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31. 发明授权

US08084167B2 Nanocomposite for fuel cell, method of preparing the nanocomposite, and fuel cell including the nanocomposite 有权
标题翻译：用于燃料电池的纳米复合材料，制备纳米复合材料的方法和包括纳米复合材料的燃料电池
公开(公告)号：US08084167B2
公开(公告)日：2011-12-27
申请号：US11985531
申请日：2007-11-14
申请人： Jeong-hee Lee , Jae-young Choi , Chan-ho Pak , Eun-ju Ra , Young-hee Lee , Kay-hyeok An
发明人： Jeong-hee Lee , Jae-young Choi , Chan-ho Pak , Eun-ju Ra , Young-hee Lee , Kay-hyeok An
IPC分类号： H01M4/02
CPC分类号： H01M4/92 , B82Y30/00 , D01F9/20 , D01F11/04 , H01M4/90 , H01M4/9083 , H01M4/926 , H01M2008/1095 , Y10S977/948
摘要： Provided is a nanocomposite for the catalyst layer of a fuel cell electrode including: a carbon nanofiber; and metal catalyst particles uniformly applied to the surface of the carbon nanofiber, wherein the carbon nanofiber has a surface oxygen content of at least 0.03 calculated by the formula: Oxygen content=[atomic percentage of oxygen/atomic percentage of carbon] using atomic percentages of oxygen and carbon, respectively calculated from an area of an oxygen peak having a binding energy of 524 to 540 eV, an area of a nitrogen peak having a binding energy of 392 to 404 eV, and an area of a carbon peak having a binding energy of 282 to 290 eV in X-ray photoelectron spectroscopy. The nanocomposite according to the present invention has high surface oxygen content and has metal catalyst nano particles densely and uniformly distributed on the outer wall of the carbon fibers, thereby having high electrochemical efficiency. Thus, efficiency of fuel cells can be improved using the nanocomposite.
摘要翻译：提供一种用于燃料电池电极的催化剂层的纳米复合材料，其包括：碳纳米纤维; 和金属催化剂颗粒均匀地施加到碳纳米纤维的表面上，其中碳纳米纤维的表面氧含量至少为0.03，由下式计算：氧含量= [原子百分比的氧/原子百分比的碳]使用原子百分比氧和碳分别由具有524至540eV的结合能的氧峰的面积，具有392至404eV的结合能的氮峰的面积和具有结合能的碳峰的面积计算在X射线光电子能谱中为282〜290eV。根据本发明的纳米复合材料具有高的表面氧含量，并且在碳纤维的外壁上密集均匀地分布有金属催化剂纳米颗粒，从而具有高的电化学效率。因此，可以使用纳米复合材料来提高燃料电池的效率。

32. 发明授权

US07910259B2 Anode for fuel cell, manufacturing method thereof, and fuel cell including the same 有权
标题翻译：燃料电池用阳极及其制造方法以及包含该阳极的燃料电池
公开(公告)号：US07910259B2
公开(公告)日：2011-03-22
申请号：US11445340
申请日：2006-06-02
申请人： Seol-ah Lee , Seung-jae Lee , Chan-ho Pak , Ji-rae Kim , Dae-jong Yoo
发明人： Seol-ah Lee , Seung-jae Lee , Chan-ho Pak , Ji-rae Kim , Dae-jong Yoo
IPC分类号： H01M8/14
CPC分类号： H01M4/8807 , H01M4/8605 , H01M4/8821 , H01M4/8828 , H01M4/92 , H01M4/928 , H01M8/0234 , H01M8/0245 , H01M2004/8684 , H01M2008/1095 , Y02P70/56
摘要： A method of manufacturing an anode for a fuel cell including: performing an acid treatment for a carbon-based compound; washing the resultant obtained from the acid treatment with water and then performing a freeze-drying (lyophilization) process; forming a microporous diffusion layer by dispersing the lyophilized resultant in a solvent, coating the dispersed resultant on a porous carbon support, and drying; and forming a catalyst layer on top of the microporous diffusion layer, an anode for a fuel cell obtained according to the method herein, and a fuel cell using the same. An anode having improved efficiency on liquid fuel diffusion can be obtained when using the fuel diffusion layer including the microporous diffusion layer formed of the carbon-based compounds obtained after an acid treatment and a freeze-drying process according to the present invention. A fuel cell having improved performance can be manufactured by using such an anode.
摘要翻译：一种制造燃料电池用阳极的方法，包括：对碳系化合物进行酸处理; 用水洗涤从酸处理得到的结果，然后进行冷冻干燥（冷冻干燥）处理; 通过将冻干的产物分散在溶剂中形成微孔扩散层，将分散的产物涂布在多孔碳载体上并干燥; 以及在微多孔扩散层的顶部形成催化剂层，根据本文方法得到的燃料电池用阳极和使用该催化剂的燃料电池。当使用包括由根据本发明的酸处理和冷冻干燥处理之后获得的碳基化合物形成的微孔扩散层的燃料扩散层时，可以获得提高液体燃料扩散效率的阳极。可以通过使用这种阳极来制造具有改进性能的燃料电池。

