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31. 发明申请

US20160114314A1 MONOLITH STRUCTURE LOADED WITH METAL PROMOTED NANOZEOLITES FOR ENHANCED PROPYLENE SELECTIVITY IN METHANOL CONVERSION 有权
标题翻译：用金属促进的纳米微粒填充的单晶结构，用于增强甲醇转化中的丙烯选择性
公开(公告)号：US20160114314A1
公开(公告)日：2016-04-28
申请号：US14520978
申请日：2014-10-22
申请人： King Fahd University of Petroleum and Minerals
发明人： Mohammad Ashraf ALI , Shakeel Ahmed
IPC分类号： B01J29/78 , B01J35/00 , B01J37/08 , B01J35/04 , B01J37/02 , C07C1/22 , B01J29/76
CPC分类号： B01J29/78 , B01J23/74 , B01J29/072 , B01J29/076 , B01J29/46 , B01J29/76 , B01J35/0006 , B01J35/04 , B01J37/0201 , B01J37/0215 , B01J37/0246 , B01J37/08 , C07C1/20 , C07C2529/46 , C07C2529/48 , C07C2529/76 , C07C2529/78 , Y02P20/52 , Y02P30/42 , C07C11/06
摘要： A catalyst system and a process for methanol to light olefin conversion with enhanced selectivity towards propylene. The catalyst system comprises a honeycomb monolith catalyst support coated with nanozeolite catalysts on the edges and inside the channels of the support structure. The nanozeolite catalysts have been pre-modified with metal. The catalyst system gives higher hydrothermal stability to the catalyst compared to randomly packed pellet catalyst and allows methanol to be converted to predominantly propylene at a low temperature, with decreased selectivity towards C2, higher olefins and paraffinic hydrocarbons.
摘要翻译：一种催化剂体系和一种甲醇使烯烃转化率降低的方法，对丙烯具有更高的选择性。催化剂体系包括在支撑结构的通道的边缘和内部涂覆有纳米沸石催化剂的蜂窝单体催化剂载体。纳米沸石催化剂已经用金属预先修饰。与随机填充的颗粒催化剂相比，催化剂体系对催化剂具有更高的水热稳定性，并允许甲醇在低温下转化为主要的丙烯，对C2，高级烯烃和链烷烃的选择性降低。

32. 发明授权

US09314780B2 Process for producing light olefins by using a ZSM-5-based catalyst 有权
标题翻译：通过使用ZSM-5系催化剂制造轻质烯烃的方法
公开(公告)号：US09314780B2
公开(公告)日：2016-04-19
申请号：US13882946
申请日：2011-10-25
申请人： Aghaddin Kh. Mammadov
发明人： Aghaddin Kh. Mammadov
IPC分类号： C07C1/22 , B01J29/48 , B01J23/83 , B01J29/40 , B01J29/46 , B01J37/02 , C01B3/38 , C07C1/20
CPC分类号： B01J29/48 , B01J23/83 , B01J29/40 , B01J29/405 , B01J29/46 , B01J37/0207 , B01J2229/37 , B01J2229/40 , B01J2229/42 , C01B3/38 , C01B2203/0238 , C01B2203/0244 , C01B2203/025 , C01B2203/062 , C01B2203/1047 , C01B2203/1058 , C01B2203/1082 , C01B2203/148 , C07C1/20 , C07C1/22 , C07C2521/08 , C07C2529/40 , C07C2529/46 , C07C2529/48 , Y02P20/125 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06
摘要： The present invention relates to a catalyst composition useful in a process for producing lower olefins from a oxygenate feedstream, a process for producing said catalyst composition and a process for producing lower olefins comprising contacting a oxygenate feedstream with the catalyst composition M1-M2-P/ZSM-5 with an oxygenate-comprising feedstream, wherein M1 is one or more basic species, M2 is one or more redox elements selected from Groups 6-8 of the Periodic Table of Elements and Sn and P is phosphorus, wherein said basic species is a molecular entity forming a weak Lewis base and/or a weak Bronsted base in the catalyst composition. In addition thereto, the present invention relates to an integrated process for producing lower olefins from a feedstream comprising hydrocarbons.
摘要翻译：本发明涉及一种可用于从含氧化合物原料流生产低级烯烃的方法的催化剂组合物，该催化剂组合物的制备方法和一种生产低级烯烃的方法，该方法包括使含氧化合物进料流与催化剂组合物M1-M2-P / ZSM-5与含氧化合物的原料流，其中M1是一种或多种碱性物质，M2是选自元素周期表第6-8族中的一种或多种氧化还原元素，Sn和P是磷，其中所述碱性物质为在催化剂组合物中形成弱路易斯碱和/或弱Bronsted碱的分子实体。除此之外，本发明涉及从包含烃的原料流中生产低级烯烃的综合方法。

