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31. 发明授权

US06693204B2 Method for purification of cyclic ester 失效
标题翻译：环酯的纯化方法
公开(公告)号：US06693204B2
公开(公告)日：2004-02-17
申请号：US10240175
申请日：2002-09-30
申请人： Tetsuo Ejiri , Kazuyuki Yamane , Kentaro Otawara
发明人： Tetsuo Ejiri , Kazuyuki Yamane , Kentaro Otawara
IPC分类号： C07D31912
CPC分类号： C07D319/12 , B01D9/00 , B01D9/0004 , B01D9/004 , B01D9/005
摘要： A method of refining a crystal of a crude cyclic ester comprises the steps of supplying the crude cyclic ester to a vertically extending cylindrical refiner (1) from an inlet (3) provided at a lower part of the refiner (1), agitating the crude cyclic ester by an agitator provided in the refiner (1) to make the crude cyclic ester flow upwardly, refining the crystals of the crude cyclic ester by counterflow-contact between the upflowing crude cyclic ester and a downflowing melted liquid containing a refined crystal component, and taking out refined crystals of the crude cyclic ester from an outlet (4) provided at an upper part of the refiner (1).
摘要翻译：精制粗环酯的晶体的方法包括以下步骤：将粗环酯从设置在精制机（1）的下部的入口（3）向垂直延伸的圆柱形精磨机（1）供应，搅拌粗品通过设置在精制机（1）中的搅拌器使环酯向上流动，使粗环酯向上流动，通过向上流动的粗环酯与含有精制晶体组分的向下流动的熔融液体之间的逆流接触来精制粗环酯的晶体，并且从设置在精制机（1）的上部的出口（4）取出粗制环酯的精制晶体。

32. 发明申请

US20110263875A1 Production Process of Glycolide 有权
标题翻译：乙交酯的生产工艺
公开(公告)号：US20110263875A1
公开(公告)日：2011-10-27
申请号：US13142012
申请日：2009-12-09
申请人： Shigeru Suzuki , Kazuyuki Yamane , Toshihiko Ono , Kazuhiko Sunagawa
发明人： Shigeru Suzuki , Kazuyuki Yamane , Toshihiko Ono , Kazuhiko Sunagawa
IPC分类号： C07D319/12
CPC分类号： C07D319/12
摘要： The invention provides a production process of glycolide comprising the respective steps of: Step 1 of heating a mixture containing a glycolic acid oligomer and a high boiling polar organic under normal or reduced pressure to reflux the mixture and at that time, conducting a total reflux operation in a reflux time within a range of 0.1 to 20 hours under conditions that substantially the whole amount of a distillate distilled out of a reflux system containing the mixture is refluxed into the reflux system; Step 2 of heating the mixture after the total reflux operation or a mixture obtained by adding the high boiling polar organic solvent to a glycolic acid oligomer component recovered from the mixture after the total reflux operation to conduct depolymerization; and Step 3 of collecting glycolide from a co-distillate.
摘要翻译：本发明提供了一种乙交酯的制备方法，其包括以下各步骤：步骤1，在正常或减压下加热含有乙醇酸低聚物和高沸点极性有机物的混合物以回流混合物，并且此时进行总的回流操作在从含有该混合物的回流系统蒸馏出的基本上全部量的馏出物回流至回流系统的条件下，在0.1至20小时的范围内的回流时间内，在全部回流操作之后加热混合物的步骤2或通过在完全回流操作后从混合物中回收的乙醇酸低聚物组分加入高沸点极性有机溶剂而获得的混合物进行解聚; 和从共馏出物收集乙交酯的步骤3。

