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31. 发明授权

US07939174B2 Heat-shrinkable polyester film roll and a process for producing the same 有权
标题翻译：热收缩聚酯薄膜卷及其制造方法
公开(公告)号：US07939174B2
公开(公告)日：2011-05-10
申请号：US11159144
申请日：2005-06-23
申请人： Satoshi Hayakawa , Norimi Tabota , Yoshinori Takegawa , Katsuya Ito , Shigeru Komeda , Katsuhiko Nose
发明人： Satoshi Hayakawa , Norimi Tabota , Yoshinori Takegawa , Katsuya Ito , Shigeru Komeda , Katsuhiko Nose
IPC分类号： B32B27/36 , C08G63/16 , C08G63/18 , C08G63/181 , C08G63/183
CPC分类号： C08J5/18 , B29C55/00 , B29C61/003 , B29K2067/00 , C08J2367/02 , Y10S428/91 , Y10T428/1328 , Y10T428/1331 , Y10T428/24 , Y10T428/31786
摘要： A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2).(1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more.(2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.
摘要翻译：一种热收缩性聚酯膜的膜卷，其特征在于，所述热收缩性聚酯膜满足以下要求（1）和（2）。（1）将样品沿着长度方向以几乎相等的间隔切断，并将其浸入85℃的热水中10秒钟，随后在25℃的水中取出，加热收缩率所有样品的最大收缩方向为20％以上。（2）用于生产上述薄膜的原料聚合物包含主要结构单元和一个或多个与其不同的亚结构单元; 确定主要次级宪法单位的内容，在100％的所有宪法单位中，每个样本中的主要次级宪法单位的内容大于7摩尔％，并且当主要次级宪法单位的内容的平均值，其所有样品的含量相对于平均值为±2摩尔％的范围。

32. 发明申请

US20090191369A1 Polyamide Based Laminated Resin Film Roll and Production Process Thereof 有权
标题翻译：聚酰胺基层压树脂薄膜卷及其生产工艺
公开(公告)号：US20090191369A1
公开(公告)日：2009-07-30
申请号：US11921866
申请日：2005-12-21
申请人： Tadashi Nishi , Yoshinori Miyaguchi , Naonobu Oda , Katsuhiko Nose
发明人： Tadashi Nishi , Yoshinori Miyaguchi , Naonobu Oda , Katsuhiko Nose
IPC分类号： B32B27/34 , B29D22/00 , B29C47/06
CPC分类号： B29C55/12 , B29C47/0021 , B29C47/8845 , B29C47/8865 , B29K2077/00 , B32B27/34 , Y10T428/1334 , Y10T428/1359 , Y10T428/24372 , Y10T428/24421
摘要： The polyamide based resin laminated film roll of the present invention has physical properties such as boiling water shrinkage percentage, surface roughness, refractive index in the thickness direction, etc., adjusted to achieve a predetermined range of degree of variability, when the polyamide based resin laminated film has a first sample cutout portion set up within 2 m from the winding end of film and final cutout portion within 2 m from the winding start of film, and at the same time, has a sample cutout portion set up at approximately every 100 m from the first sample cutout portion.
摘要翻译：本发明的聚酰胺系树脂层叠膜具有沸水收缩率，表面粗糙度，厚度方向的折射率等物理性质，其调整为达到规定的变异度范围时，聚酰胺系树脂叠层薄膜具有第一样品切口部分，其设置在离膜卷绕开始部分2m以内的膜卷绕端和最后切口部分的2μm以内，同时具有设置在大约每100个的样品切口部分 m。

