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31. 发明授权

US5387660A Polymerization process 失效
标题翻译：聚合过程
公开(公告)号：US5387660A
公开(公告)日：1995-02-07
申请号：US024600
申请日：1993-03-01
申请人： Michael J. Doyle , Willem Terlouw
发明人： Michael J. Doyle , Willem Terlouw
IPC分类号： C08F2/00 , C08F4/60 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F6/02 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/00 , C08F210/02 , C08F4/76
CPC分类号： C08F10/00 , C08F6/02 , C08F10/02 , C08F110/02 , C08F4/65908 , C08F4/65922
摘要： A process for the polymerization of ethylene and/or one or more alpha-olefins comprising contacting ethylene, and/or the alpha-olefin(s) with a catalyst comprising a first component which is a bis(cyclopentadienyl) Group IVA metal compound containing a substituent capable of reacting with a cation, and a second component which is a compound having a bulky anion containing one or more boron atoms and which is substantially non-coordinating under the reaction conditions and a cation, in which process additional first component is added.
摘要翻译：一种乙烯和/或一种或多种α-烯烃的聚合方法，包括使乙烯和/或α-烯烃与包含第一组分的催化剂接触，所述第一组分是双（环戊二烯基）IVA族金属化合物，其含有能够与阳离子反应的取代基，以及第二组分，其是具有含有一个或多个硼原子的庞大阴离子并且在反应条件下基本上不配位的化合物和阳离子，其中添加另外的第一组分。

32. 发明授权

US5244965A Polymer solution treatment process 失效
标题翻译：聚合物溶液处理工艺
公开(公告)号：US5244965A
公开(公告)日：1993-09-14
申请号：US368155
申请日：1989-06-14
申请人： Akhtar Osman , William G. Bradford
发明人： Akhtar Osman , William G. Bradford
IPC分类号： C08C2/04 , C08F6/02
CPC分类号： C08C2/04 , C08F6/02
摘要： The present invention provides a process to remove phosphine residues from a hydrogenated polymer solution.
摘要翻译：本发明提供从氢化聚合物溶液中除去磷化氢残留物的方法。

33. 发明授权

US5147506A Compatibility agent for aqueous polypigmentary suspensions containing hydrated calcium sulfate 失效
公开(公告)号：US5147506A
公开(公告)日：1992-09-15
申请号：US745402
申请日：1991-08-15
申请人： Jacques Mongoin , Georges Ravet , Jean-Marc Suau
发明人： Jacques Mongoin , Georges Ravet , Jean-Marc Suau
IPC分类号： B01F17/52 , B01J13/00 , C01F11/46 , C08F6/00 , C08F6/02 , C08F20/04 , C08F30/02 , C08F220/04 , C08L43/00 , C08L43/02 , C09C1/02 , D21H19/44 , D21H19/58
CPC分类号： D21H19/58 , C01F11/46
摘要： Copolymers having the general formula: ##STR1## are useful as compatibility, dispersion and grinding agents for aqueous pigmentary suspensions formulated from a mixture of mineral pigments, at least one of which is hydrated calcium sulfate. These suspensions are useful in papermaking.

34. 发明授权

US4950723A Organic acid halide neutrallizing agents for anionic polymerizations 失效
标题翻译：用于阴离子聚合的有机酰卤中和剂
公开(公告)号：US4950723A
公开(公告)日：1990-08-21
申请号：US299202
申请日：1989-01-23
申请人： Corwin J. Bredeweg
发明人： Corwin J. Bredeweg
IPC分类号： C08C19/44 , C08F2/38 , C08F6/02 , C08F297/04
CPC分类号： C08F297/04 , C08C19/44 , C08F6/02
摘要： A process for neutralizing the terminated remnant of an alkali metal anionic polymerization initiator comprising contacting the remnant with an organic acid halide.

35. 发明授权

US4719270A Process for production of polyethylene 失效
标题翻译：聚乙烯生产工艺
公开(公告)号：US4719270A
公开(公告)日：1988-01-12
申请号：US840545
申请日：1986-03-17
申请人： Yukimasa Miwa , Takeo Shimada , Shigekazu Hayashi , Yoshio Kobayashi , Yoshiteru Kageyama
发明人： Yukimasa Miwa , Takeo Shimada , Shigekazu Hayashi , Yoshio Kobayashi , Yoshiteru Kageyama
IPC分类号： C08F6/00 , C08F4/60 , C08F6/02 , C08F6/06 , C08F10/00 , C08F10/02
CPC分类号： C08F6/02 , Y10S526/902
摘要： A novel process for production of polyethylene comprises polymerizing ethylene or a mixture of ethylene and a copolymerizable comonomer in the presence of a Ziegler-type catalyst at a pressure of 200 atm or more and at a temperature of 125.degree. C. or more, wherein an organic peroxide is added to the resulting polymerization product taken out of a reaction zone to deactivate the remaining catalyst. Formation of undesired oligomers or low-molecular polymers is prevented because the reaction does not proceed in the polymerization product taken out of the reaction zone. There is almost no retardation of the polymerization reaction even by the recycled use of the monomer separated and collected from the polymerization product.
摘要翻译：一种生产聚乙烯的新方法包括在齐格勒型催化剂存在下，在200atm或更大的压力和125℃或更高的温度下聚合乙烯或乙烯和可共聚共聚单体的混合物，其中将有机过氧化物加入到从反应区中取出的所得聚合产物中以使剩余的催化剂失活。由于反应不在从反应区中取出的聚合产物中进行，因此可防止形成不需要的低聚物或低分子聚合物。即使通过再循环使用从聚合产物中分离和收集的单体，几乎没有聚合反应的延迟。