33. 发明授权

US07785682B2 Multilayer sheet made of polyglycolic acid resin 失效
标题翻译：由聚乙醇酸树脂制成的多层板
公开(公告)号：US07785682B2
公开(公告)日：2010-08-31
申请号：US11630255
申请日：2005-06-20
申请人： Takashi Sato , Kazuyuki Yamane , Juichi Wakabayashi , Tomoaki Sato , Takehisa Suzuki
发明人： Takashi Sato , Kazuyuki Yamane , Juichi Wakabayashi , Tomoaki Sato , Takehisa Suzuki
IPC分类号： B27M3/00 , B27N5/02
CPC分类号： B32B9/02 , B32B7/12 , B32B9/045 , B32B27/36 , B32B2307/7163 , B32B2439/70 , B65D65/466 , Y02A40/961 , Y02W90/13 , Y10T428/1303 , Y10T428/1334 , Y10T428/1338 , Y10T428/1348 , Y10T428/1352
摘要： A polyglycolic acid resin-based multilayer sheet, comprising: a plant substrate sheet and a biodegradable resin layer laminated by melt-adhesion onto the plant substrate sheet, wherein said biodegradable resin layer comprises one or plural layer including at least a polyglycolic acid resin layer, and the multilayer sheet includes on the substrate sheet a melt-adhesion layer comprising a biodegradable resin exhibiting a melt viscosity of 10-5.0×103 Pa·sec as measured at a temperature of 240° C. and a shear speed of 122 sec−1 and having a melting point of at most 235° C. The multilayer sheet has a laminate structure composed of biodegradable materials exerting little load to the environment at the time of disposable thereof and yet is excellent in oxygen-barrier property and moisture resistance, thus being suitable as a food container-forming material.
摘要翻译：一种聚乙醇酸树脂系多层片材，其特征在于，具有：植物基片和通过熔融粘合层叠在所述植物基片上的生物降解性树脂层，其中，所述生物降解性树脂层包含至少包含聚乙醇酸树脂层的一层或多层，并且所述多层片材在所述基材片材上包含熔融粘合层，所述熔融粘合层包含在240℃的温度下测定的熔融粘度为10-5.0×103Pa·sec的剪切速度和122秒-1的剪切速度的生物降解性树脂熔点为235℃以下。多层片材具有由一次性使用时对环境几乎没有负载的生物降解性材料构成的层压结构，但是具有优异的阻氧性和耐湿性，因此，适合作为食品容器形成材料。

34. 发明申请

US20100148391A1 Filament of polyglycolic acid resin and process for producing the same 有权
标题翻译：聚乙醇酸树脂的丝及其制造方法
公开(公告)号：US20100148391A1
公开(公告)日：2010-06-17
申请号：US12656810
申请日：2010-02-17
申请人： Satoshi Hashimoto , Kazuyuki Yamane , Juichi Wakabayashi , Hirokazu Matsui
发明人： Satoshi Hashimoto , Kazuyuki Yamane , Juichi Wakabayashi , Hirokazu Matsui
IPC分类号： D01D5/088
CPC分类号： D01F6/625 , D01D5/0885 , D01D5/12 , D02G3/444 , D02J1/22 , D02J1/223 , D02J1/228
摘要： A biodegradable filament of polyglycolic acid resin having practical properties represented by high tensile strength and knot strength is produced. A polyglycolic acid resin having a residual monomer content of below 0.5 wt. % is melt-spun, quenched in a liquid bath of at most 10° C. and then stretched in a liquid bath of 60-83° C. to produce a polyglycolic acid resin filament having a tensile strength of at least 750 MPa and a knot strength of at least 600 MPa.
摘要翻译：制造具有高拉伸强度和结强度代表的实用性能的聚乙醇酸树脂的生物可降解长丝。残留单体含量低于0.5重量％的聚乙醇酸树脂％熔体纺丝，在至多10℃的液槽中淬火，然后在60-83℃的液浴中拉伸，得到拉伸强度为至少750MPa的聚乙醇酸树脂长丝和结强度至少为600MPa。

