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31. 发明申请

US20090025640A1 FORMATION OF CIGS ABSORBER LAYER MATERIALS USING ATOMIC LAYER DEPOSITION AND HIGH THROUGHPUT SURFACE TREATMENT 审中-公开
标题翻译：使用原子层沉积和高通量表面处理形成CIGS吸收层材料
公开(公告)号：US20090025640A1
公开(公告)日：2009-01-29
申请号：US12110252
申请日：2008-04-25
申请人： Brian M. Sager , Craig R. Leidholm , Martin R. Roscheisen
发明人： Brian M. Sager , Craig R. Leidholm , Martin R. Roscheisen
IPC分类号： C23C16/458
CPC分类号： C23C16/45544 , C23C16/405 , C23C16/458 , C23C16/4581 , C23C16/545 , C25D7/0614 , C25D17/02 , H01L31/022425 , H01L31/0322 , H01L31/0392 , H01L31/03926 , H01L31/1864 , H01L31/1876 , Y02E10/541 , Y02P70/521
摘要： An absorber layer may be formed on a substrate using atomic layer deposition reactions. An absorber layer containing elements of groups IB, IIIA and VIB may be formed by placing a substrate in a treatment chamber and performing atomic layer deposition of a group IB element and/or one or more group IIIA elements from separate sources onto a substrate to form a film. A group VIA element is then incorporated into the film and annealed to form the absorber layer. The absorber layer may be greater than about 25 nm thick. The substrate may be coiled into one or more coils in such a way that adjacent turns of the coils do not touch one another. The coiled substrate may be placed in a treatment chamber where substantially an entire surface of the one or more coiled substrates may be treated by an atomic layer deposition process. One or more group IB elements and/or one or more group IIIA elements may be deposited onto the substrate in a stoichiometrically controlled ratio by atomic layer deposition using one or more self limiting reactions.
摘要翻译：可以使用原子层沉积反应在衬底上形成吸收层。包含IB，IIIA和VIB族元素的吸收层可以通过将基底放置在处理室中并且将IB族元素和/或一种或多种IIIA族元素从单独的源原子层沉积到基底上形成，以形成一个电影。然后将VIA族元素并入膜中并退火以形成吸收层。吸收层可以大于约25nm厚。衬底可以被卷绕成一个或多个线圈，使得线圈的相邻匝不彼此接触。卷绕的基板可以放置在处理室中，其中可以通过原子层沉积工艺来处理一个或多个卷绕的基板的基本上整个表面。可以通过使用一个或多个自限制反应的原子层沉积以化学计量控制的比例将一个或多个IB族元素和/或一个或多个IIIA族元素沉积到基底上。

32. 发明授权

US07462774B2 Photovoltaic devices fabricated from insulating nanostructured template 失效
标题翻译：由绝缘纳米结构模板制造的光伏器件
公开(公告)号：US07462774B2
公开(公告)日：2008-12-09
申请号：US10771250
申请日：2004-02-02
申请人： Martin R. Roscheisen , Brian M. Sager , Karl Pichler
发明人： Martin R. Roscheisen , Brian M. Sager , Karl Pichler
IPC分类号： H01L31/00 , H02N6/00
CPC分类号： H01L51/4233 , B82Y10/00 , H01L31/0352 , H01L31/03529 , H01L51/0035 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0047 , H01L51/0051 , H01L51/0052 , H01L51/0053 , H01L51/0078 , H01L51/0094 , H01L51/4213 , H01L51/422 , H01L51/4226 , H01L51/4253 , H01L51/447 , Y02E10/549
摘要： Photovoltaic devices, such as solar cells, and methods for their manufacture are disclosed. A device may be characterized by an architecture with an inorganic insulating nanostructured template having template elements between about 1 nm and about 500 nm in diameter with a elements density of between about 1012 elements/m2 and about 1016 elements/m2. A first charge-transfer material coats the walls of the template elements leaving behind additional space. A second charge-transfer material fills the additional space such that the first and second charge-transfer materials are volumetrically interdigitated. At least one charge transfer material has an absorbance of greater than about 103/cm. The first and second charge-transfer materials have complementary charge transfer properties with respect to each other. A lowest unoccupied molecular orbital (LUMO) or conduction band of the first charge-transfer material is offset from a LUMO or conduction band of the second charge-transfer material by greater than about 0.2 eV. An electrically conductive material may optionally be disposed between the nanostructured template and the first charge-transfer material.
摘要翻译：公开了太阳能电池等光伏器件及其制造方法。器件的特征可以在于具有无机绝缘纳米结构化模板的结构，其具有直径在约1nm至约500nm之间的模板元件，元件密度为约1012个元/ m 2至约10 16个元/ m 2。第一电荷转移材料涂覆模板元件的壁，留下额外的空间。第二电荷转移材料填充附加空间，使得第一和第二电荷转移材料是体积相互交错的。至少一种电荷转移材料的吸光度大于约103 / cm。第一和第二电荷转移材料相对于彼此具有互补的电荷转移性质。第一电荷转移材料的最低未占分子轨道（LUMO）或导带从第二电荷转移材料的LUMO或导带偏移大于约0.2eV。导电材料可以任选地设置在纳米结构化模板和第一电荷转移材料之间。

