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31. 发明授权

US5631082A Pressure-sensitive adhesive material 失效
标题翻译：压敏粘合剂材料
公开(公告)号：US5631082A
公开(公告)日：1997-05-20
申请号：US113515
申请日：1993-08-30
申请人： Toshifumi Hirose , Katsuhiko Isayama
发明人： Toshifumi Hirose , Katsuhiko Isayama
IPC分类号： C09J7/02 , C09J201/10
CPC分类号： C09J201/10 , C09J7/0282 , C09J2433/00 , C09J2483/006 , Y10T428/28 , Y10T428/2891 , Y10T428/31663
摘要： a tape or sheet form pressure-sensitive adhesive material which comprises a substrate which is obtainable by curing a curable resin composition comprising:(A) an organic elastomeric polymer which is liquid at room temperature and has, in a molecule, at least one silicon-containing group to the silicon atom of which at lease one hydroxyl group or hydrolyzable group is bonded and which is cross linkable through formation of a siloxane bond,(B) a curing catalystand(C) optionally a tackifier resin and a pressure-sensitive adhesive layer laminated on said substrate, which has good flexibility and increased adhesive force such as adhesive strength under shear and peel strength.
摘要翻译：一种胶带或片状压敏粘合剂材料，其包含可通过固化可固化树脂组合物获得的基材，该基材含有：（A）有机弹性体聚合物，其在室温下为液体，并且在分子中具有至少一个硅 - （B）固化催化剂和（C）任选的增粘树脂和压敏粘合剂，（C）任选的增粘树脂和粘合剂层压在所述基材上，其具有良好的柔韧性和增加的粘合力，例如在剪切和剥离强度下的粘合强度。

32. 发明授权

US5223495A Coating composition containing a hydrolyzable silyl group containing vinylic polymer 失效
标题翻译：含有含乙烯基聚合物的可水解硅烷基的涂料组合物
公开(公告)号：US5223495A
公开(公告)日：1993-06-29
申请号：US610897
申请日：1990-11-09
申请人： Masaharu Inoue , Hisao Furukawa , Yasushi Kato , Katsuhiko Isayama
发明人： Masaharu Inoue , Hisao Furukawa , Yasushi Kato , Katsuhiko Isayama
IPC分类号： C09D183/06 , C08L43/04 , C08L83/04 , C09D143/04 , C09D183/04 , C09D183/07
CPC分类号： C09D143/04 , C09D183/04 , C08L2205/02 , C08L43/04 , C08L83/04
摘要： A curable coating composition comprising(A) from 10 to 99 parts by weight of a silyl group-containing vinylic polymer having a number average molecular weight of at least 3,000, the main chain thereof being substantially composed of a vinylic polymer chain and having at least one silicon atom bonded to a hydrolyzable group at a terminal of the main chain and/or at a side chain in each molecule,(B) from 1 to 90 parts by weight of an organic compound having a number average molecular weight of not larger than 3,000 and having at least one silicon atom bonded to a hydrolyzable group at a terminal in each molecule, and(C) from 1 to 500 parts by weight of silanol-containing organopolysiloxane having, on an average, at least one sianol group in one molecule to 100 parts by weight of the total amount of the component (A) and the component (B).

33. 发明授权

US4965311A Curing composition having enhancing effect on drying characteristics of alkyd coating 失效
标题翻译：具有增强醇酸树脂涂层干燥特性的固化组合物
公开(公告)号：US4965311A
公开(公告)日：1990-10-23
申请号：US305137
申请日：1989-02-02
申请人： Toshifumi Hirose , Sadao Yukimoto , Katsuhiko Isayama
发明人： Toshifumi Hirose , Sadao Yukimoto , Katsuhiko Isayama
IPC分类号： C08J7/04 , C08K5/01 , C08L33/00 , C08L33/04 , C08L47/00 , C08L63/00 , C08L63/10 , C08L67/08 , C08L71/02 , C08L83/02 , C08L83/10 , C08L91/00
CPC分类号： C08J7/047 , C08L71/02 , C08J2371/02 , C08J2467/00
摘要： A curing composition showing improved drying characteristics of an alkyd coating which comprises:(A) an oxyalkylene polymer having at least one silicon atom-containing group which has a hydroxyl group or a hydrolyzable group bound to a silicon atom and is capable of crosslinking by forming a siloxane bond;(B) a polymeric plasticizer and/or a viscous plasticizer; and(C) an air curing compound.

