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31. 发明申请

US20100040823A1 HARDCOAT AGENT COMPOSITION AND OPTICAL INFORMATION MEDIUM THEREOF 有权
标题翻译： HARDCOAT试剂组合物及其光学信息介质
公开(公告)号：US20100040823A1
公开(公告)日：2010-02-18
申请号：US12581958
申请日：2009-10-20
申请人： Naoki Hayashida , Rie Ihara , Hidetake Itoh , Kazushi Tanaka
发明人： Naoki Hayashida , Rie Ihara , Hidetake Itoh , Kazushi Tanaka
IPC分类号： B32B3/02
CPC分类号： C09D175/16 , C08G18/672 , G11B7/2534 , G11B7/2542 , G11B7/2545 , G11B7/256 , G11B7/2585 , G11B2007/2431 , G11B2007/24312 , G11B2007/24314 , G11B2007/24316 , G11B2007/25706 , G11B2007/2571 , G11B2007/25715 , G11B2007/25716 , Y10T428/21 , C08G18/50
摘要： A hardcoat agent composition comprising a fluorine-containing polyether compound (A) having a perfluoropolyether unit, urethane bond and active energy ray reactive group and a curable compound (B) having equal to or more than 2 active energy ray polymerizing groups in the molecule. An optical information medium having a film substance composed of single or multiple layers containing at least the recording layer 4 or the reflecting layer on the supporting substrate 20, the optical information medium wherein at least either the surface of the supporting substrate 20 or that of the above-mentioned film substance is formed by the hardcoat layer 8 containing a curable substance of the above-mentioned hardcoat agent composition.
摘要翻译：包含具有全氟聚醚单元，氨基甲酸酯键和活性能量射线反应性基团的含氟聚醚化合物（A）和分子中具有等于或大于2个活性能量射线聚合基团的固化性化合物（B）的硬涂层剂组合物。一种光学信息介质，其具有由至少包含记录层4或支撑基板20上的反射层的单层或多层构成的薄膜物质，光学信息介质，其中支撑基板20的表面或上述膜物质由含有上述硬涂层剂组合物的固化性物质的硬涂层8形成。

32. 发明授权

US07452609B2 Article having composite hard coat layer and method for forming composite hard coat layer 失效
标题翻译：具有复合硬涂层的制品和形成复合硬涂层的方法
公开(公告)号：US07452609B2
公开(公告)日：2008-11-18
申请号：US10499648
申请日：2002-12-20
申请人： Naoki Hayashida , Kazushi Tanaka
发明人： Naoki Hayashida , Kazushi Tanaka
IPC分类号： B32B27/30 , B05D3/02
CPC分类号： G11B7/252 , G11B7/2534 , G11B7/2542 , G11B7/2585 , G11B7/26 , G11B7/266 , G11B2007/2431 , G11B2007/24312 , G11B2007/24314 , G11B2007/24316 , G11B2007/25706 , G11B2007/2571 , G11B2007/25715 , G11B2007/25716 , Y10T428/31667 , Y10T428/31928 , Y10T428/31935
摘要： The present invention provides inexpensively an article with a hard coat excellent in anti-staining property, lubricity, scratch resistance and abrasion resistance. The present invention provides a method for forming the hard coat. A hard coat agent composition comprising an active energy ray-curable compound is applied onto a surface of an article 1 to be hard-coat-treated, thereby forming a hard coat agent composition layer, a surface material layer is formed by film-forming with a surface layer material comprising an active energy ray-curable compound having anti-staining property and/or lubricating property on the surface of the hard coat agent composition layer, and active energy rays are irradiated onto the formed hard coat agent composition layer and surface material layer so as to cure the two layers simultaneously, thereby forming a hard coat layer 2 contacting the surface of the article 1 and an anti-staining surface layer 3 contacting the surface of the hard coat layer 2.
摘要翻译：本发明廉价地提供具有抗污染性，润滑性，耐擦伤性和耐磨性优异的硬涂层的制品。本发明提供一种形成硬涂层的方法。将包含活性能量射线固化性化合物的硬涂层剂组合物涂布在待硬涂层处理的制品1的表面上，形成硬涂层组合物层，通过成膜形成表面材料层，包含在硬涂层组合物层的表面上具有抗污染性和/或润滑性的活性能量射线固化性化合物的表层材料和活性能量射线照射到形成的硬涂层组合物层和表面材料以便同时固化两层，从而形成与制品1的表面接触的硬涂层2和与硬涂层2的表面接触的防污表面层3。

