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31. 发明授权

US4358429A Oxygen stabilized zirconium vanadium intermetallic compound 失效
标题翻译：氧稳定锆钒金属间化合物
公开(公告)号：US4358429A
公开(公告)日：1982-11-09
申请号：US308966
申请日：1981-10-06
申请人： Marshall H. Mendelsohn , Dieter M. Gruen
发明人： Marshall H. Mendelsohn , Dieter M. Gruen
IPC分类号： B01J20/06 , C01B3/00 , C01B3/50 , C01G31/00 , B01D53/34 , C01G25/02 , C01G31/02
CPC分类号： C01B3/508 , C01B3/001 , C01B3/0031 , C01G31/00 , Y02C10/08 , Y02E60/327 , Y10S420/90
摘要： An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.
摘要翻译：具有式Zr x O v y的氧稳定化金属间化合物，其中x = 0.7至2.0和y = 0.18至0.33。该化合物能够在低至10 -6 Torr的压力下在-196℃至450℃的温度下可逆地吸附氢。该化合物还能够在CO和CO 2的存在下从气态混合物中选择性吸附氢。

32. 发明授权

US08257494B2 Self-composite comprised of nanocrystalline diamond and a non-diamond component useful for thermoelectric applications 失效
标题翻译：由纳米晶体金刚石和可用于热电应用的非金刚石组分组成的自复合材料
公开(公告)号：US08257494B2
公开(公告)日：2012-09-04
申请号：US12966347
申请日：2010-12-13
申请人： Dieter M. Gruen
发明人： Dieter M. Gruen
IPC分类号： C30B23/00 , C30B28/12
CPC分类号： H01L35/22
摘要： One provides nanocrystalline diamond material that comprises a plurality of substantially ordered diamond crystallites that are sized no larger than about 10 nanometers. One then disposes a non-diamond component within the nanocrystalline diamond material. By one approach this non-diamond component comprises an electrical conductor that is formed at the grain boundaries that separate the diamond crystallites from one another. The resultant nanowire is then able to exhibit a desired increase with respect to its ability to conduct electricity while also preserving the thermal conductivity behavior of the nanocrystalline diamond material.
摘要翻译：一种提供纳米晶体金刚石材料，其包括尺寸不大于约10纳米的多个基本上有序的金刚石微晶。然后将纳米晶体金刚石材料中的非金刚石部件配置在一起。通过一种方法，该非金刚石部件包括在晶界处形成的电导体，其将金刚石微晶彼此分离。然后，所得到的纳米线能够相对于其传导电能的能力表现出期望的增加，同时也保持了纳米晶体金刚石材料的导热性能。

33. 发明授权

US5097125A Photo ion spectrometer 失效
标题翻译：光离子光谱仪
公开(公告)号：US5097125A
公开(公告)日：1992-03-17
申请号：US45586
申请日：1987-05-04
申请人： Dieter M. Gruen , Charles E. Young , Michael J. Pellin
发明人： Dieter M. Gruen , Charles E. Young , Michael J. Pellin
IPC分类号： H01J49/06 , H01J49/14 , H01J49/16 , H01J49/28
CPC分类号： H01J49/061 , H01J49/142
摘要： A thin film structure for providing predetermined electric field boundary conditions. A thin film configuration is disposed on an insulator substrate in a selected spatial pattern with substantially uniform electrically resistive character in each of the different areas of the spatial pattern.
摘要翻译：一种用于提供预定电场边界条件的薄膜结构。薄膜结构以选定的空间图案设置在绝缘体基板上，在空间图案的不同区域的每个区域中具有基本均匀的电阻特性。

34. 发明授权

US4633084A High efficiency direct detection of ions from resonance ionization of sputtered atoms 失效
标题翻译：高效率直接检测溅射原子的共振电离离子
公开(公告)号：US4633084A
公开(公告)日：1986-12-30
申请号：US691825
申请日：1985-01-16
申请人： Dieter M. Gruen , Michael J. Pellin , Charles E. Young
发明人： Dieter M. Gruen , Michael J. Pellin , Charles E. Young
IPC分类号： H01J37/256 , H01J49/16 , G01N23/00
CPC分类号： H01J49/162 , H01J37/256 , H01J49/0463 , H01J49/142 , H01J2237/31749
摘要： A method and apparatus are provided for trace and other quantitative analysis with high efficiency of a component in a sample, with the analysis involving the removal by ion or other bombardment of a small quantity of ion and neutral atom groups from the sample, the conversion of selected neutral atom groups to photoions by laser initiated resonance ionization spectroscopy, the selective deflection of the photoions for separation from original ion group emanating from the sample, and the detection of the photoions as a measure of the quantity of the component. In some embodiments, the original ion group is accelerated prior to the RIS step for separation purposes. Noise and other interference are reduced by shielding the detector from primary and secondary ions and deflecting the photoions sufficiently to avoid the primary and secondary ions.
摘要翻译：提供了一种方法和装置，用于对样品中组分的高效率进行痕量和其他定量分析，分析涉及通过离子或其他轰击从样品中除去少量离子和中性原子团，转化为选择的中性原子团通过激光引发的共振电离光谱法进行光致变色，用于与从样品发出的原始离子基团分离的光离子的选择性偏转，以及作为组分量的量度的光电离检测。在一些实施方案中，在用于分离目的的RIS步骤之前加速原始离子组。通过将检测器与初级和次级离子屏蔽，并充分偏转光照以避免初级和次级离子，降低了噪声和其他干扰。

