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31. 发明授权

US5698539A Mixtures of herbicides and antidotes, (hetero)-aryloxy compounds, their preparation, compositions containing them, and their use 失效
标题翻译：除草剂和解毒剂，（杂） - 芳氧基化合物的混合物，它们的制备，含有它们的组合物及其用途
公开(公告)号：US5698539A
公开(公告)日：1997-12-16
申请号：US461443
申请日：1995-06-05
申请人： Frank Ziemer , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Frank Ziemer , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N39/02 , A01N39/04 , A01N43/40 , A01N43/58 , A01N47/06 , A01N47/36 , C07C59/70 , C07C69/712 , C07C205/37 , C07D213/64 , C07D237/14 , A01N43/54
CPC分类号： C07D213/64 , A01N25/32 , A01N39/02 , A01N39/04 , A01N43/40 , A01N43/58 , A01N47/06 , A01N47/36 , C07C205/37 , C07C59/70 , C07C69/712 , C07D237/14
摘要： The invention relates to crop protection agents which comprise an active substance combination of herbicide and safener. The herbicides are selected from the group comprising the ALS inhibitors (ALS=acetolactate synthase) such as sulfonylureas, imidazolines, triazolopyrimidinesulfonamides, pyrimidyloxypyridinecarboxylic acid derivatives and pyrimidyloxybenzoic acid derivatives. The safeners are compounds of the formula I ##STR1## which are as defined in claim 1, where Z and Y are N or CH, it being possible for H to be replaced by X, X is H, Hal, haloalkyl or -alkoxy, alkyl, alkoxy, alkylthio, NO.sub.2, NH.sub.2, CN, alkylsulfonyl, A is alkylene or alkenylene, B is carboxyl or a derivative of the carboxyl group. The mixtures are mainly suitable for controlling harmful plants in the crops maize and cereals.
摘要翻译：本发明涉及包含除草剂和安全剂的活性物质组合的作物保护剂。除草剂选自包括ALS抑制剂（ALS =乙酰乳酸合成酶）如磺酰脲，咪唑啉，三唑并嘧啶磺酰胺，嘧啶氧基吡啶羧酸衍生物和嘧啶氧基苯甲酸衍生物。安全剂是如权利要求1所定义的式I（I）化合物，其中Z和Y是N或CH，H可被X代替，X是H，Hal，卤代烷基或 - 烷氧基，烷基，烷氧基，烷硫基，NO2，NH2，CN，烷基磺酰基，A是亚烷基或亚烯基，B是羧基或羧基的衍生物。混合物主要适用于控制作物玉米和谷物中的有害植物。

32. 发明授权

US5658854A Acylated aminophenylsulfonylureas; preparation and use as herbicides and plant growth regulators 失效
标题翻译：酰化氨基苯基磺酰脲作为除草剂和植物生长调节剂的制备和使用
公开(公告)号：US5658854A
公开(公告)日：1997-08-19
申请号：US268274
申请日：1994-06-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D239/42 , A01N47/36 , A01N47/46 , A01P13/02 , C07C309/89 , C07C311/39 , C07C311/65 , C07D239/47 , C07D239/48 , C07D251/44 , C07D251/46 , C07D251/48 , C07D251/52 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36 , C07C309/89 , C07C311/39 , C07C311/65
摘要： Acylated aminophenylureas, preparation and use as herbicides and plant growth regulatorsThe compounds of the formula I or their salts ##STR1## in which G is a radical G1, G2 or G3 ##STR2## R.sup.1 is H or alkyl, R.sup.2 is COOH, CSOH or a derivative of the carboxyl or thiocarboxyl group, of 1 to 20 carbon atoms, or acyl of the type CO-R.degree. of 1-12 carbon atoms, or an imino, hydrazone or oxime derivative of the group CO-R.degree., and R.degree. , R.sup.3a, R.sup.4a, R.sup.3b, R.sup.4b, W, X, Y and Z are as defined in claim 1, are suitable as selective herbicides and plant growth regulators in crops.The preparation is carried out in analogy to known processes (see claim 5) by way of intermediates, some of which are new, from the group consisting of benzene-sulfonamides (II), benzenesulfonyl isocyanates (IV) and benzesulfonyl chlorides (VI) and heterocyclically substituted carbamates (III), amines (V) and/or (thio)-isocyanates (XIX).
摘要翻译：酰化氨基苯基脲，作为除草剂和植物生长调节剂的制备和用途式I化合物或其盐，其中G是基团G1，G2或G3（G1）（图像）（G2）（G3）R1为H或烷基，R2为COOH，CSOH或含1-20个碳原子的羧基或硫代羧基的衍生物，或碳原子数为1〜12的CO-R DEG型酰基，或CO-R DEG基团的亚氨基，腙或肟衍生物，R DEG，R3a，R4a，R3b，R4b，W，X，Y和Z如权利要求1所定义，适合作为选择性除草剂和植物生长农作物的监管者。类似于已知方法（参见权利要求5），通过中间体（其中一些是新的），由苯磺酰胺（II），苯磺酰基异氰酸酯（IV）和苯磺酰氯（VI）和苯磺酰基异氰酸酯杂环取代的氨基甲酸酯（III），胺（V）和/或（硫代） - 异氰酸酯（XIX）。

