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31. 发明授权

US4760124A Crystalline polyester-imide, process for production thereof, and use thereof 失效
标题翻译：结晶聚酰亚胺，其制备方法及其用途
公开(公告)号：US4760124A
公开(公告)日：1988-07-26
申请号：US887944
申请日：1986-07-22
申请人： Shunichi Matsumura , Hiroo Inata , Shigeyoshi Hara
发明人： Shunichi Matsumura , Hiroo Inata , Shigeyoshi Hara
IPC分类号： C08G73/16
CPC分类号： C08G73/16
摘要： Melt-moldable crystalline polyester-imides comprising units of the following formula (IA) ##STR1## wherein R represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 5 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a halogen atom, and n is an integer of 2 to 12, as main recurring units. The polyester-imides are prepared by (1) condensing a starting mixture containing 1 mole of an imidodicarboxylic acid and 2 to 12 moles of an aromatic monohydroxy compound under heat while distilling water out of the reaction system or (1)' condensing a starting mixture comprising 1 mole of trimellitic anhydride, 0.5 to 0.8 mole of an aliphatic diamine and 2 to 20 moles of an aromatic monohydroxy compound under heat, and thereafter (2) polycondensing the resulting reaction mixture under heat with an amount, sufficient to distill substantially all of the aromatic monohydroxy compound from the reaction system, of a diol compound or a mixture of the diol compound and an aliphatic diamine until substantially all of the aromatic monohydroxy compound is distilled out of the reaction system.
摘要翻译：包含下式（IA）单元的可熔融模塑的结晶聚酯 - 酰亚胺其中R表示氢原子，具有1-10个碳原子的烷基，具有5-10个碳原子的环烷基，作为主要重复单元，具有6至10个碳原子的芳基，具有7至12个碳原子的芳烷基，具有1至10个碳原子的烷氧基或卤素原子，n是2至12的整数。聚酰亚胺通过以下步骤制备：（1）在加热下将含有1摩尔亚氨二羧酸和2至12摩尔芳族单羟基化合物的起始混合物冷凝，同时将水从反应体系中蒸馏出来，或（1）“将起始混合物包括1摩尔偏苯三酸酐，0.5至0.8摩尔脂族二胺和2至20摩尔芳族单羟基化合物在加热下，然后（2）将所得反应混合物在加热下缩聚，其量足以蒸馏基本上全部来自反应体系的芳族单羟基化合物，二醇化合物或二醇化合物和脂族二胺的混合物直到基本上全部芳族单羟基化合物从反应体系中蒸馏出来。

32. 发明授权

US4436894A Novel wholly aromatic copolyester, process for production thereof, and film melt-shaped therefrom 失效
标题翻译：新型全芳香族共聚酯，其制造方法和由其熔融成型的薄膜
公开(公告)号：US4436894A
公开(公告)日：1984-03-13
申请号：US286855
申请日：1981-07-27
申请人： Takanori Urasaki , Yasuji Hirabayashi , Tugusi Yoshida , Hiroo Inata
发明人： Takanori Urasaki , Yasuji Hirabayashi , Tugusi Yoshida , Hiroo Inata
IPC分类号： C08G63/19 , C08G63/60 , C08G63/64 , C08G63/672 , C08J5/18 , C08G63/18
CPC分类号： C08J5/18 , C08G63/19 , C08G63/605 , C08G63/64 , C08G63/672 , C08J2367/03
摘要： A wholly aromatic copolyester composed mainly of isophthalic acid units and hydroquinone units, the total proportion of said isophthalic acid units and hydroquinone units being at least about 80 mole % based on the entire units, said wholly aromatic copolyester having a terminal carboxyl group concentration, measured by the method described in the specification, of not more than about 90 eq/10.sup.6 g and a reduced viscosity, determined at 35.degree. C. in a mixed solvent of phenol and tetrachloroethane in a weight ratio of 4:6 in a concentration of 1.2 g/dl of at least about 0.6 and being substantially linear and melt-shapable and substantially free from a halogen atom bonded to the molecular chain, and a film prepared therefrom by melt shaping.
摘要翻译：主要由间苯二甲酸单元和氢醌单元组成的全芳香族共聚酯，所述间苯二甲酸单元和氢醌单元的总比例相对于整个单元为至少约80摩尔％，所述全芳香族共聚酯具有末端羧基浓度，通过本说明书中描述的方法，在35℃下在苯酚和四氯乙烷的混合溶剂中以4:6的重量比在浓度为1.2的浓度下测定不大于约90eq / 106g和比浓粘度 g / dl至少约0.6，并且基本上线性且可熔融成型并且基本上不含与分子链结合的卤素原子，以及通过熔融成型制备的膜。

