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31. 发明授权

US4826988A Substituted furazan pesticides 失效
标题翻译：取代呋咱农药
公开(公告)号：US4826988A
公开(公告)日：1989-05-02
申请号：US43661
申请日：1987-04-28
申请人： Wilhelm Sirrenberg , Erich Klauke , Gerhard Zoebelein , Benedikt Becker , Wilhelm Stendel
发明人： Wilhelm Sirrenberg , Erich Klauke , Gerhard Zoebelein , Benedikt Becker , Wilhelm Stendel
IPC分类号： A01N47/36 , C07D271/08 , C07D319/00 , C07D413/12 , C07D521/00 , H05B6/64 , C07D413/04
CPC分类号： C07D521/00 , A01N47/36 , C07D271/08 , C07D413/12 , H05B6/6408
摘要： Substituted furazans of the formula ##STR1## in which R and R.sup.1 are identical or different and represent optionally substituted aromatic or heteroaromatic radicals,R.sup.2 represents hydrogen, an OH or COOH grouping or an optionally substituted radical from the series comprising alkyl, alkoxy, cycloalkyl, cycloalkenyl, alkoxycarbonyl, alkoxythiocarbonyl, alkylsulphonyl, arylsulphonyl and aralkyl,Y represents oxygen or an S(O).sub.m, --CR.sup.3 R.sup.4, CO or NR.sup.5 grouping,in whichm represents the number 0, 1 or 2 andR.sup.3, R.sup.4 and R.sup.5 are identical or different andrepresent hydrogen or alkyl,n represents the number 0 or 1 andx represents oxygen or sulphur,and wherein, ifR represents phenyl,R.sup.1 represents phenyl,R.sup.2 represents hydrogen andx represents oxygen or sulphur,thenn represents the number 1,or ifn represents the number 0,R represents 4-bromophenyl,R.sup.1 represents 4-chlorophenyl andR.sup.2 represents hydrogen,thenX represents sulphur, which possess pesticidal activity.
摘要翻译： R 1和R 1相同或不同且代表任意取代的芳族或杂芳族基团的取代呋喃酮，其中R 1表示氢，OH或COOH基团或任选取代的包含烷基，烷氧基，环烷基，环烷基，烷氧基羰基，烷氧基硫代羰基，烷基磺酰基，芳基磺酰基和芳烷基，Y代表氧或S（O）m，-CR3R4，CO或NR5基团，其中m代表数字0,1或2，且R3，R4和R5相同或不同，表示氢或烷基，n表示数字0或1，x表示氧或硫，并且其中，如果R表示苯基，则R1表示苯基，R2表示氢，x表示氧或硫，则n表示数字1 ，或者如果n表示数字0，则R表示4-溴苯基，R 1表示4-氯苯基，R 2表示氢，则X表示具有杀虫活性的硫。

32. 发明授权

US4774260A Novel benzoylurea pesticides 失效
标题翻译：新型苯甲酰脲农药
公开(公告)号：US4774260A
公开(公告)日：1988-09-27
申请号：US843449
申请日：1986-03-24
申请人： Wilhelm Sirrenberg , Erich Klauke , Benedikt Becker , Ingomar Krehan , Wilhelm Stendel
发明人： Wilhelm Sirrenberg , Erich Klauke , Benedikt Becker , Ingomar Krehan , Wilhelm Stendel
IPC分类号： A01N47/34 , C07C275/54 , C07C323/20 , C07C335/26 , C07C157/12 , C07C127/22
CPC分类号： C07C275/54 , A01N47/34 , C07C323/20 , C07C335/26
摘要： 1-Phenyl-3-benzoyl-(thio)ureas of the formula ##STR1## in which X represents oxygen or sulphur,R.sup.1 represents hydrogen, halogen, nitro, alkyl or alkylthio,R.sup.2, R.sup.4 and R.sup.5 are identical or different and represent hydrogen or halogen,R.sup.3 represents hydrogen, halogen or nitro,R.sup.6 and R.sup.7 are identical or different and represent hydrogen, halogen or alkyl,R.sup.8 and R.sup.9 are identical or different and represent hydrogen or halogen andR.sup.10 represents halogenoalkylthio or halogenoalkoxy,with certain exclusions, which possess insecticidal and acaricidal activity.
摘要翻译：其中X表示氧或硫，R1表示氢，卤素，硝基，烷基或烷硫基，R2，R4和R5相同或不同的式（I）的1-苯基-3-苯甲酰基 - （硫代）脲并且表示氢或卤素，R 3表示氢，卤素或硝基，R 6和R 7相同或不同，表示氢，卤素或烷基，R 8和R 9相同或不同，表示氢或卤素，R 10表示卤代烷硫基或卤代烷氧基，排除，具有杀虫和杀螨活性。