33. 发明授权

US07235292B2 Article with composite hard coat layer and method for forming composite hard coat layer 有权
标题翻译：复合硬涂层和复合硬涂层形成方法
公开(公告)号：US07235292B2
公开(公告)日：2007-06-26
申请号：US10503130
申请日：2003-02-17
申请人： Naoki Hayashida , Kazushi Tanaka
发明人： Naoki Hayashida , Kazushi Tanaka
IPC分类号： B32B27/06 , B32B27/16 , B32B27/26 , C08J7/18
CPC分类号： G02B1/14 , B05D3/067 , G02B1/10 , G02B1/18 , G02B5/3041 , Y10T428/265 , Y10T428/31504 , Y10T428/31511 , Y10T428/31515 , Y10T428/3154 , Y10T428/31663 , Y10T428/31855
摘要： The present invention provides inexpensively an article with a hard coat excellent in anti-staining property, lubricity, scratch resistance and abrasion resistance. The present invention also provides a method for forming the hard coat. A hard coat agent composition comprising a cationic polymerization curing compound is applied onto a surface of an article (1) to be hard-coat-treated, thereby forming a hard coat agent composition layer, a surface material layer is formed by film-forming with a surface layer material comprising a cationic polymerization curing compound having anti-staining property and/or lubricating property on a surface of the hard coat agent composition layer, and active energy rays are irradiated onto the formed hard coat agent composition layer and surface material layer, or the both layers are heated so as to cure the both layers simultaneously, thereby forming a hard coat layer (2) contacting the surface of the article (1) and an anti-staining surface layer (3) contacting the surface of the hard coat layer (2).
摘要翻译：本发明廉价地提供具有抗污染性，润滑性，耐擦伤性和耐磨性优异的硬涂层的制品。本发明还提供了形成硬涂层的方法。将包含阳离子聚合固化化合物的硬涂层剂组合物施加到待硬涂层处理的制品（1）的表面上，形成硬涂层组合物层，通过成膜形成表面材料层，包含在硬涂层组合物层的表面具有抗污染性和/或润滑性的阳离子聚合固化化合物和活性能量射线的表层材料照射到所形成的硬涂层组合物层和表面材料层上，或者两层被加热以同时固化两层，从而形成与制品（1）的表面接触的硬涂层（2）和与硬涂层的表面接触的抗染色表面层（3）层（2）。

34. 发明授权

US07138155B2 Method for evaluating optical information medium and optical information medium 有权
标题翻译：光信息介质和光信息介质评估方法
公开(公告)号：US07138155B2
公开(公告)日：2006-11-21
申请号：US11106424
申请日：2005-04-15
申请人： Hidetake Itoh , Kazushi Tanaka , Naoki Hayashida
发明人： Hidetake Itoh , Kazushi Tanaka , Naoki Hayashida
IPC分类号： B05D7/00
CPC分类号： G11B7/00375 , G01N13/02 , G11B7/2467 , G11B7/2542 , G11B7/259 , G11B7/268 , G11B2007/24312 , G11B2007/24314 , G11B2007/24316 , G11B2007/25708 , G11B2007/25715
摘要： A simple method for evaluating an optical information medium by judging quantitatively and reproducibly the surface quality of the optical information medium by the use of an artificial fingerprint liquid as an evaluation dispersion liquid, is provided. An optical information medium having a remarkably excellent anti-staining property of the surface which is on the incident side of recording/reproducing beam is provided. A method for evaluating an optical information medium, comprising: adhering an artificial fingerprint liquid containing a fine-particle-form substance and a dispersion medium capable of dispersing the fine-particle-form substance onto the surface of the optical information medium which is on the incident side of a recording/reproducing beam; observing the state of the artificial fingerprint liquid droplets adhered to the surface; and judging the quality of the medium surface.
摘要翻译：提供了一种用于通过使用人造指纹液作为评价分散液定量地且可再现地评估光学信息介质的表面质量来评估光学信息介质的简单方法。提供具有在记录/再现光束的入射侧的表面的非常优异的抗污染性的光学信息介质。一种用于评估光学信息介质的方法，包括：将含有细颗粒形式物质的人造指纹液和能够将细颗粒形式物质分散的分散介质粘附在光学信息介质的表面上记录/再现光束的入射侧; 观察附着在表面上的人造指纹液滴的状态; 并判断介质表面的质量。

