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31. 发明授权

US08563781B2 Process for preparing ketones, in particular macrocyclic ketones 有权
标题翻译：制备酮的方法，特别是大环酮
公开(公告)号：US08563781B2
公开(公告)日：2013-10-22
申请号：US13269016
申请日：2011-10-07
申请人： Michael Schelper , Christoph Stock , Klaus Ebel , Joaquim Henrique Teles , Ralf Pelzer
发明人： Michael Schelper , Christoph Stock , Klaus Ebel , Joaquim Henrique Teles , Ralf Pelzer
IPC分类号： C07C45/27
CPC分类号： C07C45/28 , C07C45/62 , C07C2601/18 , C07C49/587 , C07C49/385
摘要： Ketones of the formula II where A is optionally alkyl-substituted C2-C12-alkanediyl, R1 and R2 are each, independently of one another, C1-C6-alkyl, or R1 and R2 together form optionally alkyl-substituted C3-C10-alkanediyl, and R3 is hydrogen or C1-C6-alkyl, are prepared by reacting a cyclic olefin of the formula I with dinitrogen monoxide to form the ketone of the formula II. The ketone of the formula II can be further hydrogenated to form the saturated ketone of the formula III. Macrocyclic ketones of the formula III, e.g. muscone, are sought after as fragrances.
摘要翻译：式II的酮，其中A任选为烷基取代的C 2 -C 12 - 烷二基，R 1和R 2各自彼此独立地为C 1 -C 6 - 烷基，或者R 1和R 2一起形成烷基取代的C 3 -C 10 - 烷二基 R 3是氢或C 1 -C 6烷基，是通过使式I的环状烯与一氧化二氮反应形成式II的酮制备的。式II的酮可以进一步氢化以形成式III的饱和酮。式III的大环酮，例如肌肉，被追捧为香水。

32. 发明授权

US08414744B2 Continuous process for preparing menthol in pure or enriched form 有权
标题翻译：用于制备纯粹或富集形式的薄荷醇的连续方法
公开(公告)号：US08414744B2
公开(公告)日：2013-04-09
申请号：US12677688
申请日：2008-07-23
申请人： Gunnar Heydrich , Gabriele Gralla , Klaus Ebel , Wolfgang Krause , Nawid Kashani-Shirazi
发明人： Gunnar Heydrich , Gabriele Gralla , Klaus Ebel , Wolfgang Krause , Nawid Kashani-Shirazi
IPC分类号： B01D3/14
CPC分类号： B01D3/141 , B01D3/14 , C07B2200/07 , C07C29/80 , C07C2601/14 , C07C35/12 , C07C35/17
摘要： The present invention relates to a continuous process for preparing racemic or optically active menthol in pure or enriched form by distillatively separating menthol from substance mixtures which comprise essentially menthol and diastereomers thereof. This distillatiive separation is performed in a dividing wall column with 50 to 300 theoretical plates and one or more side draw points at an absolute operating pressure of 5 to 500 mbar.
摘要翻译：本发明涉及通过将薄荷醇与基本上含有薄荷醇和非对映异构体的物质混合物蒸馏分离来制备纯的或富集形式的外消旋或光学活性薄荷醇的连续方法。该蒸馏分离在具有50至300个理论塔板和一个或多个侧向牵引点的分隔壁塔中进行，绝对操作压力为5至500毫巴。

33. 发明申请

US20120209031A1 METHOD FOR PRODUCING M-SUBSTITUTED PHENYLALKANOLS BY MEANS OF ISOMERIZATION 失效
标题翻译：通过异构化制备M取代的苯乙醇的方法
公开(公告)号：US20120209031A1
公开(公告)日：2012-08-16
申请号：US13503488
申请日：2010-10-19
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C29/56 , C07C47/228 , C07C45/51
CPC分类号： C07C29/56 , C07C45/29 , C11B9/0061 , C07C33/20 , C07C47/228
摘要： The invention relates to a process for the preparation of m-substituted phenylalkanols of the formula (I) in which R1 is C1-C5-alkyl and R2, R3, R4 and R5, independently of one another, are hydrogen or methyl, wherein a p-substituted phenylalkanol of the formula (II) in which R1, R2, R3, R4 and R5 having the meanings given under formula (I), is isomerized in the presence of a Friedel-Crafts catalyst to give an m-substituted phenylalkanol of the formula (I). From the m-substituted phenylalkanols of the formula (I) it is possible to form, by oxidation or dehydrogenation, as products of value, the corresponding aldehydes, which are known as fragrances and aroma chemicals.
摘要翻译：本发明涉及一种制备式（I）的间位取代的苯基烷醇的方法，其中R 1为C 1 -C 5 - 烷基，R 2，R 3，R 4和R 5彼此独立地为氢或甲基，其中a 式（II）的对取代的苯基链烷醇，其中具有式（I）给出的含义的R 1，R 2，R 3，R 4和R 5在Friedel-Crafts催化剂存在下异构化得到m-取代的苯基烷醇式（I）。从式（I）的间位取代的苯基烷醇可以通过氧化或脱氢形成作为有价值的产物，相应的醛被称为香料和芳香化学品。

