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31. 发明授权

US07449588B2 Methods of stabilizing thiophene derivatives 失效
标题翻译：稳定噻吩衍生物的方法
公开(公告)号：US07449588B2
公开(公告)日：2008-11-11
申请号：US11744264
申请日：2007-05-04
申请人： Friedrich Jonas , Klaus Wussow , Knud Reuter
发明人： Friedrich Jonas , Klaus Wussow , Knud Reuter
IPC分类号： C07D333/16 , C07D495/06
CPC分类号： C07D495/04
摘要： Methods of stabilizing thiophene derivatives of the general formula (I) by treatment with basic compounds: wherein R1 and R2 each independently represents a moiety selected from the group consisting of hydrogen, optionally substituted C1-20 alkyl groups which can contain up to 5 heteroatoms selected from the group consisting of oxygen and sulfur, optionally substituted C1-20 oxyalkyl groups which can contain up to 5 heteroatoms selected from the group consisting of oxygen and sulfur, or wherein R1 and R2 together represent a fused cyclic moiety selected from the group consisting of optionally substituted C1-20 dioxyalkylene groups and C1-20 dioxyarylene groups; and stabilized thiophene derivatives that can be prepared by such methods.
摘要翻译：通过用碱性化合物处理来稳定通式（I）的噻吩衍生物的方法：其中R 1和R 2各自独立地表示选自氢，任选取代的C 1-20烷基，其可以含有至多5个选自氧和硫的杂原子，任选取代的C 1-20烷氧基，其可以含有多至5个选自氧和硫的杂原子，或其中R 1和R 2一起代表稠合的环状部分，其选自任选取代的 C 1-20二氧亚烷基和C 1-20二取代的亚芳基; 和可以通过这些方法制备的稳定的噻吩衍生物。

32. 发明申请

US20060071201A1 Novel polythiophene dispersions 审中-公开
标题翻译：新型聚噻吩分散体
公开(公告)号：US20060071201A1
公开(公告)日：2006-04-06
申请号：US11288703
申请日：2005-11-29
申请人： Friedrich Jonas , Stephan Kirchmeyer
发明人： Friedrich Jonas , Stephan Kirchmeyer
IPC分类号： H01B1/12
CPC分类号： H01B1/127 , C08G61/126 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： A process for the preparation of dispersions or solutions comprising polythiophene+An− ion complexes in anhydrous or low-water-content organic solvents, characterized in that at least one water-miscible organic solvent or a water-miscible solvent mixture is added to an aqueous dispersion or solution comprising optionally substituted polythiophenes, all or some of the water is removed, and the resultant dispersion or solution is, if desired, diluted with organic solvents.
摘要翻译：一种在无水或低含水量的有机溶剂中制备包含聚噻吩和/或超级离子配合物的分散体或溶液的方法，其特征在于至少一种与水混合将有机溶剂或与水混溶的溶剂混合物加入到包含任选取代的聚噻吩的水分散体或溶液中，除去所有或部分水，如果需要，所得分散体或溶液用有机溶剂稀释。

33. 发明授权

US06737162B2 Transparent plastics molding composition 失效
标题翻译：透明塑料成型组合物
公开(公告)号：US06737162B2
公开(公告)日：2004-05-18
申请号：US10039267
申请日：2002-01-04
申请人： Friedrich Jonas , Peter Bier , Mark Peters
发明人： Friedrich Jonas , Peter Bier , Mark Peters
IPC分类号： B32B2738
CPC分类号： C08J7/04 , Y10T428/31507 , Y10T428/31511 , Y10T428/31515 , Y10T428/31533 , Y10T428/31663 , Y10T428/31928 , Y10T428/31935
摘要： Transparent moldings comprising a polymeric base material and at least one coating formed thereon is disclosed. The coating includes a primer coat that containing an epoxy and/or acrylic resin is disposed on at least one surface of the base material, a heat-absorbing coating which contains a polythiophene compound and a scratch-resistant coating. In an additional embodiment of the invention, the coating contains no primer and the heat absorbing coating contains a polythiophene compound.
摘要翻译：公开了包含聚合物基材和在其上形成的至少一个涂层的透明模制品。该涂层包括底涂层，其中含有环氧树脂和/或丙烯酸树脂，其设置在基材的至少一个表面上，含有聚噻吩化合物的耐热涂层和耐刮擦涂层。在本发明的另外的实施方案中，涂层不含底漆，并且吸热涂层含有聚噻吩化合物。

