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31. 发明授权

US4853477A Separation of diastereomers of cyclopropanecarboxylic acid esters 失效
标题翻译：环丙烷羧酸酯的非对映异构体的分离
公开(公告)号：US4853477A
公开(公告)日：1989-08-01
申请号：US87574
申请日：1987-08-20
申请人： Rainer Fuchs , Wilhelm Stendel
发明人： Rainer Fuchs , Wilhelm Stendel
IPC分类号： C07C69/747 , A01N53/00 , A01N53/08 , C07B57/00 , C07C51/487 , C07C67/00 , C07C67/60 , C07C253/00 , C07C255/39
CPC分类号： C07C51/487 , A01N53/00
摘要： A process for the separation of mutually diastereomeric forms of a cyclopropanecarboxylic acid ester of the formula ##STR1## in which R.sup.1 represents hydrogen or halogen,R.sup.2 represents hydrogen or halogen,R.sup.4 represents hydrogen, Cn, --C.dbd.CH or CH.sub.3,R.sup.5 represents hydrogen or halogen, andR.sup.6 represents hydrogen or halogen,comprising reacting such ester in a first stage with about half or an equal molar amount of a second compound of the formula ##STR2## in which R.sup.7, R.sup.8 and R.sup.9 represent hydrogen or methyl, or, together with the C atom to which they are bound and with the adjacent C atoms of the basic structure form a fused 6-membered ring,R.sup.10 represents hydrogen, methyl, ethyl, halogen, amino, methylamino or dimethylamino, andR.sup.11 represents hydrogen, methyl or ethyl,to form complexes and in a second stage allowing the less soluble complex of one part of the diastereomers to crystallize out in the presence of a solvent selected from the group consisting of a lower aliphatic alcohol or aliphatic or cyclic hydrocarbon, and separating off the crystallized complex from the still dissolved material. The first stage complexes are new and the resulting purified enantiomeric mixture is also new.
摘要翻译：分离相互非对映异构形式的式“IMAGE”的环丙烷羧酸酯的方法，其中R 1表示氢或卤素，R 2表示氢或卤素，R 4表示氢，C n，-C = CH或CH 3，R 5表示氢或卤素，并且R 6表示氢或卤素，包括使第一阶段中的这种酯与大约一半或等摩尔量的第二化学式为“IMAGE”的化合物反应，其中R 7，R 8和R 9表示氢或甲基，与其结合的C原子一起与碱性结构的相邻C原子一起形成稠合的6元环，R 10表示氢，甲基，乙基，卤素，氨基，甲基氨基或二甲基氨基，R 11表示氢，甲基或乙基，以形成复合物，并且在第二阶段中，使得一部分非对映异构体的较低溶解度的络合物在选自下列的溶剂的存在下结晶：低级脂族醇或脂族醇从而将结晶的络合物与仍溶解的物质分离出来。第一阶段复合物是新的，并且所得到的纯化的对映异构体混合物也是新的。

32. 发明授权

US4318922A Combating pests with fluorine-substituted 2,2,3,3-tetramethylcyclopropane-1-carboxylic acid benzyl esters 失效
标题翻译：防治害虫与氟取代的2,2,3,3-四甲基环丙烷-1-羧酸苄酯
公开(公告)号：US4318922A
公开(公告)日：1982-03-09
申请号：US198039
申请日：1980-10-17
申请人： Rainer Fuchs , Klaus Naumann , Hans-Jochem Riebel , Wolfgang Behrenz , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Klaus Naumann , Hans-Jochem Riebel , Wolfgang Behrenz , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C69/74 , A01N53/00 , A01N53/06 , A01N53/08 , B01J31/00 , C07C67/00 , C07C67/14 , C07C69/743 , C07C253/00 , C07C255/39 , C07C121/75
CPC分类号： A01N53/00
摘要： 2,2,3,3-Tetramethylcyclopropanecarboxylic acid fluorine-substituted-benzyl esters of the formula ##STR1## in which R.sup.1 is hydrogen, cyano, or alkyl, alkenyl or alkynyl each with up to 4 carbon atoms, andR.sup.2 is a phenyl radical which is substituted by halogen and/or by optionally halogen-substituted phenoxy, with the proviso that the radical R.sup.2 in total contains at least one fluorine substituent,which possess insecticidal and acaricidal properties.
摘要翻译：其中R 1是氢，氰基或各自具有至多4个碳原子的烷基，链烯基或炔基，R 2是苯基的2,2,3,3-四甲基环丙烷甲酸氟取代的苄基酯，其被卤素和/或任选被卤素取代的苯氧基取代，条件是基团R2总共含有至少一个具有杀虫和杀螨性质的氟取代基。

