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31. 发明授权

US06191318B1 Process for preparing hydroxylated aromatics by hydrogen and oxygen 失效
标题翻译：通过氢气和氧气制备羟基化芳烃的方法
公开(公告)号：US06191318B1
公开(公告)日：2001-02-20
申请号：US09332135
申请日：1999-06-14
申请人： Sang Eon Park , Chul Wee Lee , Jong San Chang , Yong Ki Park
发明人： Sang Eon Park , Chul Wee Lee , Jong San Chang , Yong Ki Park
IPC分类号： C07C3700
CPC分类号： C07C37/58 , Y02P20/52 , C07C39/04
摘要： The present invention relates to a process for preparing hydroxylated aromatics by using hydrogen and oxygen and more particularly, to a process for preparing hydroxylated aromatics by using hydrogen and oxygen with a two-component heterogeneous catalyst. One component consists of porous catalyst containing one of Group VIII B transition metals such as Pd, Pt, Au and Cu, and hydrogen transfer organic compounds such as anthraquinone. The other component consists of a catalyst containing a transition metal selected from Ti, V, and Sn with tetrahedral coordination geometry. The main advantages of this new catalytic system are to 1) overcome the drawbacks of liquid phase oxidation using conventional homogeneous catalysts, 2) avoid use of expensive hydrogen peroxide as an oxidant, and 3) improve the selectivity of the reaction.
摘要翻译：本发明涉及通过使用氢和氧制备羟基化芳族化合物的方法，更具体地说，涉及通过使用氢和氧与双组分多相催化剂制备羟基化芳族化合物的方法。一种组分由含有ⅧB族过渡金属如Pd，Pt，Au和Cu之一的多孔催化剂和氢转移有机化合物如蒽醌组成。另一个组分由含有选自Ti，V和Sn的过渡金属和四面体配位几何形状的催化剂组成。这种新催化体系的主要优点是1）克服使用常规均相催化剂的液相氧化的缺点，2）避免使用昂贵的过氧化氢作为氧化剂，3）提高反应的选择性。

32. 发明授权

US09056308B2 Catalyst for catalytic cracking of hydrocarbon, which is used in production of light olefin and production method thereof 有权
标题翻译：用于轻烯烃生产的烃催化裂化催化剂及其制备方法
公开(公告)号：US09056308B2
公开(公告)日：2015-06-16
申请号：US14168602
申请日：2014-01-30
申请人： Dae Hyun Choo , Hong Chan Kim , Suk Joon Kim , Ji Min Kim , Tae Jin Kim , Sun Choi , Seung Hoon Oh , Yong Seung Kim , Deuk Soo Park , Yong Ki Park , Chul Wee Lee , Hee Young Kim , Won Choon Choi , Na Young Kang , Bu Sub Song
发明人： Dae Hyun Choo , Hong Chan Kim , Suk Joon Kim , Ji Min Kim , Tae Jin Kim , Sun Choi , Seung Hoon Oh , Yong Seung Kim , Deuk Soo Park , Yong Ki Park , Chul Wee Lee , Hee Young Kim , Won Choon Choi , Na Young Kang , Bu Sub Song
IPC分类号： B01J29/06 , B01J29/48 , B01J29/076 , B01J37/00 , C10G11/05 , B01J37/28
CPC分类号： B01J29/48 , B01J29/076 , B01J37/0045 , B01J37/28 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C10G11/05 , C10G2300/301 , C10G2400/20
摘要： Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01˜5.0 wt % of MnO2 and 1˜15 wt % of P2O5 are simultaneously imbedded in catalyst which consists of zeolite, clay and inorganic complex. According to the present invention, the method that manganese and phosphate are imbedded simultaneously in zeolite and inorganic complex is used to increases thermal-stability of obtained spherical catalyst, and increase olefin yield of cracking hydrocarbon such as naphtha by protecting acid-site of zeolite. To synthesize the required catalyst, the important procedures are mixing ratio and mixing sequence of Mn, P, zeolite, and inorganic complex.
摘要翻译：公开了一种分子筛催化剂及其制备方法，用于在严酷的高温高湿环境下催化裂解石脑油。详细地，通过喷雾干燥和煅烧混合浆料制备催化剂，其中0.01〜5.0重量％的MnO 2和1〜15重量％的P 2 O 5同时嵌入由沸石，粘土和无机络合物组成的催化剂中。根据本发明，使用锰和磷酸盐同时嵌入沸石和无机络合物的方法来提高所得球形催化剂的热稳定性，并通过保护沸石的酸性位点来提高裂解烃如石脑油的烯烃产率。为了合成所需的催化剂，重要的步骤是Mn，P，沸石和无机络合物的混合比和混合顺序。

