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31. 发明申请

US20100081784A1 METHOD OF MAKING ISOSORBIDE POLYCARBONATE 有权
标题翻译：制备异辛烷聚碳酸酯的方法
公开(公告)号：US20100081784A1
公开(公告)日：2010-04-01
申请号：US12238683
申请日：2008-09-26
申请人： Hans-Peter Brack , Marianne Guyader , Han Vermeulen , Dennis James Patrick Maria Willemse
发明人： Hans-Peter Brack , Marianne Guyader , Han Vermeulen , Dennis James Patrick Maria Willemse
IPC分类号： C08G63/64 , C08G64/02
CPC分类号： C08G64/0208 , C08G64/1608 , C08G64/30
摘要： A polycarbonate is provided that contains repeat units derived from isosorbide and a residue derived from an activated diaryl carbonate. The polycarbonate has 1H-NMR peaks associated with the repeat units derived from isosorbide. The polycarbonate contains no more than a maximum allowable amount of sorbitol-derived color bodies. If these color bodies are present in the polycarbonate it has a 1H-NMR peak associated with the color bodies. The maximum allowable amount of color bodies are present when the integrated area of the 1H-NMR peak associated with the color bodies divided by the integrated areas of the 1H-NMR peaks associated with the repeat units derived from isosorbide is 0.025.
摘要翻译：提供聚碳酸酯，其包含衍生自异山梨醇的重复单元和衍生自活性碳酸二芳基酯的残基。聚碳酸酯具有与衍生自异山梨醇的重复单元相关的1 H-NMR峰。聚碳酸酯含有不超过最大允许量的山梨醇衍生的着色体。如果这些颜色体存在于聚碳酸酯中，则其具有与着色体相关联的1 H-NMR峰。当与色体相关的1 H-NMR峰的积分面积与由异山梨醇衍生的重复单元相关的1 H-NMR峰积分区域的积分面积为0.025时，存在着色体的最大允许量。

32. 发明授权

US07674872B2 Method of producing high molecular weight polymer 失效
标题翻译：生产高分子量聚合物的方法
公开(公告)号：US07674872B2
公开(公告)日：2010-03-09
申请号：US12140694
申请日：2008-06-17
申请人： Hans-Peter Brack , Maarten Antoon Jan Campman , Hans Looij , Laurus van der Wekke , Dennis James Patrick Maria Willemse
发明人： Hans-Peter Brack , Maarten Antoon Jan Campman , Hans Looij , Laurus van der Wekke , Dennis James Patrick Maria Willemse
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08G63/64 , C08G64/305
摘要： The present invention provides methods of producing high molecular weight polymer. A method of forming polycarbonate includes the step of combining in a reaction mixture a diaryl carbonate, a transesterification catalyst, an aliphatic dihydroxy compound, and a diacid compound in a reactor system. The temperature and pressure of the reactor system are adjusted to a first reactor setpoints and the reaction mixture is monitored to detect initiation of the exothermic oligomerization reaction. The reactor setpoint are adjusted to second reactor setpoints after detection of initiation of the exothermic oligomerization reaction. The reactor system is maintained at the second reactor setpoints to allow the reaction mixture to react to form an oligomer mixture. The oligomer mixture is then introduced to a polymerization reactor system operating under melt polymerization conditions sufficient to polymerize the oligomer mixture to a Mw of at least 9,000 g/mol (PC) and to remove the phenolic byproduct from the oligomer mixture to form polycarbonate.
摘要翻译：本发明提供高分子量聚合物的制造方法。形成聚碳酸酯的方法包括在反应混合物中在反应器体系中将碳酸二芳基酯，酯交换催化剂，脂族二羟基化合物和二酸化合物混合的步骤。将反应器系统的温度和压力调节至第一反应器设定点，并监测反应混合物以检测放热低聚反应的起始。在检测到放热低聚反应的起始之后，将反应器设定点调整到第二反应器设定点。将反应器系统保持在第二反应器设定点以允许反应混合物反应以形成低聚物混合物。然后将低聚物混合物引入到在熔融聚合条件下操作的聚合反应器系统，该条件足以将低聚物混合物聚合至至少9,000g / mol（PC）的Mw，并从低聚物混合物中除去酚类副产物以形成聚碳酸酯。

