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31. 发明申请

US20140005349A1 POLYISOBUTYLENES AND PROCESS FOR MAKING SAME 审中-公开
标题翻译：聚异戊二烯和制备方法
公开(公告)号：US20140005349A1
公开(公告)日：2014-01-02
申请号：US14017761
申请日：2013-09-04
申请人： Joseph P. Kennedy , Yongmoon Kwon , Subramanyam Ummadisetty
发明人： Joseph P. Kennedy , Yongmoon Kwon , Subramanyam Ummadisetty
IPC分类号： C08G18/32 , C07C51/00 , C07C19/075 , C07C211/01 , C07C17/013 , C07C31/18 , C07C209/08
CPC分类号： C08F8/00 , C07C17/013 , C07C19/075 , C07C31/18 , C07C51/00 , C07C209/08 , C07C211/01 , C08F8/06 , C08F8/10 , C08F8/12 , C08F8/20 , C08F8/26 , C08F8/30 , C08F8/32 , C08F10/10 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08G18/3206 , C08G18/6204 , C08G18/7671 , C08F4/16 , C08F2/38 , C08F8/28
摘要： The present invention generally relates to alcohol-terminated polyisobutylene (PIB) compounds, and to a process for making such compounds. In one embodiment, the present invention relates to primary alcohol-terminated polyisobutylene compounds, and to a process for making such compounds. In still another embodiment, the present invention relates to polyisobutylene compounds that can be used to synthesize polyurethanes, to polyurethane compounds made via the use of such polyisobutylene compounds, and to processes for making such compounds. In yet another embodiment, the present invention relates to primary alcohol-terminated polyisobutylene compounds having two or more primary alcohol termini and to a process for making such compounds. In yet another embodiment, the present invention relates to primary terminated polyisobutylene compounds having two or more primary termini selected from amine groups or methacrylate groups.
摘要翻译：本发明一般涉及醇封端的聚异丁烯（PIB）化合物，以及制备这些化合物的方法。在一个实施方案中，本发明涉及伯醇封端的聚异丁烯化合物及其制备方法。在另一个实施方案中，本发明涉及可用于合成聚氨酯的聚异丁烯化合物，通过使用这种聚异丁烯化合物制备的聚氨酯化合物，以及制备这些化合物的方法。在另一个实施方案中，本发明涉及具有两个或更多个伯醇末端的伯醇封端的聚异丁烯化合物及其制备方法。在另一个实施方案中，本发明涉及具有两个或更多个选自胺基或甲基丙烯酸酯基团的一级末端的一级封端的聚异丁烯化合物。

32. 发明授权

US08580900B2 Thermoplastic amphiphilic co-networks 有权
标题翻译：热塑性两亲共网络
公开(公告)号：US08580900B2
公开(公告)日：2013-11-12
申请号：US12740829
申请日：2008-11-03
申请人： Joseph P. Kennedy , Gabor Erdodi , Jungmee Kang
发明人： Joseph P. Kennedy , Gabor Erdodi , Jungmee Kang
IPC分类号： C08F283/04
CPC分类号： C08F265/00 , C08G77/442 , C08G77/458 , C08L51/085 , C08L83/10 , C08L2205/02 , C08L2666/24
摘要： The present invention relates generally to thermoplastic amphiphilic networks and/or co-networks. In one embodiment, the present invention relates to thermoplastic (TP) amphiphilic co-networks (APCNs) and the preparation of membranes from such APCNs. In another embodiment, the present invention relates to an amphiphilic network comprising at least one hydrophilic polymer-derived portion, at least one hydrophobic polymer-derived portion and at least one thermoplastic polymer-derived portion. In still another embodiment, the present invention relates to thermoplastic amphiphilic co-networks prepared by combining the chemistries of APCNs and polyurethanes (PUs) and to the preparation of membranes therefrom.
摘要翻译：本发明一般涉及热塑性两亲性网络和/或共同网络。在一个实施方案中，本发明涉及热塑性（TP）两亲性共同网络（APCN）和来自这种APCN的膜的制备。在另一个实施方案中，本发明涉及包含至少一种亲水性聚合物衍生部分，至少一种疏水性聚合物衍生部分和至少一种热塑性聚合物衍生部分的两亲网络。在另一个实施方案中，本发明涉及通过将APCN和聚氨酯（PU）的化学物质组合并由其制备的膜制备的热塑性两亲性共网络。