35. 发明授权

US07012160B2 Fluorine-containing acetophenone derivative, surface layer material containing the same as photo initiator, article with composite hard coat layer, and method for forming composite hard coat layer 有权
标题翻译：含氟苯乙酮衍生物，与光引发剂相同的表层材料，复合硬涂层的制品和复合硬涂层的形成方法
公开(公告)号：US07012160B2
公开(公告)日：2006-03-14
申请号：US10793268
申请日：2004-03-05
申请人： Naoki Hayashida , Kazushi Tanaka
发明人： Naoki Hayashida , Kazushi Tanaka
IPC分类号： C07C49/76 , C07C233/00 , B05D1/02 , B32B5/16 , G02C7/04
CPC分类号： C07C69/708 , C07C69/63 , Y10T428/25 , Y10T428/252 , Y10T428/259
摘要： The present invention provides a new fluorine-containing acetophenone derivative useful as a photo initiator, and a surface layer material containing the fluorine-containing acetophenone derivative. The present invention provides inexpensively an article with a hard coat excellent in anti-staining property, lubricity, scratch resistance and abrasion resistance, and provides a method for forming the hard coat. A fluorine-containing acetophenone derivative represented by the following general formula (I): wherein R1, R2 and R3 each independently represent an organic group other than aryl group, a hydrogen atom, a halogen atom or a hydroxyl group, provided that the following case does not take place: all of R1, R2 and R3 are simultaneously hydrogen atoms; and any two of R1, R2 and R3 may be linked to each other to form a ring, and R4 represents a fluorine-containing organic group. Hard coat layer 2 is formed to contact a surface of an article, and a fluorine-containing surface layer 3 using the compound is formed to contact a surface of the hard coat layer 2.
摘要翻译：本发明提供可用作光引发剂的新的含氟苯乙酮衍生物和含有含氟苯乙酮衍生物的表层材料。本发明廉价地提供了具有优异的抗污染性，润滑性，耐擦伤性和耐磨性的硬涂层的制品，并且提供了形成硬涂层的方法。由以下通式（I）表示的含氟苯乙酮衍生物：其中R 1，R 2和R 3各自独立地表示除了芳基以外的有机基团，氢原子，卤素原子或羟基，条件是不发生以下情况：R 1，R 2， R 3和R 3同时为氢原子; 并且R 1，R 2和R 3中的任何两个可以彼此连接形成环，并且R 4 表示含氟有机基团。形成硬涂层2与制品的表面接触，并且使用该化合物的含氟表面层3形成为与硬涂层2的表面接触。

36. 发明申请

US20050248881A1 Methods for producing optical recording medium and optical recording medium 有权
标题翻译：光记录介质和光记录介质的制造方法
公开(公告)号：US20050248881A1
公开(公告)日：2005-11-10
申请号：US11101423
申请日：2005-04-08
申请人： Naoki Hayashida , Kazushi Tanaka
发明人： Naoki Hayashida , Kazushi Tanaka
IPC分类号： G11B5/74 , G11B7/243 , G11B7/253 , G11B7/254 , G11B7/26
CPC分类号： G11B7/266 , G11B7/243 , G11B7/253 , G11B7/254 , Y10T428/21
摘要： The present invention provides a method for producing an optical recording medium having: a supporting substrate; a light transmission layer, which transmits a laser beam; and an information layer formed between the supporting substrate and the light transmission layer, which includes: applying a resin composition on the information layer by a spin coating method to form a coating film, wherein the resin composition contains, as main components: (A) a radical-curing urethane(meth)acrylate, which is obtained by reacting (a-1) a compound having three or more isocyanate groups binding to an aliphatic carbon atom per one molecule thereof and (a-2) a polycaprolacton-modified hydroxyethyl(meth)acrylate; and (B) a radical-curing monomer having a viscosity of 400 mPa.s or less at 25° C., curing the coating film by irradiating the coating film with an ultraviolet light or an electron beam to form the light transmission layer.
摘要翻译：本发明提供一种光记录介质的制造方法，其具有：支撑基板; 传输激光束的光透射层; 以及形成在所述支撑基板和所述透光层之间的信息层，其包括：通过旋涂法在所述信息层上涂布树脂组合物以形成涂膜，其中所述树脂组合物含有作为主要成分的主要成分：（A）通过使（a-1）具有三个以上与每一分子中的脂肪族碳原子结合的异氰酸酯基的化合物与（a-2）聚己内酯改性的羟乙基（A-1）反应而得到的自由基固化性氨基甲酸酯（甲基）甲基）丙烯酸酯; 和（B）在25℃下粘度为400mPa.s以下的自由基固化性单体，通过用紫外线或电子束照射该涂膜使该涂膜固化，形成透光层。