34. 发明申请

US20120209030A1 PROCESS FOR PREPARING M- OR P-SUBSTITUTED PHENYLALKANOLS BY ALKYLATION 有权
标题翻译：通过烷基化制备M取代或P-取代的苯基甘露醇的方法
公开(公告)号：US20120209030A1
公开(公告)日：2012-08-16
申请号：US13503515
申请日：2010-10-14
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C45/29 , C07C29/32
CPC分类号： C07C29/32 , C07C29/56 , C07C45/29 , C07C33/20 , C07C47/228
摘要： The invention relates to a process for the preparation of m- or p-substituted phenylalkanols of the formula (I) in which R1 is bonded to the phenyl ring in the m- or p-position and is C1-C5-alkyl, and R2, R3, R4 and R5, independently of one another, are hydrogen or methyl, wherein an unsubstituted phenylalkanol of the formula (II) in which R2, R3, R4 and R5 have the meanings given under formula (I) is alkylated together with a C1-C5-alkyl halide of the formula (III) R1-Hal (III), in which R1 has the meaning given under formula (I) and Hal is halogen, in the presence of a Friedel-Crafts catalyst to give an m- or p-alkyl-substituted phenylalkanol of the formula (I), then the reaction mixture is worked-up and the desired m- or p-alkyl-substituted phenylalkanol of the formula (I) is separated off, the other formed by-products are returned to the reaction mixture and these are isomerized in the presence of a Friedel-Crafts catalyst to give the desired m- or p-alkyl-substituted phenylalkanol. From the m- or p-alkyl-substituted phenylalkanols of the formula (I), it is possible to form, by oxidation or dehydrogenation, as products of value, the corresponding aldehydes, which play an interesting role as fragrances and aroma chemicals.
摘要翻译：本发明涉及一种制备式（I）的间 - 或对 - 取代的苯烷醇的方法，其中R 1与m-或p-位上的苯环键合并且是C1-C5-烷基，R2 R 3，R 4和R 5彼此独立地为氢或甲基，其中R 2，R 3，R 4和R 5具有式（I）所示含义的式（II）的未取代的苯基烷醇与其中R 1具有式（I）所示含义，Hal为卤素的式（III）R1-Hal（Ⅲ）的C1-C5烷基卤化物，在Friedel-Crafts催化剂存在下，得到m- 或式（I）的对烷基取代的苯基链烷醇，然后将反应混合物处理并分离所需的式（I）的间 - 或对 - 烷基取代的苯基烷醇，另一个形成的副产物返回到反应混合物中，并将它们在Friedel-Crafts催化剂存在下异构化，得到所需的间 - 或对 - 烷基取代的苯基 kanol 从式（I）的间 - 或对 - 烷基取代的苯烷醇，可以通过氧化或脱氢形成作为有价值的产物，相应的醛作为香料和香气化学品起着重要的作用。

35. 发明申请

US20120083630A1 PREPARATION OF HOMOALLYL ALCOHOLS IN THE PRESENCE OF NONCOVALENTLY SUPPORTED IONIC LIQUID PHASE CATALYSTS UNDER GAS-PHASE REACTION CONDITIONS 有权
标题翻译：在气相反应条件下，非离子支持的离子液相催化剂存在时，制备了醇油
公开(公告)号：US20120083630A1
公开(公告)日：2012-04-05
申请号：US13252386
申请日：2011-10-04
申请人： CHRISTOPH STOCK , Dirk Gerhard , Klaus Ebel
发明人： CHRISTOPH STOCK , Dirk Gerhard , Klaus Ebel
IPC分类号： C07C29/48 , C07C33/025
CPC分类号： C07C29/38 , C07C33/025
摘要： Process for preparing homoallyl alcohols by catalyzed reaction of alkenes with aldehydes or ketones, wherein the reaction is carried out in the gas phase in the presence of noncovalently supported ionic liquid phase catalysts.
摘要翻译：通过烯烃与醛或酮的催化反应制备高烯醇的方法，其中反应在气相中在非共价负载的离子液相催化剂存在下进行。

