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    • 37. 发明授权
    • Diene-containing rubber compositions having improved green strength
    • 具有改善生坯强度的含二烯橡胶组合物
    • US4414359A
    • 1983-11-08
    • US342670
    • 1982-01-25
    • David J. DoughertyBinnur GunesinJohn W. Spiewak
    • David J. DoughertyBinnur GunesinJohn W. Spiewak
    • C08F212/00C08F236/04C08F220/58
    • C08F236/04C08F212/00
    • The invention disclosed herein provides a process for preparing a diene-containing synthetic rubber having improved green strength which includes the steps of charging a reaction vessel with water, an emulsifier, an initiator, an N-(alkoxymethyl)acrylamide monomer and a monomer containing a vinyl group, purging the vessel with an inert gas, charging a diene monomer and an activator to the vessel, polymerizing the monomers to form a copolymer; and, thereafter extracting the copolymer from the vessel and any unreacted monomers. A styrene-butadiene composition containing up to about 10 percent by weight of N-(isobutoxymethyl)acrylamide exhibits better stress-strain properties than a comparable styrene-butadiene rubber without the acrylamide compound.
    • 本文公开的本发明提供了一种制备具有改善的生坯强度的含二烯的合成橡胶的方法,其包括以下步骤:向反应容器中加入水,乳化剂,引发剂,N-(烷氧基甲基)丙烯酰胺单体和含有 乙烯基,用惰性气体吹扫容器,将二烯单体和活化剂装入容器中,聚合单体以形成共聚物; 然后从容器中提取共聚物和任何未反应的单体。 含有高达约10重量%N-(异丁氧基甲基)丙烯酰胺的苯乙烯 - 丁二烯组合物表现出比不含丙烯酰胺化合物的可比较苯乙烯 - 丁二烯橡胶更好的应力 - 应变性能。