33. 发明授权

US4369207A Process for production of laminated film structure of aromatic polyester 失效
标题翻译：芳香族聚酯层压薄膜结构的生产工艺
公开(公告)号：US4369207A
公开(公告)日：1983-01-18
申请号：US122664
申请日：1980-02-19
申请人： Shunichi Matsumura , Hiroo Inata , Makoto Ogasawara
发明人： Shunichi Matsumura , Hiroo Inata , Makoto Ogasawara
IPC分类号： B32B15/08 , C08F283/02 , C08J7/18 , G03F7/00 , H05K1/03 , B05D3/06
CPC分类号： C08J7/18 , B32B15/08 , C08F283/02 , G03F7/00 , H05K1/0326 , C08J2367/02
摘要： A laminated film structure composed of a polyester film and an electroconductive metal layer laminated to at least one surface of the polyester resin film, characterized in that said polyester film is an unstretched film of a cured aromatic polyester having a crosslinking degree of not less than 70%, a swelling degree of not more than 30 and an elongation at room temperature of not less than 10%; and a process for producing said film structure.
摘要翻译：由聚酯膜和导电金属层组成的叠层膜结构层压在聚酯树脂膜的至少一个表面上，其特征在于，所述聚酯膜是交联度不小于70的固化芳族聚酯的未拉伸膜％，溶胀度不大于30，室温下的伸长率不小于10％; 以及制造所述膜结构的方法。

34. 发明授权

US4331697A Novel heparin derivative, method for production thereof, and method for rendering biomedical materials antithrombotic by use of the novel heparin derivative 失效
标题翻译：新型肝素衍生物，其生产方法，以及通过使用新型肝素衍生物制备生物医学材料抗血栓形成的方法
公开(公告)号：US4331697A
公开(公告)日：1982-05-25
申请号：US183377
申请日：1980-09-02
申请人： Akira Kudo , Hiroo Inata , Makoto Ogasawara
发明人： Akira Kudo , Hiroo Inata , Makoto Ogasawara
IPC分类号： A61L33/00 , C08B37/00 , A01N1/02
CPC分类号： C08B37/0075 , A61L33/0011
摘要： A heparin derivative in which at least 0.5% of the entire hydroxyl groups of heparin are in the form of an ester of the following formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; a method for producing aforesaid heparin derivative which comprises reacting heparin with a halide or anhydride of an unsaturated carboxylic acid of the formula ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 are the same as defined above; and a method for imparting antithrombotic activity to a biomedical material, which comprises treating that surface of the biomedical material which makes contact with the blood with actinic light in the presence of aforesaid heparin derivative.
摘要翻译：肝素衍生物，其中肝素的整个羟基的至少0.5％为下式的酯形式（Ⅰ），其中R1，R2和R3各自表示氢原子或具有1个至6个碳原子; 一种制备上述肝素衍生物的方法，其包括使肝素与式IMAIm不饱和羧酸的卤化物或酸酐反应，其中R1，R2和R3与上述定义相同; 以及向生物医学材料施加抗血栓活性的方法，其包括在上述肝素衍生物的存在下用光化学光处理与血液接触的生物医学材料的表面。

35. 发明授权

US4269947A Cured or uncured aromatic polyester composition and process for its production 失效
标题翻译：固化或未固化的芳族聚酯组合物及其生产工艺
公开(公告)号：US4269947A
公开(公告)日：1981-05-26
申请号：US78680
申请日：1979-09-25
申请人： Hiroo Inata , Makoto Ogasawara , Tsuto Morinaga , Akihiro Norike
发明人： Hiroo Inata , Makoto Ogasawara , Tsuto Morinaga , Akihiro Norike
IPC分类号： C08G63/58 , C08G63/91 , C08L67/06 , C08J3/28
CPC分类号： C08G63/916 , C08G63/58 , C08K5/16 , C08K5/34 , C08L67/06
摘要： A cured or uncured linear aromatic polyester composition melt-blended and composed of(A) 100 parts by weight of a saturated linear aromatic polyester in which at least 70 mole % of the acid component consists of an aromatic dicarboxylic acid, and(B) 0.1 to 50 parts by weight of a reactive compound which is solid at room temperature or is a liquid having a boiling point of at least 200.degree. C. under atmospheric pressure, and which contains in its molecule at least one aliphatic unsaturated group substantially non-reactive with the polyester (A) and the aliphatic unsaturated group of the reactive compound (B) under conditions of melt-blending with the polyester (A) and at least one epoxy group reactive with the polyester (A) under the melt-blending conditions. The cured linear aromatic polyester composition can be prepared by extruding the uncured linear aromatic polyester composition under melting conditions, and subjecting the resulting extrudate to a curing treatment.
摘要翻译：固化或未固化的线性芳族聚酯组合物熔融共混并由（A）100重量份的饱和直链芳族聚酯组成，其中至少70摩尔％的酸组分由芳族二羧酸组成，和（B）0.1 至50重量份在室温下为固体的反应性化合物或在大气压下为沸点为至少200℃的液体，并且其在其分子中含有至少一个基本上不反应的脂族不饱和基团与聚酯（A）的熔融共混条件下的聚酯（A）和反应性化合物（B）的脂肪族不饱和基团和至少一种与聚酯（A）反应的环氧基团在熔融共混条件下进行。固化的线性芳族聚酯组合物可以通过在熔融条件下挤出未固化的线性芳族聚酯组合物并将所得挤出物进行固化处理来制备。