33. 发明授权

US07671164B2 Aliphatic polycarbonates, methods of making, and articles formed therefrom 有权
标题翻译：脂肪族聚碳酸酯，制造方法和由其形成的制品
公开(公告)号：US07671164B2
公开(公告)日：2010-03-02
申请号：US12124583
申请日：2008-05-21
申请人： Hans-Peter Brack , Maarten Antoon Jan Campman , Jorge Garcia Agudo , Jan Henk Kamps , Hans Looij , Fernando Olmedo Fernandez , Dennis James Patrick Maria Willemse
发明人： Hans-Peter Brack , Maarten Antoon Jan Campman , Jorge Garcia Agudo , Jan Henk Kamps , Hans Looij , Fernando Olmedo Fernandez , Dennis James Patrick Maria Willemse
IPC分类号： C08G63/00 , C08G63/02
CPC分类号： C08G64/305 , C08G64/0208
摘要： A method of making a polycarbonate is described. The method comprises melt reacting an ester-substituted diaryl carbonate and a multifunctional compound of the formula: in the presence of catalyst to form an oligomer comprising less than 2,000 ppm of an ester-linked terminal group, and melt polymerizing the oligomer to form a polycarbonate. Use of specific reaction conditions produces a polycarbonate having an Mw of greater than or equal to 25,000 g/mol as determined by gel-permeation chromatography relative to polystyrene standards. Polycarbonates comprising units derived from the multifunctional compound, including homopolycarbonates, aliphatic copolycarbonates further comprising units derived from an aromatic dihydroxy compound, and aliphatic polycarbonate-polyesters, are also disclosed, as are a thermoplastic composition and an article including the disclosed polycarbonates.
摘要翻译：描述制造聚碳酸酯的方法。该方法包括使酯取代的碳酸二芳酯和下式的多官能化合物熔融反应：在催化剂存在下，形成包含小于2,000ppm的酯连接的末端基团的低聚物，并将该低聚物熔融聚合以形成聚碳酸酯。使用特定的反应条件产生通过凝胶渗透色谱法相对于聚苯乙烯标准测定的Mw大于或等于25,000g / mol的聚碳酸酯。还公开了包含衍生自多官能化合物的单元的聚碳酸酯，包括均聚碳酸酯，还包含衍生自芳族二羟基化合物的单元的脂族共聚碳酸酯和脂族聚碳酸酯聚酯，以及包含所公开的聚碳酸酯的热塑性组合物和制品。

34. 发明申请

US20090286952A1 METHOD OF FORMING POLYCARBONATE 有权
标题翻译：形成聚碳酸酯的方法
公开(公告)号：US20090286952A1
公开(公告)日：2009-11-19
申请号：US12122234
申请日：2008-05-16
申请人： Hans-Peter Brack , Peter K. Davis , David Domingo Fuster , Jorge Garcia Agudo , Gerardo Hidalgo Llinas , Miguel Angel Salomon Cheliz , Ignacio Vic Fernandez , Laurus van der Wekke , Dennis James Willemse
发明人： Hans-Peter Brack , Peter K. Davis , David Domingo Fuster , Jorge Garcia Agudo , Gerardo Hidalgo Llinas , Miguel Angel Salomon Cheliz , Ignacio Vic Fernandez , Laurus van der Wekke , Dennis James Willemse
IPC分类号： C08G64/30
CPC分类号： C08G64/205 , B01J19/1862 , B01J19/20 , B01J2219/0004 , C08G64/307
摘要： A method of forming polycarbonate includes the steps of introducing a plurality of reaction components to a reactor operating under melt polymerization conditions and removing ester-substituted phenol from the reactor. The plurality of reaction components include a dihydroxy compound, an ester-substituted diaryl carbonate, and a melt transesterification catalyst. The reaction components are introduced in a plurality of reaction component streams. A first reaction component streams includes a melt transesterification catalyst dissolved or suspended in a liquid carrier containing an ester-substituted phenol. The composition of the first reaction component stream is selected such that ester-substituted phenol is not generated as a reaction product in the first reaction component stream.
摘要翻译：形成聚碳酸酯的方法包括以下步骤：将多个反应组分引入到在熔融聚合条件下操作的反应器中，并从反应器中除去酯取代的酚。多个反应组分包括二羟基化合物，酯取代的碳酸二芳基酯和熔融酯交换催化剂。将反应组分引入多个反应组分流中。第一反应组分流包括溶解或悬浮在含有酯取代的苯酚的液体载体中的熔融酯交换催化剂。选择第一反应组分流的组成，使得在第一反应组分流中不产生酯取代的酚作为反应产物。

