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31. 发明申请

US20130026072A1 CATALYTIC COMPOSITIONS USEFUL IN REMOVAL OF SULFUR COMPOUNDS FROM GASEOUS HYDROCARBONS, PROCESSES FOR MAKING THESE AND USES THEREOF 审中-公开
标题翻译：催化组合物用于从气相烃中除去硫化合物，其制备方法及其用途
公开(公告)号：US20130026072A1
公开(公告)日：2013-01-31
申请号：US13191939
申请日：2011-07-27
申请人： Abdennour BOURANE , Omer Refa Koseoglu , Zinfer Ismagilov , Svetlana Yashnik , Mikhail Kerzhentsev , Valentin Parmon
发明人： Abdennour BOURANE , Omer Refa Koseoglu , Zinfer Ismagilov , Svetlana Yashnik , Mikhail Kerzhentsev , Valentin Parmon
IPC分类号： C10G29/16 , B01J35/08 , B01J37/08 , B01J35/10 , B01J37/03 , B01J21/02 , B01J35/02
CPC分类号： B01J35/023 , B01J23/005 , B01J23/80 , B01J23/83 , B01J35/006 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J37/009 , B01J37/031 , C10G27/00 , C10G29/16
摘要： A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide, with a spinel formula and highly dispersed crystals of ZnO, CuO, and optionally CeO2. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.
摘要翻译：公开了一种催化组合物，其显示出具有尖晶石配方的X射线无定形氧化物和ZnO，CuO和任选的CeO 2的高度分散的晶体。该组合物可用于从气态烃中除去硫的氧化过程。

32. 发明申请

US20120241358A1 INTEGRATED HYDROCRACKING AND FLUIDIZED CATALYTIC CRACKING SYSTEM AND PROCESS 有权
标题翻译：一体化水力发电和流化催化裂化系统及工艺
公开(公告)号：US20120241358A1
公开(公告)日：2012-09-27
申请号：US13069485
申请日：2011-03-23
申请人： Musaed Muhammad Al-Thubaiti , Ali Mahmood Al-Somali , Omer Refa Koseoglu
发明人： Musaed Muhammad Al-Thubaiti , Ali Mahmood Al-Somali , Omer Refa Koseoglu
IPC分类号： C10G69/04 , B01J8/00
CPC分类号： B01D3/009 , B01J8/26 , B01J21/12 , B01J29/084 , B01J29/40 , B01J29/80 , C10G11/18 , C10G69/04 , C10G2300/1059 , C10G2300/301 , C10G2300/4081 , C10G2400/02 , C10G2400/20
摘要： A system and method of cracking hydrocarbon feedstocks is provided that allows for significant flexibility in terms of the desired product yield. An integrated process includes introducing the feedstock and hydrogen into a first hydrocracking reaction zone containing a first hydrocracking catalyst to produce a first zone effluent. The first zone effluent is passed to a fractionating zone to produce at least a low boiling fraction and a high boiling fraction, and optionally one or more intermediate fractions. The bottoms fraction is conveyed to a fluidized catalytic cracking reaction and separation zone, from which olefins and gasoline are recovered. At least a portion of remaining cycle oil is passed from the fluidized catalytic cracking reaction and separation zone to a second hydrocracking reaction zone containing a second hydrocracking catalyst to produce a second stage effluent. At least a portion of the second stage effluent is recycled to the fractionating zone and/or the first hydrocracking reaction zone.
摘要翻译：提供了裂化烃原料的系统和方法，其允许在所需产物产率方面具有显着的灵活性。整合方法包括将原料和氢气引入到含有第一加氢裂化催化剂的第一加氢裂化反应区中以产生第一区流出物。第一区域流出物被送入分馏区以产生至少一个低沸点馏分和一个高沸点馏分，以及任选的一个或多个中间馏分。将塔底馏分输送到流化催化裂化反应和分离区，回收烯烃和汽油。剩余循环油的至少一部分从流化催化裂化反应和分离区通过含有第二加氢裂化催化剂的第二加氢裂化反应区，以产生第二阶段流出物。至少一部分第二阶段流出物循环到分馏区和/或第一加氢裂化反应区。