33. 发明授权

US09254479B2 Process and catalyst for cracking of ethers and alcohols 有权
公开(公告)号：US09254479B2
公开(公告)日：2016-02-09
申请号：US14479844
申请日：2014-09-08
申请人： J. Yong Ryu
发明人： J. Yong Ryu
IPC分类号： B01J21/12 , B01J27/125 , B01J27/12 , B01J37/26 , C07C1/20 , B01J38/54 , B01J38/64 , B01J37/08 , B01J38/60 , B01J38/66 , B01J23/20
CPC分类号： B01J27/125 , B01J21/12 , B01J23/20 , B01J27/12 , B01J37/086 , B01J37/088 , B01J37/26 , B01J38/54 , B01J38/60 , B01J38/64 , B01J38/66 , C07C1/20 , C07C2521/12 , C10G2300/805 , C10G2400/20 , C10G2400/22 , Y02P20/52 , Y02P30/42 , C07C11/06 , C07C11/04 , C07C11/09 , C07C11/10
摘要： A process for the production of olefins from at least one of an alcohol and ether, the process including: contacting at least one alcohol or ether with a hydrofluoric acid-treated amorphous synthetic alumina-silica catalyst under decomposition conditions to produce an olefin. Also disclosed is a process for the production of isobutylene from methyl tertiary butyl ether, the process including: feeding methyl tertiary butyl ether (MTBE) to a reactor having at least one reaction zone containing a hydrofluoric acid-treated amorphous synthetic alumina-silica catalyst; contacting the MTBE with the hydrofluoric acid-treated amorphous synthetic alumina-silica catalyst under decomposition conditions to produce a reactor effluent comprising isobutylene, unreacted MTBE, heavies, and methanol; feeding the reactor effluent to a first distillation column; separating the isobutylene from the unreacted MTBE, heavies, and the methanol in the first distillation column to recover a first bottoms fraction comprising heavies, unreacted MTBE, and methanol and an isobutylene-rich overheads fraction.

34. 发明授权

US09212104B2 Organo-catalytic biomass deconstruction 有权
标题翻译：有机催化生物质解构
公开(公告)号：US09212104B2
公开(公告)日：2015-12-15
申请号：US13339661
申请日：2011-12-29
申请人： Ming Qiao , Randy D. Cortright , Elizabeth Woods
发明人： Ming Qiao , Randy D. Cortright , Elizabeth Woods
IPC分类号： C13K13/00 , C07B63/00 , C10G1/06 , C10G3/00 , B01J20/34 , C07C29/132 , B01J23/46 , B01J23/652 , B01J23/68
CPC分类号： C13K1/02 , B01J20/34 , B01J23/462 , B01J23/464 , B01J23/52 , B01J23/6527 , B01J23/687 , C07B63/00 , C07C29/132 , C08B30/12 , C10G1/06 , C10G1/065 , C10G3/42 , C10G3/47 , C10G2300/1011 , C10G2300/1014 , C10G2300/44 , C10G2300/805 , C10G2400/30 , C13K13/00 , Y02P30/20 , Y02P30/42
摘要： The present invention provides processes for catalytic deconstruction of biomass using a solvent produced in a bioreforming reaction.
摘要翻译：本发明提供使用在生物反应形成反应中生产的溶剂来催化解构生物质的方法。