34. 发明授权

US06635729B1 Process for the preparation of water-soluble &pgr;-conjugated polymers 有权
标题翻译：制备水溶性π-共轭聚合物的方法
公开(公告)号：US06635729B1
公开(公告)日：2003-10-21
申请号：US09767474
申请日：2001-01-23
申请人： Lambertus Groenendaal , Friedrich Jonas , Tom Cloots , Frank Louwet
发明人： Lambertus Groenendaal , Friedrich Jonas , Tom Cloots , Frank Louwet
IPC分类号： C08F12806
CPC分类号： C08G61/126 , H01B1/127 , H01G9/028 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： The invention relates to a process for preparing water-soluble &pgr;-conjugated polymers by polymerizing, in aqueous solution using an oxidant, monomeric thiophene derivatives of formula (I) wherein X and Y are identical or different and are O, S, or N—R′, Z is —(CH2)m—CR2R3—(CH2)n—, R1 is aryl, C1-C18-alkyl, or hydrogen, R2 is hydrogen or —CH2)s—O—(CH2)p—SO3−M+, R3 is —(CH2)s—O—(CH2)p—SO3−M+, M+ is a cation, m and n are identical or different and are an integer from 0 to 3, s is an integer from 0 to 10, and p is an integer from 1 to 1.
摘要翻译：本发明涉及通过在水溶液中使用氧化剂，其中X和Y相同或不同且为O，S或N-R的式（I）的单体噻吩衍生物进行聚合来制备水溶性π-共轭聚合物的方法 '，Z是 - （CH 2）m-CR 2 R 3 - （CH 2）n - ，R 1是芳基，C 1 -C 18烷基或氢，R 2是氢或-CH 2 ）sO-（CH 2）p -SO 3 - ，M +，R 3是 - （CH 2）s O-（CH 2）p -SO 3 M +，M +是阳离子， m和n相同或不同，为0〜3的整数，s为0〜10的整数，p为1〜1的整数。

35. 发明授权

US06369239B2 Process for the preparation of dialkylthiophenes and alkylenedioxythiophenes 有权
标题翻译：制备二烷基噻吩和亚烷基二氧噻吩的方法
公开(公告)号：US06369239B2
公开(公告)日：2002-04-09
申请号：US09813875
申请日：2001-03-21
申请人： Günter Rauchschwalbe , Friedrich Jonas
发明人： Günter Rauchschwalbe , Friedrich Jonas
IPC分类号： C07D49504
CPC分类号： C07D495/04 , C07D333/32 , Y02P20/582
摘要： A process for the preparation of dialkoxythiophenes and alkylene-dioxythiophenes in high purity and very good yields by decarboxylation of dialkoxythiophene-dicarboxylic acids or alkylenedioxythiophenedicarboxylic acids, respectively, in solvents that have a higher boiling point than the product and contain no nitrogen bases.
摘要翻译：在沸点高于不含氮基的溶剂中分别通过二烷氧基噻吩 - 二羧酸或亚烷基二氧噻吩二羧酸脱羧来制备高纯度的二烷氧基噻吩和亚烷基二氧噻吩的方法。

36. 发明授权

US06358437B1 Screen printing paste for producing electrically conductive coatings 有权
标题翻译：用于生产导电涂料的丝网印刷浆料
公开(公告)号：US06358437B1
公开(公告)日：2002-03-19
申请号：US09581600
申请日：2000-06-14
申请人： Friedrich Jonas , Udo Guntermann
发明人： Friedrich Jonas , Udo Guntermann
IPC分类号： H01B120
CPC分类号： H01B1/127 , C09D5/24 , C09D165/00 , G02F2001/136295
摘要： The present invention relates to a screen printing paste having a viscosity of from 1 to 200 dPas, comprising a solution or dispersion of a conductive polymer and optionally binders, thickeners and fillers, and to the use thereof for the production of electrically conductive coatings.
摘要翻译：本发明涉及粘度为1至200dPas的丝网印刷浆料，其包含导电聚合物和任选的粘合剂，增稠剂和填料的溶液或分散体，以及其用于制备导电涂料的用途。