33. 发明授权

US4853397A Substituted furazans and insecticidal and acaricidal use 失效
标题翻译：取代的呋沙坦和杀虫剂和杀螨剂使用
公开(公告)号：US4853397A
公开(公告)日：1989-08-01
申请号：US66920
申请日：1987-06-25
申请人： Wilhelm Sirrenberg , Albrecht Marhold , Robert Steffens
发明人： Wilhelm Sirrenberg , Albrecht Marhold , Robert Steffens
IPC分类号： A01N47/36 , C07C23/18 , C07C205/11 , C07C265/12 , C07C331/28 , C07D271/08
CPC分类号： C07C265/12 , A01N47/36 , C07C205/11 , C07C331/28 , C07D271/08
摘要： Insecticidal and acaricidal novel substituted furazans of the formula ##STR1## n which R.sup.1 and R.sup.2 are identical or different and represent hydrogen, halogen, alkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio or optionally substituted aryloxy, orR.sup.1 and R.sup.2 together represent an optionally substituted alkylene radical which is interrupted by 1 or 2 oxygen atoms or is bonded to the phenyl radical via 1 or 2 oxygen atoms,R.sup.3 and R.sup.4 are identical or different and represent hydrogen, halogen, alkyl, alkoxy, halogenoalkyl or halogenoalkoxy,R.sup.5 represents optionally substituted cycloalkyl, andX represents oxygen or sulphur.Intermediates of the formula ##STR2## in which B is --NH.sub.2, --NO.sub.2 or --NCX,R.sup.3 and R.sup.4 are identical or different and represent hydrogen, halogen, alkyl, alkoxy, halogenoalkyl or halogenoalkoxy,R.sup.6 represents 2,2-difluoro-1-methylcycloprop-1-yl or the ##STR3## radical, Y represents hydrogen, methyl, fluorine or chlorine, andY.sup.1 and Y.sup.2 are identical or different and represent fluorine or chlorine,are also new.
摘要翻译： R1和R2相同或不同并代表氢，卤素，烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基或任选取代的芳氧基的式（Ⅰ）的杀虫和杀螨新型取代呋拉辛，或者R1和R2一起代表被1或2个氧原子间隔或通过1或2个氧原子与苯基键合的任选取代的亚烷基，R3和R4相同或不同，代表氢，卤素，烷基，烷氧基，卤代烷基或卤代烷氧基，R5代表任选取代的环烷基，X表示氧或硫。其中B是-NH 2，-NO 2或-NCX，R 3和R 4的式“IMAGE”中间体是相同或不同的，代表氢，卤素，烷基，烷氧基，卤代烷基或卤代烷氧基，R6代表2,2-二氟-1 - 甲基环丙-1-基或基，Y代表氢，甲基，氟或氯，Y1和Y2相同或不同，代表氟或氯，也是新的。

34. 发明授权

US4764524A Novel substituted furazane 失效
标题翻译：新型取代呋咱
公开(公告)号：US4764524A
公开(公告)日：1988-08-16
申请号：US816933
申请日：1986-01-08
申请人： Wilhelm Sirrenberg , Rudolph Braden , Heinz Ziemann , Gerhard Zoebelein , Wolfgang Pfluger
发明人： Wilhelm Sirrenberg , Rudolph Braden , Heinz Ziemann , Gerhard Zoebelein , Wolfgang Pfluger
IPC分类号： A01N47/36 , C07D271/08 , C07D317/00 , C07D405/04 , C07D413/04
CPC分类号： C07D413/04 , C07D271/08
摘要： Insecticidally and acaricidally active novel substituted furazanes of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is hydrogen, halogen, alkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio or optionally substituted aryloxy, orR.sup.1 and R.sup.2 together are an optionally substituted alkylene radical which is interrupted by 1 or 2 oxygen atoms,R.sup.3 and R.sup.4 each independently is hydrogen, alkyl, alkoxy, halogenoalkyl or halogenoalkoxy, andX is oxygen or sulphur.
摘要翻译：其中R1和R2各自独立地为氢，卤素，烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基或任选取代的芳氧基，或者R1和R2一起是任选取代的杀虫剂和杀螨活性的新型取代的呋喃被1或2个氧原子中断的亚烷基，R3和R4各自独立地是氢，烷基，烷氧基，卤代烷基或卤代烷氧基，X是氧或硫。