33. 发明授权

US5536698A Crop-protecting compositions containing isoxazolines or isothiazdines, novel isoxazolines, and their preparation 失效
标题翻译：含有异恶唑啉或异噻嗪类的抗坏血酸组合物，新异恶唑及其制备方法
公开(公告)号：US5536698A
公开(公告)日：1996-07-16
申请号：US467934
申请日：1995-06-06
申请人： Heinz-Josef Loher , Klaus Bauer , Hermann Bieringer
发明人： Heinz-Josef Loher , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , C07D261/04 , C07D275/02 , C07D275/03 , C07F7/08
CPC分类号： C07D275/03 , A01N25/32 , C07D261/04 , C07F7/0812
摘要： Crop-protecting compositions containing isoxazolines or isothiazolines, novel isoxazolines and isothiazolines, and their preparationCrop-protecting compositions which contain isoxazolines or isothiazolines of the formula ##STR1## in which X is oxygen or sulfur, R is hydroxyl or has the meanings given in the description, Z is halogen, nitro, cyano, in each case optionally substituted alkyl, alkoxy, alkylmercapto, cycloalkyl, amino, hydroxymethyl, alkylamino, dialkylamino, alkoxymethyl, aryl or aryloxy and n is an integer from 0 to 5. Novel isoxazolines and isothiazolines of this formula, a process for their preparation, and their use as a protection against phytotoxic secondary effects of herbicides.
摘要翻译：含有异恶唑啉或异噻唑啉的抗割草组合物，新的异恶唑啉和异噻唑啉及其制备含有式为“IMAGE”的异恶唑啉或异噻唑的作物保护组合物，其中X为氧或硫，R为羟基或具有描述，Z是卤素，硝基，氰基，在各种情况下是任选取代的烷基，烷氧基，烷基巯基，环烷基，氨基，羟甲基，烷基氨基，二烷基氨基，烷氧基甲基，芳基或芳氧基，n是0-5的整数。新的异恶唑烷和异噻唑啉的这种配方，其制备方法及其作为防止除草剂植物毒性次要作用的用途。