37. 发明授权

US5935405A Process for producing rigid and flexible circuits 失效
标题翻译：生产刚性和柔性电路的工艺
公开(公告)号：US5935405A
公开(公告)日：1999-08-10
申请号：US926111
申请日：1997-09-09
申请人： Gerhard-Dieter Wolf , Friedrich Jonas
发明人： Gerhard-Dieter Wolf , Friedrich Jonas
IPC分类号： H05K3/10 , H05K3/18 , H05K3/42 , C25D5/02
CPC分类号： H05K3/188 , C25D5/022 , H05K3/108 , H05K2201/0329 , H05K2203/1142 , H05K3/426
摘要： Rigid or flexible circuits of electrically conductor tracks can be produced on flexible or rigid, non-conductive support materials bya) coating the surfaces of the support materials including existing drill holes with a primer and a conductive polymer, preferably poly-3,4-ethylendioxythiophene, which may contain binders,b) applying an electroplating resist in the form of the negative image of the conductor tracks,c) metallizing by electroplating the surface kept free by the electroplating resist, including existing drill holes, in the form of the positive image of the conductor tracks,d) removing the electroplating resist ande) removing the conductive polymer, which had been below the electroplating resist, or converting it to a non-conductive form, wherein the conductor tracks are electrically interconnected during the metallizing step by the layer of conductive polymer, thereby avoiding the need to individually contact each conductor track.
摘要翻译：电导体轨道的刚性或柔性电路可以通过以下方式在柔性或刚性的非导电支撑材料上制造：a）用底漆和导电聚合物涂覆包括现有钻孔的载体材料的表面，优选聚3,4- 乙烯二氧噻吩，其可以包含粘合剂，b）以导体轨迹的负像形式施加电镀抗蚀剂，c）通过电镀由电镀抗蚀剂保持的表面（包括现有的钻孔）以阳性形式进行金属化导体轨迹的图像，d）去除电镀抗蚀剂，以及e）去除已经在电镀抗蚀剂下面的导电聚合物，或将其转换成非导电形式，其中导体轨道在金属化步骤期间电互连，导电聚合物层，从而避免需要单独接触每个导体轨道。

38. 发明授权

US5888372A Process for producing metal-coated films in web form 失效
标题翻译：用于生产网状金属涂膜的方法
公开(公告)号：US5888372A
公开(公告)日：1999-03-30
申请号：US873531
申请日：1997-06-12
申请人： Louis Bollens , Andre Heyvaerts , Dirk Quintens , Gerhard Dieter Wolf , Henning Giesecke , Friedrich Jonas
发明人： Louis Bollens , Andre Heyvaerts , Dirk Quintens , Gerhard Dieter Wolf , Henning Giesecke , Friedrich Jonas
IPC分类号： B32B15/08 , B32B15/088 , C23C18/16 , C23C28/02 , C25D5/56 , C25D7/06 , H05K3/00 , H05K3/18 , H05K3/38 , C25D5/54 , C25D5/34
CPC分类号： C25D5/56 , C23C18/1601 , C23C18/1653 , C23C18/208 , C23C18/30 , C25D7/0614 , H05K3/181
摘要： A metal-coated film can be produced continuously from a non-conducting film by successive electroless and galvanic metallization in such a way that a film of this kind is subjected, in a continuous "roll-to-roll" process, to the following operations:a) applying a metallizable primer,b) drying the applied primer,c) conditioning the applied primer,d) optionally activating the applied primer,e) treatment with an electroless chemical metallizing bath,f) optional treatment with a first rinsing liquid,g) treatment with a galvanic metallizing bath,h) treatment with a second rinsing liquid, andi) optional heat treatment of the metallized film.
摘要翻译：可以通过连续的无电镀和电偶金属化从非导电膜连续地制造金属涂膜，使得这种膜以连续的“卷对卷”方式经受下列操作 a）应用可镀金属化的底漆，b）干燥涂布的底漆，c）调理涂布的底漆，d）任选地活化所用的底漆，e）用无电化学金属镀液处理，f）用第一冲洗液体任选处理， g）用电镀金属浴处理，h）用第二冲洗液处理，以及i）任选的金属化膜的热处理。