35. 发明申请

US20150352538A1 ZEOLITIC MATERIALS WITH MODIFIED SURFACE COMPOSITION, CRYSTAL STRUCTURE, CRYSTAL SIZE, AND/OR POROSITY, METHODS FOR MAKING THE SAME, AND METHODS FOR CONVERTING OXYGENATES TO OLEFINS VIA REACTIONS CATALYZED BY THE SAME 审中-公开
标题翻译：具有改性表面组合物的结晶材料，晶体结构，晶体尺寸和/或孔隙率，其制备方法，以及通过相同催化反应将氧化物转化为烯烃的方法
公开(公告)号：US20150352538A1
公开(公告)日：2015-12-10
申请号：US14519441
申请日：2014-10-21
申请人： UOP LLC
发明人： Nick J. Schoenfeldt , David Stickley , Jaime G. Moscoso , Deng-Yang Jan , Benjamin Daniel Yuhas
IPC分类号： B01J29/85 , C01B39/54
CPC分类号： B01J29/85 , B01J29/06 , B01J35/023 , B01J2229/12 , B01J2229/186 , B01J2229/34 , B01J2229/38 , C01B37/08 , C01B39/026 , C01B39/54 , C07C1/20 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： Zeolitic materials with modified surface composition, crystal structure, crystal or particle size, and/or porosity, methods for making the same, and methods for converting oxygenates to olefins using the same are provided herein. In an exemplary embodiment, a method for reducing a surface silicon content of a silicon-containing zeolitic material is provided that includes providing a silicon-containing zeolitic material; and contacting the silicon-containing zeolitic material with a modifying solution comprising one or more of an amine, an alcoholamine, and an amino acid. In this embodiment, the contacting occurs under conditions suitable for the modifying solution to reduce a surface silicon content, increase the porosity, and/or decrease an average crystal or particle size of the silicon-containing zeolitic material.
摘要翻译：提供具有改性表面组成，晶体结构，晶体或粒径和/或孔隙率的沸石材料，及其制备方法，以及使用其制备含氧化合物至烯烃的方法。在一个示例性实施例中，提供了一种用于降低含硅沸石材料的表面硅含量的方法，其包括提供含硅沸石材料; 并使含硅沸石材料与包含胺，醇胺和氨基酸中的一种或多种的改性溶液接触。在该实施方案中，接触在适于改性溶液的条件下进行，以降低表面硅含量，增加孔隙率，和/或降低含硅沸石材料的平均晶体或粒度。

36. 发明授权

US09180439B2 Process for obtaining modified molecular sieves 有权
标题翻译：获得改性分子筛的方法
公开(公告)号：US09180439B2
公开(公告)日：2015-11-10
申请号：US12811219
申请日：2009-01-23
申请人： Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk , Delphine Minoux
发明人： Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk , Delphine Minoux
IPC分类号： B01J29/06 , B01J27/16 , B01J29/40 , B01J37/28 , C07C1/20 , B01J37/02
CPC分类号： C07C1/20 , B01J27/16 , B01J29/06 , B01J29/061 , B01J29/40 , B01J29/405 , B01J37/0201 , B01J37/0207 , B01J37/024 , B01J37/28 , B01J2229/16 , B01J2229/186 , B01J2229/36 , B01J2229/37 , C07C4/06 , C07C2523/02 , C07C2527/14 , C07C2529/06 , C07C2529/40 , C07C2529/82 , C07C2529/85 , C08F110/02 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The invention covers a process for obtaining an alkaline earth or rare earth metal-P-modified molecular sieve (M-P-modified molecular sieve) comprising the following steps: a). selecting at least one molecular sieve selected from one of: a P-modified molecular sieve which contains at least 0.3 wt % of P obtained by dealuminating a molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P a molecular sieve which is modified with P during step b) by dealuminating the molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P thereby introducing at least 0.3 wt % of P b). contacting said molecular sieve with an alkaline earth or rare earth metal-containing compound (M-containing compound) to introduce at least 0.05 wt % of the alkaline earth or rare earth metal to the molecular sieve. The invention also covers a catalyst composite comprising: a). at least 10 wt % of a M-P-modified molecular sieve comprising at least 0.05% by weight of an alkaline earth or rare earth metal (M) and at least 0.3 wt % of P, b). optionally metal phosphate, c). optionally matrix material, and d). optionally binder. The catalyst of the invention can also be used in a process for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted in the XTO reactor with the catalyst composite according to the invention under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The catalyst composite of the invention can also be used in addition or alternatively in an OCP process.
摘要翻译：本发明涉及一种获得碱土金属或稀土金属-P改性分子筛（M-P改性分子筛）的方法，包括以下步骤：a）。选择至少一种分子筛，其选自以下之一中的一种分子筛：P-改性分子筛，其含有至少0.3重量％的通过在蒸汽步骤中脱模分子筛获得的P，然后使用含有源的 P是在步骤b）期间用P改性的分子筛，通过在蒸汽步骤中脱分解分子筛，然后使用含有P源的酸溶液进行浸出步骤，从而引入至少0.3重量％的P b）。使所述分子筛与含碱土金属或稀土金属的化合物（含M化合物）接触，以将至少0.05重量％的碱土金属或稀土金属引入分子筛中。本发明还涉及一种催化剂复合材料，其包含：a）。至少10重量％的M-P改性分子筛包含至少0.05重量％的碱土金属或稀土金属（M）和至少0.3重量％的P，b）。任选的金属磷酸盐，c）。任选的基质材料，和d）。可选粘合剂。本发明的催化剂也可以用于从含氧，含卤素或含硫有机原料制备烯烃产物的方法，其中所述含氧卤化物或含硫有机原料接触在具有将含氧，含卤素或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下，具有根据本发明的催化剂复合材料的XTO反应器。本发明的催化剂复合材料也可以在OCP方法中加入或替代地使用。