35. 发明授权

US07615605B2 Monomer solution for producing polycarbonate 失效
标题翻译：用于生产聚碳酸酯的单体溶液
公开(公告)号：US07615605B2
公开(公告)日：2009-11-10
申请号：US12234243
申请日：2008-09-19
申请人： Hans-Peter Brack , Maarten Antoon Jan Campman , Yohana Perez de Diego , Dennis James Patrick Maria Willemse
发明人： Hans-Peter Brack , Maarten Antoon Jan Campman , Yohana Perez de Diego , Dennis James Patrick Maria Willemse
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08G64/307 , Y10T436/144444 , Y10T436/17
摘要： A non-reactive monomer mixture contains a monomer component and a diaryl carbonate dispersed in the mixture. The monomer component includes one or more monomer compounds having a melting point below the melting point of the diaryl carbonate. The monomer component has less than 600 ppb alkali metal, an acid stabilizer, or both less than 600 ppb alkali metal and an acid stabilizer. The monomer compounds of the monomer component and the diaryl carbonate are present in a mole ratio of from 0.9 to 1.1. The monomer mixture is at a temperature between the melting temperature of the lowest melting monomer compound and less than 5° C. above the melting point of the diaryl carbonate.
摘要翻译：非反应性单体混合物含有分散在混合物中的单体组分和碳酸二芳基酯。单体组分包括一种或多种熔点低于碳酸二芳基酯的熔点的单体化合物。单体组分具有小于600ppb的碱金属，酸稳定剂，或低于600ppb的碱金属和酸稳定剂。单体组分和碳酸二芳基酯的单体化合物以0.9至1.1的摩尔比存在。单体混合物处于最低熔点单体化合物的熔融温度和低于碳酸二芳基酯的熔点以上5℃以上的温度。

36. 发明授权

US07601794B2 Monomer solution for producing polycarbonate 失效
标题翻译：用于生产聚碳酸酯的单体溶液
公开(公告)号：US07601794B2
公开(公告)日：2009-10-13
申请号：US11863659
申请日：2007-09-28
申请人： Hans-Peter Brack , Maarten Antoon Jan Campman , Yohana Perez de Diego , Martin Herke Oyevaar , Laurus van der Wekke , Dennis Willemse
发明人： Hans-Peter Brack , Maarten Antoon Jan Campman , Yohana Perez de Diego , Martin Herke Oyevaar , Laurus van der Wekke , Dennis Willemse
IPC分类号： C08G64/00 , C08G63/62
CPC分类号： C08G64/30 , B01J2219/00006 , Y10T436/144444 , Y10T436/17 , Y10T436/173845
摘要： A non-reactive monomer mixture is formed from a dihydroxy component having one or more dihydroxy compounds dissolved in a melted diaryl carbonate. The dihydroxy component has less than 600 ppb alkali metal, an acid stabilizer, or both less than 600 ppb alkali metal and an acid stabilizer. The dihydroxy compounds of the dihydroxy component and the diaryl carbonate are present in a mole ratio of from 0.9 to 1.1. The monomer mixture is at a temperature between the saturation point of the monomer mixture and the highest melting temperature of the individual dihydroxy compounds. The non-reactive monomer mixture can be stored and transported and then polymerized to form polycarbonate upon addition of a catalyst.
摘要翻译：非反应性单体混合物由具有溶解在熔融的碳酸二芳基酯中的一种或多种二羟基化合物的二羟基组分形成。二羟基组分具有少于600ppb的碱金属，酸稳定剂，或两者少于600ppb的碱金属和酸稳定剂。二羟基成分和碳酸二芳基酯的二羟基化合物的摩尔比为0.9-1.1。单体混合物处于单体混合物的饱和点和各个二羟基化合物的最高熔融温度之间的温度。非反应性单体混合物可以储存和运输，然后在加入催化剂时聚合形成聚碳酸酯。