33. 发明授权

US08466234B2 Amphiphilic networks, process for producing same, and products made therefrom 有权
标题翻译：两亲网络，其制造方法以及由其制成的产品
公开(公告)号：US08466234B2
公开(公告)日：2013-06-18
申请号：US12525143
申请日：2008-04-04
申请人： Joseph P. Kennedy , Radhakrishnan Karunakaran
发明人： Joseph P. Kennedy , Radhakrishnan Karunakaran
IPC分类号： C08F287/00 , C08G77/04
CPC分类号： C08G77/392 , C08G77/442 , G02B1/041 , G02B1/043 , C08L83/10 , C08L101/14
摘要： The present invention relates to the production of amphiphilic copolymer networks, or co-networks, and to methods for preparing amphiphilic co-networks. Furthermore, the present invention relates to products and/or films made from the amphiphilic co-networks produced in accordance with the synthesis methods of the present invention. In one embodiment, the present invention is related to crosslinkable and/or polymerizable compositions that can be utilized to form amphiphilic co-networks, where such compositions are block copolymer compositions that are formed from the combination of at least one hydrophilic segment, at least one hydrophobic segment, and at least one crosslinkable and/or polymerizable segment. In yet another embodiment, the present invention relates to amphiphilic co-networks that are optically clear and highly oxyphilic.
摘要翻译：本发明涉及两亲性共聚物网络或共同网络的制备以及用于制备两亲性共网络的方法。此外，本发明涉及由根据本发明的合成方法制备的两亲性共网络制成的产品和/或膜。在一个实施方案中，本发明涉及可用于形成两亲性共网络的可交联和/或可聚合组合物，其中这样的组合物是由至少一个亲水链段至少一个疏水链段和至少一个可交联和/或可聚合链段。在另一个实施方案中，本发明涉及光学透明且高亲氧性的两亲性共网络。

34. 发明申请

US20120259069A1 POLYISOBUTYLENE-BASED POLYURETHANES, POLYUREAS AND/OR POLYURETHANE-POLYUREAS AND METHOD FOR MAKING SAME 有权
标题翻译：聚异丁烯基聚氨酯，聚氨酯和/或聚氨酯聚合物及其制备方法
公开(公告)号：US20120259069A1
公开(公告)日：2012-10-11
申请号：US13515131
申请日：2010-11-11
申请人： Joseph P. Kennedy , Gabor Erdodi , Jungmee Kang
发明人： Joseph P. Kennedy , Gabor Erdodi , Jungmee Kang
IPC分类号： C08F10/10
CPC分类号： C08G18/6204 , C08G18/10 , C08G18/4854 , C08G18/73 , C08G18/3206 , C08G18/48
摘要： The present invention generally relates to polyisobutylene-based polyurethanes, polyureas and/or polyurethane-polyureas, and to a process for making such compounds. In one embodiment, the polyisobutylene-based polyurethanes, polyureas and/or polyurethane-polyureas also include at least one flexible hydrogen bond acceptor chain extender (HACE). In another embodiment, amine telechelic and hydroxyl telechelic polyisobutylenes are utilized with at least one at least one flexible hydrogen bond acceptor chain extender (HACE) to produce polyurethane-polyureas having various desired mechanical properties in combination with various desired oxidative/hydrolytic stability.
摘要翻译：本发明一般涉及聚异丁烯基聚氨酯，聚脲和/或聚氨酯 - 聚脲，以及制备这些化合物的方法。在一个实施方案中，聚异丁烯基聚氨酯，聚脲和/或聚氨酯 - 聚脲还包括至少一个柔性氢键受体扩链剂（HACE）。在另一个实施方案中，将胺遥爪和羟基遥爪聚异丁烯与至少一种柔性氢键受体扩链剂（HACE）一起使用，以产生具有各种所需机械性能的聚氨酯 - 聚脲，并结合各种所需的氧化/水解稳定性。