33. 发明申请

US20090065979A1 Process for Producing Polyamide-Based Resin Film Roll 审中-公开
标题翻译：生产聚酰胺基树脂膜卷的方法
公开(公告)号：US20090065979A1
公开(公告)日：2009-03-12
申请号：US11918143
申请日：2005-12-27
申请人： Tadashi Nishi , Toshifumi Nagata , Yoshinori Miyaguchi , Naonobu Oda , Katsuhiko Nose
发明人： Tadashi Nishi , Toshifumi Nagata , Yoshinori Miyaguchi , Naonobu Oda , Katsuhiko Nose
IPC分类号： B29C35/10
CPC分类号： B29C55/143 , B29C48/08 , B29C48/914 , B29C48/9165 , B29C48/919 , B29K2077/00
摘要： The present invention provides a process for production of a polyamide based resin film roll comprising a step of melt-extruding and cooling wherein polyamide based resin is melt-extruded and cooled in a sheet form onto a mobile cooling material surface to obtain an unstretched sheet; a step of biaxial stretching wherein an unstretched sheet is stretched biaxially in the longitudinal direction and the transverse direction; and a step of winding up the biaxially stretched film that is biaxially stretched in a form of roll. Then, in the step of melt-extruding and cooling polyamide based resin onto a mobile cooling material surface, corona discharge in a streamer corona state is performed between an electrode applied with high DC voltage and the polyamide based resin sheet in the melted state, and sufficient electric charges that enable the polyamide based resin sheet in the melted state to come in close contact with the mobile cooling material surface are imparted.
摘要翻译：本发明提供一种聚酰胺系树脂薄膜卷的制造方法，其特征在于，包括熔融挤出和冷却步骤，其中将聚酰胺类树脂熔融挤出并以片状冷却至移动冷却材料表面，得到未拉伸片; 双轴拉伸的步骤，其中未拉伸片材在纵向和横向双轴拉伸; 卷绕卷轴双轴拉伸的双轴拉伸膜的工序。然后，在将聚酰胺类树脂熔融挤出冷却到移动冷却材料表面上的步骤中，在熔融状态下，在施加高直流电压的电极和聚酰胺类树脂片之间进行流光电晕状态的电晕放电，赋予熔融状态的聚酰胺类树脂片与移动冷却材料表面紧密接触的足够的电荷。

34. 发明申请

US20080254259A1 Polyamide Based Mixed Resin Film Roll And Process For Producing The Same 有权
标题翻译：聚酰胺混合树脂薄膜卷及其生产方法
公开(公告)号：US20080254259A1
公开(公告)日：2008-10-16
申请号：US11887101
申请日：2005-12-21
申请人： Tadashi Nishi , Yoshinori Miyaguchi , Naonobu Oda , Katsuhiko Nose
发明人： Tadashi Nishi , Yoshinori Miyaguchi , Naonobu Oda , Katsuhiko Nose
IPC分类号： B32B5/16 , B32B27/34 , B29C47/88
CPC分类号： C08J5/18 , B29C55/12 , B29D7/01 , B29K2077/00 , C08J2377/00 , Y10T428/24372 , Y10T428/24421
摘要： The problem to be solved by the present invention is to provide a biaxially oriented polyamide based mixed resin film roll with which bag forming processing by lamination is able to be performed smoothly and with high yield ratio and at the same time with which packages free of S-shaped curls can be obtained efficiently. A solution for the problem concerns the polyamide based mixed resin film roll of the present invention which includes a first sample cutout portion within 2 m from the winding end of film and a final cutout portion within 2 m from the winding start of film, and when a sample cutout portion is set up in approximately every 100 m from the first sample cutout portion, in all samples cut out from each of the cutout portions, physical properties such as elastomer content, elastic modulus in tension, boiling water shrinkage percentage and refraction index in the thickness direction are adjusted to be within a predetermined range of variation range.
摘要翻译：本发明要解决的问题是提供一种双轴取向的聚酰胺基混合树脂薄膜卷，通过层压可以顺利进行袋形成处理，并且以高收率比进行袋形成处理，同时，不含S的包装形状的卷发可以有效地获得。该问题的解决方案涉及本发明的聚酰胺基混合树脂膜卷，其包括距膜的卷绕端2m以内的第一样品切口部和离膜卷绕开始2μm以内的最终切口部，在从每个切口部分切出的所有样品中，从第一样品切口部分大约每100m设置样品切口部分，物理性质如弹性体含量，拉伸弹性模量，沸水收缩率和折射率在厚度方向上调整为在变化范围的规定范围内。

