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31. 发明授权

US4912024A Photographic material having releasable compound 失效
标题翻译：具有可释放化合物的摄影材料
公开(公告)号：US4912024A
公开(公告)日：1990-03-27
申请号：US209742
申请日：1988-06-21
申请人： Drake M. Michno , Richard P. Szajewski , Stephen P. Singer
发明人： Drake M. Michno , Richard P. Szajewski , Stephen P. Singer
IPC分类号： G03C7/305
CPC分类号： G03C7/30541 , Y10S430/158
摘要： Photographic elements are disclosed having a first coupler represented by the formula:COUP.sub.1 --T--INH--CH.sub.2 --QwhereinCOUP.sub.1 is a coupler moiety,T is a timing group that is bonded to the coupler moiety at a coupling position and that is cleaved from --INH--CH.sub.2 --Q after it is released from the coupler moiety upon exposure and processing of the element, andINH--CH.sub.2 --Q is a development inhibitor moiety wherein Q is a ballasting group, anda second coupler represented by the formula:COUP.sub.2 --(TIME).sub.n --S--R.sub.1 --R.sub.2 wherein COUP.sub.2 is a coupler moiety, TIME is a timing group, n is 0 or 1, R.sub.1 is a divalent linking group that does not include a heterocyclic ring attached directly to S, and R.sub.2 is a water solubilizing group.

32. 发明授权

US4865956A Photographic elements containing a bleach accelerator precursor 失效
标题翻译：含有漂白促进剂前体的摄影元素
公开(公告)号：US4865956A
公开(公告)日：1989-09-12
申请号：US270922
申请日：1988-11-14
申请人： John W. Harder , Stephen P. Singer
发明人： John W. Harder , Stephen P. Singer
IPC分类号： G03C1/34 , G03C1/43 , G03C7/392 , G03C7/42
CPC分类号： G03C1/346 , G03C1/43 , G03C7/3924 , G03C7/421
摘要： Silver halide photographic elements are described containing, as a bleach accelerator precursor, a silver salt of a solubilized, non-primary amino thiol. The bleach accelerators are operable with a multiplicity of bleach compositions and do not deleteriously affect the sensitometric properties of the photographic element.

33. 发明授权

US07338756B2 Method of preparation of direct dispersions of photographically useful chemicals 失效
标题翻译：制备摄影有用化学品的直接分散体的方法
公开(公告)号：US07338756B2
公开(公告)日：2008-03-04
申请号：US10692535
申请日：2003-10-24
申请人： Paul L. Zengerle , Richard K. Rothrock , Jerrold N. Poslusny , Stephen P. Singer , Peter P. Garrisi , Paul B. Merkel
发明人： Paul L. Zengerle , Richard K. Rothrock , Jerrold N. Poslusny , Stephen P. Singer , Peter P. Garrisi , Paul B. Merkel
IPC分类号： G03C1/005 , G03C1/08
CPC分类号： G03C7/3885 , G03C1/005 , G03C2001/0854
摘要： A process for making a direct dispersion of a photographically useful material comprising: mixing (i) an aqueous phase and (ii) a liquid organic phase under conditions of shear or turbulence to form a dispersion of the organic phase dispersed in the aqueous phase; wherein the liquid organic phase comprises one or more photographically useful materials and one or more organic solvents having a boiling point of at least 150° C., a molecular weight less than or equal to 300, and a solvatochromic parameter β value greater than or equal to 0.50, wherein the weight ratio of the sum of the solvents having a boiling point of at least 150° C., a molecular weight less than or equal to 300, and a solvatochromic parameter β value greater than or equal to 0.50 to the photographically useful materials does not exceed 0.25. The use of relatively low levels of specified high-boiling organic solvents enables the direct dispersion of hydrophobic photographically useful materials with low solubility in conventional primary photographic useful solvents without crystallization problems or excessive decomposition.
摘要翻译：一种用于直接分散照相的有用材料的方法，包括：（i）水相和（ii）液态有机相在剪切或湍流条件下混合以形成分散在水相中的有机相的分散体; 其中液体有机相包含一种或多种照相用的材料和一种或多种沸点为至少150℃，分子量小于或等于300的有机溶剂，溶剂化变色参数β值大于或等于至0.50，其中沸点为至少150℃，分子量小于或等于300的溶剂的总和与溶剂化变色参数β值大于或等于0.50的相对于照相的重量比有用的材料不超过0.25。使用相对低含量的特定高沸点有机溶剂使得能够在常规的主要照相有用溶剂中直接分散具有低溶解度的疏水照相用材料，而没有结晶问题或过度分解。