35. 发明授权

US4613612A Benzoylureas 失效
标题翻译：苯甲酰脲
公开(公告)号：US4613612A
公开(公告)日：1986-09-23
申请号：US763745
申请日：1985-08-08
申请人： Wilhelm Sirrenberg , Albrecht Marhold , Benedikt Becker
发明人： Wilhelm Sirrenberg , Albrecht Marhold , Benedikt Becker
IPC分类号： A01N47/34 , C07D319/12 , C07D319/20 , A01N43/32
CPC分类号： C07D319/20 , A01N47/34
摘要： Insecticidally and acaricidally active novel compounds of the formula ##STR1## in which A is --CF.sub.2 --CF.sub.2 --, --CF.sub.2 --CHF-- or --CF.sub.2 --CFCl--,X is oxygen or sulphur,R.sup.1, R.sup.2 and R.sup.3 each independently is hydrogen, halogen or alkyl,R.sup.4 and R.sup.5 each independently is hydrogen, halogen, alkyl or halogenoalkyl, andR.sup.6 is hydrogen, halogen or alkyl.The benzodioxene intermediates therefor are also new.
摘要翻译：其中A为-CF 2 -CF 2 - ， - CF2-CHF-或-CF 2 -CFCl-，X为氧或硫，R1，R2和R3各自独立地为农药和杀螨活性的新颖化合物，卤素或烷基，R 4和R 5各自独立地是氢，卤素，烷基或卤代烷基，R 6是氢，卤素或烷基。苯并二恶烯中间体也是新的。

36. 发明授权

US4225618A Combating plant pests with N-(.omega.-chloro-alkanoyl)-N'-trifluoromethylphenyl-ureas 失效
标题翻译：将植物害虫与N-（ω-氯 - 烷酰基）-N'-三氟甲基苯基脲反应
公开(公告)号：US4225618A
公开(公告)日：1980-09-30
申请号：US010289
申请日：1979-02-08
申请人： Wilhelm Sirrenberg , Erich Klauke , Wilhelm Brandes , Peter Roessler
发明人： Wilhelm Sirrenberg , Erich Klauke , Wilhelm Brandes , Peter Roessler
IPC分类号： A01N47/34 , C07C275/50 , A01N47/28 , C07C127/00
CPC分类号： A01N47/34 , C07C275/50
摘要： N-(.omega.-chloroalkanoyl)-N'-trifluoromethylphenyl-ureas of the formula ##STR1## in which n is 1 or 2, andR is halogenoalkyl or halogen, and can also be hydrogen when n is 2,which possess arthropodicidal and fungicidal properties.
摘要翻译：其中n为1或2，并且R为卤代烷基或卤素的式“IMAGE”的N-（ω-氯代烷酰基）-N'-三氟甲基苯基脲，n为2时也可为氢，其具有杀节细菌和杀真菌剂属性。

37. 发明授权

US4123478A Preparation of O, O-dimethyl-O-(2,2-dichlorovinyl)-thionophosphoric acid ester 失效
标题翻译：制备O，O-二甲基-O-（2,2-二氯乙烯基） - 硫代磷酸酯
公开(公告)号：US4123478A
公开(公告)日：1978-10-31
申请号：US820500
申请日：1977-07-29
申请人： Reimer Colln , Wilhelm Sirrenberg
发明人： Reimer Colln , Wilhelm Sirrenberg
IPC分类号： C07F9/173 , C07F9/165
CPC分类号： C07F9/173
摘要： A process for the preparation of O,O-dimethyl-O-(2,2-dichlorovinyl)-thionophosphoric acid ester of the formula ##STR1## comprising reacting O,O-dimethyl-1-hydroxy-2,2,2-trichloroethane-thionophosphonic acid ester of the formula ##STR2## in isopropanol with a 30-50% aqueous solution of an alkali metal hydroxide, possibly present in a small molar excess.
摘要翻译：制备式（I）的O，O-二甲基-O-（2,2-二氯乙烯基） - 硫代磷酸酯的方法，包括使O，O-二甲基-1-羟基-2,2，具有式（IMAGE）（II）的2-三氯乙烷 - 硫代磷酸酯在异丙醇中与30-50％的碱金属氢氧化物水溶液，可能以小摩尔过量存在。