35. 发明申请

US20070114167A1 Bundle of selectively permeable polysulfone-based hollow fiber membranes and process for manufacturing same 审中-公开
标题翻译：选择性渗透性聚砜基中空纤维膜束及其制造方法
公开(公告)号：US20070114167A1
公开(公告)日：2007-05-24
申请号：US10582052
申请日：2004-12-08
申请人： Kimihiro Mabuchi , Noriyuki Tamamura , Hidehiko Sakurai , Noriaki Kato , Hiroshi Shibano , Katsuhiko Nose
发明人： Kimihiro Mabuchi , Noriyuki Tamamura , Hidehiko Sakurai , Noriaki Kato , Hiroshi Shibano , Katsuhiko Nose
IPC分类号： B01D63/00
CPC分类号： B01D69/08 , B01D67/009 , B01D67/0095 , B01D69/02 , B01D71/44 , B01D71/68 , B01D2323/02 , B01D2323/12 , B01D2323/30 , B01D2323/34
摘要： The present invention provides polysulfone-based hollow fiber membranes having high water permeable performance and for use in therapy of chronic renal failures, said hollow fiber membranes having high safety and high stability in performance and being excellent in module-fabricating workability. The present invention also provides a process for manufacturing the same. The present invention relates to a bundle of a plurality of selectively permeable polysulfone-based hollow fiber membranes wherein the amount of a hydrophilic polymer eluting from each hollow fiber membrane is not larger than 10 ppm, and wherein the content of the hydrophilic polymer in the outer surface of the hollow fiber membrane is 25 to 50 mass %, and this bundle is characterized in that any of extracted solutions from ten fractions of said bundle, obtained by dividing the bundle at substantially regular intervals along the lengthwise direction, shows a maximum value of smaller than 0.10 in UV absorbance at a wavelength of 220 to 350 nm, with the proviso that the extracted solutions are obtained by the extraction method for tests regulated in the approval manufacturing standards for dialytic artificial kidney devices; and in that the difference between the maximum and the minimum out of the maximum values of UV absorbance of the extracted solutions from the respective fractions is not larger than 0.05.
摘要翻译：本发明提供了具有高透水性的聚砜基中空纤维膜，用于治疗慢性肾功能衰竭，所述中空纤维膜具有高安全性和高性能稳定性，模块制造加工性优异。本发明还提供一种制造该方法的方法。本发明涉及多根选择性渗透性聚砜系中空纤维膜束，其中从各中空纤维膜洗出的亲水性聚合物的量不大于10ppm，其中亲水性聚合物在外层中空纤维膜的表面为25〜50质量％，该束的特征在于，通过沿着长度方向以基本上规则的间隔分割束而获得的所述束的十个部分的提取液中的任何一个显示最大值波长为220〜350nm时紫外吸光度小于0.10，条件是通过透析人造肾装置的认可制造标准规定的试验提取方法获得提取液; 并且来自各个馏分的萃取溶液的UV吸光度的最大值的最大值和最小值之间的差异不大于0.05。

36. 发明授权

US06958178B2 Heat-shrinkable polyester film roll 有权
标题翻译：热收缩聚酯薄膜卷
公开(公告)号：US06958178B2
公开(公告)日：2005-10-25
申请号：US10480844
申请日：2002-07-30
申请人： Satoshi Hayakawa , Norimi Tabota , Yoshinori Takegawa , Katsuya Ito , Shigeru Komeda , Katsuhiko Nose
发明人： Satoshi Hayakawa , Norimi Tabota , Yoshinori Takegawa , Katsuya Ito , Shigeru Komeda , Katsuhiko Nose
IPC分类号： B29C55/06 , B29C61/00 , B29C61/06 , B29D7/01 , B29K67/00 , B29K105/02 , B29L7/00 , C08J5/18 , C08K3/10 , C08K3/32 , C08K5/00 , C08K5/098 , C08K5/521 , C08L67/02 , B32B7/00 , B32B27/06 , B32B27/10 , B32B53/00
CPC分类号： C08J5/18 , B29C55/06 , B29C61/003 , B29D7/01 , B29K2067/00 , B29K2995/0049 , C08J2367/02 , C08K5/0091 , C08K5/098 , C08K5/521 , Y10T428/1328 , Y10T428/1331 , Y10T428/24942 , Y10T428/2495 , Y10T428/31786 , Y10T428/3179 , C08L67/02
摘要： The heat-shrinkable polyester film rolls according to the present invention is characterized in that the film rolls have (1) a heat shrinkage percentage at 85° C. in the maximum shrinkage direction of 20% or more; (2) a melt resistivity at a temperature of 275° C. of 0.70×108 Ω·cm or less; (3) when samples thereof are cut off at an interval of about 100 m and the fluctuation in thickness in the maximum shrinkage direction is measured, a thickness distribution width represented by the following formula of respective samples of 7% or less. Thickness distribution width=(Maximum thickness−Minimum thickness)/Average thickness×100 Container-wrapping films excellent in processability and printability can be produced from the heat-shrinkable polyester film rolls in high yield.
摘要翻译：本发明的热收缩性聚酯薄膜卷的特征在于，薄膜卷（1）最大收缩方向的85℃的热收缩率为20％以上。（2）在275℃的温度下的熔融电阻率为0.70×10 8Ω或更小; （3）当以约100μm的间隔切断样品并测量最大收缩方向的厚度变化时，各样品的下列公式表示的厚度分布宽度为7％以下。 <？in-line-formula description =“In-line Formulas”end =“lead”？>厚度分布宽度=（最大厚度 - 最小厚度）/平均厚度×100 <？in-line-formula description =“ “end =”tail“？>可以以高收率从热收缩聚酯薄膜卷制造加工性和印刷性优异的容器包装薄膜。