33. 发明授权

US08840864B2 Method of preparing ZSM-5 zeolite using nanocrystalline ZSM-5 seeds 有权
标题翻译：使用纳米晶体ZSM-5种子制备ZSM-5沸石的方法
公开(公告)号：US08840864B2
公开(公告)日：2014-09-23
申请号：US13502607
申请日：2010-10-18
申请人： Sun Choi , Deuk Soo Park , Suk Joon Kim , Dae Hyun Choo , Yong Ki Park , Chul Wee Lee , Hee Young Kim , Won Choon Choi , Na Young Kang , Bu Sub Song
发明人： Sun Choi , Deuk Soo Park , Suk Joon Kim , Dae Hyun Choo , Yong Ki Park , Chul Wee Lee , Hee Young Kim , Won Choon Choi , Na Young Kang , Bu Sub Song
IPC分类号： C01B39/38 , B01J29/40
CPC分类号： C01B39/38 , B01J20/18 , B01J29/40 , B01J39/14
摘要： A method of preparing ZSM-5, including: providing a nanocrystalline ZSM-5 seed having a size of 70-150 nm; adding the nanocrystalline ZSM-5 seed to a stock solution including water glass as a silica source, an alumina source, a neutralizer and water to form a reaction mixture; and maintaining the reaction mixture at 150-200° C. to crystallize the reaction mixture. The method is advantageous in that ZSM-5 having small and uniform crystal sizes and including no impurities can be synthesized in a short period of time.
摘要翻译：一种制备ZSM-5的方法，包括：提供尺寸为70-150nm的纳米晶体ZSM-5种子; 将纳米晶体ZSM-5种子加入到包含水玻璃作为二氧化硅源的储备溶液中，氧化铝源，中和剂和水以形成反应混合物; 并将反应混合物保持在150-200℃以使反应混合物结晶。该方法的优点在于，可以在短时间内合成具有小而均匀的晶体尺寸且不含杂质的ZSM-5。

34. 发明授权

US07488700B2 Hydrothermally stable microporous molecular sieve catalyst and preparation method thereof 有权
标题翻译：水热稳定微孔分子筛催化剂及其制备方法
公开(公告)号：US07488700B2
公开(公告)日：2009-02-10
申请号：US11427001
申请日：2006-06-28
申请人： Sun Choi , Yong Seung Kim , Deuk Soo Park , Suk Joon Kim , Il Mo Yang , Hee Young Kim , Yong Ki Park , Chul Wee Lee , Won Choon Choi , Kwang An Ko , Na Young Kang
发明人： Sun Choi , Yong Seung Kim , Deuk Soo Park , Suk Joon Kim , Il Mo Yang , Hee Young Kim , Yong Ki Park , Chul Wee Lee , Won Choon Choi , Kwang An Ko , Na Young Kang
IPC分类号： B01J29/06 , B01J27/16 , B01J27/18 , B01J27/182
CPC分类号： B01J29/40 , B01J29/061 , B01J29/405 , B01J29/46 , B01J2229/12 , B01J2229/18 , C10G29/205 , C10G2400/20
摘要： Disclosed are a hydrothermally stable porous molecular sieve catalyst and a preparation method thereof. The catalyst consists of a product obtained by the evaporation of water from a raw material mixture comprising a molecular sieve having a framework of Si—OH—Al—, a water-insoluble metal salt and a phosphate compound. The catalyst maintains its physical and chemical stabilities even in an atmosphere of high temperature and humidity. Accordingly, the catalyst shows excellent catalytic activity even when it is used in a severe process environment of high temperature and humidity in heterogeneous catalytic reactions, such as various oxidation/reduction reactions, including catalytic cracking reactions, isomerization reactions, alkylation reactions and esterification reactions.
摘要翻译：公开了一种水热稳定的多孔分子筛催化剂及其制备方法。催化剂由通过从包含具有Si-OH-Al-骨架的分子筛，水不溶性金属盐和磷酸盐化合物的原料混合物中蒸发水得到的产物组成。即使在高温和高湿的气氛下，催化剂仍保持其物理和化学稳定性。因此，即使在非均相催化反应如催化裂化反应，异构化反应，烷基化反应，酯化反应等各种氧化/还原反应中，在恶劣的高温高湿环境下使用，催化剂也具有优异的催化活性。