37. 发明申请

US20060234062A1 Method for grafting a chemical compound to a support substrate 审中-公开
标题翻译：将化学化合物接枝到支撑基底上的方法
公开(公告)号：US20060234062A1
公开(公告)日：2006-10-19
申请号：US10563112
申请日：2004-06-12
申请人： Hans-Peter Brack , Celestino Padeste , Michal Slaski , Harun Solak
发明人： Hans-Peter Brack , Celestino Padeste , Michal Slaski , Harun Solak
IPC分类号： B05D3/00 , G11B5/64 , C23C16/00 , B32B27/00 , B32B27/30
CPC分类号： C08J7/18 , Y10T428/24355 , Y10T428/3154 , Y10T428/31544 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： According to the present invention a method for grafting a chemical compound to a predetermined region of a support substrate (4) is disclosed, comprising: a) irradiating selectively the support substrate with electromagnetic radiation and/or particle radiation in order to both define said predetermined region and to form at least one reactive functional group or a precursor thereof in said predetermined region of the support substrate; b) exposing the irradiated support substrate to said chemical compound or to a precursor thereof. Therefore, only these very few steps are needed to effectively grafting the desired chemical compound, such as an organic compound, to the predetermined regions of the support substrate. Moreover, the irradiation step can be carried out in a vastly flexible manner and allows to generate numerous distinct shapes of the predetermined regions. Further, micro- or nano-scale regions in the support substrate capable of forming reactive functional groups or precursors thereof upon exposure to particle or electromagnetic irradiation can be easily achieved.
摘要翻译：根据本发明，公开了一种用于将化学化合物接枝到支撑衬底（4）的预定区域的方法，包括：a）用电磁辐射和/或粒子辐射选择性地照射支撑衬底，以便将所述预定的并且在所述支撑衬底的所述预定区域中形成至少一个反应性官能团或其前体; b）将照射的支撑基底暴露于所述化合物或其前体。因此，为了有效地将期望的化合物（例如有机化合物）接枝到支撑基底的预定区域，仅需要这几个步骤。此外，照射步骤可以以非常灵活的方式进行，并且允许产生许多不同形状的预定区域。此外，可以容易地实现能够在暴露于粒子或电磁辐射时能够形成反应性官能团或其前体的支持基底中的微尺度或纳米级区域。

38. 发明授权

US06486294B1 Production of poly(carbonate-co-ester) copolymers 有权
标题翻译：聚（碳酸酯 - 共 - 酯）共聚物的生产
公开(公告)号：US06486294B1
公开(公告)日：2002-11-26
申请号：US09683807
申请日：2002-02-19
申请人： Hans-Peter Brack , Jan Pleun Lens
发明人： Hans-Peter Brack , Jan Pleun Lens
IPC分类号： C08G6400
CPC分类号： C08G63/64
摘要： A poly(carbonate-co-ester) block copolymer is synthesized using synthetic strategies that can be incorporated into conventional melt facilities that are commonly used in the production of polycarbonate polymers. The polycarbonate block of the poly(carbonate-co-ester) copolymer is derived from a polycarbonate reaction mixture comprising an aromatic dihydroxy compound and a carbonic acid diester, such as bisphenol A and diphenyl carbonate, respectively. The second block of the copolymer is derived from a polyester prepolymer, the polyester prepolymer comprising a diol, diacid or diester, and at least one monomer that is selected to advantageously incorporate desired properties into the poly(carbonate-co-ester) copolymer. The polyester prepolymer is introduced to the polycarbonate reaction mixture to form the poly(carbonate-co-ester) copolymer. Properties of the copolymer can be altered by varying numerous conditions of the reaction.
摘要翻译：使用可以结合到通常用于生产聚碳酸酯聚合物的常规熔融设备中的合成策略来合成聚（碳酸酯 - 共 - 酯）嵌段共聚物。聚（碳酸酯 - 共 - 酯）共聚物的聚碳酸酯嵌段衍生自包含芳族二羟基化合物和碳酸二酯的聚碳酸酯反应混合物，例如双酚A和碳酸二苯酯。共聚物的第二嵌段衍生自聚酯预聚物，聚酯预聚物包含二醇，二酸或二酯，以及至少一种选择以有利地将所需性质并入聚（碳酸酯 - 共酯）共聚物中的单体。将聚酯预聚物引入聚碳酸酯反应混合物中以形成聚（碳酸酯 - 共 - 酯）共聚物。通过改变多种反应条件可以改变共聚物的性质。

