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    • 34. 发明授权
    • Developer for photopolymerizable presensitized plate for use in making lithographic printing plate and method for preparing lithographic printing plate
    • 用于制备平版印刷版的光聚合预敏板的显影剂和制备平版印刷版的方法
    • US06641980B2
    • 2003-11-04
    • US10187605
    • 2002-07-03
    • Hiroyuki NagaseKazuto Kunita
    • Hiroyuki NagaseKazuto Kunita
    • G03F730
    • G03F7/322G03F7/027
    • A developer for a photopolymerizable presensitized plate for use in making a lithographic printing plate characterized in that it comprises an alkali silicate and a nonionic compound represented by the following general formula (I), it has a molar ratio: SiO2/M2O (wherein M represents an alkali metal or an ammonium group) ranging from 0.75 to 4.0, a pH value ranging from 11.5 to 12.8 and a conductivity ranging from 3 to 30 mS/cm: A—W  (I) wherein A represents a hydrophobic organic group whose logP as determined for A—H is not less than 1.5 and W represents a nonionic hydrophilic organic group whose logP as determined for W—H is less than 1.0; a method for preparing a lithographic printing plate comprising the steps of imagewise exposing, to light, a presensitized plate for use in making a lithographic printing plate, which comprises a substrate provided thereon with a photopolymerizable light-sensitive layer containing a compound having at least one addition-polymerizable ethylenically unsaturated double bond and a photopolymerization initiator; and then developing the exposed presensitized plate using the above developer. The developers and the method for making a lithographic printing plate according to the present invention can prevent scumming during printing and simultaneously attain sufficient printing durability without impairment of image-forming performance, and the developer can dissolve or disperse stably for a long period of time the compounds which are not soluble in the developer, and therefore the running performance of the developer can be excellent and stabilized.
    • 一种用于制备平版印刷版的可光聚合预敏板的显影剂,其特征在于其包含碱式硅酸盐和由以下通式(I)表示的非离子化合物,其摩尔比为SiO 2 / M 2 O(其中M表示 碱金属或铵基),其pH值范围为11.5至12.8,电导率范围为3至30mS / cm:其中A表示疏水性有机基团,其对于AH确定的logP值不小于 W1表示非离子亲水性有机基团,其对于WH测定的logP小于1.0; 一种制备平版印刷版的方法,包括以下步骤:成像曝光用于制备平版印刷版的预敏化板,其包括在其上设置有可光聚合的感光层的基材,所述光致聚合感光层含有至少一种 可加成聚合的烯属不饱和双键和光聚合引发剂; 然后使用上述显影剂显影出曝光的敏化板。 根据本发明的显影剂和制造平版印刷版的方法可以防止印刷过程中的浮渣并同时获得足够的印刷耐久性而不损害图像形成性能,并且显影剂可以长时间稳定地溶解或分散 不溶于显影剂的化合物,因此显影剂的运行性能可以优异且稳定。
    • 35. 发明授权
    • Photosensitive resin composition, image recording material, and planographic printing plate using the same
    • 感光树脂组合物,图像记录材料和使用其的平版印刷版
    • US06391519B1
    • 2002-05-21
    • US09362882
    • 1999-07-29
    • Kazuto Kunita
    • Kazuto Kunita
    • G03F7004
    • B41N1/08B41C1/1008B41C2210/02B41C2210/04B41C2210/06B41C2210/20B41C2210/22B41C2210/24B41C2210/262
    • An image recording material or photosensitive resin composition comprising: (A-1) a phenolic polymer having a structural unit represented by the following general formula I-(1) on a polymer backbone; (A-2) a polymer which has a structural unit represented by the following general formula II-(1) as a polymer backbone or a structural unit represented by the following general formula II-(2) as a side chain attached to a polymer backbone and which has a phenolic hydroxyl group; or (A-3) a mixture comprising a polymer having a phenolic hydroxyl group and a polymer which has a structural unit represented by the following general formula II-(1) as a polymer backbone or a structural unit represented by the following general formula II-(2) as a side chain of attached to a polymer backbone; and (B) an infrared ray absorbing agent. A planographic printing plates using the above-described image recording material and photosensitive resin composition is also provided
    • 一种图像记录材料或感光性树脂组合物,其包含:(A-1)在聚合物主链上具有由以下通式I-1表示的结构单元的酚醛聚合物;(A-2)具有结构单元 由以下通式II-(1)表示为聚合物主链或由以下通式II-(2)表示的结构单元作为连接于聚合物主链并具有酚羟基的侧链; 或(A-3)包含具有酚羟基的聚合物和具有由以下通式II-(1)表示的结构单元作为聚合物主链或由以下通式II表示的结构单元的聚合物的混合物 - (2)作为连接到聚合物骨架的侧链; 和(B)红外线吸收剂。 还提供了使用上述图像记录材料和感光性树脂组合物的平版印刷版
    • 38. 发明授权
    • Photopolymerizable composition
    • 可光聚合组合物
    • US5939465A
    • 1999-08-17
    • US903058
    • 1997-07-30
    • Kazuto KunitaYasuo Okamoto
    • Kazuto KunitaYasuo Okamoto
    • G03F7/027C08F2/50G03F7/00G03F7/029G03F7/075H01L21/027H05K3/06G03F7/038
    • G03F7/029C08F2/50G03F7/0755
    • A photopolymerizable composition comprises (i) a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 each independently represents a hydrogen atom, a cyano group, a substituted carbonyl group, a substituted or unsubstituted, alkyl group, aryl group, alkenyl group, or alkynyl group; R.sup.3, R.sup.4 and R.sup.5 each independently represents a substituted or unsubstituted, alkyl group, aryl group, alkenyl group, or alkynyl group; Z represents a nonmetallic atom group necessary for forming a heterocyclic nucleus containing an N atom; n represents an integer of 0, 1 or 2; and G.sup.1 and G.sup.2 each independently represents a hydrogen atom, a cyano group, a substituted, carbonyl group, oxy group, amino group, thio group, sulfonyl group, sulfinyl group or an atomic group represented by formula (II) described in the specification, provided that G.sup.1 and G.sup.2 are not a hydrogen atom at the same time, (ii) a compound containing at least one addition-polymerizable, ethylenically unsaturated bond and (iii) a compound which generates an active radical upon irradiation of light in the presence of component (i) together.
    • 光聚合性组合物包含(i)由式(I)表示的化合物:其中R 1和R 2各自独立地表示氢原子,氰基,取代的羰基,取代或未取代的烷基,芳基,烯基, 或炔基; R 3,R 4和R 5各自独立地表示取代或未取代的烷基,芳基,烯基或炔基; Z表示形成含有N原子的杂环的必需的非金属原子团; n表示0,1或2的整数; G1,G2各自独立地表示本说明书中记载的式(II)所示的氢原子,氰基,取代的羰基,氧基,氨基,硫基,磺酰基,亚磺酰基或原子团, 条件是G1和G2同时不是氢原子,(ii)含有至少一个可加成聚合的烯属不饱和键的化合物和(iii)在光照射下存在时产生活性自由基的化合物 组分(i)在一起。