35. 发明申请

US20080161190A1 Biomagnetic field measurement apparatus 审中-公开
公开(公告)号：US20080161190A1
公开(公告)日：2008-07-03
申请号：US11821939
申请日：2007-06-26
申请人： In Seon Kim , Yong Ho Lee , Yong Ki Park
发明人： In Seon Kim , Yong Ho Lee , Yong Ki Park
IPC分类号： G01R33/035
CPC分类号： G01R33/0354
摘要： A biomagnetic field measurement apparatus according to the present invention comprises: a head part provided with SQUID sensors (Superconducting Quantum Interference Device) for measuring a magnetocardiogram, the sensors being arranged in a row in a right and left direction at a lower end portion of the head part and being spaced apart by a predetermined space, and a non-magnetic liquid coolant container for cooling the SQUID sensors; an electronic circuitry part for controlling the SQUID sensors and measuring a signal; a signal processing software part for acquiring and storing the signal detected by the electronic circuitry part to a PC, calculating the signal and thus transforming the signal to a magnetic signal or a current signal, then mapping and displaying the transformed signal; and a bed part made of a non-magnetic material, mounted at a lower side of the head part to be spaced apart therefrom and provided with a platy sliding bed for measuring a magnetocardiogram by using the SQUID sensors of the head part at a state that a man to be measured is laid thereon, a sliding rail for allowing the sliding bed to move thereon in a front and rear direction, an up and down moving device for moving the sliding bed, for adjusting a measuring position of the man to be measured, in an up and down direction for adjusting the position of the SQUID sensors of the head part, a right and left moving device for moving the sliding bed in a right and left direction, and a front and rear moving device for moving the sliding bed in a front and rear direction by a predetermined space.The biomagnetic field measurement apparatus according to the present invention has advantages that since SQUID sensors are arranged in a row and a magnetocardiogram is measured by moving the bed in a predetermined space, it is not necessary for the high-priced SQUID sensors to be provided a lot in comparison with a conventional biomagnetic field measurement apparatus, and thus the apparatus is inexpensive, structurally simple and able to be downsized, a space taken up can be reduced and maintenance thereof is facilitated.

36. 发明授权

US06421152B1 Optical buffer utilizing a cell pointer 有权
标题翻译：光缓冲器利用单元指针
公开(公告)号：US06421152B1
公开(公告)日：2002-07-16
申请号：US09232698
申请日：1999-01-19
申请人： Kyeong Mo Yoon , Yoon Hak Bang , Su Mi Chang , Jin Sik Park , Yong Ki Park , Sang Goo Lee , Sang In Kim
发明人： Kyeong Mo Yoon , Yoon Hak Bang , Su Mi Chang , Jin Sik Park , Yong Ki Park , Sang Goo Lee , Sang In Kim
IPC分类号： H04J1400
CPC分类号： H04Q11/0003 , H04J14/02 , H04J14/0223 , H04Q11/0005 , H04Q2011/0011 , H04Q2011/0013 , H04Q2011/002 , H04Q2011/0032 , H04Q2011/0035
摘要： The present invention relates to an apparatus of a high speed optical buffer utilizing a cell pointer so that optical cells of asynchronous transfer mode can be stored and processed at high speed without the restriction of processing time for a high speed network architecture, wherein an internal switch of the apparatus would be controlled by extracting optically the cell pointer indicating starting point by using a high speed optical buffer with terahertz optical asymmetric demultiplex (Terahetz Optical Asymmetric Demultiplexer) in order to avoid a collision of each cell which is transmitted on a same channel especially at the high speed network.
摘要翻译：本发明涉及一种利用单元指针的高速光缓冲器的装置，使得可以高速存储和处理异步传输模式的光单元，而不受高速网络架构的处理时间的限制，其中内部开关通过使用具有太赫兹光学非对称解复用器（Terahetz Optical Nonymmetric Demultiplexer）的高速光学缓冲器来光学地提取指示起始点的小区指针来控制装置的控制，以避免在相同信道上发送的每个小区的冲突，特别是在高速网络。