37. 发明申请

US20050196576A1 Method for evaluating optical information medium and optical information medium 有权
公开(公告)号：US20050196576A1
公开(公告)日：2005-09-08
申请号：US11106436
申请日：2005-04-15
申请人： Hidetake Itoh , Kazushi Tanaka , Naoki Hayashida , Hiroshi Take
发明人： Hidetake Itoh , Kazushi Tanaka , Naoki Hayashida , Hiroshi Take
IPC分类号： B05D5/06 , B32B3/02 , G01N13/02 , G11B7/0037 , G11B7/24 , G11B7/243 , G11B7/246 , G11B7/2467 , G11B7/254 , G11B7/2542 , G11B7/257 , G11B7/258 , G11B7/259 , G11B7/26
CPC分类号： G11B7/00375 , G01N13/02 , G11B7/2467 , G11B7/2542 , G11B7/259 , G11B7/268 , G11B2007/24312 , G11B2007/24314 , G11B2007/24316 , G11B2007/25708 , G11B2007/25715
摘要： A simple method for evaluating an optical information medium by judging quantitatively and reproducibly the surface quality of the optical information medium by the use of an artificial fingerprint liquid as an evaluation dispersion liquid, is provided. An optical information medium having a remarkably excellent anti-staining property of the surface which is on the incident side of recording/reproducing beam is provided. A method for evaluating an optical information medium, comprising: adhering an artificial fingerprint liquid containing a fine-particle-form substance and a dispersion medium capable of dispersing the fine-particle-form substance onto the surface of the optical information medium which is on the incident side of a recording/reproducing beam; observing the state of the artificial fingerprint liquid droplets adhered to the surface; and judging the quality of the medium surface. For example, the quality of the medium surface is judged by: (1) Measurement of the area ratio of the surface occupied with the artificial fingerprint liquid droplets adhered per unit area of the surface; (2) Measurement of the diameter of the artificial fingerprint liquid droplets adhered to the surface; (3) Measurement of the number of the artificial fingerprint liquid droplets adhered per unit area of the surface; or (4) Measurement of the degree of roundness of the artificial fingerprint liquid droplets adhered to the surface.

38. 发明申请

US20050158558A1 Method of obtaining 3-d coordinates 审中-公开
标题翻译：获得3-d坐标的方法
公开(公告)号：US20050158558A1
公开(公告)日：2005-07-21
申请号：US10505020
申请日：2003-06-23
申请人： Naoki Hayashida , Kenji Yoneyama , Kazushi Tanaka
发明人： Naoki Hayashida , Kenji Yoneyama , Kazushi Tanaka
IPC分类号： B05D5/08 , B05D7/00 , C08J7/04 , G01B11/00 , G01B11/03 , G02B1/10 , G02B21/00 , G02B21/22 , G02B21/24 , G02B21/36 , G11B7/243 , G11B7/253 , G11B7/2534 , G11B7/254 , G11B7/2542 , G11B7/257 , G11B7/258 , G11B7/2585 , G11B11/105 , C08F2/46 , B32B27/00
CPC分类号： B05D7/532 , B05D5/083 , C08J7/04 , C08J7/047 , C08J2369/00 , G02B1/105 , G02B1/14 , G02B1/18 , G02B21/0016 , G02B21/22 , G02B21/241 , G02B21/365 , G11B7/252 , G11B7/2534 , G11B7/2542 , G11B7/2585 , G11B11/10589 , G11B2007/2431 , G11B2007/24312 , G11B2007/24314 , G11B2007/24316 , G11B2007/25706 , G11B2007/25708 , G11B2007/2571 , G11B2007/25715 , G11B2007/25716 , Y10T428/3154
摘要： The present invention provides inexpensively an article with a hard coat excellent in anti-staining property, lubricity, scratch resistance and abrasion resistance. The present invention also provides a method for forming the hard coat. A hard coat agent composition comprising an active energy ray-curable compound is applied onto a surface of an article (1) to be hard-coat-treated, thereby forming a hard coat agent composition layer, a surface material layer is formed by film-forming with a surface material comprising a fluorine-containing polyfunctional (meth)acrylate compound and a fluorine-containing monofunctional (meth)acrylate compound on the surface of the hard coat agent composition layer, and active energy rays are irradiated onto the formed hard coat agent composition layer and surface material layer so as to cure the both layers simultaneously, thereby forming a hard coat layer (2) contacting the surface of the article (1) and an anti-staining surface layer (3) contacting the surface of the hard coat layer (2).
摘要翻译：本发明廉价地提供具有抗污染性，润滑性，耐擦伤性和耐磨性优异的硬涂层的制品。本发明还提供了形成硬涂层的方法。将包含活性能量射线固化性化合物的硬涂层剂组合物施加到待硬涂层处理的制品（1）的表面上，由此形成硬涂层组合物层，通过膜 - 在硬涂层组合物层的表面上形成含有含氟多官能（甲基）丙烯酸酯化合物和含氟单官能（甲基）丙烯酸酯化合物的表面材料，并将活性能量射线照射到形成的硬涂层组合物层和表面材料层，以同时固化两层，从而形成与制品（1）的表面接触的硬涂层（2）和与硬涂层表面接触的抗染色表面层（3）层（2）。