35. 发明授权

US4397834A Method of gettering hydrogen under conditions of low pressure 失效
标题翻译：在低压条件下吸氢的方法
公开(公告)号：US4397834A
公开(公告)日：1983-08-09
申请号：US337339
申请日：1982-01-06
申请人： Marshall H. Mendelsohn , Dieter M. Gruen
发明人： Marshall H. Mendelsohn , Dieter M. Gruen
IPC分类号： C01B3/00 , C22C16/00
CPC分类号： C01B3/0031 , Y02E60/327 , Y10S420/90
摘要： A ternary intermetallic compound having the formula Zr(V.sub.1-x Cr.sub.x).sub.2 where x is in the range of 0.01 to 0.90 is capable of reversibly sorbing hydrogen at temperatures ranging from room temperature to 200.degree. C., at pressures down to 10.sup.-6 Torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.
摘要翻译：具有式Zr（V1-xCrx）2的三元金属间化合物，其中x在0.01至0.90的范围内，能够在室温至200℃的温度范围内，在低至10 -6乇的压力下可逆地吸附氢。该化合物适合用作低压，高温应用中的氢吸气剂，如磁约束聚变装置。

36. 发明授权

US4292265A Method for preparing porous metal hydride compacts 失效
标题翻译：多孔金属氢化物压块的制备方法
公开(公告)号：US4292265A
公开(公告)日：1981-09-29
申请号：US113873
申请日：1980-01-21
申请人： Moshe Ron , Dieter M. Gruen , Marshall H. Mendelsohn , Irving Sheft
发明人： Moshe Ron , Dieter M. Gruen , Marshall H. Mendelsohn , Irving Sheft
IPC分类号： B01J20/02 , C01B3/00 , C01B6/00 , F17C11/00 , C04B15/14
CPC分类号： C01B3/0084 , C01B3/0078 , Y02E60/321 , Y02E60/327
摘要： A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.
摘要翻译：一种制备多孔金属基体氢化物压块的方法，可以反复水合和脱水而不分解。将细碎的金属氢化物和细碎基质金属的混合物与毒物接触，该毒物防止金属氢化物在室温和大气压下脱水。然后将基质金属和中毒金属氢化物的混合物在室温下压力下压实，形成多孔金属基体氢化物压块。

37. 发明申请

US20110005564A1 Method and Apparatus Pertaining to Nanoensembles Having Integral Variable Potential Junctions 审中-公开
标题翻译：具有整体可变电位结的纳米组件的方法和装置
公开(公告)号：US20110005564A1
公开(公告)日：2011-01-13
申请号：US12860405
申请日：2010-08-20
申请人： Dieter M. Gruen
发明人： Dieter M. Gruen
IPC分类号： H01L35/22 , H01L21/205
CPC分类号： H01L35/22
摘要： Carbon-containing sp3-bonded solid refractory nanocrystalline particles that are each sized no larger than about 100 nanometers have a metal of choice disposed thereabout. A variable potential junction is formed between the metallic coatings and the particles that enables carrier entropy to be efficiently transported from the variable potential junction to the coating.
摘要翻译：每个尺寸不大于约100纳米的含碳sp3键合的固体耐火纳米晶体颗粒具有选择的金属设置在其周围。在金属涂层和颗粒之间形成可变电位结，使得能够将载体熵从可变电位结有效地传输到涂层。

