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    • 35. 发明申请
    • SULFONIUM COMPOUNDS, THEIR PREPARATION AND USE
    • 磺化合物,其制备和使用
    • US20150044509A1
    • 2015-02-12
    • US14389831
    • 2013-04-17
    • BASF SE
    • Kazuhiko KunimotoHisatoshi Kura
    • C08G59/62C07D333/46C07D307/10B05D3/00C09D163/00C07C309/10C08G59/40C07C309/08C07D309/08
    • C08G59/62B05D3/007C07C309/08C07C309/10C07C2601/08C07C2601/14C07D307/10C07D309/08C07D333/46C08G59/4064C08L63/00C09D11/02C09D163/00C09J163/00G03F7/0045
    • Compounds of the formula (I), (Ia) or (Ib) wherein A1, and A− is for example (II) is 1 or 2; X is C1-C4 alkylene or CO; Y is for example O, O(CO), O(CO)O, R1 is for example hydrogen, d-dsalkyl, C3-C30cycloalkyl, phenyl, naphthyl, anthracyl, phenanthryl, biphenylyl, fluorenyl or C3-C20heteroaryl, all of which optionally are substituted; R2 and R3 for example are C1-C10haloalkylene which is optionally substituted, or R2 and R3 are phenylene, which optionally is substituted; R4 is a group (A) or a group (B); R5 and R6 for example are C1-C20alkyl; or R4 and R5 or R4 and R6 together form a straight-chain C2-C6alkylene, R5 and R6 together form a straight-chain C2-C6alkylene; R7, R8, R9 and R10 ifor example are C1-C20alkyl; M for example is C1-C20alkylene, C2-C20alkenylene, C2-C20alkynylene; R25 and R26 are for example hydrogen, C1-C20alkyl; R27, R28, R29, R30 and R31 are for example hydrogen, C1-C20alkyl, C2-C20alkenyl, C3-C20cycloalkyl, or two radicals R27 and R28, R28 and R29, R29 and R30 and/or R30 and R31 together form a straight-chain C2-C6alkylene, or R25 and R27 together form 1,2-phenylene, R33 and R34 for example are hydrogen, C1-C20alkyl; R35, R36 and R37 for example are hydrogen, C1-C20alkyl; are suitable as thermo-acid generators.
    • 其中A1和A-为(II)的式(I),(Ia)或(Ib)的化合物为1或2; X是C 1 -C 4亚烷基或CO; Y是例如O,O(CO),O(CO)O,R 1例如是氢,d-ds烷基,C 3 -C 30环烷基,苯基,萘基,蒽基,菲基,联苯基,芴基或C 3 -C 20杂芳基, 任选被取代; R2和R3例如是任选取代的C1-C10卤代亚烷基,或R2和R3是任选被取代的亚苯基; R4是一组(A)或一组(B); R5和R6例如是C1-C20烷基; 或R 4和R 5或R 4和R 6一起形成直链C 2 -C 6亚烷基,R 5和R 6一起形成直链C 2 -C 6亚烷基; R 7,R 8,R 9和R 10如果为C 1 -C 20烷基; M例如是C 1 -C 20亚烷基,C 2 -C 20亚烯基,C 2 -C 20亚炔基; R 25和R 26是例如氢,C 1 -C 20烷基; R27,R28,R29,R30和R31是例如氢,C1-C20烷基,C2-C20链烯基,C3-C20环烷基或两个基团R27和R28,R28和R29,R29和R30和/或R30和R31一起形成直链 链C 2 -C 6亚烷基或R 25和R 27一起形成1,2-亚苯基,R 33和R 34例如是氢,C 1 -C 20烷基; R 35,R 36和R 37例如是氢,C 1 -C 20烷基; 适合作为热酸发生器。