39. 发明授权

US06596363B2 Optical information medium 有权
标题翻译：光信息媒体
公开(公告)号：US06596363B2
公开(公告)日：2003-07-22
申请号：US09829067
申请日：2001-04-10
申请人： Naoki Hayashida , Hideki Hirata
发明人： Naoki Hayashida , Hideki Hirata
IPC分类号： B32B302
CPC分类号： G11B7/2548 , G11B7/252 , G11B7/2534 , G11B7/2542 , G11B7/2545 , G11B7/2575 , G11B7/2578 , G11B2007/25417 , Y10T428/21
摘要： An optical information medium which has excellent abrasion resistance and which further exhibits sufficient smudge-proof properties is provided. The optical information medium is coated on at least one surface with a film of a silane coupling agent containing a water- or oil-repellent substituent, said silane coupling agent being represented by the following formula (1): R1—Si(X)(Y)(Z) wherein R1 is the water- or oil-repellent substituent; X, Y and Z are independently a monovalent group; and at least one of X, Y and Z is a group which is capable of forming Si—O—Si bond by polycondensation with silanol group; and said medium has an underlying layer formed in contact with said silane coupling agent film, and at least the surface of said underlying layer comprises a compound having a chemical bond represented by the formula (2): M—A wherein M is a metal atom (including a semimetal), and A is a chalcogen atom selected from O, S, Se, and Te, nitrogen atom, or carbon atom.
摘要翻译：提供了具有优异的耐磨性并进一步显示足够防污性的光学信息介质。所述光学信息介质在至少一个表面上涂布含有斥水斥油剂取代基的硅烷偶联剂的膜，所述硅烷偶联剂由下式（1）表示：其中R 1是水或拒油取代基; X，Y和Z独立地为一价基团; X，Y和Z中的至少一个是能够通过与硅烷醇基缩聚而形成Si-O-Si键的基团。并且所述介质具有与所述硅烷偶联剂膜接触形成的下层，并且至少所述下层的表面包含具有由式（2）表示的化学键的化合物：其中M是金属原子（包括半金属），A是选自O，S，Se和Te，氮原子或碳原子的硫属原子。

40. 发明授权

US07493801B2 Artificial finger print liquid, testing method for optical information medium using it, and optical information medium 有权
标题翻译：人造手指液体，使用它的光学信息介质的测试方法和光学信息介质
公开(公告)号：US07493801B2
公开(公告)日：2009-02-24
申请号：US11566453
申请日：2006-12-04
申请人： Naoki Hayashida , Toshifumi Tanaka , Kazushi Tanaka
发明人： Naoki Hayashida , Toshifumi Tanaka , Kazushi Tanaka
IPC分类号： G01N33/00
CPC分类号： G11B7/268 , C09D11/00 , G11B7/00375 , G11B11/10582 , Y10T428/21 , Y10T428/31663
摘要： A low-cost artificial fingerprint liquid for quantitatively and with a good reproducibility evaluating an anti-staining property, and a fingerprint adhering property or a fingerprint removing property on the surface of an optical disk such as a reproduction-only optical disk, optical recording disk, magneto-optical recording disk, various displays such as a CRT, and various substances such as glass including a fine-particle-form substance and a dispersion medium capable of dispersing the fine-particle-form substance.
摘要翻译：一种低成本人造指纹液，用于定量地且具有良好的再现性，评估抗污染性，以及指纹附着性能或指纹去除性能在诸如仅再现光盘的光盘的表面上，光记录盘磁光记录盘，诸如CRT的各种显示器，以及包括微粒形式物质的玻璃等各种物质和能够分散微粒形式物质的分散介质。

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