34. 发明授权

US5529976A Pyridyl sulphonyl ureas as herbicides and plant growth regulators 失效
标题翻译：吡啶磺酰脲作为除草剂和植物生长调节剂
公开(公告)号：US5529976A
公开(公告)日：1996-06-25
申请号：US336571
申请日：1994-11-09
申请人： Heinz Kehne , Lothar Willms , Oswald Ort , Klaus Bauer , Hermann Bieringer
发明人： Heinz Kehne , Lothar Willms , Oswald Ort , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N47/36 , A47B91/06 , C07D213/76 , C07D401/12 , C07D521/00 , A01N43/66 , A01N43/68
CPC分类号： C07D213/76 , A01N47/36 , C07D401/12 , C07D521/00
摘要： Compounds of formula (I), where R.sup.1, R.sup.2, n, W, R.sup.3 and A are as defined in claim 1, are suitable for use as herbicides and plant growth regulators. They can be produced by a process similar to known processes. To produce them, new compounds of formula (II) are reacted with a carbamate of formula R.sup.* --O--CO--NR.sup.3 A, where R.sup.3 stands for phenyl or alkyl. The compounds of formula (II) can be obtained from the corresponding sulphochlorides.
摘要翻译：式（I）的化合物，其中R 1，R 2，n，W，R 3和A如权利要求1中所定义，适用于除草剂和植物生长调节剂。它们可以通过与已知方法类似的方法生产。为了制备它们，式（II）的新化合物与式R * -O-CO-NR 3 A的氨基甲酸酯反应，其中R3代表苯基或烷基。式（II）化合物可以从相应的氯化亚砜获得。

35. 发明授权

US5516750A Substituted isoxazolines, process for their preparation, composition containing them, and their use of safeners 失效
标题翻译：取代的异恶唑啉，其制备方法，含有它们的组合物及其使用安全剂
公开(公告)号：US5516750A
公开(公告)日：1996-05-14
申请号：US306110
申请日：1994-09-14
申请人： Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D261/04 , A01N25/32 , A01N35/06 , A01N39/02 , A01N43/80 , A01N47/36 , A01P13/00 , C07D413/04 , C07D413/06 , A01N43/72 , C07D261/02
CPC分类号： A01N25/32 , A01N43/80
摘要： Substituted isoxazolines, process for their preparation, compositions containing them, and their use as safeners.Compounds of the formula (I) and salts thereof, ##STR1## in which R.sup.1 is carboxyl, formyl or another acyl radical or a derivative of the last-mentioned 3 groups,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.18 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.2 -C.sub.8 -alkynyl, C.sub.1 -C.sub.18 -alkoxy, C.sub.2 -C.sub.8 -alkenyloxy, C.sub.2 -C.sub.8 -alkynyloxy, C.sub.1 -C.sub.18 -alkylthio, C.sub.2 -C.sub.8 -alkenylthio, each of the last-mentioned 9 radicals in each case being unsubstituted or substituted, or (C.sub.1 -C.sub.8 -alkoxy)carbonyl, andR.sup.3 and R.sup.4 independently of one another are an aliphatic, araliphatic or heteroaraliphatic radical having 1 to 30 carbon atoms which is unsubstituted or substituted by one or more functional groups, oran aromatic or heteroaromatic radical which is unsubstituted or substituted,are suitable as safenets for pesticides, preferably herbicides, in crop plants. The compounds can be prepared from alkenes (II) and nitrile oxides (III) by the process of claim 6.
摘要翻译：取代的异恶唑啉，其制备方法，含有它们的组合物及其作为安全剂的用途。式（I）化合物及其盐，其中R1是羧基，甲酰基或另一个酰基或最后提到的3个基团的衍生物，其中R 2是氢，卤素，C 1 -C 18 - 烷基，C 3 -C 8 - 环烷基，C 2 -C 8 - 烯基，C 2 -C 8 - 炔基，C 1 -C 18 - 烷氧基，C 2 -C 8 - 烯氧基，C 2 -C 8 - 炔氧基，C 1 -C 18烷硫基，在每种情况下最后提及的9个基团是未取代的或取代的，或（C 1 -C 8 - 烷氧基）羰基，且R 3和R 4彼此独立地是具有1至30个碳原子的脂族，芳脂族或杂脂族基团，其是未取代的或被一个或多个官能团取代，或未取代或取代的芳族或杂芳族基团适合作为农作物的保藏剂，优选除草剂在作物植物中。化合物可以通过权利要求6的方法由烯烃（II）和氧化腈（III）制备。