33. 发明授权

US07253017B1 Molding technique for fabrication of optoelectronic devices 有权
标题翻译：用于制造光电器件的成型技术
公开(公告)号：US07253017B1
公开(公告)日：2007-08-07
申请号：US10303665
申请日：2002-11-22
申请人： Martin R. Roscheisen , Brian M. Sager , Jacqueline Fidanza , Klaus Petritsch , Gregory A. Miller , Dong Yu
发明人： Martin R. Roscheisen , Brian M. Sager , Jacqueline Fidanza , Klaus Petritsch , Gregory A. Miller , Dong Yu
IPC分类号： H01L21/00
CPC分类号： B82Y30/00 , H01L31/0352 , H01L31/03529 , H01L51/0015 , H01L51/422 , H01L51/4253 , Y02E10/549
摘要： Charge splitting networks for optoelectronic devices may be fabricated using a nanostructured porous film, e.g., of SiO2, as a template. The porous film may be fabricated using surfactant temptation techniques. Any of a variety of semiconducting materials including semiconducting metals and metal oxides (such as TiO2, CdSe, CdS, CdTe, or CuO) may be deposited into the pores of the porous template film. After deposition, the template film may be removed by controlled exposure to acid or base without disrupting the semiconducting material leaving behind a nanoscale network grid. Spaces in the network grid can then be filled with complementary semiconducting material, e.g., a semiconducting polymer or dye to create a exciton-splitting and charge transporting network with superior optoelectronic properties for an optoelectronic devices, particularly photovoltaic devices.
摘要翻译：用于光电子器件的电荷分束网络可以使用纳米结构多孔膜（例如SiO 2）作为模板来制造。多孔膜可以使用表面活性剂诱导技术制造。包括半导体金属和金属氧化物（例如TiO 2，CdSe，CdS，CdTe或CuO）的各种半导体材料中的任何一种可以沉积到多孔模板膜的孔中。沉积后，可以通过控制暴露于酸或碱而不破坏半导体材料留下纳米尺度网格来除去模板膜。然后可以用互补半导体材料（例如半导体聚合物或染料）填充网格中的空间，以产生具有用于光电子器件，特别是光伏器件的优异光电子性质的激子分裂和电荷传输网络。

34. 发明申请

US20100269428A1 Cost Effective, Elongate Member Mounting System For Photovoltaic Devices 审中-公开
标题翻译：光伏器件成本效益高的成员安装系统
公开(公告)号：US20100269428A1
公开(公告)日：2010-10-28
申请号：US12601240
申请日：2008-05-23
申请人： Robert Stancel , Martin R. Roscheisen , Jeremy H. Scholz
发明人： Robert Stancel , Martin R. Roscheisen , Jeremy H. Scholz
IPC分类号： E04D13/18 , F16M13/00 , E04B1/38
CPC分类号： H02S20/23 , F24S25/16 , F24S25/33 , F24S25/50 , F24S25/61 , F24S25/636 , F24S2025/6008 , Y02B10/12 , Y02B10/20 , Y02E10/47
摘要： Methods and devices are provided for improved rooftop solar module mounting assemblies. In one embodiment, an assembly is provided for mounting a plurality of photovoltaic devices over a roof surface. The assembly comprises of a plurality of elongate metal rods, wherein the elongate metal rods are connected together to define a support grid; a plurality of non-roof penetrating grid supports configured to elevate the support grid above the roof surface; and a plurality of grid-to-roof anchors that secure the entire support grid over the roof surface, wherein the number of grid-to-roof anchors is less than about ¼ of the number of non-roof penetrating grid supports to minimize the number of locations where water may enter the roof surface.
摘要翻译：提供了改进屋顶太阳能模块安装组件的方法和装置。在一个实施例中，提供了用于将多个光伏器件安装在屋顶表面上的组件。组件包括多个细长金属杆，其中细长金属杆连接在一起以限定支撑格栅; 多个非屋顶穿透网格支撑件，其构造成将支撑栅格提升到屋顶表面上方; 以及将整个支撑格栅固定在屋顶表面上的多个格栅到屋顶的锚固件，其中网格到屋顶锚的数量小于非屋顶穿透网格支撑件的数量的大约1/4，以最小化数量水可能进入屋顶表面的位置。

