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31. 发明授权

US5136008A Polyurethane containing acryloyl or methacryloyl groups, and a process for their production and their use 失效
标题翻译：含有丙烯酸或甲基丙烯酸的聚氨酯，以及其生产方法及其使用
公开(公告)号：US5136008A
公开(公告)日：1992-08-04
申请号：US744607
申请日：1991-08-13
申请人： Jurgen Meixner , Wolfgang Fischer
发明人： Jurgen Meixner , Wolfgang Fischer
IPC分类号： C08G18/67 , C08G18/73 , C08G18/81 , C09D5/00 , C09D175/14 , C09D175/16 , C09J175/16 , D21H19/00
CPC分类号： C08G18/73 , C08G18/671 , C08G18/8158 , C09D175/16 , C09J175/16
摘要： The present invention is directed to polyurethanes containing (meth)acryloyl groups and to a method of manufacture thereof. The polyurethanes are produced by reactinga) a polyisocyanate component of which at least 50 NCO-equivalent-% consists of at least one acyclic aliphatic diisocyanate containing 6 to 12 carbon atoms in the aliphatic radical,b) an alcohol component containing (meth)acryloyl groups consisting essentially of a monohydric alcohol containing (meth)acryloyl groups and having a molecular weight of from 116 to 1000,c) at least one .beta.,.gamma.-ethylenically unsaturated ether alcohol containing 5 to 14 carbon atoms, andd) at least one polyhydric alcohol, at an NCO:OH equivalent ratio, based on all the starting components a) to d), of from 0.5:1 to 1:1.
摘要翻译：本发明涉及含有（甲基）丙烯酰基的聚氨酯及其制造方法。所述聚氨酯通过使a）多异氰酸酯组分（其至少50NCO当量）由至少一种在脂族基团中含有6至12个碳原子的非环状脂肪族二异氰酸酯组成，b）含有（甲基）丙烯酰基基本上由含有（甲基）丙烯酰基并且分子量为116至1000的一元醇组成的基团，c）至少一种含有5至14个碳原子的β，γ-烯键式不饱和醚醇，和d）至少一种多元醇，以NCO:OH当量比计，基于所有起始组分a）至d），为0.5:1至1:1。

32. 发明授权

US4921883A Unsaturated polyester resins, a process for their preparation and compositions containing these polyester resins 失效
标题翻译：不饱和聚酯树脂，其制备方法和含有这些聚酯树脂的组合物
公开(公告)号：US4921883A
公开(公告)日：1990-05-01
申请号：US169967
申请日：1988-03-18
申请人： Jurgen Meixner , Wolfgang Kremer , Manfred Muller
发明人： Jurgen Meixner , Wolfgang Kremer , Manfred Muller
IPC分类号： C08F2/50 , C08F299/04 , C08G63/553 , C09D167/06
CPC分类号： C09D167/06 , C08F299/0435 , C08G63/553
摘要： Unsaturated polyester resins having an acid number of from 0 to 50 and a hydroxyl number of from 10 to 150 which are composed of 0.6 to 0.8 moles of groups derived from maleic and/or fumaric acid, 0.2 to 0.4 moles of groups derived from norbornene dicarboxylic acid, 0.6 to 0.8 moles of groups derived from ethylene and/or propylene glycol, 0.2 to 0.4 moles of groups derived from diethylene glycol, 0.1 to 0.2 moles of groups derived from benzylalcohol and/or benzoic acid and 0 to 0.2 moles of groups derived from other alcohols, a process for their manufacture by a solvent-free or azeotropic esterification of said monomers and compositions which can be cured under influence of UV radiation, containing from 40 to 80 parts by weight of said polyester resins, from 20 to 60 parts by weight of styrene from 0.5 to 5 parts by weight of at least one photoinitiator and optionally known auxiliary agents and additives.
摘要翻译：由0.6至0.8摩尔衍生自马来酸和/或富马酸的基团组成的酸值为0至50且羟基数为10至150的不饱和聚酯树脂，衍生自降冰片烯二羧酸的基团为0.2至0.4摩尔酸，0.6至0.8摩尔衍生自乙烯和/或丙二醇的基团，0.2至0.4摩尔衍生自二甘醇的基团，0.1至0.2摩尔衍生自苄醇和/或苯甲酸的基团和0至0.2摩尔衍生的基团来自其它醇的方法，其通过所述单体的无溶剂或共沸酯化制备的方法，所述单体和组合物可以在UV辐射的影响下固化，所述组合物含有40至80重量份的所述聚酯树脂，20至60重量份的苯乙烯0.5至5重量份的至少一种光引发剂和任选地已知的助剂和添加剂。

