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    • 32. 发明授权
    • Method for preparing a water-soluble polyamide
    • 水溶性聚酰胺的制备方法
    • US08541539B2
    • 2013-09-24
    • US12345171
    • 2008-12-29
    • Yu-Chi TsengChin-Wen ChenS-P Rwei
    • Yu-Chi TsengChin-Wen ChenS-P Rwei
    • C08G69/08
    • H01B1/24C08G69/36C08G69/42C08J3/212C08J3/226C08J2377/00C08J2477/00C08L77/06D01F1/09D01F6/80Y10T428/249921
    • A method for preparing a water-soluble polyamide, includes copolymerizing reactive monomers including caprolactam; ethylene glycol bis(2-aminoethyl)ether or ethylene glycol bis(3-aminopropyl)ether; and 5-sulfoisophthalic acid monosodium salt, wherein a molar ratio of caprolactam:ethylene glycol bis(2-aminoethyl)ether or ethylene glycol bis(3 -aminopropyl)ether:5-sulfoisophthalic acid monosodium salt is about 0:1:1 to about 5:1:1, advantageously about 1.85:1:1. Copolymerizing takes place at a copolymerization temperature of about 222-250° C. and a copolymerization pressure of about 3 Bar. The method further includes maintaining a temperature of about 222-250° C. for about 2-3 hours under normal pressure after the copolymerization step. The water-soluble polyamide has a solubility in water of about 10-70%.
    • 一种制备水溶性聚酰胺的方法,包括使包含己内酰胺的反应性单体共聚; 乙二醇双(2-氨基乙基)醚或乙二醇双(3-氨基丙基)醚; 和5-磺基间苯二甲酸单钠盐,其中己内酰胺:乙二醇双(2-氨基乙基)醚或乙二醇双(3-氨基丙基)醚:5-磺基间苯二甲酸一钠盐的摩尔比为约0:1:1至约 5:1:1,有利地约1.85:1:1。 共聚发生在约222-250℃的共聚温度和约3巴的共聚压力下进行。 该方法还包括在共聚步骤之后在常压下保持约222-250℃的温度约2-3小时。 水溶性聚酰胺在水中的溶解度为约10-70%。
    • 33. 发明申请
    • Polyamide Resin
    • 聚酰胺树脂
    • US20130046074A1
    • 2013-02-21
    • US13695205
    • 2011-04-27
    • Shuichi MaedaTomoyuki Nakagawa
    • Shuichi MaedaTomoyuki Nakagawa
    • C08G69/26
    • C08G69/265C08G69/36C08L77/06
    • This is to provide a polyamide resin which can sufficiently ensure all of a relative viscosity ηr (high degree of polymerization), moldable temperature range estimated from a temperature difference (Td−Tm), heat resistance estimated from a melting point Tm, melt moldability estimated from a temperature difference (Tm−Tc), and low water absorbability as compared with the conventional polyoxamide resin.This is a polyamide resin comprising a dicarboxylic acid-derived unit and a diamine-derived unit being bonded, wherein the above-mentioned dicarboxylic acid contains oxalic acid (Compound A), and the above-mentioned diamine contains 1,6-hexanediamine (Compound B) and 2-methyl-1,5-pentanediamine (Compound C).
    • 这是提供一种聚酰胺树脂,其可以充分确保所有的相对粘度和聚合度(高聚合度),从温差(Td-Tm)估计的可成型温度范围,从熔点Tm估计的耐热性,熔融 与常规聚酰胺树脂相比,由温差(Tm-Tc)估计的成型性和低吸水性。 这是包含二羧酸衍生单元和二胺衍生单元键合的聚酰胺树脂,其中上述二羧酸含有草酸(化合物A),上述二胺含有1,6-己二胺(化合物 B)和2-甲基-1,5-戊二胺(化合物C)。
    • 37. 发明授权
    • Polyamide molding compound and its use for producing transparent, hot-steam-sterilizable molded parts and extrudates
    • 聚酰胺模塑料及其用于生产透明,热蒸汽灭菌的模制零件和挤出物的用途
    • US08044171B2
    • 2011-10-25
    • US12162981
    • 2006-01-31
    • Friedrich Severin BuhlerRalf Hala
    • Friedrich Severin BuhlerRalf Hala
    • C08G69/26
    • C08G69/36C08G69/265C08L77/00C08L77/02C08L77/06C08L2205/02C08L2666/20
    • The invention relates to a polyamide molding material or copolyamide molding material and the use of such a polyamide molding material or copolyamide molding material for producing steam-sterilizable transparent moldings and extrudates. This polyamide molding material is characterized in that it comprises at least one copolyamide formed from 35-42 mol % of bis(4-amino-3-methylcyclohexyl)methane (MACM), 35-42 mol % of isophthalic acid (IPS) and 16-30 mol % of laurolactam (LC12). MACM may be replaced up to 50% by bis(4-aminocyclohexyl)-methane (PACM) and IPA up to 50% by terephthalic acid (TPA). The polyamide molding material may also be a blend of copolyamides or a blend of copolyamides with polyamide 12. The relative viscosity (RV) of the polyamide molding material or copolyamide molding material is in any case adjusted to a value which is greater than 1.45. Steam-sterilizable and transparent standard specimens which are produced from such polyamide molding materials or copolyamide molding materials and whose composition corresponds to the transparent moldings and extrudates have a tensile strain at break which, after undergoing at least 140 and especially preferably at least 350 steam sterilization cycles, is above the stretching limit.