35. 发明申请

US20100218441A1 Wind Uplift Resistant Module Mounting System 审中-公开
标题翻译：防风升降模块安装系统
公开(公告)号：US20100218441A1
公开(公告)日：2010-09-02
申请号：US12626878
申请日：2009-11-27
申请人： Robert Stancel , Martin R. Roscheisen
发明人： Robert Stancel , Martin R. Roscheisen
IPC分类号： E04D13/18
CPC分类号： H02S20/00 , F24S25/16 , F24S25/35 , F24S25/50 , F24S25/61 , F24S25/634 , F24S40/85 , F24S2025/014 , F24S2025/017 , H02S20/24 , H02S20/30 , Y02B10/12 , Y02B10/20 , Y02E10/47 , Y02E10/50
摘要： Methods and devices are provided for improved rooftop solar module mounting assemblies. In one embodiment, an assembly is provided for mounting a plurality of photovoltaic devices over a roof surface. The assembly comprises of a plurality of elongate metal rods, wherein the elongate metal rods are connected together to define a support grid; a plurality of non-roof penetrating grid supports configured to elevate the support grid above the roof surface, wherein the panels are grouped to define a rigid combination of modules and beams wherein the combination covers sufficient area and has sufficient rigidity which minimizes the risk of module lift off. Some embodiments are non-ballasted systems without features added to increase the weight of the system above a minimum required for conventional wind load ballasting for solar installations.
摘要翻译：提供了改进屋顶太阳能模块安装组件的方法和装置。在一个实施例中，提供了用于将多个光伏器件安装在屋顶表面上的组件。组件包括多个细长金属杆，其中细长金属杆连接在一起以限定支撑格栅; 多个非屋顶穿透网格支撑件，其被配置为提升顶板表面上方的支撑格栅，其中，所述面板被分组以限定模块和梁的刚性组合，其中所述组合覆盖足够的面积并且具有足够的刚性，从而最小化模块的风险升空。一些实施例是非压载系统，没有添加特征以将系统的重量提高到高于太阳能装置的常规风载荷镇流所需的最小值。

36. 发明授权

US07732232B2 Series interconnected optoelectronic device module assembly 失效
标题翻译：系列互连光电器件组件
公开(公告)号：US07732232B2
公开(公告)日：2010-06-08
申请号：US11865691
申请日：2007-10-01
申请人： James R. Sheats , Sam Kao , Gregory A. Miller , Martin R. Roscheisen
发明人： James R. Sheats , Sam Kao , Gregory A. Miller , Martin R. Roscheisen
IPC分类号： H01L21/00
CPC分类号： H01L31/0392 , H01L27/3204 , H01L31/03925 , H01L31/03928 , H01L31/046 , H01L31/0465 , H01L31/0749 , H01L31/18 , H01L51/5203 , Y02E10/541 , Y02P70/521
摘要： Series interconnection of optoelectronic device modules is disclosed. Each device module includes an active layer disposed between a bottom electrode and a transparent conducting layer. An insulating layer is disposed between the bottom electrode of a first device module and a backside top electrode of the first device module. One or more vias are formed through the active layer, transparent conducting layer and insulating layer of the first device module. Sidewalls of the vias are coated with an insulating material such that a channel is formed through the insulating material to the backside top electrode of the first device module. The channel is at least partially filled with an electrically conductive material to form a plug that makes electrical contact between the transparent conducting layer and the backside top electrode of the first device module. Portions of the backside top electrode and insulating layer of a second device module are cut back to expose a portion of the bottom electrode of the second device module. The first and second device modules are attached to an insulating carrier substrate. Electrical contact is made between the backside top electrode of the first device module and the exposed portion of the bottom electrode of the second device module.
摘要翻译：公开了光电器件模块的串联互连。每个器件模块包括设置在底部电极和透明导电层之间的有源层。绝缘层设置在第一器件模块的底部电极和第一器件模块的背面顶部电极之间。通过第一器件模块的有源层，透明导电层和绝缘层形成一个或多个通孔。通孔的侧壁涂覆有绝缘材料，使得通过绝缘材料形成通道到第一器件模块的背面顶部电极。通道至少部分地填充有导电材料以形成在第一器件模块的透明导电层和背面顶部电极之间形成电接触的插塞。背面顶部电极和第二器件模块的绝缘层的部分被切割以暴露第二器件模块的底部电极的一部分。第一和第二器件模块附接到绝缘载体衬底。在第一器件模块的背面顶部电极和第二器件模块的底部电极的暴露部分之间形成电接触。