37. 发明授权

US09162941B2 Process to make olefins from isobutanol 有权
标题翻译：从异丁醇制备烯烃的方法
公开(公告)号：US09162941B2
公开(公告)日：2015-10-20
申请号：US14694282
申请日：2015-04-23
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C1/24 , C07C6/04 , C12P7/16
CPC分类号： C07C1/24 , B01J29/40 , B01J2229/42 , C07C1/22 , C07C4/06 , C07C6/04 , C07C2529/40 , C08F10/02 , C10G3/42 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： A process for the conversion of an alcohol mixture to make propylene may include introducing into a reactor a stream that includes the alcohol mixture. The alcohol mixture may include 20 to 100 weight percent isobutanol. The process may include contacting the stream with a single catalyst at a temperature above 450° C. in the reactor at conditions effective to dehydrate the isobutanol, forming C4+ olefins, and to catalytically crack the C4+ olefins. The single catalyst may be an acid catalyst adapted to cause both the dehydration and the catalytic cracking. The process may include recovering from the reactor an effluent that includes ethylene, propylene, water, and various hydrocarbons. The process may include fractionating the effluent to produce an ethylene stream, a propylene stream, a fraction of hydrocarbons having 4 carbon atoms or more, and water.
摘要翻译：将醇混合物转化成丙烯的方法可包括向反应器中引入包含醇混合物的流。醇混合物可以包括20至100重量％的异丁醇。该方法可以包括在反应器内在高于450℃的温度下将流与单一催化剂接触，所述条件有效地使异丁醇脱水，形成C4 +烯烃，并催化裂解C4 +烯烃。单一催化剂可以是适于引起脱水和催化裂化两者的酸催化剂。该方法可以包括从反应器中回收包括乙烯，丙烯，水和各种烃的流出物。该方法可以包括对流出物进行分馏以产生乙烯流，丙烯流，具有4个碳原子或更多个碳原子的部分和水。

38. 发明授权

US09162940B2 Process to make olefins from isobutanol 有权
标题翻译：从异丁醇制备烯烃的方法
公开(公告)号：US09162940B2
公开(公告)日：2015-10-20
申请号：US14692408
申请日：2015-04-21
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C1/24 , C07C4/06 , C12P7/16 , C07C29/00
CPC分类号： C07C1/24 , C07C1/20 , C07C1/22 , C07C2/12 , C07C4/06 , C07C11/06 , C07C29/00 , C07C2529/40 , C07C2529/85 , C08F210/02 , C08F210/06 , C12P7/16 , Y02P30/42
摘要： A process for the conversion of an alcohol mixture may include introducing into a reactor a stream including the alcohol mixture mixed with a stream including olefins having 4 carbon atoms or more. The process may include contacting the stream with a single catalyst at a temperature above 500° C. in the reactor at conditions effective to dehydrate isobutanol, forming C4+ olefins, and to catalytically crack the C4+ olefins. The single catalyst may be an acid catalyst adapted to cause both the dehydration and catalytic cracking. The process may include recovering an effluent including ethylene, propylene, and water, and fractionating the effluent.
摘要翻译：醇混合物的转化方法可以包括将包含醇混合物的物流与包含具有4个或更多个碳原子的烯烃的物流混合到反应器中。该方法可以包括在反应器中在高于500℃的温度下将流与单一催化剂接触，所述条件有效地使异丁醇脱水，形成C4 +烯烃，并催化裂解C4 +烯烃。单一催化剂可以是适于引起脱水和催化裂化两者的酸催化剂。该方法可以包括回收包括乙烯，丙烯和水在内的流出物，并对流出物进行分馏。