36. 发明授权

US5446013A 2-alkyl-or-aryl-substituted-2-(pyrimidinyl-or-traizinyl-ox y(or-thio))-acotic acid derivatives, process for preparation, and use as herbicides or plant-growth regulators 失效
标题翻译： 2-烷基 - 或 - 芳基取代的-2-（嘧啶基 - 或 - 炔丙氧基（或硫代）） - 丙酸衍生物，制备方法和用作除草剂或植物生长调节剂
公开(公告)号：US5446013A
公开(公告)日：1995-08-29
申请号：US168981
申请日：1993-12-17
申请人： Frank Zurmuhlen , Klaus Bauer , Hermann Bieringer
发明人： Frank Zurmuhlen , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N43/54 , A01N43/66 , A01N43/76 , A01N43/78 , A01N55/00 , C07D239/46 , C07D239/60 , C07D251/30 , C07D401/12 , C07D405/12 , C07F7/08 , C07F7/18 , C07F9/6512 , C07F9/6521 , C07D239/42
CPC分类号： C07D401/12 , A01N43/54 , A01N55/00 , C07D239/60 , C07D251/30 , C07D405/12 , C07F7/0812 , C07F7/1896 , C07F9/65122 , C07F9/65212
摘要： Pyrimidinyl- or triazinyloxy- (or -thio)-carboxylic acid derivatives, processes for their preparation, and their use as herbicides or plant growth regulatorsCompounds of the formula (I) ##STR1## in which A is ##STR2## and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, X and Y are as defined in claim 1 are suitable as selective herbicides and plant growth regulators.
摘要翻译：嘧啶基或三嗪氧基 - （或 - 硫代） - 羧酸衍生物，其制备方法及其作为除草剂或植物生长调节剂的用途式（I）的化合物其中A为和 R1，R2，R3，R4，R5，R6，X和Y如权利要求1中所定义适合作为选择性除草剂和植物生长调节剂。

37. 发明授权

US5380852A 5-chloroquinolin-8-oxyalkanecarboxylic acid derivatives, useful as antidotes for herbicides 失效
标题翻译： 5-氯喹啉-8-氧碳基羧酸衍生物，可用作除草剂的解毒剂
公开(公告)号：US5380852A
公开(公告)日：1995-01-10
申请号：US810487
申请日：1991-12-19
申请人： Rainer Schutze , Heinz-Josef Loher , Frank Ziemer , Klaus Bauer , Hermann Bieringer
发明人： Rainer Schutze , Heinz-Josef Loher , Frank Ziemer , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N43/42 , A01N25/32 , C07D215/28 , C07F7/10
CPC分类号： C07D215/28 , A01N25/32
摘要： Disclosed are compounds of the formula (I): ##STR1## The substituents are disclosed in the specification. The compounds are herbicidal safenets. Accordingly, processes for the preparation and use of the compounds of formula (I) are also disclosed.
摘要翻译：公开了式（I）的化合物：（I）取代基在说明书中公开。这些化合物是除草剂。因此，还公开了式（I）化合物的制备和使用的方法。

38. 发明授权

US5103004A N-sultamsulfonamides 失效
标题翻译： N-SULTAMSULFONAMIDES
公开(公告)号：US5103004A
公开(公告)日：1992-04-07
申请号：US749158
申请日：1991-08-23
申请人： Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
发明人： Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
IPC分类号： A01N47/36 , C07D417/12 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Heterocyclically substituted N-sultamsulfonamides, processes for their preparation and their use as herbicides and plant growth regulators.Compounds of the formula I or their salts ##STR1## wherein R.sup.1 and R.sup.2 denote H, halogen, alkyl, alkenyl, alkynyl or alkoxy, which can be substituted, or denote --(CH.sub.2).sub.n --COOR.sup.11 ;R.sup.3 denotes H, alkyl, alkenyl or alkynyl;R.sup.4 denotes a heterocyclic radical of the formulae ##STR2## where E is CH or N; X is O or S and a, b, c, d, e in each case denote 0, 1 or 2, with the proviso that c+d+e.gtoreq.2, possess excellent herbicidal and plant growth-regulating properties.