33. 发明授权

US4317834A Combating arthropods with fluorine-substituted spiro-carboxylic acid benzyl esters 失效
标题翻译：将节肢动物与氟取代的螺 - 羧酸苄酯相结合
公开(公告)号：US4317834A
公开(公告)日：1982-03-02
申请号：US203032
申请日：1980-11-03
申请人： Rainer Fuchs , Klaus Naumann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
发明人： Rainer Fuchs , Klaus Naumann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
IPC分类号： C07C69/753 , A01N53/00 , A01N53/06 , A01N53/08 , C07C67/00 , C07C253/00 , C07C255/39 , C07C121/75
CPC分类号： A01N53/00
摘要： Fluorine-substituted spirocarboxylic acid benzyl esters of the formula ##STR1## in which R.sup.1 represents hydrogen, cyano or alkyl, alkenyl or alkynyl, with in each case up to 4 carbon atoms,R.sup.2 represents a phenyl radical which is substituted by halogen and/or by optionally halogen-substituted phenoxy, with the proviso that the radical R.sup.2 contains in total at least one fluorine substituent, andR.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represent hydrogen, halogen or alkyl, orR.sup.3 and R.sup.4, taken together, and/or R.sup.5 and R.sup.6, taken together, represent alkanediyl (alkylene) or a fused-on benzo radical,and the C atoms of the 5-member spirocyclic ring are linked to one another either by double bonds or by single bonds, which possess arthropodicidal properties.
摘要翻译：氟取代的式“IMAGE”的螺羧酸苄基酯，其中R 1表示氢，氰基或烷基，烯基或炔基，在每种情况下最多4个碳原子，R 2表示被卤素和/或通过任选的卤素取代的苯氧基，条件是基团R 2总共含有至少一个氟取代基，并且R 3，R 4，R 5和R 6各自代表氢，卤素或烷基，或者R 3和R 4一起，和/或 R 5和R 6一起代表烷二基（亚烷基）或稠合的苯并基，5元螺环的C原子通过具有节肢动物特性的双键或单键彼此连接。

34. 发明授权

US4316913A Arthropodicidally active styrylcyclopropanecarboxylic acid esters 失效
标题翻译：节肢动物活性苯乙烯基环丙烷羧酸酯
公开(公告)号：US4316913A
公开(公告)日：1982-02-23
申请号：US136023
申请日：1980-03-31
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C67/08 , A01N53/00 , A01N53/08 , A01N53/10 , B01J31/00 , C07B61/00 , C07C62/34 , C07C67/00 , C07C69/743 , C07C69/757 , C07C253/00 , C07C255/39 , C07C255/53 , C07C313/00 , C07C323/62 , C07D317/46 , C07D317/60 , C07D319/20 , C07F9/40 , C07C121/75
CPC分类号： C07F9/4056 , A01N53/00 , C07C323/00 , C07C62/34 , C07D317/46 , C07D317/60 , C07D319/20
摘要： Substituted styrylcyclopropanecarboxylic acid esters of the formula ##STR1## in which R represents C.sub.1-4 -alkyl or an alcohol radical customary in pyrethroids,R.sup.1 represents alkoxy or alkylthio, either of which is optionally substituted by halogen andR.sup.2 represents hydrogen or alkoxy, orR.sup.1 and R.sup.2 together represent optionally halogen-substituted alkylenedioxy, andR.sup.3 represents hydrogen or chlorine,exhibit arthropodicidal activity. A novel synthesis is shown involving reaction of ##STR2## in the presence of an alkali metal cyanide to produce an end product wherein R is an .alpha.-cyano-3-phenoxybenzyl ester. ##STR3## is reacted with ##STR4## in the presence of a base to produce certain novel intermediates.
摘要翻译：取代的苯甲酰基环丙烷羧酸酯，其中R表示C1-4烷基或拟除虫菊酯中通常的醇基，R1表示烷氧基或烷硫基，其任一个任选被卤素取代，R 2表示氢或烷氧基，或R 1 并且R 2一起代表卤素取代的亚烷基二氧基，并且R 3表示氢或氯，表现出节肢动物杀伤活性。显示了一种新的合成，其涉及在碱金属氰化物存在下的反应，以产生最终产物，其中R是α-氰基-3-苯氧基苄基酯。在一个碱的存在下，与反应产生某些新的中间体。

