公开(公告)日：1974-01-15
申请号：US3785943D
申请日：1971-11-23
申请人： SALZDETFURTH AG
发明人： HAASE J , EBERLE H , MEYER W
IPC分类号： C25B1/20 , C01B7/06 , C01F5/18
CPC分类号： C25B1/20
摘要： A PROCESS FOR THE ELECTROLYSIS OF MAGNESIUM CHLORIDE SOLUTIONS, IN THE PRESENCE OF AN ALKALI METAL CHLORIDE TO YIELD CHLORINE AND MAGNESIUM HYDROXIDE.

39. 发明授权

US3705090A Novel electrolytic cell and method for producing chlorine and metal hydroxides 失效
标题翻译：新型电解槽及其生产氯化铝和金属氢氧化物的方法
公开(公告)号：US3705090A
公开(公告)日：1972-12-05
申请号：US3705090D
申请日：1970-10-01
申请人： DOW CHEMICAL CO
发明人： BERGERON GRAFTON L , LEDDY JAMES J
IPC分类号： C25B1/20 , C25B1/26 , C23B5/68
CPC分类号： C25B1/20 , C25B1/26
摘要： A NOVEL ELECTROLYTIC CELL FOR PRODUCING BOTH CHLORINE AND ALKALINE EARTH HYDROXIDES SIMULTANEOUSLY, IN WHICH BRINE SUPPLY MEANS ARE CONNECTED TO EACH OF THE AMODE AND CATHODE CHAMBERS.

40. 发明授权

US3598707A Method for producing chlorine and metal hydroxides 失效
标题翻译：生产氯和金属氢氧化物的方法
公开(公告)号：US3598707A
公开(公告)日：1971-08-10
申请号：US3598707D
申请日：1968-09-16
申请人： DOW CHEMICAL CO
发明人： BERGERON GRAFTON L , LEDDY JAMES J
IPC分类号： C25B1/20 , C25B1/26 , C01F11/14
CPC分类号： C25B1/20 , C25B1/26
摘要： A NOVEL ELECTROLYTIC CELL AND PROCESS FOR PRODUCING BOTH CHLORINE AND ALKALINE EARTH HYDROXIDES SIMULTANEOUSLY.

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