39. 发明授权

US4925478A Novel quinolinoxy compounds, a process for their preparation, and their use as antidotes 失效
标题翻译：新型喹啉氧基化合物，其制备方法及其用作解毒剂
公开(公告)号：US4925478A
公开(公告)日：1990-05-15
申请号：US76111
申请日：1987-07-21
申请人： Erich Sohn , Reinhard Handte , Hilmar Mildenberger , Klaus Bauer , Hermann Bieringer
发明人： Erich Sohn , Reinhard Handte , Hilmar Mildenberger , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N43/42 , A01N25/32 , A61K31/47 , A61P39/02 , C07D215/26 , C07D215/28 , C07D215/60 , C07D405/12 , C07D409/12 , C07D411/12
CPC分类号： C07D405/12 , A01N25/32 , C07D215/26 , C07D215/28 , C07D215/60 , C07D409/12 , C07D411/12
摘要： Compounds of the formula ##STR1## in which R.sub.n denotes hydrogen, halogen or alkyl, Z denotes oxygen or sulfur, R.sup.1 and R.sup.2, independently of one another, denote hydrogen, alkyl, alkoxyalkyl, haloalkyl or phenalkyl, or, together, denote a (optionally substituted) C.sub.2 -C.sub.4 -alkylene bridge, and R.sup.3 denotes hydrogen or alkyl, are effective antidotes for protecting crop plants against phytotoxic side effects of herbicides.
摘要翻译：其中Rn表示氢，卤素或烷基，Z表示氧或硫，R1和R2彼此独立地表示氢，烷基，烷氧基烷基，卤代烷基或苯基烷基的式I化合物，或者一起表示（任选取代的）C 2 -C 4亚烷基桥，R 3表示氢或烷基，是保护作物对除草剂的植物毒性副作用的有效解毒剂。

40. 发明授权

US4891057A Phenylpyrazolecarboxylic acid derivatives, their preparation, and their use as plant-growth regulators and safeners 失效
标题翻译：苯基吡唑羧酸衍生物，它们的制备及其作为植物生长调节剂和安全剂的用途
公开(公告)号：US4891057A
公开(公告)日：1990-01-02
申请号：US104820
申请日：1987-10-02
申请人： Erich Sohn , Reinhard Handte , Hilmar Mildenberger , Helmut Burstell , Klaus Bauer , Hermann Bieringer
发明人： Erich Sohn , Reinhard Handte , Hilmar Mildenberger , Helmut Burstell , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N43/56 , A01N43/836 , A01N55/10 , C07D231/14 , C07D231/16 , C07D231/24 , C07D403/04 , C07D403/06 , C07D403/10 , C07D405/04 , C07D413/04
CPC分类号： C07D403/04 , A01N25/32 , A01N43/56 , C07D231/14 , C07D231/16 , C07D403/06 , C07D403/10 , C07D413/04
摘要： Compounds of the formula I ##STR1## in which R denotes halogen, hydroxyl, cyano, nitro, (substituted) alkyl, (substituted) alkoxy, (halo)alkylthio, carboxyl, alkoxycarbonyl; (halo)alkylsulf(inyl)(onyl) or -(onyloxy); (halo)phenyl or (halo)phenoxy; X in the 3- or 5-position denotes a (thio)carboxylic acid--or an optionally heterocyclic radical which is derived therefrom; Y denotes halogen, m denotes the number 0 or 1, and n denotes a number from 0 to 5, have valuable plant growth-regulating properties and are suitable, in addition, as safeners for protecting crop plants against phytotoxic side effects of herbicides.
摘要翻译：式I的化合物其中R表示卤素，羟基，氰基，硝基，（取代的）烷基，（取代的）烷氧基，（卤代）烷硫基，羧基，烷氧基羰基; （卤代）烷基亚磺酰基（壬基）（甲苯基）或 - （苯氧基）; （卤代）苯基或（卤代）苯氧基; 3-或5-位的X表示（硫代）羧酸 - 或由其衍生的任选的杂环基; Y表示卤素，m表示数字0或1，n表示0至5的数字，具有有价值的植物生长调节性质，另外也适合作为保护作物的安全剂免受除草剂的植物毒副作用。

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