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31. 发明授权

US4734122A Substituted 5-acylamino-1-phenylpyrazoles composition containing them, and herbicidal method of using them 失效
标题翻译：含有它们的取代的5-酰基氨基-1-苯基吡唑组合物和使用它们的除草方法
公开(公告)号：US4734122A
公开(公告)日：1988-03-29
申请号：US743459
申请日：1985-06-11
申请人： Reinhold Gehring , Jorg Stetter , Otto Schallner , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Jorg Stetter , Otto Schallner , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N47/18 , A01N47/22 , A01N47/36 , C07D231/40 , A01N43/56
CPC分类号： C07D231/40 , A01N47/18 , A01N47/22 , A01N47/36
摘要： 5-acylamino-1-phenylpyrazole herbicides of the formula ##STR1## in which R represents cyano, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, aminocarbonyl, alkylaminocarbonyl, alkenylaminocarbonyl or alkinylaminocarbonyl,R.sup.1 represents alkyl, alkenyl, alkinyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl, cycloalkyl or optionally substituted aryl, and, in the case in which Y represents the ##STR2## group, also represents hydrogen, X represents oxygen or sulphur,Y represents oxygen, sulphur or the ##STR3## group, whereinZ represents hydrogen, alkyl, alkoxy, alkenyl, alkinyl or optionally substituted aryl,R.sup.2 represents hydrogen or the radical ##STR4## and R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7, which are identical or different, represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylsulphonyl, alkoxycarbonyl or a radical --(X').sub.n --R.sup.8,whereinX' represents oxygen, sulphur, sulphinyl or sulphonyl,n represents 0 or 1 andR.sup.8 represents halogenoalkyl, with the proviso that at least one of the radicals R.sup.3, R.sup.4, R.sup.5, R.sup.6 or R.sup.7 represents a radical --(X').sub.n --R.sup.8, but R does not represent cyano when R.sup.5 represents trifluoromethyl.
摘要翻译：其中R代表氰基，烷氧基羰基，烯氧基羰基，烷氧基羰基，氨基羰基，烷基氨基羰基，链烯基氨基羰基或烷基氨基羰基，R1代表烷基，烯基，炔基，烷氧基烷基，烷硫基烷基，卤代烷基，环烷基或并且在Y代表基团的情况下也表示氢，X表示氧或硫，Y表示氧，硫或基团，其中Z表示氢，烷基，烷氧基，烯基，炔基或任选取代的芳基，R 2表示氢或基团，且R 3，R 4，R 5，R 6和R 7相同或不同，表示氢，卤素，氰基，硝基，烷基，烷氧基，烷基磺酰基，或基团 - （X'）n -R 8，其中X'表示氧，硫，亚磺酰基或磺酰基，n表示0或1，并且R 8表示卤代烷基，条件是至少一个碱基 R 3，R 4，R 5，R 6或R 7表示基团 - （X'）n -R 8，但当R 5表示三氟甲基时，R不表示氰基。