35. 发明申请

US20080069988A1 Multilayer Sheet Made of Polyglycolic Acid Resin 失效
标题翻译：由聚乙醇酸树脂制成的多层板
公开(公告)号：US20080069988A1
公开(公告)日：2008-03-20
申请号：US11630255
申请日：2005-06-20
申请人： Takashi Sato , Kazuyuki Yamane , Juichi Wakabayashi , Tomoaki Sato , Takeshi Suzuki
发明人： Takashi Sato , Kazuyuki Yamane , Juichi Wakabayashi , Tomoaki Sato , Takeshi Suzuki
IPC分类号： B32B27/10 , B32B27/06
CPC分类号： B32B9/02 , B32B7/12 , B32B9/045 , B32B27/36 , B32B2307/7163 , B32B2439/70 , B65D65/466 , Y02A40/961 , Y02W90/13 , Y10T428/1303 , Y10T428/1334 , Y10T428/1338 , Y10T428/1348 , Y10T428/1352
摘要： A multilayer sheet made of a polyglycolic acid resin which is constructed by the fusion/lamination of a biodegradable resin layer on a base sheet of vegetable origin, characterized in that the biodegradable resin layer comprises one or more layers involving at least one polyglycolic acid resin layer and the layer fused with the base sheet is made of a biodegradable resin having a melt viscosity of 10 to 5.0×103 Pa·sec at a temperature of 240° C. and a shear speed of 122 sec−1 and a melting point of 235° C. or lower. Although the multilayer sheet has a lamination structure made of biodegradable materials with light environmental burden at disposal, it is excellent in oxygen-barrier properties and resistance to moisture transmission. Thus, it is appropriately usable as a food container material.
摘要翻译：由聚乙醇酸树脂制成的多层片材，其通过植物性基片上的生物降解性树脂层的熔融/层叠而构成，其特征在于，所述生物降解性树脂层包含一层以上的涉及至少一种聚乙醇酸树脂层并且与基片熔合的层由在240℃的温度和122秒的剪切速度下的熔体粘度为10至5.0×10 3 Paa.sec的可生物降解的树脂制成， SUP> -1和熔点235℃以下。虽然多层片材具有由可生物降解的材料制成的层叠结构，具有处理轻的环境负担，但是其阻氧性和耐湿性传导性优异。因此，可以适当地用作食品容器材料。

36. 发明申请

US20050221032A1 Container of biodegradable heat-resistant hard resin molding 审中-公开
标题翻译：容器可生物降解耐热硬树脂成型
公开(公告)号：US20050221032A1
公开(公告)日：2005-10-06
申请号：US10515387
申请日：2003-05-28
申请人： Kazuyuki Yamane , Yukichika Kawakami , Tomoaki Sato , Hisanori Tobita , Takehisa Suzuki
发明人： Kazuyuki Yamane , Yukichika Kawakami , Tomoaki Sato , Hisanori Tobita , Takehisa Suzuki
IPC分类号： B32B27/08 , B32B27/36 , B65D65/46 , B65D1/00
CPC分类号： B32B27/08 , B32B27/36 , B32B2307/7163 , B32B2439/70 , B65D65/466 , Y02A40/961 , Y02W90/13 , Y10T428/1328 , Y10T428/1352
摘要： A shaped container of biodegradable, heat-resistant and rigid resin having a laminate structure including a glycolic acid polymer layer and another biodegradable resin layer, is formed by shaping under heating so that another biodegradable resin forms an outer and/or inner layer. The container is excellent in biodegradability, stiffness and heat resistance as well as excellent see-through of contents, and is suitable as a temporary preservation container for food, etc.
摘要翻译：通过在加热下成形，形成具有包含乙醇酸聚合物层和另一生物降解性树脂层的叠层结构的可生物降解，耐热和刚性树脂的成形容器，从而形成外层和/或内层。容器的生物降解性，刚度和耐热性优异，内容物透明性好，适用于食品等的临时保存容器。