37. 发明授权

US6037511A Catalyst for dehydrogenating aromatic with carbon dioxide 失效
标题翻译：用二氧化碳使芳香族脱氢的催化剂
公开(公告)号：US6037511A
公开(公告)日：2000-03-14
申请号：US265359
申请日：1999-03-10
申请人： Sang-Eon Park , Jong-San Chang , Yong Ki Park , Min Seok Park , Chul Wee Lee , Jermim Noh
发明人： Sang-Eon Park , Jong-San Chang , Yong Ki Park , Min Seok Park , Chul Wee Lee , Jermim Noh
IPC分类号： C07C5/32 , C07C5/333 , C07C5/327
CPC分类号： C07C5/322 , C07C5/3332 , C07C2523/745 , Y02P20/582
摘要： The invention herein relates to a catalyst for enhancing the conversion of the dehydrogenation reaction of aromatic hydrocarbons such as ethylbenzene under a flow of carbon dioxide, which is expressed by the following formula I, wherein a catalyst in which an active component of iron oxides is highly dispersed onto a zeolite, activated charcoal, .gamma.-alumina or silica carrier. Further, the invention relates to a dehydrogenation method of aromatic hydrocarbons by means of using said catalyst:(Fe.sup.II.sub.x Fe.sup.III.sub.y O.sub.z)/S (I)wherein S denotes a zeolite, activated charcoal, .gamma.-alumina or silica carrier, and the initial state of iron oxide is as follows:x=0.1-2 x+y=3and z=(2x+3y)/2As compared to the case in which the reaction is carried out without carbon dioxide, the invention herein is characterized by the significant enhancement of the activity of the dehydrogenation reaction of aromatic hydrocarbons in conjunction with the catalytic stability under a flow of carbon dioxide in the reaction temperature range of 500.about.700.degree. C. In particular, the invention provides a method of enhancing the dehydrogenation activity, wherein a catalyst is used, in which having a carrier such as a zeolite, active carbon, .gamma.-alumina or silica is loaded with iron oxides containing a high concentration of Fe(II) species.
摘要翻译：本发明涉及一种催化剂，其用于增强在二氧化碳流下的芳烃如乙苯的脱氢反应的转化，其由下式I表示，其中，其中氧化铁的活性组分是高度的分散在沸石，活性炭，γ-氧化铝或二氧化硅载体上。此外，本发明涉及通过使用所述催化剂的芳烃的脱氢方法：（FeIIxFeIIIyOz）/ S（I）其中S表示沸石，活性炭，γ-氧化铝或二氧化硅载体，以及氧化铁的初始状态如下：与没有二氧化碳进行反应的情况相比，x = 0.1-2×+ y = 3和z =（2x + 3y）/ 2As），本发明的特征在于活性的显着提高的芳烃的脱氢反应以及在二氧化碳流动下在700℃的反应温度范围内的催化稳定性。特别地，本发明提供一种提高脱氢活性的方法，其中使用催化剂，其中具有诸如沸石，活性炭，γ-氧化铝或二氧化硅的载体载有含有高浓度Fe（II）物质的氧化铁。