39. 发明授权

US09162937B2 Process to make olefins from organics with reduced side reactions 有权
标题翻译：从有机物制备烯烃，减少副反应的方法
公开(公告)号：US09162937B2
公开(公告)日：2015-10-20
申请号：US13055019
申请日：2009-07-03
申请人： Giacomo Grasso , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath , Eric Duchesne
发明人： Giacomo Grasso , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath , Eric Duchesne
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , Y02P30/42 , C07C11/02 , C07C11/06
摘要： The present invention is a process for making an olefin product from an oxygen-containing organic feedstock comprising: providing a mixture of said oxygen-containing feedstock, an hydrocarbon and optionally an inert diluent, contacting said mixture in a reaction zone having an inner surface (the MTO reactor) with a zeolitic catalyst at conditions effective to convert at least a part of the oxygen-containing organic feedstock to olefin products (the MTO reactor effluent), recovering a reactor effluent comprising light olefins, a heavy hydrocarbon fraction and undesired by-products, wherein: at least a part of the inner surface is passivated such that the undesired by-products are reduced by comparison with a non passivated inner surface and/or one or more sulphur compound is co-injected with the said oxygen-containing feedstock and the hydrocarbon and said sulphur compound is capable to reduce the undesired by-products by comparison with a non injection of sulphur compound. The present invention is of high interest for the catalyst of the ZSM type such as ZSM-5 optionally containing phosphorus and regenerated in the MTO reactor.
摘要翻译：本发明是从含氧有机原料制备烯烃产物的方法，包括：提供所述含氧原料，烃和任选的惰性稀释剂的混合物，使所述混合物在具有内表面的反应区 MTO反应器），在有效地将至少一部分含氧有机原料转化为烯烃产物（MTO反应器流出物）的条件下使用沸石催化剂，回收包含轻质烯烃，重质烃馏分和不希望的副产物的反应器流出物，产品，其中：所述内表面的至少一部分被钝化，使得通过与非钝化内表面相比减少不需要的副产物和/或一种或多种硫化合物与所述含氧原料共注入并且烃和所述硫化合物能够通过与非注射硫化合物相比而减少不期望的副产物。本发明对ZSM型催化剂如ZSM-5任选含磷并在MTO反应器中再生而感兴趣。

40. 发明申请

US20150291484A1 PROCESSES FOR THE PREPARATION OF AN OLEFINIC PRODUCT 有权
标题翻译：制备烯烃产品的方法
公开(公告)号：US20150291484A1
公开(公告)日：2015-10-15
申请号：US14439292
申请日：2013-10-29
申请人： SHELL OIL COMPANY
发明人： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
IPC分类号： C07C1/20 , C07C4/04
CPC分类号： C07C1/20 , C07C4/04 , C07C2529/06 , C10G9/00 , Y02P30/42 , C07C11/02
摘要： The invention provides a process for preparing an olefin, comprising: (a) reacting an oxygenate, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature lower than the dew point temperature of the effluent stream by direct injection of an aqueous liquid into the effluent stream, to form a quench effluent stream; and (d) passing the quench effluent stream into a quench tower and contacting the quench effluent stream with a second aqueous liquid in the presence of at least one set of internals, to produce a quench tower gaseous stream comprising the olefin.
摘要翻译：本发明提供了一种制备烯烃的方法，包括：（a）使反应区中的含氧化合物在分子筛催化剂存在下，在350至1000℃的温度下反应，以产生流出物流，其包含至少含氧化合物，烯烃，水和酸性副产物; （b）通过间接热交换将反应流出物流冷却至大于流出物流的露点温度的温度; （c）通过将水性液体直接注入流出物流中，将流出物流进一步快速冷却至低于流出物流的露点温度的温度，以形成骤冷流出物流; 和（d）将骤冷流出物流送入淬火塔并在至少一组内部存在下使骤冷流出物流与第二含水液体接触，以产生包含该烯烃的骤冷塔气流。

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