34. 发明授权

US06472133B1 Silver halide element with improved high temperature storage 失效
标题翻译：具有改善的高温储存的卤化银元件
公开(公告)号：US06472133B1
公开(公告)日：2002-10-29
申请号：US09592705
申请日：2000-06-13
申请人： James H. Reynolds , Steven P. Szatynski , Stephen P. Singer , George J. Burgmaier , Janet N. Younathan , Lillian M. Kellogg
发明人： James H. Reynolds , Steven P. Szatynski , Stephen P. Singer , George J. Burgmaier , Janet N. Younathan , Lillian M. Kellogg
IPC分类号： G03C7305
CPC分类号： G03C7/30511 , G03C7/30552
摘要： This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and wherein INH is a development inhibitor; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.
摘要翻译：本发明涉及一种卤化银照相元件，其包含至少一种含有染料形成成色剂的卤化银乳剂层，其与氧化的彩色显影剂反应形成染料，所述卤化银元素还包含式I的酰氨基化合物，其中INH为显影抑制剂; LINK是连接或时序基团，m是0,1或2; 并且其中INH是开发抑制剂; R 1和R 2独立地表示脂族，芳族或杂环基团，或者R 1和R 2与它们所连接的氮一起代表形成5或6元环或多环体系所必需的原子，或者R 1和R 2独立地为-C（= O）（LINK）m-INH基团，或被-NR 3 a C（= O） - （LINK）m-INH基团取代，其中R 3a定义与R 1或 R2，并且其中式I的化合物基本上不与氧化的显影剂反应以释放INH。

35. 发明授权

US6043012A Color negative photographic elements with modified scavenging compound distributions 失效
标题翻译：具有改进的清除化合物分布的彩色负片摄影元件
公开(公告)号：US6043012A
公开(公告)日：2000-03-28
申请号：US282259
申请日：1999-03-31
申请人： Allan F. Sowinski , William J. Begley , Stephen P. Singer
发明人： Allan F. Sowinski , William J. Begley , Stephen P. Singer
IPC分类号： G03C7/20 , G03C7/30 , G03C7/392 , G03C1/46
CPC分类号： G03C7/3029 , G03C2007/3034 , G03C2200/19 , G03C2200/26 , G03C5/266 , G03C7/3041
摘要： A color negative photographic element is disclosed containing higher levels of oxidized developer agent scavenging compound in the lowest and intermediate sensitivity layers of a triple-coated image recording unit than in the fast layer. Reduced fog and granularity are obtained, and increased speed and latitude are obtained.
摘要翻译：公开了一种彩色负型照相材料，其在三层涂布图像记录单元的最低和中等敏感层中含有比在快速层中更高含量的氧化显影剂清除化合物。获得降低雾度和粒度，并获得提高的速度和纬度。