36. 发明授权

US5876851A Film from polycarbonate, polyester to be laminated on metal 失效
标题翻译：聚碳酸酯膜，聚酯层压在金属上
公开(公告)号：US5876851A
公开(公告)日：1999-03-02
申请号：US367360
申请日：1995-01-19
申请人： Shunichi Matsumura , Ryoji Tsukamoto , Masaaki Tsukioka , Hiroo Inata , Seiji Itoh
发明人： Shunichi Matsumura , Ryoji Tsukamoto , Masaaki Tsukioka , Hiroo Inata , Seiji Itoh
IPC分类号： B21D22/20 , B32B27/36 , C08J5/18 , C08L69/00 , C08L67/02
CPC分类号： C08J5/18 , B21D22/201 , B32B27/36 , C08L69/00 , C08J2369/00 , Y10T428/31507
摘要： A film to be laminated on a metal, which is formed of a polycarbonate resin having a high concentration of terminal hydroxyl groups or a composition comprising said resin and a polyester resin or a film to be laminated on a metal, which is formed by laminating the above film and a polyester film. The film is excellent in adhesion to a metal plate, moldability, heat resistance, retort resistance, odor retention property, impact resistance dent resistance and processability into a can, such as drawing fabrication, ironing fabrication or the like for producing metal cans.
摘要翻译： PCT No.PCT / JP94 / 00801 Sec。 371日期1995年1月19日 102（e）1995年1月19日PCT PCT 1994年5月18日PCT公布。公开号WO94 / 26809 日期：1994年11月24日将层压在金属上的膜，该金属由具有高浓度末端羟基的聚碳酸酯树脂或包含所述树脂的组合物和聚酯树脂或层压在金属上的膜形成，通过层压上述膜和聚酯膜形成。该膜对于金属板的粘附性，成型性，耐热性，耐蒸煮性，气味保持性，耐冲击性凹陷阻力和加工成罐的加工性优异，例如用于制造金属罐的拉丝加工，熨烫加工等。

37. 发明授权

US5068307A Polyamideimides containing 3,4'-diamino-diphenylether as diamine component and process for preparing the same 失效
标题翻译：包含3,4'-二氨基二苯醚作为DIAMINE组分的聚酰亚胺及其制备方法
公开(公告)号：US5068307A
公开(公告)日：1991-11-26
申请号：US433194
申请日：1989-11-08
申请人： Shigeyoshi Hara , Hiroo Inata , Shunichi Matsumura
发明人： Shigeyoshi Hara , Hiroo Inata , Shunichi Matsumura
IPC分类号： C08G73/10 , C08G73/14 , C08K5/41 , C08L79/08 , H05K1/03 , H05K3/38
CPC分类号： C08L79/08 , C08G73/105 , C08G73/1071 , C08G73/14 , C08K5/41 , H05K1/0346 , H05K3/386
摘要： A polyamideimide having an inherent viscosity of above 0.48 which comprises a unit of the following formula (II) ##STR1## and a unit of the following formula (IV) ##STR2## as main units forming the molecular chains of the polyamideimide, and an intimate mixture of the polyamideimide and a plasticising material for the polyamideimide.

38. 发明授权

US5068062A Reversibly color-changeable materials 失效
标题翻译：可逆变色材料
公开(公告)号：US5068062A
公开(公告)日：1991-11-26
申请号：US333257
申请日：1989-04-05
申请人： Hiroo Inata , Shunichi Matsumura , Seiji Itoh , Masuhiro Okada
发明人： Hiroo Inata , Shunichi Matsumura , Seiji Itoh , Masuhiro Okada
IPC分类号： C08F8/44 , C08G59/28 , C08G59/40 , C09K9/02
CPC分类号： C09K9/02 , C08F8/44 , C08G59/28 , C08G59/40
摘要： An electrochromic resin composition comprising (A) 100 parts by weight of a network comprising a crosslinked polymer containing 4,4'-diaminodiphenylmethane units in a form in which the amino groups in the formula are quaternized, and (B) 5 to 150 parts by weight of an electrolytic material uniformly dispersed in the network (A). The crosslinked polymer containing the units with the amino groups therein being in the quaternized state is useful as an electrochromic or photochromic material.