38. 发明授权

US6034032A Catalyst for dehydrogenating aromatic hydrocarbons with carbon dioxide 失效
标题翻译：用二氧化碳使芳烃脱氢的催化剂
公开(公告)号：US6034032A
公开(公告)日：2000-03-07
申请号：US163350
申请日：1998-09-30
申请人： Sang-Eon Park , Jong-San Chang , Yong Ki Park , Min Seok Park , Chul Wee Lee , Jermim Noh
发明人： Sang-Eon Park , Jong-San Chang , Yong Ki Park , Min Seok Park , Chul Wee Lee , Jermim Noh
IPC分类号： B01J23/74 , B01J23/745 , B01J29/072 , B01J29/46 , B01J35/02 , C07B61/00 , C07C5/32 , C07C5/333 , C07C15/46 , B01J23/70 , B01J21/08 , B01J21/18 , B01J23/40 , B01J29/06
CPC分类号： C07C5/322 , B01J23/745 , C07C5/3332 , C07C2521/04 , C07C2521/08 , C07C2521/18 , C07C2523/745 , C07C2529/06 , Y02P20/582
摘要： The invention herein relates to a catalyst for enhancing the conversion of the dehydrogenation reaction of aromatic hydrocarbons such as ethylbenzene under a flow of carbon dioxide, which is expressed by the following formula I, wherein a catalyst in which an active component of iron oxides is highly dispersed onto a zeolite, activated charcoal, .gamma.-alumina or silica carrier. Further, the invention relates to a dehydrogenation method of aromatic hydrocarbons by means of using said catalyst:(Fe.sup.II.sub.x Fe.sup.III.sub.y O.sub.z)/S (I)wherein S denotes a zeolite, activated charcoal, .gamma.-alumina or silica carrier, and the initial state of iron oxide is as follows:x=0.1-2, x+y=3 and z=(2x+3y)/2As compared to the case in which the reaction is carried out without carbon dioxide, the invention herein is characterized by the significant enhancement of the activity of the dehydrogenation reaction of aromatic hydrocarbons in conjunction with the catalytic stability under a flow of carbon dioxide in the reaction temperature range of 500.about.700.degree. C. In particular, the invention provides a method of enhancing the dehydrogenation activity, wherein a catalyst is used, in which having a carrier such as a zeolite, active carbon, .gamma.-alumina or silica is loaded with iron oxides containing a high concentration of Fe(II) species.
摘要翻译：本发明涉及一种催化剂，其用于增强在二氧化碳流下的芳烃如乙苯的脱氢反应的转化，其由下式I表示，其中，其中氧化铁的活性组分是高度的分散在沸石，活性炭，γ-氧化铝或二氧化硅载体上。此外，本发明涉及通过使用所述催化剂的芳烃的脱氢方法：（FeIIxFeIIIyOz）/ S（I）其中S表示沸石，活性炭，γ-氧化铝或二氧化硅载体，以及氧化铁的初始状态如下：x = 0.1-2，x + y = 3，z =（2x + 3y）/ 2与没有二氧化碳进行反应的情况相比，本发明的特征在于显着增强的芳烃的脱氢反应的活性与在二氧化碳流动下的催化稳定性在500-6,000℃的反应温度范围内。特别地，本发明提供了一种增强脱氢活性的方法，其中a 使用其中具有载体如沸石，活性炭，γ-氧化铝或二氧化硅的催化剂负载含有高浓度Fe（II）物质的氧化铁。