37. 发明授权

US5458965A Polyester laminated film 失效
标题翻译：聚酯层压膜
公开(公告)号：US5458965A
公开(公告)日：1995-10-17
申请号：US116224
申请日：1993-09-02
申请人： Yasuo Yoshinaka , Katsuhiko Nose , Yoshinori Takegawa , Norimi Tabota , Akito Hamano , Katsuaki Kuze
发明人： Yasuo Yoshinaka , Katsuhiko Nose , Yoshinori Takegawa , Norimi Tabota , Akito Hamano , Katsuaki Kuze
IPC分类号： B32B27/36 , C08J7/04 , B32B5/16
CPC分类号： C08J7/047 , B32B27/36 , C08J2367/02 , C08J2467/00 , Y10T428/1352 , Y10T428/25 , Y10T428/31786 , Y10T428/31797
摘要： A polyester laminated film with excellent sealing ability is provided. The polyester laminated film comprises a base film of a polyester resin and a sealing film of a polyester composition, said sealing film being disposed on at least one side of said base film, wherein the sealing energy, which is measured when two pieces of said laminated films are joined together with the respective sealing films facing each other, is 300 g.cm/15 mm or more.
摘要翻译：提供了具有优异的密封能力的聚酯层压膜。聚酯层压膜包括聚酯树脂的基膜和聚酯组合物的密封膜，所述密封膜设置在所述基膜的至少一侧上，其中密封能量是当两片所述层压体薄膜与彼此面对的各个密封膜连接在一起，为300g·cm / 15mm以上。

38. 发明授权

US4605591A Thermoplastic resin film laminate and production thereof 失效
标题翻译：热塑性树脂薄膜层压板及其制造
公开(公告)号：US4605591A
公开(公告)日：1986-08-12
申请号：US664199
申请日：1984-10-24
申请人： Katsuhiko Nose , Hajime Suzuki , Osamu Makimura
发明人： Katsuhiko Nose , Hajime Suzuki , Osamu Makimura
IPC分类号： B32B27/36 , C08J7/04 , G03C1/795 , B32B27/08
CPC分类号： C08J7/047 , G03C1/7954 , C08J2467/00 , Y10T428/26 , Y10T428/31786 , Y10T428/31797
摘要： A thermoplastic resin film laminate which comprises a thermoplastic resin film, particularly, a polyester film and a layer of a polyester resin composition provided on at least one surface of the film, said composition comprising(A) a water insoluble polyester copolymer composed of a mixed dicarboxylic acid component containing a dicarboxylic acid having metal sulfonate group in an amount of 0.5 to 15 mol % based on all the dicarboxylic acid component and a glycol component; and(B) inert particles; the weight ratio of (A)/(B)=100,000/0.5-3,000. Optionally, the composition can contain one or more ingredients selected from the group consisting of a water soluble silicone, a polyfunctional reactive compound, a polyethylene glycol and its derivative and an antistatic agent. The thermoplastic resin film laminate is preferably produced by so-called in-line coating.
摘要翻译：一种热塑性树脂薄膜层叠体，其特征在于，在所述薄膜的至少一个表面上设置有热塑性树脂薄膜，特别是聚酯薄膜和聚酯树脂组合物层，所述组合物包含（A）水不溶性聚酯共聚物，二羧酸成分含有相对于所有二羧酸成分和二醇成分为0.5〜15摩尔％的具有金属磺酸盐基的二羧酸的二羧酸成分; 和（B）惰性颗粒; （A）/（B）的重量比= 100,000 / 0.5-3,000。任选地，组合物可以含有一种或多种选自水溶性硅氧烷，多官能反应性化合物，聚乙二醇及其衍生物和抗静电剂的成分。热塑性树脂膜层叠体优选通过所谓的在线涂布来制造。