35. 发明授权

US4284645A 3-Chlorostyryl-2,2-dimethyl-cyclopropanecarboxylic acid 4-fluoro-3-phenoxy-.alpha.-cyano-benzyl esters and their use as ectoparasiticides 失效
标题翻译： 3-氯苯乙烯基-2,2-二甲基 - 环丙烷羧酸4-氟-3-苯氧基-α-氰基 - 苄基酯及其作为外寄生物杀虫剂
公开(公告)号：US4284645A
公开(公告)日：1981-08-18
申请号：US77502
申请日：1979-09-20
申请人： Rainer Fuchs , Wilhelm Stendel
发明人： Rainer Fuchs , Wilhelm Stendel
IPC分类号： C07C253/00 , A01N53/08 , C07C67/00 , C07C255/38 , C07C255/39 , C07C255/53 , A01N53/00 , C07C121/75
CPC分类号： C07C255/53
摘要： 3-Chlorostyryl-2,2-dimethyl-cyclopropanecarboxylic acid 4-fluoro-3-phenoxy-.alpha.-cyano-benzyl esters, which are useful as agents for combating ectoparasites, and a process for their preparation are described.
摘要翻译：描述了可用作对抗外寄生物的试剂的3-氯苯乙烯基-2,2-二甲基 - 环丙烷羧酸4-氟-3-苯氧基-α-氰基 - 苄基酯及其制备方法。

36. 发明授权

US4279923A Combating pests with 3-(2,3-dichloro-3,3-difluoro-prop-1-en-1-yl)-2,2-dimethyl-cyclo-propanec arboxylic acid fluoro-benzyl esters 失效
标题翻译：将害虫与3-（2,3-二氯-3,3-二氟 - 丙-1-烯-1-基）-2,2-二甲基 - 环丙烷羧酸氟代苄酯
公开(公告)号：US4279923A
公开(公告)日：1981-07-21
申请号：US185836
申请日：1980-09-10
申请人： Rainer Fuchs , Klaus Naumann , Reinhard Lantzsch , Hermann Hagemann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
发明人： Rainer Fuchs , Klaus Naumann , Reinhard Lantzsch , Hermann Hagemann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
IPC分类号： C07C69/747 , A01N53/00 , A01N53/06 , A01N53/08 , B01J31/02 , C07C61/40 , C07C67/00 , C07C67/08 , C07C67/14 , C07C253/00 , C07C255/39 , C07C69/743 , C07C121/75
CPC分类号： C07C61/40 , A01N53/00
摘要： 3-(2,3-Dichloro-3,3-difluoro-prop-1-en-1-yl)-2,2-dimethyl-cyclo-propanecarboxylic acid fluoro-benzyl esters of the formula ##STR1## in which R.sup.1 represents hydrogen, cyano, alkyl with up to 4 carbon atoms, alkenyl with up to 4 carbon atoms or alkynyl with up to 4 carbon atoms, andR.sup.2 represents a phenyl radical which is substituted by fluorine and/or optionally fluorine-substituted phenoxy, with the proviso that the radical R.sup.2 in total contains at least one fluorine substituent,which possess pesticidal activity.
摘要翻译：具有式“IMAGE”的3-（2,3-二氯-3,3-二氟 - 丙-1-烯-1-基）-2,2-二甲基 - 环丙烷 - 羧酸氟 - 苄基酯，其中R1 表示氢，氰基，具有至多4个碳原子的烷基，具有至多4个碳原子的烯基或具有至多4个碳原子的炔基，R 2表示被氟和/或任选氟取代的苯氧基取代的苯基，条件是基团R2总计含有至少一个具有杀虫活性的氟取代基。

37. 发明授权

US4215141A Combating insects and acarids with 4,4,5,5-tetrachloro-2,2-dimethyl-spiropentane-1-carboxylic acid 3-phenoxy-benzyl esters 失效
标题翻译：用4,4,5,5-四氯-2,2-二甲基 - 异丙基-1-羧酸3-苯氧基 - 苄基酯与昆虫和螨虫相结合
公开(公告)号：US4215141A
公开(公告)日：1980-07-29
申请号：US41222
申请日：1979-05-21
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C69/753 , A01N53/00 , A01N53/08 , C07C61/15 , C07C67/00 , C07C253/00 , C07C255/39 , A01N9/20 , A01N9/24 , C07C69/74 , C07C121/66
CPC分类号： C07C61/15 , A01N53/00
摘要： 4,4,5,5-tetrachloro-2,2-dimethyl-spiropentane-1-carboxylic acid 3-phenoxy-benzyl esters of the formula ##STR1## in which R and R.sup.1 each independently is hydrogen or halogen, andR.sup.2 is hydrogen, cyano or ethynyl,which possess insecticidal and acaricidal properties.
摘要翻译：具有式“IMAGE”的4,4,5,5-四氯-2,2-二甲基 - 异丙烷-1-羧酸3-苯氧基 - 苄基酯，其中R和R 1各自独立地是氢或卤素，R 2是氢，氰基或乙炔基，其具有杀虫和杀螨性质。