37. 发明授权

US08722907B2 Production process of glycolide 有权
标题翻译：乙交酯的生产过程
公开(公告)号：US08722907B2
公开(公告)日：2014-05-13
申请号：US13142012
申请日：2009-12-09
申请人： Shigeru Suzuki , Kazuyuki Yamane , Toshihiko Ono , Kazuhiko Sunagawa
发明人： Shigeru Suzuki , Kazuyuki Yamane , Toshihiko Ono , Kazuhiko Sunagawa
IPC分类号： C07D319/00
CPC分类号： C07D319/12
摘要： The invention provides a production process of glycolide comprising the respective steps of: Step 1 of heating a mixture containing a glycolic acid oligomer and a high boiling polar organic under normal or reduced pressure to reflux the mixture and at that time, conducting a total reflux operation in a reflux time within a range of 0.1 to 20 hours under conditions that substantially the whole amount of a distillate distilled out of a reflux system containing the mixture is refluxed into the reflux system; Step 2 of heating the mixture after the total reflux operation or a mixture obtained by adding the high boiling polar organic solvent to a glycolic acid oligomer component recovered from the mixture after the total reflux operation to conduct depolymerization; and Step 3 of collecting glycolide from a co-distillate.
摘要翻译：本发明提供了一种乙交酯的制备方法，其包括以下各步骤：步骤1，在正常或减压下加热含有乙醇酸低聚物和高沸点极性有机物的混合物以回流混合物，并且此时进行总的回流操作在从含有该混合物的回流系统蒸馏出的基本上全部量的馏出物回流至回流系统的条件下，在0.1至20小时的范围内的回流时间内，在全部回流操作之后加热混合物的步骤2或通过在完全回流操作后从混合物中回收的乙醇酸低聚物组分加入高沸点极性有机溶剂而获得的混合物进行解聚; 和从共馏出物收集乙交酯的步骤3。

38. 发明授权

US08119699B2 Method of recycling laminated molding 失效
标题翻译：层压成型方法
公开(公告)号：US08119699B2
公开(公告)日：2012-02-21
申请号：US10579560
申请日：2004-11-11
申请人： Kazuyuki Yamane , Ryo Kato , Akiko Wakamatsu
发明人： Kazuyuki Yamane , Ryo Kato , Akiko Wakamatsu
IPC分类号： C08J11/04 , B08B9/20 , B02C17/00 , B29D22/00
CPC分类号： C08J11/06 , C08J11/04 , C08J2367/02 , C08J2467/04 , Y02P20/143 , Y02P20/582 , Y02W30/70 , Y02W30/701 , Y10T428/1352
摘要： A method of recycling a laminate shaped product, including the steps of: breaking a shaped product having a laminate structure including at least one layer of aliphatic polyester resin in addition to a principal resin layer, storing resultant broken pieces in a moisturizing environment to adjust a moisture content of the aliphatic polyester resin (layer) to at least 0.5 wt. %, and then washing the broken pieces with alkaline water to remove the aliphatic polyester resin layer, thereby recovering the principal resin. As a result, it becomes possible to shorten an induction period in the alkaline water washing step that is a principal process step, thereby rationalizing the entire process.
摘要翻译：一种回收层压成形产品的方法，包括以下步骤：除了主树脂层之外，将具有包括至少一层脂肪族聚酯树脂的叠层结构的成形产品破碎，将保存在保湿环境中的破碎片调节脂肪族聚酯树脂（层）的水分含量至少为0.5重量％％，然后用碱性水洗涤破碎片以除去脂族聚酯树脂层，从而回收主要树脂。结果，可以缩短作为主要处理步骤的碱性水洗涤步骤中的诱导期，从而使整个过程合理化。