39. 发明授权

US4581438A Aromatic polyester of 6,6'-(ethylenedioxy)di-2-naphthoic acid, process for production thereof and film, fiber and other shaped articles therefrom 失效
标题翻译： 6,6' - （亚乙二氧基）二-2-萘甲酸的芳族聚酯，其制备方法和薄膜，纤维和其它成型制品
公开(公告)号：US4581438A
公开(公告)日：1986-04-08
申请号：US682760
申请日：1984-12-17
申请人： Hiroo Inata , Hiroyuki Umetani , Shunichi Matsumura
发明人： Hiroo Inata , Hiroyuki Umetani , Shunichi Matsumura
IPC分类号： C08G63/00 , C08G63/18 , C08G63/181 , C08G63/672 , C08G63/688 , D01F6/62 , D01F6/86 , C08G63/66
CPC分类号： C08G63/672 , C08G63/6886
摘要： A novel, substantially linear aromatic polyester comprising 6,6'-(ethylenedioxy)di-2-naphthoic acid as a main acid component and an aliphatic glycol having 2 to 10 carbon atoms in the main chain of the glycol as a main glycol component. The aromatic polyester is prepared by condensing an ethylene glycol diester of 6,6'-(ethylenedioxy)di-2-naphthoic acid, or a mixture of a major proportion of said naphthoate with a dicarboxylic acid, a diol, a hydroxycarboxylic acid or an ester-forming derivative thereof, at an elevated temperature. The aromatic polyester has excellent mechanical properties such as strength and Young's modulus.
摘要翻译：一种新型的基本上为线性的芳族聚酯，其包含作为主要酸成分的6,6' - （亚乙二氧基）二-2-萘甲酸和作为主要二元醇组分的二醇主链中具有2至10个碳原子的脂族二醇。芳族聚酯通过将6,6' - （亚乙二氧基）二-2-萘甲酸的乙二醇二酯或主要比例的所述萘甲酸酯的混合物与二羧酸，二醇，羟基羧酸或酯形成衍生物。芳族聚酯具有优异的机械性能，如强度和杨氏模量。

40. 发明授权

US4419308A Process for producing porous, film-like or fibrous structure of aromatic polyester 失效
标题翻译：生产芳族聚酯多孔，薄膜状或纤维结构的方法
公开(公告)号：US4419308A
公开(公告)日：1983-12-06
申请号：US479724
申请日：1983-03-28
申请人： Shunichi Matsumura , Hiroo Inata
发明人： Shunichi Matsumura , Hiroo Inata
IPC分类号： B01D67/00 , B01D71/48 , C08J9/26 , C08K5/34 , B29D27/04
CPC分类号： C08J9/26 , B01D67/0027 , B01D67/003 , B01D71/48 , C08K5/34 , C08J2367/02
摘要： A process for producing a porous, film-like or fibrous structure of an aromatic polyester, which comprises(1) forming a substantially non-oriented film-like or fibrous structure by melt-molding an aromatic polyester blend composed of(A) an aromatic polyester containing an aromatic dicarboxylic acid as a main acid component and an aliphatic diol and/or an alicyclic diol as a main glycol component, and(B) at least one low-molecular-weight compound selected from the group consisting of imide compounds and isocyanurate compounds being compatible, but substantially non-reactive, with the aromatic polyester and having a molecular weight of not more than 1,000, the amount of the low-molecular-weight compound being present in an amount of 10 to 300 parts by weight per 100 parts by weight of the aromatic polyester, and(2) extracting at least a major part of the low-molecular-weight compound from the resulting substantially non-oriented film-like or fibrous structure with an organic solvent which can dissolve the low-molecular-weight compound but under the extracting conditions does not substantially dissolve the aromatic polyester.
摘要翻译：一种制备芳族聚酯多孔，薄膜状或纤维结构体的方法，其包括（1）通过熔融模塑由（A）芳族化合物组成的芳族聚酯共混物形成基本上未取向的薄膜状或纤维结构体含有作为主要酸成分的芳香族二羧酸和脂肪族二醇和/或脂环式二醇作为主要二醇成分的聚酯，（B）至少一种选自酰亚胺化合物和异氰脲酸酯的低分子量化合物化合物与芳族聚酯相容但基本上不反应，分子量不超过1,000，低分子量化合物的量为每100份10至300重量份的芳族聚酯，和（2）从有机溶剂得到的基本上未取向的膜状或纤维结构中提取至少大部分低分子量化合物其可溶解低分子量化合物，但在萃取条件下基本上不溶解芳族聚酯。

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