38. 发明授权

US4886823A Furazanylurea acaricides 失效
标题翻译：呋喃基脲类杀螨剂
公开(公告)号：US4886823A
公开(公告)日：1989-12-12
申请号：US269263
申请日：1988-11-09
申请人： Wilhelm Sirrenberg , Albrecht Marhold , Ulrike Wachendorff-Neumann
发明人： Wilhelm Sirrenberg , Albrecht Marhold , Ulrike Wachendorff-Neumann
IPC分类号： C07C331/28 , A01N47/36 , C07C67/00 , C07C241/00 , C07C265/12 , C07C325/00 , C07C331/30 , C07D271/08 , C07D413/04
CPC分类号： C07D413/04 , A01N47/36 , C07C265/12 , C07C331/30 , C07D271/08
摘要： Acaricidal 1-arylfurazanyl-3-(2-alkyl-4-halogenoalkoxyphenyl)-(thio)ureas of the formula ##STR1## in which Q stands for oxygen or sulphur,R.sup.1 stands for hydrogen, halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, alkylthio or halogenoalkylthio, andR.sup.2 stands for hydrogen, halogen, alkyl or alkoxy, orR.sup.1 and R.sup.2 together stand for alkylenedioxy which is optionally substituted by halogen,R.sup.3 stands for alkyl andR.sup.4 stands for alkyl which is substituted by fluorine and optionally in addition by chlorine and/or bromine.The corresponding isocyanates of the formula ##STR2## are also new.
摘要翻译：其中Q代表氧或硫的式（I）的吖啶-1-芳基呋喃基-3-（2-烷基-4-卤代烷氧基苯基） - （硫代）脲，R1代表氢，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基或卤代烷硫基，R2代表氢，卤素，烷基或烷氧基，或R1和R2一起代表烷基二氧基，任选被卤素取代，R3代表烷基，R4代表被氟取代的烷基，任选地还有氯和/或溴。相应的式（IMAGE）（III）的异氰酸酯也是新的。

39. 发明授权

US5405858A Furazanylureas 失效
标题翻译：呋喃菌尿脲
公开(公告)号：US5405858A
公开(公告)日：1995-04-11
申请号：US28857
申请日：1993-03-10
申请人： Wilhelm Sirrenberg , Reinhard Lantzsch , Albrecht Marhold , Ulrike Wachendorff-Neumann , Alfred Elbert
发明人： Wilhelm Sirrenberg , Reinhard Lantzsch , Albrecht Marhold , Ulrike Wachendorff-Neumann , Alfred Elbert
IPC分类号： A01N47/36 , C07C217/90 , C07D271/08
CPC分类号： A01N47/36 , C07C217/90 , C07D271/08
摘要： The invention relates to the new furazanylureas of the general formula (I) ##STR1## in which R.sup.1 represents hydrogen or fluorine,R.sup.2 represents hydrogen, fluorine or chlorine,R.sup.3 represents hydrogen, fluorine or chlorine andR.sup.4 represents phenyl which is substituted by trifluoromethyl and additionally monosubstituted to tetrasubstituted by fluorine and/or chlorine, and, in the event that R.sup.1 represents fluorine and/or R.sup.2 and/or R.sup.3 represent fluorine or chlorine, R.sup.4 furthermore also represents difluoromethyl, trifluoromethyl, chlorodifluoromethyl, trifluoroethyl, tetrafluoroethyl, chlorotrifluoroethyl, hexafluoropropyl, hexafluoropropenyl or trifluoromethylphenyl,which can be used as pesticides.
摘要翻译：本发明涉及通式（I）的化合物，其中R 1表示氢或氟，R 2表示氢，氟或氯，R 3表示氢，氟或氯，R 4表示被取代的苯基。另外由氟和/或氯单取代至四取代，并且在R 1表示氟和/或R 2和/或R 3表示氟或氯的情况下，R 4还表示二氟甲基，三氟甲基，氯二氟甲基，三氟乙基，四氟乙基，氯三氟乙基，六氟丙基，六氟丙烯基或三氟甲基苯基，可用作农药。

40. 发明授权

US4757086A N-benzoyl-N'-(2,2,-difluoro-3-methyl-benzo-1,4-dioxanyl)-ureas 失效
标题翻译： N-苯甲酰基-N' - （2,2， - 二氟-3-甲基 - 苯并-1,4-二恶烷基） - 脲
公开(公告)号：US4757086A
公开(公告)日：1988-07-12
申请号：US762980
申请日：1985-08-06
申请人： Wilhelm Sirrenberg , Albrecht Marhold , Benedikt Becker
发明人： Wilhelm Sirrenberg , Albrecht Marhold , Benedikt Becker
IPC分类号： A01N47/34 , C07D319/20 , A61K31/335
CPC分类号： C07D319/20 , A01N47/34
摘要： Novel insecticidally and acaricidally active compounds of the formula ##STR1## in which R.sup.1 is halogen or alkyl,R.sup.2 is hydrogen, halogen or alkyl,R.sup.3 is hydrogen or methyl, andX is oxygen or sulphur.Several of the intermediates are also new.
摘要翻译： R1为卤素或烷基，R2为氢，卤素或烷基，R3为氢或甲基，X为氧或硫的新颖杀虫剂和杀螨活性化合物。几个中间体也是新的。

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