33. 发明授权

US4870152A Process for the production of compounds containing isocyanurate groups and olefinic double bonds and their use as binders 失效
标题翻译：用于生产含有异氰脲酸酯基和烯属双键的化合物的方法及其作为粘合剂的用途
公开(公告)号：US4870152A
公开(公告)日：1989-09-26
申请号：US262623
申请日：1988-10-26
申请人： Jurgen Meixner , Manfred Bock , Josef Pedain , Manfred Schonfelder
发明人： Jurgen Meixner , Manfred Bock , Josef Pedain , Manfred Schonfelder
IPC分类号： C07D251/34 , C08G18/42 , C08G18/67 , C08G18/72 , C08G18/79 , C08G18/81 , C09D175/00 , C09D175/14
CPC分类号： C08G18/672 , C07D251/34 , C08G18/4216 , C08G18/4238 , C08G18/792 , C08G18/8175
摘要： Binders which are hardenable by radiation or peroxides and are useful in coating compositions are compounds containing isocyanurate groups and olefinic double bonds produced by the reaction of components (a), (b) and (c) wherein(a) is a polyisocyanate component containing isocyanurate polyisocyanates which is(i) N,N',N"-tris-(isocyanatohexyl)-isocyanurate alone or in admixture with its higher homologs containing more than one isocyanurate ring or(ii) mixtures of the polyisocyanates (i) with up to 40 NCO-equivalent-%, based on the total component (a), of other polyisocyanates containing aliphatically or cycloaliphatically bound isocyanate groups;(b) is an olefinically unsaturated alcohol component comprising at least one hydroxyalkyl ester of acrylic acid or methacrylic acid; and(c) is a polyol component consisting essentially of a polyester polyol having an OH value of 80 to 350 based on (i) an acid component, of which at least 80 carboxyl equivalent-% is adipic acid, isophthalic acid or a mixture of both and (ii) a polyhydroxy component of which at least 70 hydroxyl equivalent-% is hexane-1, 6-diol;wherein component (c) amounts to 20 to 150% by weight, based on the weight of component (b), and the reaction is carried out at with an NCO:OH equivalent ratio maintained at 0.9:1 to 1.1:1, and wherein components (b) and (c) are reacted with the polyisocyanate component in any order or in admixture.
摘要翻译：通过辐射或过氧化物可硬化并且可用于涂料组合物的粘合剂是含有通过组分（a），（b）和（c）反应生成的异氰脲酸酯基团和烯属双键的化合物，其中（a）是含有异氰脲酸酯的多异氰酸酯组分多异氰酸酯，其是单独的或与其含有多于一个异氰脲酸酯环的较高同系物混合的（i）N，N'，N“ - 三 - （异氰酸根合己基） - 异氰脲酸酯的多异氰酸酯，或（ii）多异氰酸酯（i）基于总组分（a），含有脂族或环脂族结合的异氰酸酯基团的其它多异氰酸酯的40NCO当量％; （b）是包含至少一种丙烯酸或甲基丙烯酸的羟烷基酯的烯属不饱和醇组分; 和（c）是基于（i）酸组分的羟值为80至350的聚酯多元醇组成的多元醇组分，其中至少80羧基当量 - ％是己二酸，间苯二甲酸或两者和（ii）多羟基组分，其中至少70个羟基当量 - ％是己烷-1,6-二醇; 其中组分（c）基于组分（b）的重量计为20至150重量％，并且以保持在0.9:1至1.1:1的NCO:OH当量比进行反应，其中组分（b）和（c）以多异氰酸酯组分的任何顺序或混合物反应。