34. 发明授权

US4774356A Process for preparing polyalkylene oxide having unsaturated end groups 失效
标题翻译：制备具有不饱和端基的聚环氧烷的方法
公开(公告)号：US4774356A
公开(公告)日：1988-09-27
申请号：US843389
申请日：1986-03-24
申请人： Shohei Inoue , Takuzo Aida , Michihide Honma , Katsuhiko Isayama
发明人： Shohei Inoue , Takuzo Aida , Michihide Honma , Katsuhiko Isayama
IPC分类号： C08G65/32 , C08G65/12 , C08G65/332 , C08G65/337 , C07C69/52 , C07C43/11
CPC分类号： C08G65/3322 , C08G65/12 , C08G65/337
摘要： Polypropylene oxide having unsaturated end groups is prepared by polymerizing alkylene oxide in the presence of a complex catalyst prepared by reacting an organoaluminum compound with a porphyrin compound and an active hydrogen-containing compound and converting at least one hydroxyl end groups into an unsaturated end group(s), the prepared polymer having a narrow distribution of molecular weight.
摘要翻译：具有不饱和端基的聚环氧丙烷通过在有机铝化合物与卟啉化合物和含活性氢化合物反应制备的复合催化剂的存在下聚合烯化氧并将至少一个羟基端基转化为不饱和端基来制备（ s），所制备的聚合物分子量分布窄。

35. 发明授权

US4687818A Polymer and pressure sensitive adhesive composition 失效
标题翻译：聚合物和压敏粘合剂组合物
公开(公告)号：US4687818A
公开(公告)日：1987-08-18
申请号：US759877
申请日：1985-07-29
申请人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
发明人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
IPC分类号： C08F291/00 , C08F283/06 , C08F290/06 , C08L57/00 , C08L71/02 , C08L83/12
CPC分类号： C08L57/00 , C08F290/062 , C08L71/02 , C08L83/12
摘要： A novel moisture-curable polymer useful as a pressure sensitive adhesive, a paint, a sealant, etc. obtained by polymerizing a polymerizable monomer in the presence of an organic polymer having at least one reactive silicon-containing functional group in the molecule on the average. A pressure sensitive adhesive composition having excellent adhesive property as well as excellent initial tackiness, heat resistance, workability and weather resistance comprising a polymer obtained by polymerizing a polymerizable monomer in the presence of (A) an organic polymer having at least one reactive silicon functional group in the molecule on the average and/or (B) an organic polymer having at least one olefin group in the molecule on the average. The composition is also useful as a sealant, a coating material, a packing, an electric insulation, a corrosionproof, a masking and a surface-protection.
摘要翻译：在分子中具有至少一个反应性含硅官能团的有机聚合物的存在下，通过使可聚合单体聚合而获得的用作压敏粘合剂，油漆，密封剂等的新型湿气固化性聚合物平均。一种具有优异的粘合性能以及优异的初始粘合性，耐热性，可加工性和耐候性的压敏粘合剂组合物，其包含通过在（A）具有至少一个反应性硅官能团的有机聚合物存在下使可聚合单体聚合而获得的聚合物在平均分子中和/或（B）平均分子中具有至少一个烯基的有机聚合物。该组合物还可用作密封剂，涂料，包装，电绝缘，防腐，掩蔽和表面保护。