39. 发明授权

US08273849B2 Isosorbide-based polycarbonates, method of making, and articles formed therefrom 失效
标题翻译：基于异山梨醇的聚碳酸酯，制造方法和由其形成的制品
公开(公告)号：US08273849B2
公开(公告)日：2012-09-25
申请号：US12893500
申请日：2010-09-29
申请人： Jan Henk Kamps , Bernardus Jansen , Hans-Peter Brack
发明人： Jan Henk Kamps , Bernardus Jansen , Hans-Peter Brack
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08L69/00 , C08G64/0266 , C08G64/1666 , C08G64/186 , C08L83/10 , C08L2205/02 , C08L2666/18
摘要： Disclosed herein is a polycarbonate polymer comprising: an isosorbide unit, and an aliphatic unit different from the isosorbide unit, wherein the isosorbide unit and aliphatic unit are each carbonate, or a combination of carbonate and ester units and the aliphatic unit is derived from an aliphatic oligomer having a molecular weight of 900 to 4000.
摘要翻译：本文公开了一种聚碳酸酯聚合物，其包含：异山梨醇单元和不同于异山梨醇单元的脂肪族单元，其中所述异山梨醇单元和脂族单元各自为碳酸酯，或碳酸酯和酯单元的组合，并且所述脂族单元衍生自脂族低聚物的分子量为900〜4000。

40. 发明授权

US08058469B2 Method for making carbamates, ureas and isocyanates 有权
标题翻译：制造氨基甲酸酯，脲和异氰酸酯的方法
公开(公告)号：US08058469B2
公开(公告)日：2011-11-15
申请号：US12347131
申请日：2008-12-31
申请人： Hatem Abdallah Belfadhel , Hans-Peter Brack , Ricardo Godoy-Lopez , Dennis James Patrick Maria Willemse
发明人： Hatem Abdallah Belfadhel , Hans-Peter Brack , Ricardo Godoy-Lopez , Dennis James Patrick Maria Willemse
IPC分类号： C07C261/00 , C07C275/00
CPC分类号： C07D233/34 , C07C263/04 , C07C263/06 , C07C269/04 , C07C271/58 , C07C273/1836 , C07D263/22 , C07D263/58 , C07D265/18 , C07C265/08 , C07C265/12 , C07C271/44 , C07C275/06 , C07C275/24 , C07C275/28
摘要： The present invention provides methods of forming carbamates, ureas, and isocyanates. In certain embodiments these methods include the step of reacting an amine with an ester-substituted diaryl carbonate to form an activated carbamate which can be further derivitized to form non-activated carbamate or a urea. The urea or carbamate can be subjected to a pyrolysis reaction to form isocyanate.
摘要翻译：本发明提供了形成氨基甲酸酯，脲和异氰酸酯的方法。在某些实施方案中，这些方法包括使胺与酯取代的二芳基碳酸酯反应以形成活化的氨基甲酸酯的步骤，其可被进一步衍生以形成未活化的氨基甲酸酯或脲。可以对尿素或氨基甲酸酯进行热解反应以形成异氰酸酯。

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