33. 发明授权

US07763163B2 Process for removal of nitrogen and poly-nuclear aromatics from hydrocracker feedstocks 有权
标题翻译：从加氢裂化器原料中除去氮和多核芳烃的方法
公开(公告)号：US07763163B2
公开(公告)日：2010-07-27
申请号：US11593968
申请日：2006-11-06
申请人： Omer Refa Koseoglu
发明人： Omer Refa Koseoglu
IPC分类号： C10G67/06
CPC分类号： C10G25/06 , C10G25/00 , C10G25/003 , C10G55/06 , C10G67/06
摘要： A feedstream to a hydrocracking unit is treated to remove or reduce the content of polynuclear aromatics and nitrogen-containing compounds by contacting the feedstream with an adsorbent compound selected from attapulgus clay, alumina, silica gel and activated carbon in a fixed bed or slurry column and separating the treated feedstream that is lower in the undesired compounds from the adsorbent material. The adsorbent can be mixed with a solvent for the undesired compounds and stripped for re-use.
摘要翻译：处理加氢裂化装置的进料流，以通过使固定床或浆料塔中的进料流与选自粘土，氧化铝，硅胶和活性炭的吸附剂化合物接触来除去或降低多核芳烃和含氮化合物的含量，将不需要的化合物中较低的经处理的原料流与吸附材料分离。可以将吸附剂与不需要的化合物的溶剂混合并剥离以供再利用。

34. 发明申请

US20090321309A1 Process for upgrading hydrocarbon feedstocks using solid adsorbent and membrane separation of treated product stream 有权
标题翻译：使用固体吸附剂升级烃原料和处理产物流的膜分离的方法
公开(公告)号：US20090321309A1
公开(公告)日：2009-12-31
申请号：US12454298
申请日：2009-05-15
申请人： Omer Refa Koseoglu
发明人： Omer Refa Koseoglu
IPC分类号： C10C1/00 , C10G29/00 , C10G29/16 , C10G29/02
CPC分类号： C10G25/06 , C10G25/05 , C10G25/12 , C10G31/09 , C10G31/11 , C10G53/08 , C10G2300/1033 , C10G2300/1044 , C10G2300/1055 , C10G2300/1059 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/301 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/06
摘要： A process for upgrading crude oil fractions or other hydrocarbon oil feedstreams boiling in the range of 36° to 520° C., and preferably naphtha and gas oil fractions boiling in the range of 36° to 400° C., employs a solid adsorption material to lower sulfur and nitrogen content by contacting the hydrocarbon oil, and optionally a viscosity-reducing solvent, with one or more solid adsorbents such as silica gel or silica, silica alumina, alumina, attapulgus clay and activated carbon in a mixing vessel for a predetermined period of time; passing the resulting slurry to a membrane separation zone, optionally preceded by a primary filtration step (i.e., single stage or multiple stages), to separate the solid adsorption material with the adsorbed sulfur and nitrogen compounds from the treated oil; recovering the upgraded hydrocarbon product having a significantly reduced nitrogen and sulfur content as the membrane permeate; mixing the solid adsorbent material with one or a combination of aromatic solvents such as toluene, benzene, the xylenes and tetrahydrofuran to remove and stabilize the sulfur and nitrogen compounds; transferring the solvent to a fractionation tower to recover the solvent, which can be recycled for use in the process; and recovering the hydrocarbons that are rich in sulfur and nitrogen for processing in a relatively small high-pressure hydrotreating unit or transferring them to a fuel oil pool for blending.
摘要翻译：一种在36℃至520℃范围内沸腾的原油馏分或其它烃油原料流优化的方法，优选在36℃至400℃范围内沸腾的石脑油和粗柴油馏分，采用固体吸附材料通过使烃油和任选的降粘溶剂与混合容器中的一种或多种固体吸附剂如硅胶或二氧化硅，二氧化硅氧化铝，氧化铝，粘土粘土和活性炭接触来降低硫和氮含量，用于预定的一段的时间; 将所得到的浆液通过一个膜分离区，任选地在一次过滤步骤（即单级或多级）之前，将固体吸附材料与经处理的油中吸附的硫和氮化合物分离; 回收具有显着降低的氮和硫含量的升级的烃产品作为膜渗透物; 将固体吸附剂材料与芳族溶剂如甲苯，苯，二甲苯和四氢呋喃的一种或其组合混合以除去和稳定硫和氮化合物; 将溶剂转移到分馏塔以回收溶剂，其可以再循环用于该方法; 并回收富含硫和氮的烃，以在相对小的高压加氢处理装置中加工或将其转移到燃料油池中进行混合。

