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31. 发明授权

US5304524A Asymmetric hydrogenation of aromatic-substituted olefins using organoruthenium catalyst 失效
标题翻译：使用有机钌催化剂对芳族取代烯烃进行不对称氢化
公开(公告)号：US5304524A
公开(公告)日：1994-04-19
申请号：US958525
申请日：1992-10-08
申请人： W. Dirk Klobucar , Charles H. Kolich , Thanikavelu Manimaran , Tse-Chong Wu
发明人： W. Dirk Klobucar , Charles H. Kolich , Thanikavelu Manimaran , Tse-Chong Wu
IPC分类号： B01J31/22 , B01J31/24 , B01J31/00
CPC分类号： B01J31/2295 , B01J31/2234 , B01J31/24 , B01J31/2452 , B01J2231/645 , B01J2531/0266 , B01J2531/821 , B01J31/0235 , B01J31/30
摘要： A process for the asymmetric reduction of carboxylic acids of the formula ##STR1## or the amine salts thereof, where R and R.sub.1 are the same or different and are hydrogen, alkyl, cycloalkyl or haloalkyl and Ar is aryl or substituted aryl is disclosed.
摘要翻译：公开了用于不对称还原式IMA的羧酸或其胺盐的方法，其中R和R 1相同或不同，并且是氢，烷基，环烷基或卤代烷基，Ar是芳基或取代的芳基。

32. 发明授权

US5006324A Polymerization of phosphonitrilic chloride 失效
标题翻译：磷酰氯的聚合
公开(公告)号：US5006324A
公开(公告)日：1991-04-09
申请号：US569611
申请日：1984-01-10
申请人： Charles H. Kolich , Bernard R. Meltsner , Henry G. Braxton, Jr.
发明人： Charles H. Kolich , Bernard R. Meltsner , Henry G. Braxton, Jr.
IPC分类号： C01B21/098
CPC分类号： C01B21/0986
摘要： High molecular weight phosphonitrillic chloride polymers that are soluble in benzene, toluene and tetrahydrofuran, tetrameric phosphonitrilic chloride, or mixtures thereof at elevated temperatures in the presence of a catalytic amount of an aprotic Lewis acid halogen acceptor. For example, soluble high molecular weight phosphonitrillic chloride can be made by heating the aforementioned trimer at 220.degree.-270.degree. C. in the presence of 5-1000 ppm of AlCl.sub.3.
摘要翻译：在催化量的非质子路易斯酸卤素受体存在下，在升高的温度下可溶于苯，甲苯和四氢呋喃，四聚磷酸二氯化物或其混合物的高分子量膦酰氯化物聚合物。例如，可溶性高分子量的草腈氯化物可以通过在5-1000ppm AlCl 3存在下，在220-270℃下加热上述三聚体来制备。

33. 发明授权

US08071688B2 Brominated anionic styrenic polymers and their preparation 有权
标题翻译：溴化阴离子苯乙烯聚合物及其制备
公开(公告)号：US08071688B2
公开(公告)日：2011-12-06
申请号：US12636250
申请日：2009-12-11
申请人： Charles H. Kolich , John F. Balhoff , Martin B. Berdon , Ronny W. Lin
发明人： Charles H. Kolich , John F. Balhoff , Martin B. Berdon , Ronny W. Lin
IPC分类号： C08F12/08
CPC分类号： C08F8/20 , C08F8/22 , C08F12/00 , C08F12/08
摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.
摘要翻译：同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。这些组件至少有两个单独的进料流。进料成比例以维持（a）基于所加入的聚合物中芳族单体单元的量，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。

34. 发明授权

US07638583B2 Brominated anionic styrenic polymers and their preparation 有权
标题翻译：溴化阴离子苯乙烯聚合物及其制备
公开(公告)号：US07638583B2
公开(公告)日：2009-12-29
申请号：US11612991
申请日：2006-12-19
申请人： Charles H. Kolich , John F. Balhoff , Martin B. Berdon , Ronny W. Lin
发明人： Charles H. Kolich , John F. Balhoff , Martin B. Berdon , Ronny W. Lin
IPC分类号： C08F12/08
CPC分类号： C08F8/20 , C08F8/22 , C08F12/00 , C08F12/08
摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.
摘要翻译：同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。这些组件至少有两个单独的进料流。进料成比例以维持（a）以所加入的聚合物中的芳族单体单元的量为基准，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。