36. 发明授权

US5563026A Color negative element having improved green record printer compatibility 失效
标题翻译：彩色负面元件具有改善的绿色记录打印机兼容性
公开(公告)号：US5563026A
公开(公告)日：1996-10-08
申请号：US431243
申请日：1995-04-28
申请人： Stephen P. Singer
发明人： Stephen P. Singer
IPC分类号： G03C7/00 , G03C7/18 , G03C7/30 , G03C7/384 , G03C1/46
CPC分类号： G03C7/3003 , G03C7/3041 , G03C7/384 , G03C7/3029
摘要： The invention provides a multicolor negative photographic element comprising a support bearing at least two green light sensitive silver halide emulsion layers of differing light sensitivity, the least and only the least sensitive layer containing a 1-phenyl-3-acylamino-4-nitrogenheterocycle-pyrazolin-5-one dye forming hue correction coupler which reacts with oxidized developer during development to form a dye having a D580/D550 ratio greater than that exhibited by the element absent the hue correction coupler. The invention also provides an imaging process.
摘要翻译：本发明提供了一种多色负照相元件，其包括支持不同光敏度的至少两个绿色感光卤化银乳剂层的载体，最少且仅有最不敏感层含有1-苯基-3-酰基氨基-4-氮杂环 - 吡唑啉 -5-一种染料形成色调校正成色剂，其在显影期间与氧化显影剂反应形成D580 / D550比大于不含色调校正偶合剂的元素所显示的染料。本发明还提供了一种成像过程。

37. 发明授权

US5561036A Photographic elements containing scavengers for oxidized developing agent 失效
标题翻译：含有氧化显影剂清除剂的摄影元素
公开(公告)号：US5561036A
公开(公告)日：1996-10-01
申请号：US413746
申请日：1995-03-30
申请人： Stephen P. Singer , Ronald E. Leone
发明人： Stephen P. Singer , Ronald E. Leone
IPC分类号： G03C7/00 , G03C1/06 , G03C7/392 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号： G03C7/39216 , G03C1/06
摘要： An improved photographic element comprises a support bearing at least one silver halide emulsion layer having associated therewith a hydroquinone compound that functions as a scavenger for oxidized developing agent. The hydroquinone compound has sufficient bulk that it is substantially non-diffusible in the photographic element and has in the two-position thereof an asymmetric tertiary carbamoyl substituent. These scavenger compounds exhibit very high activity, have excellent stability upon long-term storage and do not leave colored residues after processing.
摘要翻译：一种改进的照相元件包含一种载体，该支持体带有至少一个卤化银乳剂层，其具有与用作氧化显影剂的清除剂起作用的氢醌化合物。对苯二酚化合物具有足够的体积，其在照相元件中基本上不可扩散，并且在两位上具有不对称的叔氨基甲酰基取代基。这些清除剂化合物表现出非常高的活性，在长期保存时具有优异的稳定性，并且在加工后不会留下有色残留物。

38. 发明授权

US5364745A Azoaniline masking couplers for photographic materials 失效
标题翻译：用于摄影材料的偶氮苯掩蔽成色剂
公开(公告)号：US5364745A
公开(公告)日：1994-11-15
申请号：US778828
申请日：1991-12-19
申请人： Jared B. Mooberry , Stephen P. Singer , James J. Seifert , Robert J. Ross , Daniel L. Kapp
发明人： Jared B. Mooberry , Stephen P. Singer , James J. Seifert , Robert J. Ross , Daniel L. Kapp
IPC分类号： G03C7/305 , G03C7/333 , G03C5/54 , G03C7/18 , G03C7/32 , G03C7/34
CPC分类号： G03C7/3335 , G03C7/30547 , Y10S430/159
摘要： A photographic element including a support bearing a silver halide photographic emulsion, at least one color-forming coupler and a masking coupler, wherein said masking coupler is represented by the formula A:COUP--LINK--DYE (A)wherein COUP is a coupler moiety;LINK is any group releasable or cleavable from COUP by coupling with an oxidized developing agent during photographic processing; and DYE is an azoaniline dye and preferably an azoaniline dye blocked at the nitrogen-inclusive auxochromic site.
摘要翻译： PCT No.PCT / US91 / 09640 Sec。 371 1991年12月19日第 102（e）1991年12月19日PCT PCT 1991年12月19日PCT公布。出版物WO92 / 日本时间1992年7月9日。一种照相元件，包括带有卤化银照相乳剂的支持物，至少一种成色剂和遮蔽偶联剂，其中所述掩蔽成色剂由式A表示：COUP-LINK-DYE ）其中COUP是成色剂部分; LINK是通过在照相处理过程中与氧化的显影剂耦合而从COUP可释放或可切割的组; 并且DYE是偶氮苯胺染料，优选在包含氮的辅助色素位点处阻断的偶氮苯胺染料。