36. 发明申请

US20110196176A1 PROCESS FOR THE PREPARATION OF M-SUBSTITUTED ALKYLTOLUENES BY ISOMERIZATION WITH IONIC LIQUIDS AS CATALYSTS 有权
标题翻译：通过与作为催化剂的离子液体异构化制备M取代的烷基甲苯的方法
公开(公告)号：US20110196176A1
公开(公告)日：2011-08-11
申请号：US13024786
申请日：2011-02-10
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C45/45 , C07C5/22
CPC分类号： C07C45/62 , C07C5/2732 , C07C45/74 , C07C2527/126 , C07C15/02 , C07C47/228 , C07C47/232
摘要： The invention relates to a process for the preparation of m-substituted alkyltoluenes of the formula (I) in which R1 is C1-C5-alkyl, wherein a p-substituted alkyltoluene of the formula (II) in which R1 has the meaning given under formula (I), is isomerized in the presence of ionic liquids to give an m-substituted alkyltoluene of the formula (I). The m-substituted alkyltoluenes obtainable according to the invention are starting compounds for the preparation of fragrances and aroma substances.
摘要翻译：本发明涉及一种制备其中R 1为C 1 -C 5 - 烷基的式（I）的间位取代的烷基甲苯的方法，其中式（II）的对取代烷基甲苯其中R 1具有下面给出的含义式（I）的化合物在离子液体的存在下异构化，得到式（I）的间位取代的烷基甲苯。根据本发明可获得的m取代的烷基甲苯是用于制备香料和香料物质的起始化合物。

37. 发明申请

US20100191021A1 PROCESS FOR PREPARATION OF MENTHOL BY HYDROGENATION OF ISOPULEGOL 有权
标题翻译：通过加氢异烟肼制备精胺的方法
公开(公告)号：US20100191021A1
公开(公告)日：2010-07-29
申请号：US12670328
申请日：2008-07-16
申请人： Gabriele Gralla , Gunnar Heydrich , Eike Johannes Bergner , Klaus Ebel
发明人： Gabriele Gralla , Gunnar Heydrich , Eike Johannes Bergner , Klaus Ebel
IPC分类号： C07C29/00
CPC分类号： C07C29/172 , C07B2200/07 , C07C2601/14 , C07C35/12
摘要： The present invention relates to a process for preparing racemic or optically active menthol by catalytically hydrogenating racemic or optically active isopulegol in the presence of hydrogen and catalysts which comprise nickel-, copper-, zirconium- and molybdenum-containing compounds. The present invention relates specifically to a corresponding process far continuously catalytically hydrogenating L-isopulegol to L-menthol.
摘要翻译：本发明涉及一种通过在氢气存在下催化氢化外消旋或光学活性异胡胆醇来制备外消旋或光学活性薄荷醇的方法和包含含镍，铜，锆和钼的化合物的催化剂。本发明具体涉及将L-异胡胆醇连续催化氢化成L-薄荷醇的相应方法。