35. 发明授权

US07632893B2 Brominated styrenic polymers and their preparation 有权
标题翻译：溴化苯乙烯聚合物及其制备方法
公开(公告)号：US07632893B2
公开(公告)日：2009-12-15
申请号：US11453542
申请日：2006-06-14
申请人： Charles H. Kolich , Jeffrey Todd Aplin , John F. Balhoff
发明人： Charles H. Kolich , Jeffrey Todd Aplin , John F. Balhoff
IPC分类号： C08F12/08
CPC分类号： C08F8/20 , C08F8/22 , C08F12/08 , C08F12/16 , C08F12/00 , C08F4/48
摘要： Preparing brominated styrenic polymer by maintaining a mixture formed from (i) brominating agent, (ii) a solvent solution of styrenic polymer, and (iii) aluminum halide catalyst, at −20 to +20° C., and terminating bromination in 20 minutes or less. New brominated anionic styrenic polymers have better melt flow and/or lower initial ΔE values than the best previously-known brominated anionic styrenic polymers. Other features of such new polymers include high thermal stabilities at 320° C. and/or very low initial color values. Brominated styrenic polymers, especially brominated anionic styrenic polymers, are useful as flame retardants for thermoplastic polymers.
摘要翻译：通过保持由（i）溴化剂，（ii）苯乙烯聚合物的溶剂溶液和（iii）卤化铝催化剂）在-20至+ 20℃形成的混合物，并在20分钟内终止溴化，制备溴化苯乙烯聚合物或更少。新的溴化阴离子苯乙烯聚合物具有比先前已知的溴代阴离子苯乙烯聚合物更好的熔体流动和/或较低的初始DeltaE值。这种新聚合物的其它特征包括在320℃下的高热稳定性和/或非常低的初始颜色值。溴化苯乙烯聚合物，特别是溴化阴离子苯乙烯聚合物，可用作热塑性聚合物的阻燃剂。

36. 发明申请

US20080167427A1 Brominated Styrenic Polymer Compositions and Processes For Producing Same 审中-公开
标题翻译：溴化苯乙烯聚合物组合物和生产方法
公开(公告)号：US20080167427A1
公开(公告)日：2008-07-10
申请号：US11971149
申请日：2008-01-08
申请人： Ronny W. Lin , Charles H. Kolich , Douglas W. Luther
发明人： Ronny W. Lin , Charles H. Kolich , Douglas W. Luther
IPC分类号： C08L27/00
CPC分类号： C08L25/04 , C08F8/20 , C08L25/06 , C08L2205/02 , C08F12/08 , C08L2666/04
摘要： This invention provides a multimodal brominated anionic styrenic polymer composition. The composition is comprised of at least two brominated anionic styrenic polymer weight fractions which have different weight average molecular weights. Also provided by this invention are processes for producing multimodal brominated anionic styrenic polymer compositions.
摘要翻译：本发明提供了一种多峰溴化阴离子苯乙烯聚合物组合物。该组合物由至少两种具有不同重均分子量的溴化阴离子苯乙烯类聚合物重量组分组成。本发明还提供了制备多峰溴化阴离子苯乙烯聚合物组合物的方法。

37. 发明申请

US20080164445A1 Brominated Styrenic Polymer Compositions and Processes For Producing Same 审中-公开
标题翻译：溴化苯乙烯聚合物组合物和生产方法
公开(公告)号：US20080164445A1
公开(公告)日：2008-07-10
申请号：US11971124
申请日：2008-01-08
申请人： Ronny W. Lin , Charles H. Kolich , Douglas W. Luther
发明人： Ronny W. Lin , Charles H. Kolich , Douglas W. Luther
IPC分类号： C09K21/14 , C08F14/16
CPC分类号： C08L25/06 , C08F8/20 , C08L25/18 , C08L2205/02 , C08F12/08 , C08L2666/04
摘要： This invention provides a multimodal brominated styrenic polymer composition. The composition is comprised of at least one brominated anionic styrenic polymer and at least one brominated non-anionic styrenic polymer. Also provided by this invention are processes for producing multimodal brominated styrenic polymer compositions.
摘要翻译：本发明提供了一种多峰溴化苯乙烯聚合物组合物。该组合物由至少一种溴化阴离子苯乙烯聚合物和至少一种溴化非阴离子苯乙烯聚合物组成。本发明还提供了制备多峰溴化苯乙烯聚合物组合物的方法。