33. 发明授权

US07718570B2 Carbon molecular sieve and method for manufacturing the same 有权
标题翻译：碳分子筛及其制造方法
公开(公告)号：US07718570B2
公开(公告)日：2010-05-18
申请号：US10949525
申请日：2004-09-27
申请人： Chan-ho Pak , Ji-man Kim , Hyung-ik Lee
发明人： Chan-ho Pak , Ji-man Kim , Hyung-ik Lee
IPC分类号： C01B31/08
CPC分类号： H01M4/926 , B01J20/20 , B01J20/28057 , B01J20/2808 , B01J20/30 , B01J20/3057 , B01J21/18 , B01J23/42 , B01J37/0018 , B01J37/084 , C01B32/00 , H01M4/92
摘要： A method for manufacturing a carbon molecular sieve with increased microporosity; a method for manufacturing a carbon molecular sieve with increased microporosity and improved structural regularity; a carbon molecular sieve with increased microporosity; a carbon molecular sieve with increased microporosity and improved structural regularity; a catalyst for a fuel cell using the carbon molecular sieve; and a fuel cell using the catalyst are provided.
摘要翻译：具有增加的微孔的碳分子筛的制造方法; 制造具有增加的微孔性和改善的结构规整性的碳分子筛的方法; 具有增加的微孔的碳分子筛; 具有增加的微孔和增加的结构规律性的碳分子筛; 用于使用碳分子筛的燃料电池的催化剂; 并提供使用该催化剂的燃料电池。

34. 发明申请

US20080176129A1 Nanocomposite for fuel cell, method of preparing the nanocomposite, and fuel cell including the nanocomposite 有权
标题翻译：用于燃料电池的纳米复合材料，制备纳米复合材料的方法和包括纳米复合材料的燃料电池
公开(公告)号：US20080176129A1
公开(公告)日：2008-07-24
申请号：US11985531
申请日：2007-11-14
申请人： Jeong-hee Lee , Jae-young Choi , Chan-ho Pak , Eun-ju Ra , Young-hee Lee , Kay-hyeok An
发明人： Jeong-hee Lee , Jae-young Choi , Chan-ho Pak , Eun-ju Ra , Young-hee Lee , Kay-hyeok An
IPC分类号： H01M4/86 , B29C47/00
CPC分类号： H01M4/92 , B82Y30/00 , D01F9/20 , D01F11/04 , H01M4/90 , H01M4/9083 , H01M4/926 , H01M2008/1095 , Y10S977/948
摘要： Provided is a nanocomposite for the catalyst layer of a fuel cell electrode including: a carbon nanofiber; and metal catalyst particles uniformly applied to the surface of the carbon nanofiber, wherein the carbon nanofiber has a surface oxygen content of at least 0.03 calculated by the formula: Oxygen content=[atomic percentage of oxygen/atomic percentage of carbon] using atomic percentages of oxygen and carbon, respectively calculated from an area of an oxygen peak having a binding energy of 524 to 540 eV, an area of a nitrogen peak having a binding energy of 392 to 404 eV, and an area of a carbon peak having a binding energy of 282 to 290 eV in X-ray photoelectron spectroscopy. The nanocomposite according to the present invention has high surface oxygen content and has metal catalyst nano particles densely and uniformly distributed on the outer wall of the carbon fibers, thereby having high electrochemical efficiency. Thus, efficiency of fuel cells can be improved using the nanocomposite.
摘要翻译：提供一种用于燃料电池电极的催化剂层的纳米复合材料，其包括：碳纳米纤维; 和金属催化剂颗粒均匀地施加到碳纳米纤维的表面上，其中碳纳米纤维的表面氧含量至少为0.03，由下式计算：氧含量= [原子百分比的氧/原子百分比的碳]使用原子百分比氧和碳分别由具有524至540eV的结合能的氧峰的面积，具有392至404eV的结合能的氮峰的面积和具有结合能的碳峰的面积计算在X射线光电子能谱中为282〜290eV。根据本发明的纳米复合材料具有高的表面氧含量，并且在碳纤维的外壁上密集均匀地分布有金属催化剂纳米颗粒，从而具有高的电化学效率。因此，可以使用纳米复合材料来提高燃料电池的效率。