35. 发明申请

US20080105595A1 Process for removal of nitrogen and poly-nuclear aromatics from hydrocracker and FCC feedstocks 有权
标题翻译：从加氢裂化器和FCC原料中除去氮和多核芳烃的方法
公开(公告)号：US20080105595A1
公开(公告)日：2008-05-08
申请号：US11593968
申请日：2006-11-06
申请人： Omer Refa Koseoglu
发明人： Omer Refa Koseoglu
IPC分类号： C10G25/03
CPC分类号： C10G25/06 , C10G25/00 , C10G25/003 , C10G55/06 , C10G67/06
摘要： A feedstream to a hydrocracking unit is treated to remove or reduce the content of polynuclear aromatics and nitrogen-containing compounds by contacting the feedstream with an adsorbent compound selected from attapulgus clay, alumina, silica gel and activated carbon in a fixed bed or slurry column and separating the treated feedstream that is lower in the undesired compounds from the adsorbent material. The adsorbent can be mixed with a solvent for the undesired compounds and stripped for re-use.
摘要翻译：处理加氢裂化装置的进料流，以通过使固定床或浆料塔中的进料流与选自粘土，氧化铝，硅胶和活性炭的吸附剂化合物接触来除去或降低多核芳烃和含氮化合物的含量，将不需要的化合物中较低的经处理的原料流与吸附材料分离。可以将吸附剂与不需要的化合物的溶剂混合并剥离以供再利用。

36. 发明授权

US09574144B2 Process for oxidative desulfurization and denitrogenation using a fluid catalytic cracking (FCC) unit 有权
标题翻译：使用流化催化裂化（FCC）装置进行氧化脱硫脱氮的方法
公开(公告)号：US09574144B2
公开(公告)日：2017-02-21
申请号：US12876702
申请日：2010-09-07
申请人： Abdennour Bourane , Omer Refa Koseoglu , Stephane Cyrille Kressmann
发明人： Abdennour Bourane , Omer Refa Koseoglu , Stephane Cyrille Kressmann
IPC分类号： C10G55/06 , C10G21/20 , C10G27/04 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/22 , C10G21/28 , C10G25/00 , C10G27/12 , C10G53/04 , C10G53/08 , C10G53/14
CPC分类号： C10G55/06 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/22 , C10G21/28 , C10G25/003 , C10G27/04 , C10G27/12 , C10G53/04 , C10G53/08 , C10G53/14 , C10G2300/1074 , C10G2300/202 , C10G2300/44
摘要： A method and apparatus for recovering components from a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds and nitrogen compounds present in the hydrocarbon feedstock; (b) separating the hydrocarbons, the oxidized sulfur compounds, and the oxidized nitrogen compounds by solvent extraction; (c) collecting a residue stream that includes the oxidized sulfur compounds and the oxidized nitrogen compounds; and (d) supplying the residue stream to a fluid catalytic cracking unit.
摘要翻译：提供了一种从烃原料中回收组分的方法和装置。该方法包括以下步骤：（a）将烃原料供应至氧化反应器，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物和氮化合物的条件下被氧化; （b）通过溶剂萃取分离烃，氧化的硫化合物和氧化的氮化合物; （c）收集包含氧化的硫化合物和氧化的氮化合物的残余物流; 和（d）将残余物流供应到流化催化裂化装置。

37. 发明授权

US09574142B2 Process for oxidative desulfurization and sulfone management by gasification 有权
标题翻译：通过气化进行氧化脱硫和砜处理
公开(公告)号：US09574142B2
公开(公告)日：2017-02-21
申请号：US12876822
申请日：2010-09-07
申请人： Abdennour Bourane , Omer Refa Koseoglu , Stephane Cyrille Kressmann
发明人： Abdennour Bourane , Omer Refa Koseoglu , Stephane Cyrille Kressmann
IPC分类号： C10G27/04 , C10G21/20 , C10G53/14 , C10G53/04 , C10G21/12 , C10G27/12 , C10G27/14 , C01B3/38
CPC分类号： C10G53/04 , C01B3/386 , C01B2203/0261 , C01B2203/127 , C01B2203/84 , C10G21/12 , C10G27/04 , C10G27/12 , C10G27/14 , C10G53/14 , C10G2300/1037 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/44 , C10J2300/1665 , C10J2300/1807
摘要： A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; (c) separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; (d) collecting a residue stream that includes the oxidized sulfur compounds; and (e) supplying the residue stream to a gasifier to produce a syngas stream and a hydrogen sulfide stream.
摘要翻译：提供了一种用于升级烃原料的方法和装置。该方法包括以下步骤：（a）向烃氧化反应器提供烃原料，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物的条件下被氧化; （c）通过溶剂萃取分离烃和氧化的硫化合物; （d）收集包含氧化硫化合物的残余物流; 和（e）将残余物流供应到气化器以产生合成气流和硫化氢流。