36. 发明授权

US4476297A Process for removing catalyst residues from polyolefins 失效
标题翻译：从聚烯烃中除去催化剂残留物的方法
公开(公告)号：US4476297A
公开(公告)日：1984-10-09
申请号：US407123
申请日：1982-08-11
申请人： Hans-Jurgen Kablitz , Helmut Strametz
发明人： Hans-Jurgen Kablitz , Helmut Strametz
IPC分类号： C08F6/02 , C08F6/08
CPC分类号： C08F6/02
摘要： In polyolefins, the content of titanium and light metal halides and aluminum compounds emanating from the catalyst system can be considerably reduced by treatment with a higher, preferably branched, aliphatic monocarboxylic acid having 6 to 10 carbon atoms.
摘要翻译：在聚烯烃中，通过用具有6至10个碳原子的较高优选支化的脂肪族单羧酸处理，可以显着降低从催化剂体系发出的钛和轻金属卤化物和铝化合物的含量。

37. 发明授权

US4433098A Process for preparing a copolymer aqueous solution from which a catalyst residue is removed 失效
标题翻译：制备除去催化剂残余物的共聚物水溶液的方法
公开(公告)号：US4433098A
公开(公告)日：1984-02-21
申请号：US312821
申请日：1981-10-19
申请人： Hiroyuki Itoh , Teruaki Yamanashi , Hirosuke Imai
发明人： Hiroyuki Itoh , Teruaki Yamanashi , Hirosuke Imai
IPC分类号： C08F6/00 , C08F6/02 , C08F6/06 , C08F6/08 , C08F220/00 , C08F220/04 , C08F222/00 , C08F222/06 , C08F236/00 , C08F236/06
CPC分类号： C08F6/02
摘要： A process involves preparing an aqueous solution of a diolefin-maleic anhydride copolymer prepared by solution polymerization, said aqueous solution being free of tetramethylsuccinonitrile (TMSN), a by-product resulting from the decomposition of azobisisobutyronitrile (AIBN) used as a polymerization initiator for the copolymerization of the diolefin-maleic anhydride copolymer. The aqueous solution free of TMNS is obtained without the separation of the copolymer from the polymerization liquid in which the copolymer was prepared. The process is composed of the two distillation steps, the first distillation being for the removal of a solvent for polymerization and the second distillation being for the removal of water as well as TMSN. The first and second distillation steps can be carried out in a continuous or discontinuous manner. The first distillation step is carried out after and/or during the addition of water or a basic aqueous solution, and the second distillation can be effected with or without the addition of such liquid. This process is particularly effective for removal of TMSN which is highly toxic and causes problems from the safety point of view.
摘要翻译：一种方法包括制备通过溶液聚合制备的二烯烃 - 马来酸酐共聚物的水溶液，所述水溶液不含作为用作聚合引发剂的偶氮二异丁腈（AIBN）分解产生的副产物四甲基琥珀腈（TMSN）二烯烃 - 马来酸酐共聚物的共聚合。在不将共聚物与制备共聚物的聚合液体分离的情况下得到不含TMNS的水溶液。该方法由两个蒸馏步骤组成，第一次蒸馏用于除去聚合用溶剂，第二次蒸馏用于除去水以及TMSN。第一和第二蒸馏步骤可以以连续或不连续的方式进行。第一蒸馏步骤在加入水或碱性水溶液之后和/或之后进行，第二蒸馏可以在添加或不添加这种液体的情况下进行。该方法对于去除高毒性并从安全角度引起问题的TMSN特别有效。

38. 发明授权

US4369306A Method for treating olefin polymer for removing catalyst 失效
标题翻译：处理烯烃聚合物以除去催化剂的方法
公开(公告)号：US4369306A
公开(公告)日：1983-01-18
申请号：US240404
申请日：1981-03-04
申请人： Akinori Toyota , Norio Kashiwa
发明人： Akinori Toyota , Norio Kashiwa
IPC分类号： C08F6/00 , C08F4/62 , C08F6/02 , C08F6/06 , C08F10/00 , C08F6/08
CPC分类号： C08F6/02
摘要： A method for treating an olefin polymer, which comprises contacting an olefin polymer obtained by polymerizing an olefin in the presence of a catalyst composed of (A) a highly active transition metal compound, (B) an organoaluminum compound and (C) a carbonyl- or Si-containing electron donor, with (D) an organometallic compound of a metal of Groups I to III of the periodic table after the polymerization. This method can markedly reduce the amount of an electron donor remaining in an olefin polymer after polymerization, the electron donor being an ingredient of a catalyst used in the polymerization and constituting the main cause of an offensive odor which the resulting polymer gives off.
摘要翻译：一种处理烯烃聚合物的方法，其包括在由（A）高活性过渡金属化合物，（B）有机铝化合物和（C）羰基化合物）组成的催化剂存在下使通过聚合烯烃获得的烯烃聚合物接触，或含Si的电子给体，与（D）聚合后的元素周期表第I至III族金属的有机金属化合物。该方法可以显着降低聚合后残留在烯烃聚合物中的电子给体的量，电子给体是聚合中使用的催化剂的成分，并且构成所得聚合物发出的恶臭的主要原因。