35. 发明申请

US20080107956A1 CATALYST USED TO FORM FUEL CELL AND FUEL CELL USING THE SAME 审中-公开
标题翻译：用于形成燃料电池和燃料电池的催化剂
公开(公告)号：US20080107956A1
公开(公告)日：2008-05-08
申请号：US11690341
申请日：2007-03-23
申请人： Dae-jong Yoo , Chan-ho Pak , Hyuk Chang , Sang-hoon Joo
发明人： Dae-jong Yoo , Chan-ho Pak , Hyuk Chang , Sang-hoon Joo
IPC分类号： H01M4/92 , B01J23/14 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/52 , H01M4/88 , H01M4/90
CPC分类号： H01M4/92 , H01M4/8657 , H01M4/8885
摘要： A catalyst, a method of preparing the catalyst, and a fuel cell using the catalyst. The catalyst includes a catalyst metal particle, and a porous coating layer of a conductive ceramic material disposed on the surface of the catalyst metal particle. The catalyst has a methanol tolerance index of 80%, or more, a smaller particle size than a commercially available Pt-black catalyst manufactured through a polyol process. The catalyst can include a PT catalyst metal particle that is surface treated, or coated, with a conductive ceramic ATO. The catalyst has an excellent ORR activity in the presence of methanol, and an enhanced tolerance with respect to methanol. A fuel cell, including an electrode manufactured using the catalyst, has a high energy density and a high fuel efficiency.
摘要翻译：催化剂，制备催化剂的方法和使用该催化剂的燃料电池。催化剂包括催化剂金属颗粒和设置在催化剂金属颗粒表面上的导电陶瓷材料的多孔涂层。与通过多元醇法制造的市售Pt-black催化剂相比，催化剂的甲醇耐受指数为80％以上，粒径小。催化剂可以包括用导电陶瓷ATO进行表面处理或涂覆的PT催化剂金属颗粒。该催化剂在甲醇存在下具有优异的ORR活性，并且相对于甲醇具有增强的耐受性。包括使用该催化剂制造的电极的燃料电池具有高能量密度和高燃料效率。