37. 发明申请

US20110121353A1 OPTOELECTRONIC ARCHITECTURE HAVING COMPOUND CONDUCTING SUBSTRATE 失效
标题翻译：具有复合导体基板的光电结构
公开(公告)号：US20110121353A1
公开(公告)日：2011-05-26
申请号：US12952174
申请日：2010-11-22
申请人： James R. Sheats , Sam Kao , Martin R. Roscheisen
发明人： James R. Sheats , Sam Kao , Martin R. Roscheisen
IPC分类号： H01L33/62 , H01L31/0224
CPC分类号： H01L31/18 , H01L27/3204 , H01L31/0392 , H01L31/03923 , H01L31/03925 , H01L31/046 , H01L31/0463 , H01L31/0465 , H01L31/0749 , H01L51/5203 , Y02E10/541 , Y02P70/521
摘要： Optoelectronic device modules, arrays optoelectronic device modules and methods for fabricating optoelectronic device modules are disclosed. The device modules are made using a starting substrate having an insulator layer sandwiched between a bottom electrode made of a flexible bulk conductor and a conductive back plane. An active layer is disposed between the bottom electrode and a transparent conducting layer. One or more electrical contacts between the transparent conducting layer and the back plane are formed through the transparent conducting layer, the active layer, the flexible bulk conductor and the insulating layer. The electrical contacts are electrically isolated from the active layer, the bottom electrode and the insulating layer.
摘要翻译：公开了光电器件模块，阵列光电器件模块和用于制造光电器件模块的方法。器件模块使用具有夹在由柔性体导体制成的底电极和导电背面之间的绝缘体层的起始衬底制成。有源层设置在底部电极和透明导电层之间。通过透明导电层，有源层，柔性体导体和绝缘层形成透明导电层与背面之间的一个或多个电接触。电触点与有源层，底电极和绝缘层电隔离。

38. 发明申请

US20090178706A1 OPTOELECTRONIC ARCHITECTURE HAVING COMPOUND CONDUCTING SUBSTRATE 有权
标题翻译：具有复合导体基板的光电结构
公开(公告)号：US20090178706A1
公开(公告)日：2009-07-16
申请号：US12245734
申请日：2008-10-04
申请人： James R. Sheats , Sam Kao , Martin R. Roscheisen
发明人： James R. Sheats , Sam Kao , Martin R. Roscheisen
IPC分类号： H01L31/048 , H01L31/0216 , H01L31/042
CPC分类号： H01L31/18 , H01L27/3204 , H01L31/0392 , H01L31/03923 , H01L31/03925 , H01L31/046 , H01L31/0463 , H01L31/0465 , H01L31/0749 , H01L51/5203 , Y02E10/541 , Y02P70/521
摘要： Optoelectronic device modules, arrays optoelectronic device modules and methods for fabricating optoelectronic device modules are disclosed. The device modules are made using a starting substrate having an insulator layer sandwiched between a bottom electrode made of a flexible bulk conductor and a conductive back plane. An active layer is disposed between the bottom electrode and a transparent conducting layer. One or more electrical contacts between the transparent conducting layer and the back plane are formed through the transparent conducting layer, the active layer, the flexible bulk conductor and the insulating layer. The electrical contacts are electrically isolated from the active layer, the bottom electrode and the insulating layer.
摘要翻译：公开了光电器件模块，阵列光电器件模块和用于制造光电器件模块的方法。器件模块使用具有夹在由柔性体导体制成的底电极和导电背面之间的绝缘体层的起始衬底制成。有源层设置在底部电极和透明导电层之间。通过透明导电层，有源层，柔性体导体和绝缘层形成透明导电层与背面之间的一个或多个电接触。电触点与有源层，底电极和绝缘层电隔离。

