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    • 35. 发明授权
    • Rechargeable lithium battery
    • 可充电锂电池
    • US5851696A
    • 1998-12-22
    • US593636
    • 1996-01-29
    • M. Yazid SaidiJeremy Barker
    • M. Yazid SaidiJeremy Barker
    • H01M4/02H01M4/48H01M4/485H01M4/50H01M4/505H01M10/0525H01M10/36
    • H01M4/485H01M10/0525H01M4/505H01M2004/027H01M2300/0025
    • The present invention provides an electrochemical cell or battery, which has a nonmetal negative electrode (anode). That is, no solid metal active material is used in the cell. Rather than the conventional solid lithium metal anode, the active material of the new anode comprises a compound of vanadium oxide. Accordingly, the lithium cell of the invention comprises a positive electrode and a negative electrode, where the negative electrode comprises a compound of vanadium oxide which in a fully discharged state is represented by the nominal general formula V.sub.6 O.sub.13 or Li.sub.y V.sub.6 O.sub.13, y equal to 0; and, in a fully or partially lithiated, fully or partially charged state, is represented by the nominal general formula Li.sub.y V.sub.6 O.sub.13, where y is greater than 0 and less than or equal to 8. The unique negative electrode of the invention demonstrates exceptional performance without the disadvantages of metallic lithium negative electrodes.
    • 本发明提供一种具有非金属负极(阳极)的电化学电池或电池。 也就是说,在电池中不使用固体金属活性材料。 而不是传统的固体锂金属阳极,新阳极的活性材料包括氧化钒的化合物。 因此,本发明的锂电池包括正极和负极,其中负极包括氧化钒的化合物,其在完全放电状态下由标称通式V6O13或LiyV6O13表示,y等于0; 并且在完全或部分锂化的完全或部分充电状态下,由标称通式Li y V 6 O 13表示,其中y大于0且小于或等于8.本发明的独特负极表现出卓越的性能,而没有 金属锂负极的缺点。