32. 发明授权

US4685956A 1-aryl-5-hydrazino-pyrazoles, compositions containing them, and herbicidal method of using them 失效
标题翻译： 1-芳基-5-肼基 - 吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4685956A
公开(公告)日：1987-08-11
申请号：US885051
申请日：1986-07-14
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/40 , A01N43/56 , A01N47/02 , A01N47/24 , A01N47/34 , C07D231/16 , C07D231/38 , C07D231/40 , C07D231/42 , C07D401/04
CPC分类号： C07D231/38 , A01N43/56 , A01N47/02 , A01N47/24 , A01N47/34 , C07D231/16 , C07D401/04
摘要： Herbicidally active 1-aryl-5-hydrazinopyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen or alkyl,R.sup.2 represents cyano or nitro,R.sup.3 represents hydrogen, or represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, or represents a radical ##STR2## or represents a radical --SO.sub.2 --R.sup.7, R.sup.4 represents hydrogen, or represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, or represents a radical ##STR3## or represents a radical --SO.sub.2 --R.sup.7, R.sup.5 represents hydrogen: or, in the case where R.sup.4 represents hydrogen, also represents a radical ##STR4## or represents a radical --SO.sub.2 --R.sup.7, or represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, wherein, in each case,X represents oxygen or sulphur,R.sup.6 represents hydrogen, alkyl, alkoxy, alkoxyalkyl, alkylthio, alkylthioalkyl, alkylamino, dialkylamino, halogenoalkyl, alkenyl or alkinyl, or represents optionally substituted cycloalkyl, or represents in each case optionally substituted aryl, aryloxy, arylthio or arylamino andR.sup.7 represents alkyl, hydroxyalkyl, alkoxyalkyl, halogenoalkyl, alkenyl, alkinyl or cycloalkyl, or represents in each case optionally substituted aralkyl or aryl andAr represents substituted phenyl, or represents optionally substituted pyridyl.
摘要翻译：其中R1代表氢或烷基，R2代表氰基或硝基，R3代表氢或在各种情况下代表任选取代的烷基，链烯基，炔基或环烷基，或代表（甲基）丙烯酸或者代表基团-SO 2 -R 7，R 4代表氢，或在各种情况下表示任选取代的烷基，链烯基，炔基或环烷基，或表示基团-SO 2 -R 7，R 5 表示氢;或者，在R4表示氢的情况下也表示基团，或表示基团-SO 2 -R 7，或表示在各种情况下为任选取代的烷基，烯基，炔基或环烷基，其中，在每种情况下， X表示氧或硫，R6表示氢，烷基，烷氧基，烷氧基烷基，烷硫基，烷硫基烷基，烷基氨基，二烷基氨基，卤代烷基，烯基或炔基，或表示任意取代的环烷基，芳基，芳硫基或芳基氨基，R 7表示烷基，羟基烷基，烷氧基烷基，卤代烷基，烯基，炔基或环烷基，或在各种情况下表示任选取代的芳烷基或芳基，Ar表示取代的苯基，或表示任意取代的吡啶基。

33. 发明授权

US5021082A Herbicidal substituted sulphonylaminoazoles 失效
标题翻译：除草取代磺酰基氨基唑
公开(公告)号：US5021082A
公开(公告)日：1991-06-04
申请号：US504442
申请日：1990-04-03
申请人： Rolf Kirsten , Joachim Kluth , Christa Fest , Ernst Gesing , Klaus-Helmut Muller , Hans-Jochem Riebel , Peter Babczinski , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
发明人： Rolf Kirsten , Joachim Kluth , Christa Fest , Ernst Gesing , Klaus-Helmut Muller , Hans-Jochem Riebel , Peter Babczinski , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
IPC分类号： C07D401/14 , A01N43/56 , A01N43/653 , A01N43/66 , A01N43/80 , A01N51/00 , C07D249/14 , C07D401/04 , C07D403/04 , C07D403/14 , C07D409/14 , C07D417/14
CPC分类号： C07D401/04 , A01N43/56 , A01N43/653 , A01N43/66 , A01N43/80 , A01N51/00 , C07D403/04 , C07D403/14 , C07D409/14 , C07D417/14
摘要： Herbicidal substituted sulphonylaminoazoles of the formula ##STR1## in which R.sup.1 is optionally substituted alkyl, aralkyl, aryl or heteroaryl,R.sup.2 is hydrogen or --SO.sub.2 --R.sup.1,R.sup.3 is hydrogen, halogen, hydroxyl, mercapto, amino, or an optionally substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino radical,A is CH, nitrogen or,at least one of A, D and E is ##STR2## and the others may be that or CH or nitrogen, and X, Y and Z each is nitrogen or optionally substituted C, and salts thereof.