    • 本发明涉及一种聚酰胺成型材料或共聚酰胺成型材料以及这种聚酰胺成型材料或共聚酰胺模塑材料用于生产蒸汽灭菌透明模制品和挤出物的用途。 该聚酰胺成型材料的特征在于它包含至少一种由35-42mol%的双(4-氨基-3-甲基环己基)甲烷(MACM),35-42mol%间苯二甲酸(IPS)和16 -30摩尔%的月桂内酰胺(LC12)。 通过双(4-氨基环己基) - 甲烷(PACM)和MACA可以通过对苯二甲酸(TPA)将高达50%的MACM替代为高达50%。 聚酰胺成型材料也可以是共聚酰胺或共聚酰胺与聚酰胺12的共混物的混合物。聚酰胺成型材料或共聚酰胺模塑材料的相对粘度(RV)在任何情况下调整到大于1.45的值。 由这种聚酰胺成型材料或共聚酰胺模塑材料生产的蒸汽灭菌和透明的标准样品,其组成对应于透明模制品和挤出物具有断裂拉伸应变,在经历至少140次,特别优选至少350次蒸汽灭菌 循环,高于拉伸极限。
    • 39. 发明申请
    • POLYAMIDE RESIN, COMPOSITION CONTAINING THE POLYAMIDE RESIN, AND MOLDED ARTICLES OF THE POLYAMIDE RESIN AND THE COMPOSITION
    • 聚酰胺树脂,含有聚酰胺树脂的组合物和聚酰胺树脂和组合物的成型品
    • US20110105683A1
    • 2011-05-05
    • US13001791
    • 2009-06-29
    • Koya KatoMasaru AkitaHideo Matsuoka
    • Koya KatoMasaru AkitaHideo Matsuoka
    • C08G69/26C08L77/06
    • C08G69/265C08G69/36C08K7/28C08L77/06
    • Disclosed is a polyamide resin which is produced by the polycondensation of (A) pentamethylenediamin, (B) terephthalic acid and/or a derivative thereof, and (C) at least one member selected from adipic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, isophthalic acid, 1,9-diaminononane, 1,10-diaminodecane, 1,12-diaminododecane, caprolactam, undecalactam, laurolactam, aminocaproic acid, 11-aminoundecanoic acid, 12-aminododecanoic acid, and derivatives of these compounds. In the polyamide resin, the ratio of a repeating unit derived from the component (C) is 10 to 50 wt % (inclusive) relative to the total weight of the polymer. A solution of the polyamide resin in 98% sulfuric acid, which contains the polyamide resin at a concentration of 0.01 g/ml, has a relative viscosity of 1.5 to 4.5 at 25° C.
    • 公开了通过(A)五亚甲基二胺,(B)对苯二甲酸和/或其衍生物的缩聚制备的聚酰胺树脂,(C)选自己二酸,癸二酸,十一烷二酸,十二烷二酸 间苯二甲酸,1,9-二氨基壬烷,1,10-二氨基十二烷,1,12-二氨基十二烷,己内酰胺,十一内酰胺,月桂内酰胺,氨基己酸,11-氨基十一烷酸,12-氨基十二烷酸和这些化合物的衍生物。 在聚酰胺树脂中,衍生自(C)成分的重复单元的比例相对于聚合物的总重量为10〜50重量%(以下)。 聚酰胺树脂在含有浓度为0.01g / ml的聚酰胺树脂的98%硫酸中的溶液在25℃下的相对粘度为1.5〜4.5。