39. 发明申请

US20100168446A1 METHOD FOR PURIFICATION OF CYCLIC ESTER 有权
标题翻译：循环酶纯化方法
公开(公告)号：US20100168446A1
公开(公告)日：2010-07-01
申请号：US12449669
申请日：2008-01-28
申请人： Kazuyuki Yamane , Tomohiro Hoshi , Tomoyuki Ogawa
发明人： Kazuyuki Yamane , Tomohiro Hoshi , Tomoyuki Ogawa
IPC分类号： C07D319/12
CPC分类号： C07D319/12
摘要： A method of purifying a cyclic ester, comprising: mixing a co-distillated liquid comprising a cyclic ester produced by heating depolymerization of a hydroxycarboxylic acid oligomer in the presence of a depolymerization solvent and the depolymerization solvent with an organic solvent for washing which is mutually soluble with the depolymerization solvent and has a lower boiling point than the cyclic ester; subjecting the resultant mixture liquid to liquid-liquid separation into an organic solvent phase containing the depolymerization solvent and a cyclic ester phase containing the organic solvent; and then evaporating the organic solvent from the cyclic ester phase containing the organic solvent to recover the cyclic ester containing a reduced amount of the depolymerization solvent. As a result, purified cyclic ester is recovered at high heat efficiency, purification efficiency and operation efficiency, from the co-distillate liquid containing the depolymerization solvent and the cyclic ester from the depolymerization system for thermal decomposition of the hydroxycarboxylic acid oligomer in the presence of the depolymerization solvent.
摘要翻译：一种环状酯的提纯方法，其特征在于，包括：在解聚溶剂和解聚溶剂的存在下，通过将羟基羧酸低聚物的解聚反应与溶解有机溶剂进行溶解而得到的包含环状酯的共蒸馏液，具有解聚溶剂并且具有比环酯低的沸点; 将所得混合液进行液 - 液分离成含有解聚溶剂的有机溶剂相和含有有机溶剂的环状酯相; 然后从含有机溶剂的环状酯相中蒸发有机溶剂，回收含有减少量的解聚溶剂的环状酯。结果，从含有解聚溶剂的共馏出液和来自用于羟基羧酸低聚物的热分解的解聚体系的环状酯在高热效率，净化效率和操作效率下，在存在解聚溶剂。

40. 发明授权

US07067611B2 Polyhydroxycarboxylic acid and its production process 有权
标题翻译：聚羟基羧酸及其生产工艺
公开(公告)号：US07067611B2
公开(公告)日：2006-06-27
申请号：US10483039
申请日：2002-07-05
申请人： Kazuyuki Yamane , Yukichika Kawakami
发明人： Kazuyuki Yamane , Yukichika Kawakami
IPC分类号： C08G63/02
CPC分类号： C08G63/80 , C08G63/08
摘要： Polyhydroxycarhoxylic acids are provided, which are controlled in terms of the rate of biodegradability, and give molded or otherwise formed articles that are of uniform quality with neither premature strength drop nor premature deterioration of retention of outside shape, and their production process is provided as well. The poly-hydroxycarboxylic acids are obtained by ring-opening polymerization of cyclic esters. The polyhydroxy-carboxylic acids have a weight-average molecular weight (Mw) in the range of 10,000 to 1,000,000, a molecular weight distribution in the range of 1.0 to 2.5 as represented by the weight-average molecular weight-to-number-average molecular weight ratio (Mw/Mn) and a yellowness index (YI) of 40 or less, and have a precisely controlled rate of biodegradability.
摘要翻译：提供了多羟基甲氧基酸，其以生物降解性的速率进行控制，并且得到具有均匀质量的成型制品或其它成型制品，既不过早强度下降也不会使外部形状保持力过早劣化，并且还提供其制造方法。多羟基羧酸通过环状酯的开环聚合得到。多羟基羧酸的重均分子量（Mw）为10,000〜1,000,000，分子量分布范围为1.0〜2.5，以重均分子量与数均分子量重量比（Mw / Mn）和黄色指数（YI）为40以下，具有精确控制的生物降解率。

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