39. 发明申请

US20080308148A1 Photovoltaic Devices With Conductive Barrier Layers and Foil Substrates 失效
标题翻译：具有导电阻挡层和箔基板的光伏器件
公开(公告)号：US20080308148A1
公开(公告)日：2008-12-18
申请号：US12064031
申请日：2006-08-16
申请人： Craig R. Leidholm , Brent Bollman , James R. Sheats , Sam Kao , Martin R. Roscheisen
发明人： Craig R. Leidholm , Brent Bollman , James R. Sheats , Sam Kao , Martin R. Roscheisen
IPC分类号： H01L31/00
CPC分类号： B82Y10/00 , H01L31/022425 , H01L31/02245 , H01L31/03928 , H01L31/046 , H01L31/0465 , H01L31/0512 , H01L31/0749 , H01L51/5203 , H01L2251/5338 , H02S20/23 , Y02B10/12 , Y02E10/541 , Y02P70/521
摘要： Methods and devices are provided for absorber layers formed on foil substrate. In one embodiment, a method of manufacturing photovoltaic devices may be comprised of providing a substrate comprising of at least one electrically conductive aluminum foil substrate, at least one electrically conductive diffusion barrier layer, and at least one electrically conductive electrode layer above the diffusion barrier layer. The diffusion barrier layer may prevent chemical interaction between the aluminum foil substrate and the electrode layer. An absorber layer may be formed on the substrate. In one embodiment, the absorber layer may be a non-silicon absorber layer. In another embodiment, the absorber layer may be an amorphous silicon (doped or undoped) absorber layer. Optionally, the absorber layer may be based on organic and/or inorganic materials.
摘要翻译：为在箔基片上形成的吸收层提供了方法和装置。在一个实施例中，制造光伏器件的方法可以包括提供包括至少一个导电铝箔衬底，至少一个导电扩散阻挡层和在扩散阻挡层上方的至少一个导电电极层的衬底。扩散阻挡层可以防止铝箔衬底和电极层之间的化学相互作用。可以在基板上形成吸收层。在一个实施例中，吸收层可以是非硅吸收层。在另一个实施例中，吸收层可以是非晶硅（掺杂或未掺杂）吸收层。任选地，吸收层可以基于有机和/或无机材料。

40. 发明授权

US08525152B2 Formation of solar cells with conductive barrier layers and foil substrates 失效
标题翻译：形成具有导电阻挡层和箔基板的太阳能电池
公开(公告)号：US08525152B2
公开(公告)日：2013-09-03
申请号：US12795594
申请日：2010-06-07
申请人： Craig Leidholm , Brent Bollman , James R. Sheats , Sam Kao , Martin R. Roscheisen
发明人： Craig Leidholm , Brent Bollman , James R. Sheats , Sam Kao , Martin R. Roscheisen
IPC分类号： H01L29/06 , H01L21/00
CPC分类号： B82Y10/00 , H01L31/022425 , H01L31/02245 , H01L31/03928 , H01L31/046 , H01L31/0465 , H01L31/0512 , H01L31/0749 , H01L51/5203 , H01L2251/5338 , H02S20/23 , Y02B10/12 , Y02E10/541 , Y02P70/521
摘要： Methods and devices are provided for absorber layers formed on foil substrate. In one embodiment, a method of manufacturing photovoltaic devices may be comprised of providing a substrate comprising of at least one electrically conductive aluminum foil substrate, at least one electrically conductive diffusion barrier layer, and at least one electrically conductive electrode layer above the diffusion barrier layer. The diffusion barrier layer may prevent chemical interaction between the aluminum foil substrate and the electrode layer. An absorber layer may be formed on the substrate. In one embodiment, the absorber layer may be a non-silicon absorber layer. In another embodiment, the absorber layer may be an amorphous silicon (doped or undoped) absorber layer. Optionally, the absorber layer may be based on organic and/or inorganic materials.
摘要翻译：为在箔基片上形成的吸收层提供了方法和装置。在一个实施例中，制造光伏器件的方法可以包括提供包括至少一个导电铝箔衬底，至少一个导电扩散阻挡层和在扩散阻挡层上方的至少一个导电电极层的衬底。扩散阻挡层可以防止铝箔衬底和电极层之间的化学相互作用。可以在基板上形成吸收层。在一个实施例中，吸收层可以是非硅吸收层。在另一个实施例中，吸收层可以是非晶硅（掺杂或未掺杂）吸收层。任选地，吸收层可以基于有机和/或无机材料。

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