39. 发明授权

US08062740B2 Polyamide based mixed resin film roll and process for producing the same 有权
标题翻译：聚酰胺类混合树脂膜卷及其制造方法
公开(公告)号：US08062740B2
公开(公告)日：2011-11-22
申请号：US11887101
申请日：2005-12-21
申请人： Tadashi Nishi , Yoshinori Miyaguchi , Naonobu Oda , Katsuhiko Nose
发明人： Tadashi Nishi , Yoshinori Miyaguchi , Naonobu Oda , Katsuhiko Nose
IPC分类号： B32B27/34 , B32B5/16 , B29C47/88
CPC分类号： C08J5/18 , B29C55/12 , B29D7/01 , B29K2077/00 , C08J2377/00 , Y10T428/24372 , Y10T428/24421
摘要： The problem to be solved by the present invention is to provide a biaxially oriented polyamide based mixed resin film roll with which bag forming processing by lamination is able to be performed smoothly and with high yield ratio and at the same time with which packages free of S-shaped curls can be obtained efficiently. A solution for the problem concerns the polyamide based mixed resin film roll of the present invention which includes a first sample cutout portion within 2 m from the winding end of film and a final cutout portion within 2 m from the winding start of film, and when a sample cutout portion is set up in approximately every 100 m from the first sample cutout portion, in all samples cut out from each of the cutout portions, physical properties such as elastomer content, elastic modulus in tension, boiling water shrinkage percentage and refraction index in the thickness direction are adjusted to be within a predetermined range of variation range.
摘要翻译：本发明要解决的问题是提供一种双轴取向的聚酰胺基混合树脂薄膜卷，通过层压可以顺利进行袋形成处理，并且以高收率比进行袋形成处理，同时，不含S的包装形状的卷发可以有效地获得。该问题的解决方案涉及本发明的聚酰胺基混合树脂膜卷，其包括距膜的卷绕端2m以内的第一样品切口部和离膜卷绕开始2μm以内的最终切口部，在从每个切口部分切出的所有样品中，从第一样品切口部分大约每100m设置样品切口部分，物理性质如弹性体含量，拉伸弹性模量，沸水收缩率和折射率在厚度方向上调整为在变化范围的规定范围内。

40. 发明授权

US07749584B2 Heat-shrinkable polyester films 失效
标题翻译：热收缩聚酯薄膜
公开(公告)号：US07749584B2
公开(公告)日：2010-07-06
申请号：US10482870
申请日：2002-07-10
申请人： Satoshi Hayakawa , Norimi Tabota , Yoshinori Takegawa , Katsuya Ito , Shigeru Komeda , Katsuhiko Nose
发明人： Satoshi Hayakawa , Norimi Tabota , Yoshinori Takegawa , Katsuya Ito , Shigeru Komeda , Katsuhiko Nose
IPC分类号： B29C55/00 , B65B53/02 , C08G63/02 , C08G63/12 , C08G63/16
CPC分类号： C08J5/18 , B29K2067/00 , B29K2995/0049 , C08J2367/02 , Y10T428/1328 , Y10T428/1331 , Y10T428/31786
摘要： In heat-shrinkable polyester films, the content of 1,4-cyclohexane dimethanol is 10 to 50% by mole based on the polyhydric alcohol component and that the heat shrinkage factors of a 10 cm square sample of the films in (A) hot water of 75° C., (B) hot water of 85° C., and (C) hot water of 95° C. are 30 to 40%, 50 to 60%, and 65 to 77%, respectively. The films can be produced by drawing under specified conditions.
摘要翻译：在热收缩性聚酯膜中，1,4-环己烷二甲醇的含量相对于多元醇成分为10〜50摩尔％，（A）热水中的膜的10cm见方的样品的热收缩系数为75℃，（B）为85℃的热水，（C）95℃的热水分别为30〜40％，50〜60％，65〜77％。这些胶片可以在规定的条件下进行拉丝。

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