34. 发明授权

US4877439A Herbicidal 1-arylpyrazoles, compositions and use 失效
标题翻译：除草1-芳基吡唑，组合物和用途
公开(公告)号：US4877439A
公开(公告)日：1989-10-31
申请号：US210607
申请日：1988-06-23
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
IPC分类号： A01N57/24 , C07F9/6503
CPC分类号： A01N57/24 , C07F9/65037
摘要： Herbicidal 1-arylpyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen or nitro,R.sup.2 represents hydrogen or alkyl,R.sup.3 and R.sup.4 independently of one another each represent alkyl, halogenoalkyl or optionally substituted aryl,Ar represents optionally substituted phenyl or optionally substituted pyridyl,x represents a number 0 or 1 andy represents a number 0 or 1.
摘要翻译：式（I）的除草1-芳基吡唑其中R1代表氢或硝基，R2代表氢或烷基，R3和R4彼此独立地表示烷基，卤代烷基或任选取代的芳基，Ar代表任意取代的苯基或任选取代的吡啶基，x表示数字0或1，y表示数字0或1。

35. 发明授权

US4804398A 1-aryl-4-cyano-5-halogenopyrazoles, composition containing them, and method of using them as selective herbicides 失效
标题翻译： 1-芳基-4-氰基-5-卤代吡唑，含有它们的组合物，以及使用它们作为选择性除草剂的方法
公开(公告)号：US4804398A
公开(公告)日：1989-02-14
申请号：US57471
申请日：1987-06-03
申请人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/16 , C07D231/22 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56 , C07D231/16
摘要： Herbicidally active novel 1-phenyl-4-cyano-5-halogenopyrazoles of the formula ##STR1## in which R is hydrogen or alkyl,Hal is halogen, andAr is phenyl substituted at least once by a radical other than halogen.Intermediates of the formulas ##STR2## are also new.
摘要翻译：式“IMAGE”的除草活性新型1-苯基-4-氰基-5-卤代吡唑，其中R为氢或烷基，Hal为卤素，Ar为至少一个被卤素以外的基团取代的苯基。公式 + TR 的中间体也是新的。

36. 发明授权

US4695308A Herbicidal substituted 5-amino-1-aryl-pyrazoles 失效
标题翻译：除草取代的5-氨基-1-芳基 - 吡唑
公开(公告)号：US4695308A
公开(公告)日：1987-09-22
申请号：US925845
申请日：1986-10-30
申请人： Reinhold Gehring , Markus Lindig , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Jorg Stetter
发明人： Reinhold Gehring , Markus Lindig , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Jorg Stetter
IPC分类号： A01N57/08 , A01N57/32 , C07F9/6503 , C07F9/6561 , C07F9/65
CPC分类号： C07F9/65037 , A01N57/32
摘要： Herbicidally active substituted 5-amino-1-aryl-pyrazoles of the formula ##STR1## in which R represents hydrogen, cyano, nitro or alkoxycarbonyl,R.sup.1 represents hydrogen or alkyl,R.sup.2 and R.sup.3 independently of one another in each case represent alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl, cycloalkyl, alkoxy or cycloalkoxy, or represent in each case optionally substituted aryl, aryloxy, aralkyl or aralkyloxy,X represents oxygen or sulphur andAr represents in each case optionally substituted phenyl or pyridyl,or salts thereof.
摘要翻译：其中R表示氢，氰基，硝基或烷氧羰基的除草活性取代的5-氨基-1-芳基 - 吡唑，R1代表氢或烷基，R2和R3各自独立地表示烷基，烯基，烷基，卤代烷基，烷氧基烷基，环烷基，烷氧基或环烷氧基，或在每种情况下表示任选取代的芳基，芳氧基，芳烷基或芳烷氧基，X表示氧或硫，Ar表示在任何情况下均为任选取代的苯基或吡啶基或其盐。

37. 发明授权

US5104439A Herbicidal agents based on pyrazole derivatives 失效
标题翻译：基于吡唑衍生物的除草剂
公开(公告)号：US5104439A
公开(公告)日：1992-04-14
申请号：US569493
申请日：1990-08-20
申请人： Otto Schallner , Reinhold Gehring , Erich Klauke , Jorg Stetter , Heinz-Jurgen Wroblowsky , Robert R. Schmidt , Hans-Joachim Santel
发明人： Otto Schallner , Reinhold Gehring , Erich Klauke , Jorg Stetter , Heinz-Jurgen Wroblowsky , Robert R. Schmidt , Hans-Joachim Santel
IPC分类号： A01N43/56 , A01N47/02 , A01N47/18 , A01N47/22 , A01N47/36 , A01N53/00 , A01N57/22 , A01N57/24 , C07C67/00 , C07C253/00 , C07C255/66 , C07C317/32 , C07C317/48 , C07C323/48 , C07D231/38 , C07D231/40 , C07F9/40 , C07F9/6509
CPC分类号： C07D231/38 , A01N43/56 , A01N47/02 , A01N47/18 , A01N47/22 , A01N47/36 , A01N53/00 , A01N57/22 , C07D231/40 , C07F9/4015 , C07F9/650935
摘要： Herbicidally active 5-amino-1-phenyl-pyrazoles, most of which are new, of the formula ##STR1##