36. 发明授权

US4665127A Pressure sensitive adhesive composition 失效
标题翻译：压敏胶组合物
公开(公告)号：US4665127A
公开(公告)日：1987-05-12
申请号：US770475
申请日：1985-08-29
申请人： Toshifumi Hirose , Katsuhiko Isayama
发明人： Toshifumi Hirose , Katsuhiko Isayama
IPC分类号： C08L71/00 , C08G65/332 , C08G65/336 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L71/02 , C08L77/00 , C08L101/00 , C09J7/02 , C09J11/06 , C09J133/04 , C09J133/08 , C09J171/00 , C09J171/02 , C09J183/10 , C09J201/00 , C08F8/00
CPC分类号： C09J7/0207 , C08G65/3322 , C08G65/336 , C09J171/02 , C09J183/10 , Y10T428/31663
摘要： A pressure sensitive adhesive composition comprising:(A) an organic polymer having in its molecule at least one reactive silicon-containing group represented by the formula (I): ##STR1## wherein R.sup.2 is a monovalent hydrocarbon group having 1 to 20 carbon atoms or a triorganosiloxy group having the formula (II):(R').sub.3 SiO-- (II) in which R' is a monovalent hydrocarbon group having 1 to 20 carbon atoms and may be the same or different, X is hydroxyl group or a hydrolyzable group, and may be the same or different when 2 or more X groups are attached, a is O or an integer of 1 to 3, b is 0, 1 or 2, and m is O or an integer of 1 to 18, and(B) 0.1 to 20 parts by weight of, per 100 parts by weight of the organic polymer, at least one curing catalyst selected from the group consisting of an organic aluminum and an organic zirconium. The composition has excellent heat resistance and releasability from substrates, e.g. a release paper coated with a silicone release agent.
摘要翻译：一种压敏粘合剂组合物，其包含：（A）在其分子中具有由式（I）表示的至少一种反应性含硅基团的有机聚合物：其中R 2是具有1至20个的一价烃基碳原子或具有式（II）的三有机甲硅烷氧基：（R'）3 SiO - （II）其中R'是具有1至20个碳原子的一价烃基，可以相同或不同，X是羟基或 2个以上的X基，a为0或1〜3的整数，b为0,1或2，m为0或1〜18的整数时，可以相同或不同。，和（B）每100重量份有机聚合物0.1至20重量份的至少一种选自有机铝和有机锆的固化催化剂。该组合物具有优异的耐热性和与底物的脱模性，例如涂有硅酮脱模剂的剥离纸。

37. 发明授权

US4618653A Novel polymer and cured product of the same 失效
标题翻译：新型聚合物和固化产物相同
公开(公告)号：US4618653A
公开(公告)日：1986-10-21
申请号：US727296
申请日：1985-04-25
申请人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
发明人： Fumio Kawakubo , Miyako Takanoo , Sadao Yukimoto , Katsuhiko Isayama
IPC分类号： C08F2/00 , C08F2/02 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/28 , C08F4/32 , C08F4/42 , C08F4/72 , C08F283/00 , C08F283/06 , C08F283/12 , C08F290/12 , C08G77/46 , C08L71/02
CPC分类号： C08F290/12 , C08F283/004 , C08F283/124
摘要： A polymer which is prepared by polymerizing at least one polymerizable monomer in the presence of an organic polymer having a reactive silicone group and a polymerizable ethylenically unsaturated group in a molecule, the total number of the silicone group and the unsaturated group being on the average not less than 1.1 and the number of the ethylenically unsaturated group being on the average not less than 0.1 by use of a radical polymerization initiator having a reactive silicone group and/or a chain transfer agent having a reactive silicone group, which is cured with moisture to give a product having improved properties such as tensile properties and weather resistance.
摘要翻译：通过在分子中具有反应性硅氧烷基和可聚合的烯键式不饱和基团的有机聚合物的存在下使至少一种可聚合单体聚合制备的聚合物，硅氧烷基和不饱和基团的总数平均不是通过使用具有反应性硅氧烷基团的自由基聚合引发剂和/或具有反应性硅氧烷基团的链转移剂，烯键式不饱和基团的数量平均不小于0.1，其通过水分固化得到具有改善的性能如拉伸性能和耐候性的产品。