34. 发明授权

US4748269A Process for the preparation of (meth)acrylic acid esters and their use 失效
标题翻译：制备（甲基）丙烯酸酯的方法及其用途
公开(公告)号：US4748269A
公开(公告)日：1988-05-31
申请号：US851742
申请日：1986-04-14
申请人： Jurgen Meixner , Josef Pedain , Peter Hohlein , Dieter Margotte
发明人： Jurgen Meixner , Josef Pedain , Peter Hohlein , Dieter Margotte
IPC分类号： C07C69/54 , C08F2/46 , C08F220/36 , C07C69/52
CPC分类号： C07C69/54 , C07C67/08 , C07C67/60
摘要： (Meth)acrylic acid esters can be prepared by acid-catalyzed reaction of (meth)acrylic acid with alcohols in a water-immiscible solvent. After the esterification, the reaction mixture is washed with aqueous solutions having an alkaline reaction and then reacted at elevated temperature with carbodiimides. Acid numbers below 0.5 (mg of KOH/g of substance) are obtained in this way. (Meth)acrylic acid esters are used, for example, as reactive diluents or as comonomers.
摘要翻译：（甲基）丙烯酸酯可以通过（甲基）丙烯酸与醇在水不混溶溶剂中的酸催化反应来制备。酯化后，反应混合物用碱性反应的水溶液洗涤，然后在高温下与碳二亚胺反应。以这种方式获得酸值低于0.5（KOH / g的物质）。（甲基）丙烯酸酯用作例如作为反应性稀释剂或共聚单体。

35. 发明申请

US20060237682A1 Size composition 审中-公开
标题翻译：尺寸组成
公开(公告)号：US20060237682A1
公开(公告)日：2006-10-26
申请号：US11405249
申请日：2006-04-17
申请人： Thorsten Rische , Gerald Kurek , Jurgen Meixner , Thomas Feller
发明人： Thorsten Rische , Gerald Kurek , Jurgen Meixner , Thomas Feller
IPC分类号： D06M15/564 , C08L75/04 , B32B27/40
CPC分类号： C03C25/26 , C03C25/326 , C08G18/0828 , C08G18/12 , C08G18/283 , C08G18/4018 , C08G18/4238 , C08G18/44 , C08G18/4854 , C08G18/706 , C08G18/722 , C08G18/7831 , C08G18/8074 , C09D175/12 , C08G18/3857 , C08G18/3234 , C08G18/3231 , C08G18/3865
摘要： The invention provides hydrolysis-stable size compositions based on polycarbonate polyols and polytetramethylene glycol polyols, their preparation and use.
摘要翻译：本发明提供了基于聚碳酸酯多元醇和聚四亚甲基二醇多元醇的水解稳定的大小组合物，其制备和用途。

36. 发明申请

US20050256261A1 Aqueous polyurethane dispersions and their use as adhesives 审中-公开
标题翻译：水性聚氨酯分散体及其作为粘合剂的用途
公开(公告)号：US20050256261A1
公开(公告)日：2005-11-17
申请号：US11122890
申请日：2005-05-05
申请人： Wolfgang Arndt , Wolfgang Henning , Jurgen Meixner , Thomas Munzmay , Ralf Werner
发明人： Wolfgang Arndt , Wolfgang Henning , Jurgen Meixner , Thomas Munzmay , Ralf Werner
IPC分类号： C08G18/08 , C08G18/28 , C08J5/12 , C08K3/20 , C08L75/02 , C08L75/04 , C09D5/02 , C09J175/02 , C09J175/04
CPC分类号： C09J175/04 , C08G18/0828 , C08G18/283
摘要： The present invention relates to new polyurethane and/or polyurethane-urea dispersions having ionic or potentially ionic or nonionic groups in the polymer backbone, to a process for preparing these dispersions and to their use as adhesives.
摘要翻译：本发明涉及在聚合物主链中具有离子或潜在离子或非离子基团的新的聚氨酯和/或聚氨酯 - 脲分散体，制备这些分散体的方法和用作粘合剂。