39. 发明授权

US4195145A Process for the purification of highly crystalline polyolefins 失效
标题翻译：纯化高结晶性聚烯烃的方法
公开(公告)号：US4195145A
公开(公告)日：1980-03-25
申请号：US959806
申请日：1978-11-13
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Takatoshi Suzuki
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Takatoshi Suzuki
IPC分类号： C08F6/00 , C08F6/02 , C08F6/06 , C08F6/26 , C08F6/28
CPC分类号： C08F6/26 , C08F6/02
摘要： A process for purifying propylene homopolymers or copolymers which comprises:(i) polymerizing or copolymerizing propylene with other unsaturated hydrocarbon monomers in liquid propylene in the presence of a catalyst system consisting essentially of (a) an activated titanium trichloride obtained by reducing titanium tetrachloride with an organo-aluminum compound followed by activation and (b) an organo-aluminum compound;(ii) introducing the resulting polymer slurry into an upper portion of a counter-current washing tower to counter-currently contact the polymer slurry with a C.sub.3 -C.sub.8 alcohol and liquid propylene, whereby said catalyst is deactivated and at the same time the propylene homopolymers or copolymers dissolved in the polymer slurry and the catalyst are removed by washing, wherein said alcohol is used in an amount 0.1 to 50 times by mole based on said organo-aluminum compound (b) and is supplied to the washing tower lower than the point of introduction of said polymer slurry, and said liquid propylene is supplied to a lower portion of the washing tower; and(iii) then after removing volatile monomers by flashing, contacting the powdery propylene homopolymers or copolymers with a gaseous epoxide at a temperature lower than melting point of said polymer or copolymer.
摘要翻译：一种用于纯化丙烯均聚物或共聚物的方法，其包括：（i）在液体丙烯中，在催化剂体系存在下，将丙烯与其它不饱和烃单体聚合或共聚，所述催化剂体系基本上由（a）通过将四氯化钛还原成四氯化钛得到的活化三氯化钛有机铝化合物，然后活化，（b）有机铝化合物; （ii）将所得聚合物浆料引入逆流洗涤塔的上部，以与C3-C8醇和液体丙烯反应地接触聚合物浆料，由此所述催化剂失活，同时丙烯均聚物或溶解在聚合物浆料中的共聚物和催化剂通过洗涤除去，其中所述醇的用量相对于所述有机铝化合物（b）为0.1至50倍摩尔量，并且供应至低于该点的洗涤塔引入所述聚合物浆料，并将所述液态丙烯供应到洗涤塔的下部; 和（iii）然后在通过闪蒸除去挥发性单体之后，在低于所述聚合物或共聚物的熔点的温度下使粉末丙烯均聚物或共聚物与气态环氧化物接触。

40. 发明授权

US4065610A Treatment of contaminated hydrocarbon from olefin polymerization 失效
标题翻译：从烯烃聚合中处理污染的烃
公开(公告)号：US4065610A
公开(公告)日：1977-12-27
申请号：US731593
申请日：1976-10-12
申请人： Jan W. De Beukelaar , Henry Van Zwet , Jacob B. Roest
发明人： Jan W. De Beukelaar , Henry Van Zwet , Jacob B. Roest
IPC分类号： C08F6/00 , C08F2/00 , C08F6/02 , C08F6/06 , C08F10/00 , C08F10/06
CPC分类号： C08F6/02 , Y10S526/912
摘要： In conventional olefin polymerization using TiCl.sub.3 -containing Ziegler type catalysts, the catalyst-containing reaction product may be de-ashed by treatment with titanium-solubilizing compounds such as alcohols and the polymer product from the de-ashing step washed with a hydrocarbon to separate it from catalyst residue. It is desirable to treat the dirty hydrocarbon wash liquid to recover purified hydrocarbon suitable for recycle to the polymerization reaction. According to this invention the dirty hydrocarbon wash liquid is treated with an epoxy compound in the presence of an alcohol and distilled to recover purified hydrocarbon suitable for recycle.
摘要翻译：在使用含TiCl 3的齐格勒型催化剂的常规烯烃聚合中，含催化剂的反应产物可以通过用钛增溶化合物如醇处理脱落，并且去除步骤的聚合物产物用烃洗涤以分离来自催化剂残留物。理想的是处理脏的碳氢化合物洗涤液以回收适于再循环到聚合反应中的纯化烃。根据本发明，在醇的存在下用环氧化合物处理脏的烃洗液，并蒸馏回收适于再循环的纯化烃。

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