39. 发明授权

US5766515A Conductive coatings 失效
标题翻译：导电涂料
公开(公告)号：US5766515A
公开(公告)日：1998-06-16
申请号：US856042
申请日：1997-05-14
申请人： Friedrich Jonas , Alexander Karbach , Bavo Muys , Etienne van Thillo , Rolf Wehrmann , Andreas Elschner , Ralf Dujardin
发明人： Friedrich Jonas , Alexander Karbach , Bavo Muys , Etienne van Thillo , Rolf Wehrmann , Andreas Elschner , Ralf Dujardin
IPC分类号： C08G61/12 , C09D5/24 , G02F1/1343 , H01B1/12 , H01L51/00 , H01L51/30 , H01L51/50 , H01L51/52 , H05K3/18 , H01B1/00 , C08G75/10 , H01B1/20
CPC分类号： H01L51/5203 , C08G61/126 , C09D5/24 , H01B1/127 , H01B1/128 , H01G11/48 , H01G11/56 , H01L51/5206 , G02F1/13439 , H01L51/0036 , H01L51/5088 , H05K3/188 , Y02E60/13 , Y10S428/917
摘要： Mixtures of A) neutral polythiophenes of formula (I), ##STR1## wherein R.sub.1 and R.sub.2 separately from one another represent hydrogen or a C.sub.1-4 alkyl group or together form an optionally substituted C.sub.1-4 alkylene radical, preferably a methylene radical optionally substituted by alkyl groups, an ethylene-1,2 radical optionally substituted by C.sub.1-12 alkyl or phenyl groups, or a cyclohexylene-1,2 radical, and B) organic compounds containing dihydroxy or polyhydroxy and/or carboxyl groups or amide groups or lactam groups, as well as transparent, electrically conducting coatings made therefrom and electroluminescent systems containing a conductive layer produced from the abovementioned mixtures as the electrode.
摘要翻译：式（I）的A）中性聚噻吩的混合物，其中R1和R2彼此分开代表氢或C1-4烷基，或一起形成任选取代的C 1-4亚烷基，优选任选取代的亚甲基烷基，任选被C 1-12烷基或苯基取代的亚乙基-1-2基团或亚环己基-1,2-基，和B）含有二羟基或多羟基和/或羧基或酰胺基团或内酰胺的有机化合物基团，以及由其制成的透明导电涂层和含有由上述混合物制成的导电层作为电极的电致发光体系。

40. 发明授权

US5443944A Photographic material 失效
标题翻译：摄影材料
公开(公告)号：US5443944A
公开(公告)日：1995-08-22
申请号：US290597
申请日：1994-08-15
申请人： Werner Krafft , Friedrich Jonas , Prem Lalvani , Hartwig Andries , Willem Mues
发明人： Werner Krafft , Friedrich Jonas , Prem Lalvani , Hartwig Andries , Willem Mues
IPC分类号： C08G61/12 , G03C1/89 , G03C11/02 , G11B5/633 , G11B5/72 , G03C1/76
CPC分类号： G11B5/72 , C08G61/126 , G03C1/89 , G11B5/633 , G03C11/02
摘要： A photographic material comprising a transparent film support having on one side at least one light-sensitive layer and on the other side a transparent magnetic layer and an antistatic layer of a polythiophene arranged above or below said transparent magnetic layer shows transparency and good mechanical and antistatic properties.
摘要翻译：一种包含透明薄膜载体的照相材料，其在一侧具有至少一个感光层，另一侧具有透明磁性层和布置在所述透明磁性层之上或之下的聚噻吩的抗静电层，显示透明性和良好的机械和抗静电性属性。

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