37. 发明申请

US20050182188A1 Coating material composition 有权
标题翻译：涂料组成
公开(公告)号：US20050182188A1
公开(公告)日：2005-08-18
申请号：US11034137
申请日：2005-01-12
申请人： Thorsten Rische , Torsten Pohl , Jurgen Meixner , Uwe Klippert , Thomas Feller
发明人： Thorsten Rische , Torsten Pohl , Jurgen Meixner , Uwe Klippert , Thomas Feller
IPC分类号： C08G18/08 , C08G18/12 , C08G18/28 , C09D5/00 , C09D175/04 , C08K3/00
CPC分类号： C08G18/0819 , C08G18/0828 , C08G18/12 , C08G18/283 , C09D5/00 , C09D175/04 , Y10T428/31551 , C08G18/3234 , C08G18/3231 , C08G18/3857 , C08L2666/20
摘要： Coating compositions that are stable to thermal yellowing that include coating materials containing I) one or more dispersions of hydroxyl-free polyurethanes and/or polyurethane-ureas, II) one or more aqueous solutions or dispersions of ionically modified, hydroxyl-containing polyurethanes and/or polyurethane-ureas, other than the constituents of component I), and III) at least one crosslinker. The dispersions are obtained by A) preparing an NCO-containing polyurethane prepolymer by reacting polyisocyanates with polymeric polyols and/or polyamines having number-average molecular weights of 400 to 8000 g/mol, isocyanate-reactive, ionically or potentially ionically hydrophilicizing compounds and/or isocyanate-reactive nonionically hydrophilicizing compounds; B) either dissolving the prepolymer obtained from step A) in aliphatic ketones or, diluting the prepolymer solution if the preparation has already been carried out in the presence of A6) by further addition of aliphatic ketones, and C) reacting the remaining free NCO groups of the prepolymer with a chain extender component.
摘要翻译：对于热黄变具有稳定性的涂料组合物，其包括含有I）一种或多种无羟基聚氨酯和/或聚氨酯 - 脲的分散体的涂料，II）一种或多种离子改性的含羟基聚氨酯的水溶液或分散体和/ 或聚氨酯 - 脲，除了组分I的组分之外）和III）至少一种交联剂。分散体通过以下方式获得：A）通过使多异氰酸酯与数均分子量为400-8000g / mol，异氰酸酯反应性，离子或潜在离子亲水化的化合物和/或多异氰酸酯的聚合多元醇和/或多胺反应来制备含NCO的聚氨酯预聚物和/ 或异氰酸酯反应性非离子亲水化化合物; B）将通过步骤A）获得的预聚物溶解在脂族酮中，或者如果制备已经在A6的存在下进一步添加脂肪族酮，则稀释预聚物溶液），和C）使剩余的游离NCO基团的预聚物与扩链剂组分。

38. 发明申请

US20050159541A1 Size composition 审中-公开
标题翻译：尺寸组成
公开(公告)号：US20050159541A1
公开(公告)日：2005-07-21
申请号：US11034112
申请日：2005-01-12
申请人： Thorsten Rische , Thomas Feller , Jurgen Meixner
发明人： Thorsten Rische , Thomas Feller , Jurgen Meixner
IPC分类号： C08G18/10 , C03C25/26 , C03C25/32 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/65 , C08G18/70 , D06M15/564 , C08K3/20 , C08K3/40 , C08K9/00
CPC分类号： C08G18/706 , C03C25/26 , C03C25/326 , C08G18/0866 , C08G18/12 , C08G18/283 , C08G18/3231
摘要： Size compositions that include one or more polyurethane-polyurea dispersions; optionally further film-forming resins; and optionally crosslinkers. The dispersions are obtained by preparing an NCO-containing polyurethane prepolymer by reacting polyisocyanates with polymeric polyols and/or polyamines, optionally low molecular weight compounds, isocyanate-reactive, ionically or potentially ionically hydrophilicizing compounds and/or isocyanate-reactive nonionically hydrophilicizing compounds, and optionally in inert solvents with the proviso that none of components contains primary or secondary amino groups; followed by either dissolving the prepolymer in aliphatic ketones or, diluting the prepolymer solution by further addition of aliphatic ketones; and reacting the remaining free NCO groups of the prepolymer with a chain extender component. The dispersions are used in mouldings and/or coatings that can be used to caot substrates, such as glass fibers.
摘要翻译：包括一种或多种聚氨酯 - 聚脲分散体的尺寸组合物; 任选地进一步的成膜树脂; 和任选的交联剂。通过使多异氰酸酯与聚合多元醇和/或多胺，任选的低分子量化合物，异氰酸酯反应性，离子或潜在离子亲水化的化合物和/或异氰酸酯反应性非离子亲水化的化合物反应制备含NCO的聚氨酯预聚物，任选地在惰性溶剂中，条件是组分不含有伯或仲氨基; 然后将预聚物溶解在脂族酮中，或者通过进一步加入脂族酮稀释预聚物溶液; 并使预聚物的剩余游离NCO基与扩链剂组分反应。分散体用于可用于烧结基材（例如玻璃纤维）的模制品和/或涂料中。