39. 发明授权

US09321039B2 Catalyst for decomposition of perfluorinated compound containing halogen acid gas, and preparation method thereof 有权
标题翻译：用于分解含卤素酸性气体的全氟化合物的催化剂及其制备方法
公开(公告)号：US09321039B2
公开(公告)日：2016-04-26
申请号：US14356718
申请日：2012-08-16
申请人： Won Choon Choi , Yong Ki Park , Na Young Kang , Min-Whee Cho , Song-Jong Cho , Sung Ho Cho , Sung Jin Yoon , Young-Ju Son
发明人： Won Choon Choi , Yong Ki Park , Na Young Kang , Min-Whee Cho , Song-Jong Cho , Sung Ho Cho , Sung Jin Yoon , Young-Ju Son
IPC分类号： B01J27/185 , B01J37/03 , B01J23/00 , B01D53/86 , B01J37/00
CPC分类号： B01J27/1856 , B01D53/8662 , B01D2255/1026 , B01D2255/2092 , B01D2257/2066 , B01D2258/0216 , B01J23/002 , B01J37/0045 , B01J37/031 , B01J2523/00 , Y02C20/30 , B01J2523/31 , B01J2523/51 , B01J2523/822
摘要： The present invention provides a catalyst for the decomposition of a perfluorinated compound containing a halogen acid gas, and a preparation method thereof. According to the present invention, the Ru—P—Al tri-component catalyst for the decomposition of a perfluorinated compound shows an excellent decomposition activity and durability with respect to the decomposition and removal of a perfluorinated compound containing a halogen acid gas, and thus can be used to decompose a chamber cleaning gas, an etchant, a solvent and the like of a perfluorinated compound from the semiconductor manufacturing industry to the LCD processing field. In addition, the present invention can be useful for decomposing and removing a perfluorinated compound discharged in a process using a halogen acid gas such as F2, Cl2, Br2 and the like.
摘要翻译：本发明提供一种分解含有卤素酸气体的全氟化合物的催化剂及其制备方法。根据本发明，用于分解全氟化合物的Ru-P-Al三组分催化剂在分解和除去含有卤素酸气体的全氟化合物方面具有优异的分解活性和耐久性，因此可以用于将全氟化合物的室清洁气体，蚀刻剂，溶剂等从半导体制造工业分解成LCD处理领域。此外，本发明可用于分解和除去在使用诸如F2，Cl2，Br2等的卤素酸气体的方法中排出的全氟化合物。

40. 发明授权

US08044663B2 Ultra-sensitive susceptibility detection apparatus of anharmonic resonance measurement type using atomic magnetometer, and method of using same 有权
标题翻译：使用原子磁强计的非谐振共振测量型超敏感度检测装置及其使用方法
公开(公告)号：US08044663B2
公开(公告)日：2011-10-25
申请号：US12266726
申请日：2008-11-07
申请人： Ki Woong Kim , Yong Ho Lee , Hyuk Chan Kwon , Jin Mok Kim , Yong Ki Park
发明人： Ki Woong Kim , Yong Ho Lee , Hyuk Chan Kwon , Jin Mok Kim , Yong Ki Park
IPC分类号： G01V3/00
CPC分类号： G01N27/76
摘要： The ultra-sensitive susceptibility detection apparatus of anharmonic resonance measurement type using an atomic magnetometer detects a change in susceptibility by a specimen containing an object to be measured. The apparatus includes an atomic magnetometer. The atomic magnetometer includes a cell containing an alkaline metallic atom, a light source for magnetically polarizing the alkaline metallic atom of the cell, and a bias magnetic field applicator for applying a bias magnetic field to adjust a measuring resonance frequency of the alkaline metallic atom. The apparatus includes an excitation magnetic field applicator for applying an excitation magnetic fields of different frequencies to magnetically excite the specimen, but not to couple the excitation field directly to the measuring atomic resonance frequency, and a measuring device for measuring a change in magnetic polarization of the alkaline metallic atom, which is affected by a magnetic field caused by the specimen being magnetically excited by the excitation magnetic field.
摘要翻译：使用原子磁强计的非谐振共振测量型超灵敏度敏感度检测装置检测包含待测物体的试样的磁敏度变化。该装置包括原子磁强计。原子磁力计包括含有碱金属原子的电池，用于使电池的碱金属原子磁极化的光源和用于施加偏磁场的偏置磁场施加器，以调节碱金属原子的测量共振频率。该装置包括：励磁磁场施加器，用于施加不同频率的激励磁场，以使激励磁场激发样本，但不将激励场直接耦合到测量原子共振频率;以及测量装置，用于测量磁极化的变化碱性金属原子受到被激发磁场磁激发的试样所引起的磁场的影响。

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