38. 发明申请

US20100010253A1 RECOVERY OF BIS(DIARYLPHENOL) LIGANDS DURING THE PRODUCTION OF ISOPULEGOL 有权
标题翻译：在ISOPULEGOL生产过程中恢复BIS（DIARYLPHENOL）配体
公开(公告)号：US20100010253A1
公开(公告)日：2010-01-14
申请号：US12439270
申请日：2007-08-31
申请人： Gunnar Heydrich , Gabriele Gralla , Klaus Ebel
发明人： Gunnar Heydrich , Gabriele Gralla , Klaus Ebel
IPC分类号： C07C29/14 , C07C29/17 , C07C37/68 , C07C45/78 , C07C67/48
CPC分类号： C07C29/56 , B01J31/0214 , B01J31/143 , B01J31/4015 , B01J2531/31 , C07B2200/07 , C07C29/172 , C07C29/80 , C07C2601/14 , Y02P20/584 , C07C35/12 , C07C35/17
摘要： The present invention relates to a method of working up an aluminium-containing reaction product from the production of isopulegol by cyclization of citronellal in the presence of complex compounds, comprising at least one ligand of the formula (I), where Ar1, Ar2, Ar3, Ar4 are chosen from C6-C15-aryl or C2-C15-hetero; R1, R2, R3, R4 are chosen from H, C1-C6-alkyl, C1-C6-perfluoroalkyl, C1-C6-alkoxy, C7-C12-aralkyl, halogen, SiR5bR6bR7b, C6-C10-aryl, NR8bR9b, SR10b, NO2; and where R1 or R2 and/or R3 or R4, together with A, can form an aromatic or nonaromatic cycle; etc.; in which a) the aluminum-containing reaction product is subjected to distillative separation, b) the isopulegol-depleted bottom product is brought into close contact with an aqueous base and c) the ligand of the formula (I) is separated off from the organic phase, preferably by crystallization. Moreover, the invention relates to a method of producing isopulegol, and to a method of producing menthol.
摘要翻译：本发明涉及一种通过在络合物存在下使香茅醛环化制备异胡醇的方法，所述复合化合物包含至少一种式（I）的配位体，其中Ar 1，Ar 2，Ar 3 ，Ar 4选自C 6 -C 15 - 芳基或C 2 -C 15 - 杂原子; R1，R2，R3，R4选自H，C1-C6-烷基，C1-C6-全氟烷基，C1-C6-烷氧基，C7-C12-芳烷基，卤素，SiR5bR6bR7b，C6-C10-芳基，NR8bR9b，SR10b， NO2; 并且其中R 1或R 2和/或R 3或R 4与A一起可以形成芳族或非芳族化合物; 等等。; 其中a）使含铝反应产物进行蒸馏分离，b）将异底三醇消耗的底部产物与碱水溶液紧密接触，并且c）将式（I）的配体与有机物分离出来相，优选通过结晶。此外，本发明涉及一种生产异胡母醇的方法和一种制备薄荷醇的方法。

39. 发明申请

US20080089010A1 Electorlyte Solution for Double-Layred Capacitors and Double-Layered Capacitor Containing Said Electroylte Solution 失效
标题翻译：含有所述电解质溶液的双层电容器和双层电容器的电解液解决方案
公开(公告)号：US20080089010A1
公开(公告)日：2008-04-17
申请号：US11659138
申请日：2005-08-03
申请人： Georg Degen , Klaus Ebel , Kristin Tiefensee , Andee Schwake
发明人： Georg Degen , Klaus Ebel , Kristin Tiefensee , Andee Schwake
IPC分类号： H01G9/155 , H01G9/038 , H01G9/035
CPC分类号： H01G9/038 , H01G11/62 , Y02E60/13
摘要： An electrolyte solution proposed for double layer capacitors contains at least one conducting salt comprising a cation having a maximum diameter
摘要翻译：提出用于双层电容器的电解质溶液包含至少一种导电盐，其包含最大直径<9.20的阳离子，该阳离子另外包含中心原子上的取代基，其不完全相同，并且进一步含有至少一种选自以下官能团的溶剂：来自内酯和亚硝酸盐。当乙腈是溶剂时，这种电解质溶液在低温下优于常规电解质溶液，使得根据本发明提供电解质溶液的双层电容器在低温下具有改善的电性能。

40. 发明授权

US07247753B2 Method for producing macrocyclic ketones by means of dieckmann codensation in the gas phase 有权
标题翻译：通过在气相中的羟丙基甲烷聚合法制备大环酮的方法
公开(公告)号：US07247753B2
公开(公告)日：2007-07-24
申请号：US10519549
申请日：2003-07-10
申请人： Alexander Wartini , Klaus Ebel , Gisela Hieber , Hagen Weigl
发明人： Alexander Wartini , Klaus Ebel , Gisela Hieber , Hagen Weigl
IPC分类号： C07C45/67
CPC分类号： C07C45/48 , C07C49/587 , C07C49/385
摘要： The invention relates to a method for producing macrocyclic ketones of general formula (I) by direct cyclisation of compounds of general formula (II) in the gas phase on a heterogeneous catalyst. In general formula (I), X represents a monounsaturated or polyunsaturated or saturated C10–C17 alkyl radical which can be optionally substituted by a C1–C6 alkyl radical, and in general formula (II), R1, R2 can respectively be the same or different and represent hydrogen or C1–C6 alkyl, and has the above-mentioned designation.
摘要翻译：本发明涉及通过在气相中在非均相催化剂上直接环化通式（II）的化合物来制备通式（I）的大环酮的方法。在通式（I）中，X表示可以任选被C 1'烷基取代的单不饱和或多不饱和或饱和的C 1 -C 12烷基，通式（II）中，R 1，R 2可以分别相同或不同，并且R 1，R 2，R 2，表示氢或C 1 -C 6烷基，并具有上述名称。

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