38. 发明授权

US4941912A Herbicidal substituted sulphonylaminoazoles 失效
标题翻译：除草取代磺酰基氨基唑
公开(公告)号：US4941912A
公开(公告)日：1990-07-17
申请号：US317219
申请日：1989-02-28
申请人： Rolf Kirsten , Joachim Kluth , Christa Fest , Ernst Gesing , Klaus-Helmut Muller , Hans-Jochem Riebel , Peter Babczinski , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
发明人： Rolf Kirsten , Joachim Kluth , Christa Fest , Ernst Gesing , Klaus-Helmut Muller , Hans-Jochem Riebel , Peter Babczinski , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
IPC分类号： C07D401/14 , A01N43/56 , A01N43/653 , A01N43/66 , A01N43/80 , A01N51/00 , C07D249/14 , C07D401/04 , C07D403/04 , C07D403/14 , C07D409/14 , C07D417/14
CPC分类号： C07D401/04 , A01N43/56 , A01N43/653 , A01N43/66 , A01N43/80 , A01N51/00 , C07D403/04 , C07D403/14 , C07D409/14 , C07D417/14
摘要： Herbicidal substituted sulphonylaminoazoles of the formula ##STR1## in which R.sup.1 is optionally substituted alkyl, aralkyl, aryl or heteroaryl,R.sup.2 is hydrogen or --SO.sub.2 --R.sup.1,R.sup.3 is hydrogen, halogen, hydroxyl, mercapto, amino, or an optionally substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino radical,A is CH, nitrogen or,at least one of A, D and E is ##STR2## and the others may be that or CH or nitrogen, and X, Y and Z each is nitrogen or optionally substituted C, and salts thereof.
摘要翻译： R 1为任选取代的烷基，芳烷基，芳基或杂芳基，R 2为氢或-SO 2 -R 1，R 3为氢，卤素，羟基，巯基，氨基或任意取代的芳族取代的磺酰基氨基唑取代的烷基，烷氧基，烷硫基，烷基氨基或二烷基氨基，A是CH，氮，或者，A，D和E中的至少一个是，而其余可以是CH或氮，X，Y和Z各自是氮或任选取代的C，及其盐。

39. 发明授权

US4806144A 5-Sulphonamido-1-aryl-pyrazoles 失效
标题翻译： 5-磺酰氨基-1-芳基 - 吡唑
公开(公告)号：US4806144A
公开(公告)日：1989-02-21
申请号：US817181
申请日：1986-01-08
申请人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/38 , C07D231/42
CPC分类号： C07D231/42
摘要： A 5-sulphonamido-1-aryl-pyrazole of the formula (I) ##STR1## in which R.sup.1 represents hydrogen, nitro, nitroso or halogen,R.sup.2 represents hydrogen, alkyl or a radical R.sup.3 --SO.sub.2 --, or an inorganic or organic cation bonded in the form of a salt,R.sup.3 represents alkyl, alkenyl, cycloalkyl, halogeno-alkyl, hydroxyalkyl, alkoxyalkyl or unsubstituted or substituted aryl,R.sup.4 and R.sup.6 independently of one another represent cyano, nitro, halogen, alkyl, alkoxy, alkoxycarbonyl, halogenoalkyl, halogenoalkoxy or a radical --(O).sub.n --R.sup.9 andR.sup.5, R.sup.7 and R.sup.8 independently of one another and of R.sup.4 and R.sup.6 represent the same radicals as R.sup.4 and R.sup.6, and additionally represent hydrogen,whereinR.sup.9 represents alkyl, halogenoalkyl, amino, alkyl-amino or dialkylamino andn represents the number 0, 1 or 2.Such 5-sulphonamido-1-aryl-pyrazole being useful as a herbicide.
摘要翻译：式（I）的5-磺酰氨基-1-芳基 - 吡唑其中R 1表示氢，硝基，亚硝基或卤素，R 2表示氢，烷基或基团R 3 -SO 2 - 或无机或以盐形式键合的有机阳离子，R 3表示烷基，烯基，环烷基，卤代烷基，羟烷基，烷氧基烷基或未取代或取代的芳基，R 4和R 6彼此独立地表示氰基，硝基，卤素，烷基，烷氧基，烷氧基羰基，卤代烷基，卤代烷氧基或基团 - （O）n -R 9和R 5，R 7和R 8彼此独立地表示，并且R 4和R 6表示与R 4和R 6相同的基团，并且另外表示氢，其中R 9表示烷基，卤代烷基，氨基，烷基 - 氨基或二烷基氨基，n代表数字0,1或2.这种5-磺酰氨基-1-芳基 - 吡唑可用作除草剂。