38. 发明授权

US3951888A Process for preparing polyoxyalkylene having allyl end-group 失效
标题翻译：制备具有烯丙基端基的聚氧化烯的方法
公开(公告)号：US3951888A
公开(公告)日：1976-04-20
申请号：US477409
申请日：1974-06-07
申请人： Katsuhiko Isayama , Itaru Hatano
发明人： Katsuhiko Isayama , Itaru Hatano
IPC分类号： C08G65/337 , C08G65/32
CPC分类号： C08G65/337
摘要： A process for preparing a polyalkylene oxide having allyl end-group, by subjecting an alkylene oxide monomer to addition polymerization in the presence of potassium hydroxide in an amount of 2 to 30% by mole to the monomer at a temperature of 20.degree. to 100.degree.C., and reacting the polymerized alkylene oxide with an allyl halide compound, or by subjecting the monomer to addition polymerization in the presence of potassium hydroxide, reacting the polymerized alkylene oxide with an organic polyhalide and then reacting with an allyl halide compound. Potassium hydroxide is preferably employed in combination with the specific initiator. There can be prepared polyalkylene oxide of which all of the chain ends are substantially allyl group.
摘要翻译：一种制备具有烯丙基端基的聚环氧烷烃的方法，该方法是在二氧化碳单体在氢氧化钾存在下，在20〜100℃的温度下，以2〜30摩尔％的量进行加成聚合。使聚合的烯化氧与烯丙基卤化物反应，或在氢氧化钾存在下使单体进行加成聚合，使聚合的烯化氧与有机多卤化物反应，然后与烯丙基卤化物反应。氢氧化钾优选与特定引发剂组合使用。可以制备其全部链端基本上是烯丙基的聚环氧烷。

39. 发明授权

US5185418A Hydrolyzable silyl group-containing azo compound, process for producing the same and silyl group-containing vinyl polymer produced by using the same 失效
标题翻译：含有水解性甲硅烷基的偶氮化合物，其制造方法和使用该方法生产的含甲硅烷基的乙烯基聚合物
公开(公告)号：US5185418A
公开(公告)日：1993-02-09
申请号：US863270
申请日：1992-04-03
申请人： Hisao Furukawa , Katsuhiko Isayama , Yasushi Kato
发明人： Hisao Furukawa , Katsuhiko Isayama , Yasushi Kato
IPC分类号： C07F7/18 , C08F2/00 , C08F4/04 , C08F8/42
CPC分类号： C07F7/182 , C08F4/04 , C08F8/42
摘要： A hydrolyzable silyl group-containing azo compound is represented by the following general formula (I): ##STR1## wherein A represents a group originating from an azo compound having one or more active hydrogen groups;R.sup.1 represents a monovalent organic group;R.sup.2 represents a divalent organic group;X represents a hydrolyzable group;Y represents --O--, --S--, ##STR2## m is an integer of 1 to 3; and n is an integer of 1 or 2;and process for producing the same is disclosed. The hydrolyzable silyl group-containing azo compound is used to prepare a hydrolyzable silyl group-containing vinyl polymer produced by polymerizing vinyl monomer as a radical polymerization initiator.
摘要翻译：含有水解性甲硅烷基的偶氮化合物由以下通式（I）表示：其中A表示源自具有一个或多个活性氢基团的偶氮化合物的基团; R1表示一价有机基团; R2表示二价有机基团; X表示水解性基团; Y表示-O - ， - S-，m表示1〜3的整数。 n为1或2的整数; 并公开了其制造方法。含有水解性甲硅烷基的偶氮化合物用于制备通过聚合乙烯基单体作为自由基聚合引发剂制备的可水解甲硅烷基的乙烯基聚合物。

40. 发明授权

US4904745A Polyalkylene oxide having unsaturated end group and narrow molecular weight distribution 失效
标题翻译：具有不饱和端基和窄分子量分布的聚环氧烷
公开(公告)号：US4904745A
公开(公告)日：1990-02-27
申请号：US170571
申请日：1988-03-14
申请人： Shohei Inoue , Takuzo Aida , Michihide Honma , Katsuhiko Isayama
发明人： Shohei Inoue , Takuzo Aida , Michihide Honma , Katsuhiko Isayama
IPC分类号： C08G65/12 , C08G65/337
CPC分类号： C08G65/337 , C08G65/12
摘要： A polyalkylene oxide having unsaturated end groups. The polymer has a distribution of molecular weight Mw/Mn of not more than 1.5, and a process for the same. The polymer is useful as rubber materials, and can provide cured rubber having an excellent elongation.
摘要翻译：具有不饱和端基的聚环氧烷。聚合物的分子量Mw / Mn不大于1.5，其分子量为1.5以上。聚合物可用作橡胶材料，并且可以提供具有优异伸长率的固化橡胶。

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