39. 发明授权

US5482649A Aminoacrylates and a process for their preparation 失效
标题翻译：氨基丙烯酸酯及其制备方法
公开(公告)号：US5482649A
公开(公告)日：1996-01-09
申请号：US95886
申请日：1993-07-22
申请人： Jurgen Meixner , Wolfgang Fischer , Christian Zwiener
发明人： Jurgen Meixner , Wolfgang Fischer , Christian Zwiener
IPC分类号： C08F20/36 , C07C69/54 , C07C217/50 , C07C219/08 , C07C227/06 , C07C229/12 , C07C229/14 , C07C229/16 , C08F20/34 , C08F220/36 , C08F299/02 , C08G65/332 , C09D4/00 , C09D4/02 , C09J4/02 , C09K3/00
CPC分类号： C08G65/3322 , C07C227/06 , C07C229/12 , C07C229/14 , C07C69/54 , C08F299/024 , C09D4/00
摘要： The present invention relates to aminoacrylates which have a viscosity of 200 to 3000 mPa.s at 23.degree. C. and 100% solids, a content of olefinic double bonds (calculated as C=C, molecular weight=24) of 8 to 20% by weight and a nitrogen content of 0.4 to 2.0% by weight, and which are prepared by an addition reaction by reacting at a molar ratio of primary amino groups from component a) to olefinic double bonds from component b) of 0.05:1 to 0.25:1a) mono- or diamines having a molecular weight of 31 to 300 and having aliphatically bound amino groups withb) acrylic esters of polyhydric alcohols which have been prepared at a COOH/OH equivalent ratio of 0.8:1 to 1:1 fromb1) acrylic acid andb2) ether-alcohols which have 3 or 4 hydroxyl groups and a molecular weight of 136 to 1000, possess at least one ethylene oxide unit --CH.sub.2 --CH.sub.2 --O-- as part of the ether structure and do not contain propylene oxide units --CH.sub.2 --CH(CH.sub.3)--O--.The present invention also relates to a process for the preparation these aminoacrylates.
摘要翻译：本发明涉及在23℃和100％固体粘度为200-3000mPa.s，烯属双键（C = C，分子量= 24计算）的含量为8至20％的氨基丙烯酸酯，并且氮含量为0.4〜2.0重量％，并且其通过加成反应制备，其通过使组分a）中的伯氨基与组分b）的烯属双键的摩尔比为0.05:1至0.25 ：1a）分子量为31〜300，具有脂族结合氨基的单胺或二胺，b）以0.8:1〜1:1的COOH / OH当量比制备的多元醇丙烯酸酯， b1）丙烯酸和b2）具有3或4个羟基并且分子量为136至1000的醚醇具有至少一个环氧乙烷单元-CH 2 -CH 2 -O-作为醚结构的一部分，并且不含环氧丙烷单元-CH2-CH（CH3）-O-。本发明还涉及制备这些氨基丙烯酸酯的方法。

40. 发明授权

US5470897A Radically curable coating compositions and their use for coating wood substrates 失效
标题翻译：可自由基固化的涂料组合物及其用于涂覆木质基材的用途
公开(公告)号：US5470897A
公开(公告)日：1995-11-28
申请号：US234753
申请日：1994-04-28
申请人： Jurgen Meixner , Wolfgang Fischer , Manfred Muller
发明人： Jurgen Meixner , Wolfgang Fischer , Manfred Muller
IPC分类号： C08F283/01 , C08G63/676 , C09D7/12 , C09D167/06 , C08L67/06 , C08K5/01 , C08K5/10
CPC分类号： C08G63/676 , C08F283/01 , C09D167/06
摘要： A radically curable coating composition containing) 50 to 95 parts by weight of an unsaturated polyester component having a viscosity at 23.degree. C. of 1,000 to 15,000 mPa.s, B) 5 to 50 parts by weight of compounds containing (meth)acryloyl groups and/or vinyl ether groups, C) 0.01 to 0.3 wt. %, based on the total weight, of waxes and/or paraffins having a melting point of 35+ to 100.degree. C. and D) 0 to 10 wt. %, based on the total weight, of at least one plasticizer or carbamic acid resin, and the use of the coating composition for coating substrates, in particular wood substrates.
摘要翻译：一种可自由基固化的涂料组合物，其含有50至95重量份的在23℃下的粘度为1,000至15,000mPa.s的不饱和聚酯组分，B）5至50重量份含（甲基）丙烯酰基的化合物和/或乙烯基醚基，C）0.01〜0.3重量％％，基于总重量，熔点为35℃至100℃的蜡和/或链烷烃，和D）0至10重量％。基于总重量，至少一种增塑剂或氨基甲酸树脂，以及用于涂覆基材，特别是木质基材的涂料组合物的用途。

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