40. 发明授权

US4772312A 5-amino-1-pyridyl-pyrazoles, composition containing them, and herbicidal method of using them 失效
标题翻译： 5-氨基-1-吡啶基 - 吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4772312A
公开(公告)日：1988-09-20
申请号：US866638
申请日：1986-05-22
申请人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56
摘要： Herbicidally active novel 5-amino-1-pyridyl-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen or represents alkyl with 1 to 12 carbon atoms,R.sup.2 represents hydrogen, nitro, nitroso or halogen, or represents a radical ##STR2## wherein R.sup.5 represents hydrogen, hydroxyl, alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl or alkylthioalkyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents alkoxy or alkylthio, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents alkylamino or dialkylamino, or represents optionally substituted arylamino,R.sup.3 represents hydrogen, or represents a radical ##STR3## or represents a radical --S(O).sub.n --R.sup.7, R.sup.4 represents hydrogen, or represents alkyl, or represents a radical ##STR4## or represents a radical --S(O).sub.n --R.sup.7, and, in the case where R.sup.3 represents an --SO.sub.2 --R.sup.7 radical, also represents an inorganic or organic cation bonded in salt form, andR.sup.6 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl or alkylthioalkyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents alkoxy or alkylthio, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents alkylamino or dialkylamino, or represents optionally substituted arylamino,X represents oxygen or sulphur,n represents the number 0, 1 or 2,R.sup.7 represents alkyl, halogenoalkyl or optionally substituted aryl andPy represents substituted C-linked pyridyl.Some of the intermediates wherein the 5-position of the pyrazole carries a halogen atom are also new.
摘要翻译：其中R1代表氢或代表具有1-12个碳原子的烷基，R2代表氢，硝基，亚硝基或卤素的除草活性的新颖的5-氨基-1-吡啶基吡唑，其中R1代表氢或代表基团或代表任意取代的环烷基，或表示任意取代的芳基，或表示烷氧基或烷硫基，或表示任选取代的芳氧基，或表示任选取代的芳硫基，或表示任选取代的芳硫基，或或表示任选取代的芳基氨基，R 3表示氢，或表示基团，或表示基团-S（O）n -R 7，R 4表示氢，或表示烷基，或表示基团。或表示基团-S（O）n -R 7，并且在R 3表示-SO 2 -R 7基团的情况下，也表示以盐形式键合的无机或有机阳离子，R 6表示代表氢，烷基，烯基，炔基，卤代烷基，烷氧基烷基或烷硫基烷基，或表示任意取代的环烷基，或表示任意取代的芳基，或表示烷氧基或烷硫基，或表示任意取代的芳氧基，或表示任意取代的芳硫基，或表示烷基氨基或二烷基氨基，或表示任选取代的芳基氨基，X表示氧或硫，n表示0,1或2，R7表示烷基，卤代烷基或任意取代的芳基，Py表示取代的C-连接的吡啶基。其中吡唑的5-位带有卤素原子的一些中间体也是新的。

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