35. 发明授权

US08124693B2 Polyisobutylene-based block anionomers and cationomers and synthesis thereof 有权
标题翻译：聚异丁烯类嵌段阴离子和阳离子及其合成
公开(公告)号：US08124693B2
公开(公告)日：2012-02-28
申请号：US11605025
申请日：2006-11-28
申请人： Joseph P. Kennedy , Zheng Fang
发明人： Joseph P. Kennedy , Zheng Fang
IPC分类号： C08F293/00 , C08F255/08
CPC分类号： C08F297/00 , C08F8/06 , C08F8/12 , C08F8/22 , C08F293/005 , C08F2438/01 , C08F2810/30 , C08F2810/40 , Y10S525/901 , C08F112/12 , C08F8/42 , C08F110/10
摘要： Various novel block cationomers comprising polyisobutylene (PIB) and poly(2-dimethylamino)ethyl methacrylate) (PDMAEMA) segments have been synthesized and characterized. The specific targets were various molecular weight diblocks (PDMAEMA+) and triblocks (PDMAEMA+-b-PIB-b-PDMAEMA+) with the PIB blocks in the DPn=50-200 (Mn=3,000-9,000 g/mol) range connected to blocks of PDMAEMA+ cations in the DPn=5-20 range. The overall synthetic strategy for the preparation of these block cationomers comprised four steps: 1) Synthesis by living cationic polymerization of mono- and di-allyltelechelic polyisobutylenes, 2) End group transformation to obtain PIBs fitted with termini capable of mediating the atom transfer radical polymerization (ATRP) of DMAEMA, 3) ATRP of DMAEMA and 4) Quaternization of PDMAEMA to PDMAEMA+I− by CH3I. Kinetic and model experiments provided guidance to develop convenient synthesis methods. The microarchitecture of PIB-PDMAEMA di- and triblock and the corresponding block cationomers were confirmed by 1H NMR and FTIR spectroscopy and solubility studies.
摘要翻译：已经合成了各种包含聚异丁烯（PIB）和聚（2-二甲基氨基）乙基甲基丙烯酸酯）（PDMAEMA）链段的新型嵌段阳离子。具体目标是各种分子量二嵌段（PDMAEMA +）和三嵌段（PDMAEMA + -b-PIB-b-PDMAEMA +），DPn = 50-200（Mn = 3,000-9,000g / mol）范围内的PIB嵌段连接到 PDMAEMA +阳离子在DPn = 5-20范围内。制备这些嵌段阳离子的总体合成策略包括四个步骤：1）通过单 - 和二 - 烯丙基可可聚异丁烯的阳离子聚合合成2）端基转化获得配有能够介导原子转移自由基聚合的末端的PIB （ATRP），3）DMAEMA的ATRP和4）通过CH 3 I对PDMAEMA + I-的PDMAEMA进行季铵化。动力学和模型实验为开发方便的合成方法提供了指导。通过1 H NMR和FTIR光谱和溶解度研究证实了PIB-PDMAEMA二 - 和三嵌段的微结构和相应的嵌段阳离子。

36. 发明授权

US07642332B2 Amphiphilic networks, process for producing same, and products made therefrom 有权
标题翻译：两亲网络，其制造方法以及由其制成的产品
公开(公告)号：US07642332B2
公开(公告)日：2010-01-05
申请号：US11891899
申请日：2007-08-14
申请人： Joseph P. Kennedy , Radhakrishnan Karunakaran
发明人： Joseph P. Kennedy , Radhakrishnan Karunakaran
IPC分类号： C08G77/12 , C08G77/04
CPC分类号： C08F230/08 , C08F283/00 , C08F283/06 , C08F290/06 , C08F2230/085
摘要： The present invention relates to the production of amphiphilic copolymer networks, or co-networks, and to methods for preparing amphiphilic co-networks. Furthermore, the present invention relates to products and/or films made from the amphiphilic co-networks produced in accordance with the synthesis methods of the present invention. Additionally, the present invention relates to crosslinked amphiphilic co-networks comprising at least one hydrophilic segment and at least one hydrophobic segment. In one embodiment, the hydrophilic segments include at least one polyalkyl glycol (e.g., polyethylene glycol (PEG)) and the hydrophobic segments include at least one di-alkenyl and/or di-alkynyl terminated polysiloxane (e.g., polydimethylsiloxane (PDMS)). In another embodiment, the amphiphilic co-networks of the present invention are optically clear and highly oxophilic.
摘要翻译：本发明涉及两亲性共聚物网络或共同网络的制备以及用于制备两亲性共网络的方法。此外，本发明涉及由根据本发明的合成方法制备的两亲性共网络制成的产品和/或膜。另外，本发明涉及包含至少一个亲水链段和至少一个疏水链段的交联两亲性共网络。在一个实施方案中，亲水链段包括至少一个聚烷基二醇（例如聚乙二醇（PEG）），疏水链段包括至少一个二烯基和/或二炔基封端的聚硅氧烷（例如聚二甲基硅氧烷（PDMS））。在另一个实施方案中，本发明的两亲性共网络是光学透明的和高亲氧的。

37. 发明申请

US20080248745A1 System and Method for Identifying the Path or Devices on the Path of a Communication Signal Using (1+r(T)) Amplitude Modulation 失效
标题翻译：使用（1 + r（T））幅度调制识别通信信号路径上的路径或设备的系统和方法
公开(公告)号：US20080248745A1
公开(公告)日：2008-10-09
申请号：US10586744
申请日：2005-05-11
申请人： Martin Alles , Joseph P. Kennedy , John P. Carlson
发明人： Martin Alles , Joseph P. Kennedy , John P. Carlson
IPC分类号： H04B3/36
CPC分类号： H04B7/155
摘要： A system and method of applying a known modification to a signal to enable a determination of a signal received by a first node is received directly from a second node or indirectly through a repeater. The repeater receives a primary signal and creates a secondary signal as a function of the primary signal and a known modification, wherein the known modification identifies the repeater. The primary signal is transmitted and injected with the secondary signal as the first signal to the primary receiver.
摘要翻译：直接从第二节点或通过中继器间接接收对信号应用已知修改以实现由第一节点接收的信号的确定的系统和方法。中继器接收主信号并产生作为主信号和已知修改的函数的次信号，其中已知修改识别中继器。主信号以辅助信号作为第一信号被发送和注入到主接收机。