36. 发明申请

US20070196258A1 Desulfurizer for fuel gas for fuel cell and desulfurization method using the same 有权
标题翻译：燃料电池用燃气脱硫装置及其脱硫方法
公开(公告)号：US20070196258A1
公开(公告)日：2007-08-23
申请号：US11656377
申请日：2007-01-23
申请人： Doo-hwan Lee , Soon-ho Kim , Hyun-chul Lee , Eun-duck Park , Eun-yong Ko , Chan-ho Pak , Woo-sung Jeon
发明人： Doo-hwan Lee , Soon-ho Kim , Hyun-chul Lee , Eun-duck Park , Eun-yong Ko , Chan-ho Pak , Woo-sung Jeon
IPC分类号： B01D53/86 , C01B21/00 , B01J8/00
CPC分类号： B01D53/0407 , B01D2253/108 , B01D2253/1085 , B01D2253/30 , B01D2257/30 , B01D2257/306 , B01D2258/0208 , B01D2259/402 , H01M8/0675 , Y02C20/20 , Y02P10/146
摘要： A desulfurizer for fuel gas for a fuel cell includes: a first adsorption tank including an adsorber having selective adsorption capacity for a thiophene-based compound and a second adsorption tank including an adsorber having selective adsorption capacity for a mercaptan-based compound. The desulfurizer uses separate adsorbers having selective adsorption capacity for a thiophene-based compound and a mercaptan-based compound, in multiple stages to perform a more efficient and economical desulfurizing of a fuel gas to remove various sulfur compounds, especially thiophene-based compounds and mercaptan-based compounds compared to a desulfurizer using a single adsorber.
摘要翻译：燃料电池用燃料气体脱硫装置包括：具有对噻吩系化合物具有选择吸附能力的吸附剂的第一吸附槽和具有对硫醇类化合物具有选择性吸附容量的吸附剂的第二吸附槽。脱硫剂使用对噻吩类化合物和硫醇类化合物具有选择性吸附容量的分离吸附剂，其分级为多级，以进行更有效和经济的燃料气脱硫以除去各种硫化合物，特别是噻吩类化合物和硫醇与使用单一吸附器的脱硫剂相比。

37. 发明申请

US20070059585A1 Supported catalyst, electrode using the supported catalyst and fuel cell including the electrode 有权
标题翻译：负载催化剂，使用负载催化剂的电极和包括电极的燃料电池
公开(公告)号：US20070059585A1
公开(公告)日：2007-03-15
申请号：US11445333
申请日：2006-06-02
申请人： Dae-jong Yoo , Chan-ho Pak , Seol-ah Lee
发明人： Dae-jong Yoo , Chan-ho Pak , Seol-ah Lee
IPC分类号： H01M4/96 , H01M4/92 , B01J21/18
CPC分类号： B01J23/38 , B01J21/18 , B01J23/40 , B01J23/42 , B01J35/0013 , B01J37/0244 , H01M4/8842 , H01M4/92 , H01M4/926 , H01M8/1007 , H01M8/1011 , Y02E60/523 , Y02P70/56 , Y10T428/2991
摘要： Provided are a supported catalyst, an electrode including the same, and a fuel cell using the electrode. The supported catalyst includes a carbon-based catalyst support and metal catalyst particles having an average diameter of 3.5 to 5 nm and an amount of 80 to 90 parts by weight based on 100 parts by weight of the supported catalyst in a multi-layer structure adsorbed on a surface of the carbon-based catalyst support. In the supported catalyst of the present invention, as small metal catalyst particles with an average diameter of 3.5 to 5 nm are dispersed with high concentration, high dispersion, and the multi-layer structure, catalytic efficiency is increased. A fuel cell having improved energy density and fuel efficiency characteristics can be prepared using an electrode formed using the supported catalyst.
摘要翻译：提供了一种负载型催化剂，包括该催化剂的电极和使用该电极的燃料电池。载体催化剂包括碳基催化剂载体和平均直径为3.5至5nm的金属催化剂颗粒和基于100重量份吸附的多层结构中的负载型催化剂的量为80至90重量份的金属催化剂载体在碳基催化剂载体的表面上。在本发明的负载型催化剂中，作为平均粒径为3.5〜5nm的小金属催化剂粒子以高浓度，高分散性，多层结构分散，催化效率提高。可以使用使用负载的催化剂形成的电极来制备具有改善的能量密度和燃料效率特性的燃料电池。