38. 发明授权

US5883297A Preparation and recovery of N-hydrocarbylthiophosphoric triamides or N-hydrocarbylphosphoric triamides 失效
标题翻译： N-烃基硫代磷酸三酰胺或N-烃基磷酸三酰胺的制备和回收
公开(公告)号：US5883297A
公开(公告)日：1999-03-16
申请号：US58367
申请日：1998-04-09
申请人： Gerald M. Sulzer , Chi Hung Cheng , W. Dirk Klobucar , Charles H. Kolich
发明人： Gerald M. Sulzer , Chi Hung Cheng , W. Dirk Klobucar , Charles H. Kolich
IPC分类号： C01C1/16 , C07F9/02 , C07F9/22 , C07F9/26
CPC分类号： C01C1/164 , C07F9/025 , C07F9/224 , C07F9/26
摘要： A reaction mixture containing N-hydrocarbylthiophosphoric triamide or N-hydrocarbylphosphoric triamide ("Triamide") is formed by reacting ammonia with N-hydrocarbylaminothiophosphoryl dichloride or N-hydrocarbylaminophosphoryl dichloride in a liquid organic medium, in proportions of at least 16 moles of ammonia per mole of such dichloride and that keep in solution the ammonium chloride co-product formed in the reaction. The temperature of the reaction mixture is kept high enough to keep ammonium chloride-ammonia complex from forming a solid phase in the reaction mixture, but low enough to avoid significant reduction in Triamide yield. The reaction mixture is then caused/allowed to separate into an inorganic phase comprising ammonia, ammonium chloride and co-product thiophosphoric triamide or phosphoric triamide, and an organic phase comprising Triamide, liquid organic medium, dissolved ammonia and, usually, phosphorus impurities. These phases are separated from each other. The ammonia is removed from the organic phase to leave a concentrated solution of Triamide in residual liquid organic medium usually also containing phosphorus impurities. The Triamide is separated or recovered from this residual mixture by continuously introducing a stream of the liquid mixture into a wiped film evaporator operating at a temperature of about 60.degree.-140.degree. C., and at a pressure that avoids solids formation on the heating surface of the wiped film evaporator, and continuously collecting the Triamide product. Triamides are urease inhibitors for use with urea-based fertilizers.
摘要翻译：通过使氨与N-烃基氨基硫代磷酰基二氯化物或N-烃基氨基磷酰基二氯化物在液体有机介质中反应，按每摩尔至少16摩尔氨的比例形成含有N-烃基硫代磷酰三胺或N-烃基磷酸三酰胺（“三酰胺”）的反应混合物的这种二氯化物，并保持溶液中形成的氯化铵副产物在反应中。反应混合物的温度保持足够高以保持氯化铵 - 氨络合物在反应混合物中形成固相，但足够低以避免三酰胺产率的显着降低。然后使反应混合物分离成包含氨，氯化铵和副产物硫代磷酸三酰胺或磷酸三酰胺的无机相，以及包含三酰胺，液体有机介质，溶解氨和通常为磷杂质的有机相。这些阶段相互分离。从有机相中除去氨，留下通常也含有磷杂质的残留液体有机介质中的三酰胺浓缩溶液。通过将液体混合物流连续地引入到在约60-140℃的温度下操作的擦拭膜蒸发器中并且在避免在加热表面上形成固体的压力下将三酰胺分离或回收的擦拭膜蒸发器，并连续收集三酰胺产物。三酰胺是用于尿素肥料的尿素酶抑制剂。

39. 发明授权

US5852132A Process for brominating polystyrenic resins 失效
标题翻译：溴化聚苯乙烯树脂的工艺
公开(公告)号：US5852132A
公开(公告)日：1998-12-22
申请号：US872985
申请日：1997-06-11
申请人： Billie B. Dadgar , Donald E. Balhoff , Charles H. Kolich , Meng-Sheng Ao , Homer C. Lin
发明人： Billie B. Dadgar , Donald E. Balhoff , Charles H. Kolich , Meng-Sheng Ao , Homer C. Lin
IPC分类号： C08F8/22
CPC分类号： C08F8/22
摘要： This invention features a process for brominating styrenic polymers, which process comprises forming a reaction mass by feeding a mixture, (i) which is substantially free of a bromination catalyst and (ii) which is formed from at least brominating agent and a styrenic polymer, to a catalytic quantity of a bromination catalyst.
摘要翻译：本发明的特征在于溴化苯乙烯聚合物的方法，该方法包括通过加入混合物形成反应物质，（i）其基本上不含溴化催化剂，和（ii）由至少溴化剂和苯乙烯聚合物形成，至催化量的溴化催化剂。

40. 发明授权

US5677390A Process for brominating polystyrenic resins 失效
标题翻译：溴化聚苯乙烯树脂的工艺
公开(公告)号：US5677390A
公开(公告)日：1997-10-14
申请号：US727341
申请日：1996-10-26
申请人： Billie B. Dadgar , Donald E. Balhoff , Charles H. Kolich , Meng-Sheng Ao , Homer C. Lin
发明人： Billie B. Dadgar , Donald E. Balhoff , Charles H. Kolich , Meng-Sheng Ao , Homer C. Lin
IPC分类号： C08F8/22
CPC分类号： C08F8/22
摘要： This invention features a process for brominating styrenic polymers, which process comprises forming a reaction mass by feeding a mixture, (i) which is substantially free of a bromination catalyst and (ii) which is formed from at least brominating agent and a styrenic polymer, to a catalytic quantity of a bromination catalyst.
摘要翻译：本发明的特征在于溴化苯乙烯聚合物的方法，该方法包括通过加入混合物形成反应物质，（i）其基本上不含溴化催化剂，和（ii）由至少溴化剂和苯乙烯聚合物形成，至催化量的溴化催化剂。

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