38. 发明授权

US09556388B2 Selective series-flow hydroprocessing system and method 有权
标题翻译：选择性串联加氢处理系统及方法
公开(公告)号：US09556388B2
公开(公告)日：2017-01-31
申请号：US13559958
申请日：2012-07-27
申请人： Omer Refa Koseoglu
发明人： Omer Refa Koseoglu
IPC分类号： C10G65/14 , C10G67/04 , C10G65/02 , C10G21/00
CPC分类号： C10G67/14 , B01J8/04 , B01J2208/027 , C10G21/00 , C10G65/02 , C10G65/14 , C10G67/0418 , C10G67/0445 , C10G2300/1096 , C10G2300/202 , C10G2300/44 , C10G2400/02 , C10G2400/04
摘要： Aromatic extraction and hydrocracking processes are integrated to optimize the hydrocracking units design and/or performance. By processing aromatics-rich and aromatic-lean fractions separately, the hydrocracking operating severity and or catalyst reactor volume requirement decreases.
摘要翻译：整合芳香提取和加氢裂化工艺，以优化加氢裂化装置的设计和/或性能。通过分别处理富含芳香族和芳香族馏分，加氢裂化操作严重度和/或催化剂反应器体积要求降低。

39. 发明授权

US09550948B2 Sulfone cracking using supercritical water 有权
标题翻译：使用超临界水的砜开裂
公开(公告)号：US09550948B2
公开(公告)日：2017-01-24
申请号：US15148033
申请日：2016-05-06
申请人： Omer Refa Koseoglu , Farhan M. Al-Shahrani , Abdennour Bourane
发明人： Omer Refa Koseoglu , Farhan M. Al-Shahrani , Abdennour Bourane
IPC分类号： C10G53/12 , C10G1/00 , C10G17/02 , C10G19/02 , C10G29/04 , C10G31/08 , C10G53/10
CPC分类号： C10G53/12 , C10G1/002 , C10G17/02 , C10G17/04 , C10G19/02 , C10G27/00 , C10G29/00 , C10G29/02 , C10G29/04 , C10G29/16 , C10G31/08 , C10G53/10 , C10G53/14 , C10G2300/1033 , C10G2300/202 , C10G2300/805
摘要： The invention relates to a process for removing sulfur compounds from a hydrocarbon stream. The hydrocarbon stream is contacted with water, at supercritical conditions and also subjects an effluent hydrocarbon stream to separation techniques. The resulting hydrocarbon stream is substantially free of sulfur oxides, sulfoxides, and sulfones.
摘要翻译：本发明涉及从烃流中除去硫化合物的方法。碳氢化合物流在超临界条件下与水接触，并且还将流出的烃流接受到分离技术。所得烃流基本上不含硫氧化物，亚砜和砜。

40. 发明授权

US09023192B2 Delayed coking process utilizing adsorbent materials 有权
标题翻译：使用吸附材料的延迟焦化工艺
公开(公告)号：US09023192B2
公开(公告)日：2015-05-05
申请号：US13533431
申请日：2012-06-26
申请人： Omer Refa Koseoglu
发明人： Omer Refa Koseoglu
IPC分类号： C10B55/00 , C10G51/02 , C10B57/06 , C10B55/02 , C10G9/00
CPC分类号： C10B57/06 , C10B55/02 , C10G9/005
摘要： A delayed coking process includes: a. introducing a fresh hydrocarbon feedstock containing undesirable sulfur and/or nitrogen compounds for preheating into the lower portion of a coking unit product fractionator; b. introducing at least a portion of an intermediate fraction derived from the fractionator and at least one adsorbent material that selectively adsorbs sulfur- and/or nitrogen-containing compounds into a mixing zone to form an adsorbent slurry stream; c. discharging a bottoms fraction from the fractionator; d. adding all or a portion of the slurry stream to the bottoms fraction to form a mixed coking unit feedstream; e. heating the mixed feedstream in the coking unit furnace to a predetermined coking temperature; and f. passing the heated mixed feedstream to a drum of the delayed coking to produce a delayed coking product stream while depositing the adsorbent material having adsorbed sulfur and/or nitrogen compounds with the coke in the coking drum.
摘要翻译：延迟焦化过程包括：a。引入含有不希望的硫和/或氮化合物的新鲜烃原料用于预热到焦化装置产品分馏器的下部; b。引入至少一部分来自分馏器的中间馏分和至少一种选择性地将含硫和/或含氮化合物吸附到混合区中以形成吸附浆料流的吸附剂材料; C。从分馏器排出塔底馏分; d。将全部或一部分浆料流加入塔底馏分以形成混合焦化装置进料流; e。将焦化单元炉中的混合进料流加热到预定的焦化温度; 和f。将加热的混合进料流通入延迟焦化的滚筒以产生延迟焦化产物流，同时将具有吸附的硫和/或氮化合物的吸附材料与焦炭放置在焦化鼓中。

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