39. 发明授权

US5256528A Magenta image-dye couplers of improved hue 失效
标题翻译：洋红色图像染料成色剂改善色调
公开(公告)号：US5256528A
公开(公告)日：1993-10-26
申请号：US872880
申请日：1992-04-23
申请人： Paul B. Merkel , Stephen P. Singer , Bernard Arthur Clark , Paul Louis R. Stanley
发明人： Paul B. Merkel , Stephen P. Singer , Bernard Arthur Clark , Paul Louis R. Stanley
IPC分类号： G03C7/305 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号： G03C7/30529
摘要： A photographic element and process provide a magenta coupler of the formula: ##STR1## wherein (a) at least one of X1, X2 and R1 and at least one of R2 and R3 is a substituent individually selected from carbamoyl, alkoxycarbonyl, aryloxycarbonyl, sulfamoyl, alkylsulfonyl, arylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, alkylsulfoxyl, arylsulfoxyl, acyloxy, cyano, nitro, and trifluoromethyl;(b) the substituents X1, X2, R1, R2 and R3 not selected from the (a) group may be selected from alkyl, alkoxy, aryloxy, acylamino, alkylthio, arylthio, sulfonamido, alkylureido, arylureido, alkoxycarbonylamino, aryloxycarbonylamino, and halogen and in the case of R3 hydrogen;(c) substituents R1 and R2 are para or meta to the carbon attached to the nitrogen atom;(d) a and b are 1 to 3;(e) Q is an alkylthio or arylthio coupling-off group.The element provides a deeper magenta hue and reduced blue absorption by the resulting magenta dye.
摘要翻译：照相元件和方法提供下式的品红成色剂：其中（a）X 1，X 2和R 1中的至少一个和R 2和R 3中的至少一个是分别选自氨基甲酰基，烷氧基羰基，芳氧基羰基，氨磺酰基，烷基磺酰基，芳基磺酰基，烷氧基磺酰基，芳氧基磺酰基，烷基亚砜基，芳基亚砜基，酰氧基，氰基，硝基和三氟甲基; （b）未选自（a）基团的取代基X1，X2，R1，R2和R3可以选自烷基，烷氧基，芳氧基，酰氨基，烷硫基，芳硫基，亚磺酰氨基，烷基脲基，芳基脲基，烷氧基羰基氨基，芳氧基羰基氨基和卤素在R3氢的情况下; （c）取代基R 1和R 2与连接在氮原子上的碳对位或间位; （d）a和b为1〜3; （e）Q是烷硫基或芳硫基离去基团。该元素提供更深的品红色色调，并由所得品红色染料减少蓝色吸收。

40. 发明授权

US5019492A Photographic element and process comprising a blocked photographically useful compound 失效
标题翻译：摄影元件和包含封闭的照相用化合物的方法
公开(公告)号：US5019492A
公开(公告)日：1991-05-28
申请号：US343981
申请日：1989-04-26
申请人： John M. Buchanan , Ewell R. Cook , Jared B. Mooberry , Gary S. Proehl , Stephen P. Singer , William N. Washburn
发明人： John M. Buchanan , Ewell R. Cook , Jared B. Mooberry , Gary S. Proehl , Stephen P. Singer , William N. Washburn
IPC分类号： G03C1/06 , G03C1/43 , G03C7/305 , G03C7/392
CPC分类号： G03C7/30511 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159 , Y10S430/16 , Y10S430/161
摘要： A novel blocked photographically useful compound comprises a new blocking group that (a) comprises two electrophilic groups, the least electrophilic of which is bonded directly or through a timing group to the photographically useful group (PUG) of the compound, (b) is capable of reacting with a dinucleophile reagent, and (c) has the two electrophilic groups separated from each other by a bond or unsubstituted or substituted atom that enables nucleophilic displacement to occur with release of PUG when the compound is reacted with a dinucleophile reagent. Such a blocked photographically useful compound is useful in a photographic material and process to provide increased stability and enable more rapid release of the photographically useful group upon reaction with a dinucleophile reagent.

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