38. 发明申请

US20080233006A1 Method and Apparatus For Determining the Oxygen Permeability of a Polymer 有权
标题翻译：用于确定聚合物的透氧性的方法和装置
公开(公告)号：US20080233006A1
公开(公告)日：2008-09-25
申请号：US11815489
申请日：2006-02-24
申请人： Joseph P. Kennedy , Gabor Erdodi
发明人： Joseph P. Kennedy , Gabor Erdodi
IPC分类号： B01J19/00 , G01N15/08
CPC分类号： G01N15/0826 , Y10T436/20
摘要： The present invention is relates to an apparatus and method for the determination of the oxygen gas permeability of a polymer. In one embodiment, the present invention relates to an apparatus and method for determining the oxygen gas permeability of a polymer membrane (e.g., a polydimethylsiloxane and/or polysiloxane polymer or copolymer). In still another embodiment, the present invention relates to oxygen gas permeable polymer compositions.
摘要翻译：本发明涉及一种用于测定聚合物的氧气渗透性的装置和方法。在一个实施方案中，本发明涉及用于测定聚合物膜（例如聚二甲基硅氧烷和/或聚硅氧烷聚合物或共聚物）的氧气渗透性的装置和方法。在另一个实施方案中，本发明涉及氧气可透过的聚合物组合物。

39. 发明申请

US20080200184A1 METHOD FOR ANGLE OF ARRIVAL DETERMINATION ON FREQUENCY HOPPING AIR INTERFACES 有权
标题翻译：频率选择空气界面上的方位角测量方法
公开(公告)号：US20080200184A1
公开(公告)日：2008-08-21
申请号：US12111346
申请日：2008-04-29
申请人： Joseph P. Kennedy , Thomas B. Gravely , John P. Carlson , Doug Blackburn , Martin Alles
发明人： Joseph P. Kennedy , Thomas B. Gravely , John P. Carlson , Doug Blackburn , Martin Alles
IPC分类号： H04Q7/20
CPC分类号： H04B1/713
摘要： A method for calibrating an antenna and signal processing system enabling angle of arrival (AOA) determination for a frequency hopping signal, in which a calibration coefficient is determined in response to one or more calibration signals injected into the system at one or more of the frequencies in the hopping sequence and proximate in time to reception of the communication signal. The calibration coefficients are reflective of a frequency and time dependent parameter of a path between the antenna and wireless location sensor. The AOA is determined as a function of the calibration coefficient and the radio frequency energy of the received communication signal. Several embodiment of the method are illustrated.
摘要翻译：一种校准天线和信号处理系统的方法，所述天线和信号处理系统使得能够对跳频信号进行确定（AOA），所述跳频信号响应于在一个或多个频率处注入到系统中的一个或多个校准信号来确定校准系数在跳频序列中并且在时间上接近通信信号。校准系数反映了天线和无线位置传感器之间路径的频率和时间相关参数。 AOA被确定为接收到的通信信号的校准系数和射频能量的函数。示出了该方法的几个实施例。

40. 发明授权

US06930151B2 Star block copolymers comprising polyisobutylene-B-polyacrylonitrile arms radiating from an aromatic core 失效
标题翻译：包含从芳族核心辐射的聚异丁烯-B-聚丙烯腈臂的星形嵌段共聚物
公开(公告)号：US06930151B2
公开(公告)日：2005-08-16
申请号：US10406372
申请日：2003-04-03
申请人： Joseph P. Kennedy , Zheng Fang , Ahmed F. Moustafa
发明人： Joseph P. Kennedy , Zheng Fang , Ahmed F. Moustafa
IPC分类号： C08F8/06 , C08F293/00 , C08F295/00 , C08F297/00 , C08L53/00 , C08F10/10 , C08L25/12
CPC分类号： C08F293/005 , C08F8/06 , C08F8/14 , C08F295/00 , C08F297/00 , C08F2438/01 , C08F2810/30 , C08F2810/40 , C08L53/00 , C08L53/005 , C08L2666/02 , C08F8/42 , C08F110/10
摘要： Block copolymers and star polymers having copolymer arms of PIB-PAN have been synthesized via living carbocationic polymerization and atom transfer radical polymerization in a methylene chloride/cyclohexanone solvent system.
摘要翻译：已经通过活性碳阳离子聚合和原子转移自由基聚合在二氯甲烷/环己酮溶剂体系中合成了具有PIB-PAN共聚物臂的嵌段共聚物和星形聚合物。

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