38. 发明授权

US07368658B1 High efficiency diamond solar cells 失效
标题翻译：高效率金刚石太阳能电池
公开(公告)号：US07368658B1
公开(公告)日：2008-05-06
申请号：US10697048
申请日：2003-10-31
申请人： Dieter M. Gruen
发明人： Dieter M. Gruen
IPC分类号： H01L31/0256
CPC分类号： H01L31/1804 , H01L31/028 , H01L31/0288 , H01L31/03682 , H01L31/068 , Y02E10/546 , Y02E10/547 , Y02P70/521
摘要： A photovoltaic device and method of making same. A layer of p-doped microcrystalline diamond is deposited on a layer of n-doped ultrananocrystalline diamond such as by providing a substrate in a chamber, providing a first atmosphere containing about 1% by volume CH4 and about 99% by volume H2 with dopant quantities of a boron compound, subjecting the atmosphere to microwave energy to deposit a p-doped microcrystalline diamond layer on the substrate, providing a second atmosphere of about 1% by volume CH4 and about 89% by volume Ar and about 10% by volume N2, subjecting the second atmosphere to microwave energy to deposit a n-doped ultrananocrystalline diamond layer on the p-doped microcrystalline diamond layer. Electrodes and leads are added to conduct electrical energy when the layers are irradiated.
摘要翻译：一种光电器件及其制造方法。将p掺杂的微晶金刚石层沉积在n掺杂的超晶体金刚石层上，例如通过在室中提供衬底，提供含有约1体积％CH 4的第一气氛和约 99％体积H 2 2与掺杂剂量的硼化合物混合，使大气经微波能量在基底上沉积p掺杂的微晶金刚石层，提供约1体积％的第二气氛 CH 4和约89体积％的Ar和约10体积％的N 2，使第二个气氛经受微波能量以在其上沉积n掺杂的超微晶金刚石层 p掺杂的微晶金刚石层。当照射层时，加入电极和引线以传导电能。

39. 发明授权

US5370855A Conversion of fullerenes to diamond 失效
标题翻译：富勒烯转化为金刚石
公开(公告)号：US5370855A
公开(公告)日：1994-12-06
申请号：US35419
申请日：1993-03-23
申请人： Dieter M. Gruen
发明人： Dieter M. Gruen
IPC分类号： C01B31/06 , C23C14/06 , C23C14/22 , C23C16/27 , C30B23/02 , C30B25/10 , C30B33/00 , H01J9/02
CPC分类号： C23C16/274 , C01B31/06 , C23C14/0605 , C23C14/0611 , C23C14/221 , C23C16/27 , C23C16/277 , C30B23/02 , C30B25/105 , C30B29/04 , C30B33/00 , H01J9/025 , Y10S423/39 , Y10S427/102 , Y10S427/106 , Y10T428/30
摘要： A method of forming synthetic hydrogen defect free diamond or diamond like films on a substrate. The method involves providing vapor containing fullerene molecules with or without an inert gas, providing a device to impart energy to the fullerene molecules, fragmenting at least in part some of the fullerene molecules in the vapor or energizing the molecules to incipient fragmentation, ionizing the fullerene molecules, impinging ionized fullerene molecules on the substrate to assist in causing fullerene fragmentation to obtain a thickness of diamond on the substrate.
摘要翻译：在基材上形成合成的无氢缺陷金刚石或类金刚石膜的方法。该方法涉及提供含有或不含有惰性气体的含有富勒烯分子的蒸气，提供了向富勒烯分子赋能的装置，至少部分地蒸发蒸气中的一些富勒烯分子或使分子激发以使其快速碎裂，将富勒烯离子化分子，在基底上撞击离子化的富勒烯分子，以帮助引起富勒烯碎裂以在基底上获得金刚石的厚度。

40. 发明授权

US4855596A Photo ion spectrometer 失效
标题翻译：光离子光谱仪
公开(公告)号：US4855596A
公开(公告)日：1989-08-08
申请号：US46117
申请日：1987-05-05
申请人： Dieter M. Gruen , Charles E. Young , Michael J. Pellin
发明人： Dieter M. Gruen , Charles E. Young , Michael J. Pellin
IPC分类号： G01Q30/02 , G01Q30/04 , G01Q90/00 , H01J49/06 , H01J49/14 , H01J49/16 , H01J49/28
CPC分类号： H01J49/484 , H01J49/061 , H01J49/142 , H01J49/161 , H01J49/282
摘要： A method and apparatus for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected autoionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy.
摘要翻译：一种用于提取样品的选定原子成分的离子进行定量分析的方法和装置。透镜系统被配置为为包含所选择的原子分量的体积提供缓慢减小的场区域，使得能够对在缓慢减小的场区域中产生的离子进行精确的能量分析。透镜系统还可以沿垂直于样品的路径长度聚焦在带电粒子束（例如离子束）的样品上，并且沿垂直于样品的路径长度提取带电粒子。在进行定量分析之前，通过激光激发离子到选择的自动电位状态来实现信噪比的提高。通过使用设置在绝缘体衬底上的预选电阻厚膜配置来确保能量带电粒子的精确能量分析，以产生预定的电场边界条件以实现所需电场电位的分析。光谱仪也适用于SIMS，ISS和电子光谱学领域。

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