38. 发明申请

US20060116284A1 Mesoporous carbon composite containing carbon nanotube 失效
公开(公告)号：US20060116284A1
公开(公告)日：2006-06-01
申请号：US11265177
申请日：2005-11-03
申请人： Chan-ho Pak , Hyuk Chang , Dae-jong Yoo , Ji-man Kim
发明人： Chan-ho Pak , Hyuk Chang , Dae-jong Yoo , Ji-man Kim
IPC分类号： B01J21/18
CPC分类号： B01J21/185 , B01J23/42 , B01J29/0308 , B01J35/10 , B01J35/1061 , B82Y30/00 , C01B33/124 , C01B37/02 , C04B35/14 , C04B35/521 , C04B35/524 , C04B35/80 , C04B35/83 , C04B38/00 , C04B38/0045 , C04B38/045 , C04B2111/0081 , C04B2111/00853 , C04B2235/3201 , C04B2235/3217 , C04B2235/483 , C04B2235/5288 , C04B2235/6028 , H01M4/8673 , H01M4/92 , H01M4/926 , H01M2008/1095 , C04B14/026 , C04B28/24 , C04B38/0054 , C04B28/26 , C04B38/0022 , C04B38/0064
摘要： Provided are a CNT-mesoporous silica composite, a CNT-mesoporous carbon composite, a supported catalyst using the CNT-mesoporous carbon composite as a support, and a fuel cell using the supported catalyst as the anode, cathode, or both anode and cathode. The CNT-mesoporous carbon composite is prepared using the CNT-mesoporous silica composite. The CNT-mesoporous carbon composite has a high electrical conductivity due to the CNTs contained therein, and thus, when the CNT-mesoporous carbon composite is used in an electrode of a fuel cell, the fuel cell has a remarkably improved performance relative to the conventional catalyst support which does not contain CNTs.

39. 发明申请

US20050036935A1 Carbon molecular sieve and method for manufacturing the same 有权
标题翻译：碳分子筛及其制造方法
公开(公告)号：US20050036935A1
公开(公告)日：2005-02-17
申请号：US10949525
申请日：2004-09-27
申请人： Chan-ho Pak , Ji-man Kim , Hyung-ik Lee
发明人： Chan-ho Pak , Ji-man Kim , Hyung-ik Lee
IPC分类号： C04B38/04 , B01J20/20 , B01J20/30 , B01J21/18 , B01J23/42 , B01J29/03 , B01J37/00 , B01J37/08 , C01B31/00 , C01B31/02 , C01B37/00 , C04B35/52 , C04B41/88 , H01M4/90 , H01M4/92 , H01M4/96
CPC分类号： H01M4/926 , B01J20/20 , B01J20/28057 , B01J20/2808 , B01J20/30 , B01J20/3057 , B01J21/18 , B01J23/42 , B01J37/0018 , B01J37/084 , C01B32/00 , H01M4/92
摘要： A method for manufacturing a carbon molecular sieve with increased microporosity; a method for manufacturing a carbon molecular sieve with increased microporosity and improved structural regularity; a carbon molecular sieve with increased microporosity; a carbon molecular sieve with increased microporosity and improved structural regularity; a catalyst for a fuel cell using the carbon molecular sieve; and a fuel cell using the catalyst are provided.
摘要翻译：具有增加的微孔的碳分子筛的制造方法; 制造具有增加的微孔性和改善的结构规整性的碳分子筛的方法; 具有增加的微孔的碳分子筛; 具有增加的微孔和增加的结构规律性的碳分子筛; 用于使用碳分子筛的燃料电池的催化剂; 并提供使用该催化剂的燃料电池。

40. 发明授权

US5814577A Catalyst and fabrication method of same for purifying exhaust gases of automobile 失效
标题翻译：用于净化汽车废气的催化剂及其制备方法
公开(公告)号：US5814577A
公开(公告)日：1998-09-29
申请号：US728121
申请日：1996-10-09
申请人： Sang-cheol Park , Chan-ho Pak
发明人： Sang-cheol Park , Chan-ho Pak
IPC分类号： B01J23/10 , B01D53/94 , B01J23/83 , B01J23/89 , B01J37/02
CPC分类号： B01D53/945 , B01J23/83 , B01J23/894 , B01J37/0248 , B01D2255/206 , B01D2255/20746 , B01D2255/40 , B01D2255/908 , Y02T10/22
摘要： A catalyst capable of purifying exhaust gases comprising an oxygen absorbing material and a carrier impregnated with a noble metal, and wherein the oxygen absorbing material comprises cobalt-cerium oxide.
摘要翻译：一种能够净化含氧吸收材料的废气和浸渍有贵金属的载体的催化剂，其中所述氧吸收材料包括氧化钴 - 氧化铈。

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