38. 发明申请

US20050159603A1 Substituted 4-pyrazolyl pyrazonlines used for pest control 失效
标题翻译：用于病虫害防治的取代的4-吡唑基吡嗪啉
公开(公告)号：US20050159603A1
公开(公告)日：2005-07-21
申请号：US10504357
申请日：2003-02-23
申请人： Fritz Maurer , Rainer Fuchs , Christoph Erdelen , Angelika Lubos-Erdelen , Jorg Konze , Andreas Turberg
发明人： Fritz Maurer , Rainer Fuchs , Christoph Erdelen , Angelika Lubos-Erdelen , Jorg Konze , Andreas Turberg
IPC分类号： A01N25/30 , A01N47/38 , C07B61/00 , C07D403/04 , C07D403/14 , C07D413/04 , C07D413/14 , C07D417/14
CPC分类号： C07D403/04 , A01N47/38 , C07D403/14 , C07D413/04 , C07D413/14
摘要： This invention relates to novel substituted 4-pyrazolylpyrazolines of formula (I) in which R1, R2, R3 and R4 are as defined in the disclosure, to a plurality of processes for preparing these substances and their use for controlling pests, and to novel intermediates and processes for their preparation.
摘要翻译：本发明涉及式（I）的新的取代的4-吡唑基吡唑啉，其中R 1，R 2，R 3和R 3， 4的定义如本公开所定义，涉及制备这些物质的多种方法及其用于防治害虫的方法，以及新型中间体及其制备方法。

39. 发明申请

US20080064732A1 Substituted 4-hetarylpyrazolines 审中-公开
标题翻译：取代的4-噻吨基吡唑
公开(公告)号：US20080064732A1
公开(公告)日：2008-03-13
申请号：US11978886
申请日：2007-10-30
申请人： Fritz Maurer , Rainer Fuchs , Christoph Erdelen , Angelika Lubos-Erdelen , Jorg Konze , Peter Losel , Andreas Turberg
发明人： Fritz Maurer , Rainer Fuchs , Christoph Erdelen , Angelika Lubos-Erdelen , Jorg Konze , Peter Losel , Andreas Turberg
IPC分类号： A01N43/713 , A01N43/824 , A01P7/00 , C07D257/04 , C07D417/04
CPC分类号： C07D403/04 , A01N47/38 , C07D417/04
摘要： The present invention relates to novel substituted pyrazolines of the formula (I) in which R1, R2, R3 and R4 are as defined in the disclosure, to a plurality of processes for preparing these substances and their use for controlling pests, and to novel intermediates and processes for their preparation.
摘要翻译：本发明涉及式（I）的新的取代的吡唑啉，其中R 1，R 2，R 3和R 3， 4的定义如本公开所定义，涉及制备这些物质的多种方法及其用于防治害虫的方法，以及新型中间体及其制备方法。

40. 发明申请

US20090143454A1 Pyrazoline Derivatives and Their Use As Pesticides 审中-公开
标题翻译：吡唑啉衍生物及其作为农药的用途
公开(公告)号：US20090143454A1
公开(公告)日：2009-06-04
申请号：US10483619
申请日：2002-07-08
申请人： Fritz Maurer , Rainer Fuchs , Christoph Erdelen , Angelika Lubos-Erdelen , Udo Reckmann , Andreas Turberg
发明人： Fritz Maurer , Rainer Fuchs , Christoph Erdelen , Angelika Lubos-Erdelen , Udo Reckmann , Andreas Turberg
IPC分类号： A01N43/56 , C07D403/04 , C07C255/44 , C07D231/14 , A01P7/00
CPC分类号： C07C255/29 , A01N47/38 , C07C255/25 , C07C271/04 , C07C323/36 , C07C323/43 , C07D231/14
摘要： The present invention relates to novel pyrazoline derivatives of the formula (I) in which R1, R2, R3 and R4 are as defined in the disclosure, to a plurality of processes for preparing these substances, and to their use for controlling pests, and further relates to novel intermediates and processes for their preparation.
摘要翻译：本发明涉及式（I）的新的吡唑啉衍生物，其中R1，R2，R3和R4如本公开所定义，涉及制备这些物质的多种方法及其用于防治害虫的方法涉及新型中间体及其制备方法。

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